WO2002054884A1 - Verfahren zur herstellung von emulgierfähigen proteinprodukten aus einer ölsaat - Google Patents
Verfahren zur herstellung von emulgierfähigen proteinprodukten aus einer ölsaat Download PDFInfo
- Publication number
- WO2002054884A1 WO2002054884A1 PCT/EP2001/015214 EP0115214W WO02054884A1 WO 2002054884 A1 WO2002054884 A1 WO 2002054884A1 EP 0115214 W EP0115214 W EP 0115214W WO 02054884 A1 WO02054884 A1 WO 02054884A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- plant seeds
- products
- protein
- emulsifiable
- lecithin
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J7/00—Phosphatide compositions for foodstuffs, e.g. lecithin
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J1/00—Obtaining protein compositions for foodstuffs; Bulk opening of eggs and separation of yolks from whites
- A23J1/14—Obtaining protein compositions for foodstuffs; Bulk opening of eggs and separation of yolks from whites from leguminous or other vegetable seeds; from press-cake or oil-bearing seeds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/14—Vegetable proteins
- A23J3/16—Vegetable proteins from soybean
Definitions
- the invention relates to a method for producing emulsifiable protein products from the plant seeds of an oilseed, in particular from soybeans.
- those emulsions tend to separate again independently, so that additional substances must be added for long-term or storage-stable emulsions, by means of which the separation of both phases oil or fat and water to a thermodynamically stable final state is prevented or delayed until the emulsions have fulfilled their purpose.
- Such substances are known as stabilizers or emulsifiers.
- Most natural and / or technical emulsions consist of water and oil or fat as immiscible phases.
- oil is the inner phase
- O / W emulsion the basic character of which is shaped by the water, such as milk, mayonnaise or ice cream.
- oil or fat is the outer phase and water is the inner phase
- W / O emulsion whereby the basic character is determined by the oil, as is the case with butter, margarine or ointments, for example.
- protein isioates are also known, which, depending on the treatment and Manufacturing technology, have specially optimized functional properties.
- emulsifying properties of such optimized protein isioates which are used as emulsifiers in particular in the food sector.
- lecithins are also suitable as emulsifiable auxiliaries for stabilizing the disperse systems described above.
- Mixed products of both substances are also known, which can be obtained by spray drying by applying lecithin to protein isolates.
- lecithins as well as protein isioates originate from the same raw material, for example from soybeans, lupins or rapeseed, in a manner known per se, a material separation is initially carried out in the production.
- the soybeans are subjected to a deoiling process after appropriate cleaning and comminution, in which the soybeans are exposed to an organic solvent, such as hexane or ethanol.
- an organic solvent such as hexane or ethanol.
- the deoiling step contains, in addition to the lipid fraction, deoiled flour which is rich in proteins and from which proteins can be isolated by means of further extraction steps.
- lecithin-rich protein isolates which, as described above, have excellent emulsifying properties and are therefore of great interest in the food industry
- the purified lecithin or crude lecithin and the isolated protein are back-mixed, for example using the spray technique.
- Such a procedure undoubtedly represents a considerable outlay in terms of process technology and thus also economically, in order to obtain protein isiates with exceptionally emulsifying properties.
- a conceivable alternative to produce undoiled and therefore lecithinated protein isioates leads to products that emulsify very well, but these are not stable over the long term or in storage, since the oil they contain tends to oxidize and has a rancid odor and taste after longer storage caused.
- the same also applies to well-emulsifying products with a lower protein content, which have not been de-oiled or have not been de-oiled sufficiently.
- the invention is therefore based on the object of specifying a method for producing emulsifiable protein products from the plant seeds of an oilseed, in particular from soybeans, in which the disadvantages mentioned above with respect to the prior art can be avoided and in particular an emulsifiable protein product, for example protein isolate, can be obtained, that is inexpensive to manufacture, has exceptional emulsifying properties and is stable in storage and long-term.
- the preferably shredded plant seeds are fed to a de-oiling step in which supercritical CO 2 is added to the shredded plant seeds as a solvent.
- a de-oiling step in which supercritical CO 2 is added to the shredded plant seeds as a solvent.
- crude oil and a deoiled residue are obtained, in which the emulsifiable protein products are contained.
- it has been recognized that deliberate use of supercritical CO 2 ' s for deoiling oilseeds can be used to obtain a deoiled raffinate, from which a protein isolate is obtained as a protein product with a high content of lecithin using known downstream cleaning and fractionation processes and is almost free of oils susceptible to oxidation.
- the protein isioates obtained from the above-mentioned oilseeds by extraction with supercritical CO 2 are distinguished by an outstanding emulsifying ability, which distinguishes them clearly from comparable products which are obtained by conventional processes, as described at the beginning.
- the protein isiates characterized above with outstanding emulsifying capabilities it is also possible to obtain other products from the deoiled residue contained in the supercritical C0 2 deoiling process, for example in the form of deoiled flour, which are distinguished by a comparatively high lecithin content , These are protein-reduced flours, such as fiber or the flour itself or protein concentrates. Due to the different possibilities of further refining the deoiled residue obtained, the protein content in the product obtained can be variably adjusted between 15 and 95% in dry matter.
- the lecithin content in the end product can also be variably reduced by using an additional entrainer in the C0 2 extraction.
- propane is suitable as an entrainer, whereby lecithin is extracted from the seed meal in the same way as the crude oil. If all entraining agents are dispensed with and only supercritical CO 2 is used as a solvent in the deoiling step, the products deoiled in this way can flow directly into the food chain and feed chain without additional requirements. These products even meet the requirements for so-called organic foods.
- the seed is cleaned, peeled, Breaking, flaking and / or possibly pelletizing are preconditioned in such a way that the subsequent deoiling process, ie the targeted use of supercritical C0 2 as an organic solvent, largely completely soaks the correspondingly preconditioned seeds.
- the production of flakes or pellets using a flaking roller over which the peeled and preferably halved plant seeds are passed and pressed is particularly suitable.
- the flaking rollers are preheated to a denaturation temperature, which is preferably below 35 ° C, whereby the comminuted plant seeds are heated to inactivate their own enzymes, but the native properties of their seeds remain largely unaffected in their native properties.
- a denaturation temperature which is preferably below 35 ° C
- the preconditioned plant seeds are exposed to supercritical CO 2 , which acts on the plant seeds at temperatures between 40 ° - 69 ° C and under pressure conditions between 240 - 300 bar. Under these deoiling conditions, all triglycerides are washed out of the plant seeds.
- lecithins but also other so-called fat accompanying substances such as carotenoids, isoflavonoids, tocopherols remain in the de-oiled residue to a very high percentage and remain unaffected by the supercritical CO 2 within the plant matrix.
- the fat accompanying substances and in particular the lecithin remain in very large proportions in the protein isolate even by standard methods of further extraction in order to obtain protein isolates.
- the protein isioates obtained in this way have an exceptionally high emulsifying capacity.
- the protein products obtained in the above manner, in particular protein isioates can be used advantageously without further processing in all food systems in which the emulsifying function plays an important role. These are in particular products such as baked goods, sausages and meat products, ice cream, confectionery, chocolate, delicatessen products, drinks, etc.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Edible Oils And Fats (AREA)
- Fats And Perfumes (AREA)
- Peptides Or Proteins (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01988061A EP1351581A1 (de) | 2001-01-13 | 2001-12-21 | Verfahren zur herstellung von emulgierfähigen proteinprodukten aus einer ölsaat |
US10/466,148 US20040047972A1 (en) | 2001-01-13 | 2001-12-21 | Method for producing protein products which can be emulsified from an oilseed |
CA002434395A CA2434395A1 (en) | 2001-01-13 | 2001-12-21 | Method for producing emulsifiable protein products from an oilseed crop |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10101326A DE10101326A1 (de) | 2001-01-13 | 2001-01-13 | Verfahren zur Herstellung von emulgierfähigen Proteinprodukten aus einer Ölsaat |
DE10101326.4 | 2001-01-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002054884A1 true WO2002054884A1 (de) | 2002-07-18 |
Family
ID=7670438
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2001/015214 WO2002054884A1 (de) | 2001-01-13 | 2001-12-21 | Verfahren zur herstellung von emulgierfähigen proteinprodukten aus einer ölsaat |
Country Status (5)
Country | Link |
---|---|
US (1) | US20040047972A1 (de) |
EP (1) | EP1351581A1 (de) |
CA (1) | CA2434395A1 (de) |
DE (1) | DE10101326A1 (de) |
WO (1) | WO2002054884A1 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006003110A1 (en) * | 2004-06-29 | 2006-01-12 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. | Process for the purification of protein fractions from lupin seeds, active on lipid metabolism |
WO2017041776A1 (de) | 2015-09-11 | 2017-03-16 | B+B Engineering Gmbh | Verfahren zum kombinierten zellaufschluss und extraktion ölhaltiger saaten |
US12052994B2 (en) | 2019-02-03 | 2024-08-06 | Terviva, Inc. | Methods for controlling black sigatoka in bananas using pongamia oil and formulations thereof |
Families Citing this family (8)
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---|---|---|---|---|
MX2007008669A (es) * | 2005-01-18 | 2007-07-25 | Fraunhofer Ges Forschung | Metodo para producir un ingrediente de proteina vegetal para helado y un helado que contiene dicho ingrediente de proteina. |
DE102005017407A1 (de) * | 2005-04-15 | 2006-10-19 | Degussa Ag | Verfahren zur Behandlung von natürlichen Ausgangsmaterialien mit Hilfe verdichteter Gase |
US7638155B2 (en) * | 2005-06-23 | 2009-12-29 | Solae, Llc | Process for making soy protein products having reduced off-flavor |
US8182765B2 (en) * | 2006-02-21 | 2012-05-22 | Universal Biosensors Pty Ltd | Fluid transfer mechanism |
US20080113075A1 (en) * | 2006-11-09 | 2008-05-15 | Barry Callebaut Ag | Compositions |
CN102919511B (zh) * | 2012-10-27 | 2013-09-04 | 江苏新广生物科技有限公司 | 一种脱脂酶活性植物蛋白的生产方法及其应用 |
WO2018178119A1 (de) | 2017-03-28 | 2018-10-04 | Dietz Max | Verfahren zur prozessökonomischen ab-/auftrennung von konstituenten pflanzlicher ausgangsmaterialien sowie deren gewinnung und verwendung |
DE102018005383A1 (de) | 2018-07-06 | 2020-01-09 | Daimler Ag | Wasserpumpe für ein Kraftfahrzeug, insbesondere für einen Kraftwagen |
Citations (6)
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US4493854A (en) * | 1983-09-20 | 1985-01-15 | The United States Of America As Represented By The Secretary Of Agriculture | Production of defatted soybean products by supercritical fluid extraction |
FR2705031A1 (fr) * | 1993-05-10 | 1994-11-18 | Sederma Sa | Nouvelles compositions cosmétiques et dermopharmaceutiques contenant des protéines végétales amphipathiques (oléosines) extraites des globules gras des graines de colza, de soja, de lin. |
EP0702903A1 (de) * | 1994-09-19 | 1996-03-27 | SKW Trostberg Aktiengesellschaft | Verfahren zur Herstellung von fett- und cholesterin-reduzierten pulverförmigen Produkten auf Eibasis mit einem hohen Gehalt an Phospholipiden |
US5725899A (en) * | 1978-03-16 | 1998-03-10 | Cole; Morton S. | Protein-lipid emulsifying and gelling composition and method of preparing same |
DE19813207C1 (de) * | 1997-10-08 | 1999-06-24 | Fraunhofer Ges Forschung | Verfahren zur Behandlung und Verarbeitung alkaloid-, öl- und proteinhaltiger Lupinensamen |
WO2000047059A1 (en) * | 1999-02-10 | 2000-08-17 | The United States Of America, As Represented By The Secretary Of Agriculture | Production of high protein concentrates |
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US2548434A (en) * | 1945-08-01 | 1951-04-10 | Swift & Co | Selective extraction and fractionation of fatty materials |
US4360537A (en) * | 1976-05-03 | 1982-11-23 | International Telephone And Telegraph Corporation | Lipoprotein emulsions for food use and methods for preparing the same |
DE4010400C1 (de) * | 1990-03-31 | 1991-05-29 | Fried. Krupp Gmbh, 4300 Essen, De | |
US5335044A (en) * | 1992-02-26 | 1994-08-02 | Nikon Corporation | Projection type exposure apparatus and method of exposure |
DE4222153C2 (de) * | 1992-07-06 | 1998-12-03 | Peter Siegfried | Verfahren zur Entölung von Rohlecithin |
US5405633A (en) * | 1992-10-08 | 1995-04-11 | Skw Trostberg Aktiengesellschaft | Process for the extraction of fats and oils |
DE4326399C2 (de) * | 1992-10-08 | 1995-04-06 | Sueddeutsche Kalkstickstoff | Verfahren zur Extraktion von Fetten und Ölen |
EP1132008B1 (de) * | 2000-03-10 | 2004-01-14 | Sanko Corporation | Aus Sojabohnen hergestelltes Nahrungsmittel und Herstellungsverfahren |
US6514546B2 (en) * | 2001-01-31 | 2003-02-04 | Koji Tsukuda | Easily dispersible granules of soybean protein and methods for preparing the same |
-
2001
- 2001-01-13 DE DE10101326A patent/DE10101326A1/de not_active Ceased
- 2001-12-21 WO PCT/EP2001/015214 patent/WO2002054884A1/de not_active Application Discontinuation
- 2001-12-21 EP EP01988061A patent/EP1351581A1/de not_active Withdrawn
- 2001-12-21 US US10/466,148 patent/US20040047972A1/en not_active Abandoned
- 2001-12-21 CA CA002434395A patent/CA2434395A1/en not_active Abandoned
Patent Citations (6)
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US5725899A (en) * | 1978-03-16 | 1998-03-10 | Cole; Morton S. | Protein-lipid emulsifying and gelling composition and method of preparing same |
US4493854A (en) * | 1983-09-20 | 1985-01-15 | The United States Of America As Represented By The Secretary Of Agriculture | Production of defatted soybean products by supercritical fluid extraction |
FR2705031A1 (fr) * | 1993-05-10 | 1994-11-18 | Sederma Sa | Nouvelles compositions cosmétiques et dermopharmaceutiques contenant des protéines végétales amphipathiques (oléosines) extraites des globules gras des graines de colza, de soja, de lin. |
EP0702903A1 (de) * | 1994-09-19 | 1996-03-27 | SKW Trostberg Aktiengesellschaft | Verfahren zur Herstellung von fett- und cholesterin-reduzierten pulverförmigen Produkten auf Eibasis mit einem hohen Gehalt an Phospholipiden |
DE19813207C1 (de) * | 1997-10-08 | 1999-06-24 | Fraunhofer Ges Forschung | Verfahren zur Behandlung und Verarbeitung alkaloid-, öl- und proteinhaltiger Lupinensamen |
WO2000047059A1 (en) * | 1999-02-10 | 2000-08-17 | The United States Of America, As Represented By The Secretary Of Agriculture | Production of high protein concentrates |
Non-Patent Citations (4)
Title |
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ALAMANOU S ET AL: "EFFECT OF WET EXTRACTION METHODS ON THE EMULSIFYING AND FOAMING PROPERTIES OF LUPIN SEED PROTEIN ISOLATES (LUPINUS ALBUS SSP. GRAECUS)", FOOD HYDROCOLLOIDS, IRL PRESS, OXFORD, GB, vol. 11, no. 4, 1997, pages 409 - 413, XP002068529 * |
COCERO M J ET AL: "SUPERCRITICAL FLUID EXTRACTION OF SUNFLOWER SEED OIL WITH CO2- ETHANOL MIXTURES", JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, AMERICAN OIL CHEMISTS' SOCIETY. CHAMPAIGN, US, vol. 73, no. 11, 1 November 1996 (1996-11-01), pages 1573 - 1578, XP000637469, ISSN: 0003-021X * |
LEE ET AL: "Concentration of Tocopherols from Soybean Sludge by Supercritical Carbon Dioxide", JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, AMERICAN OIL CHEMISTS' SOCIETY. CHAMPAIGN, US, vol. 68, no. 8, 1991, pages 571 - 573, XP002160342, ISSN: 0003-021X * |
MONTANARI L ET AL: "SELECTIVE EXTRACTION OF PHOSPHOLIPIDS FROM SOYBEANS WITH SUPERCRITICAL CARBON DIOXIDE AND ETHANOL", JOURNAL OF SUPERCRITICAL FLUIDS, PRA PRESS, US, vol. 14, no. 2, January 1999 (1999-01-01), pages 87 - 93, XP000792991, ISSN: 0896-8446 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006003110A1 (en) * | 2004-06-29 | 2006-01-12 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. | Process for the purification of protein fractions from lupin seeds, active on lipid metabolism |
WO2017041776A1 (de) | 2015-09-11 | 2017-03-16 | B+B Engineering Gmbh | Verfahren zum kombinierten zellaufschluss und extraktion ölhaltiger saaten |
US10577558B2 (en) | 2015-09-11 | 2020-03-03 | B+B Engineering Gmbh | Method for a combined cell digestion and extraction of oil-containing seeds |
US12052994B2 (en) | 2019-02-03 | 2024-08-06 | Terviva, Inc. | Methods for controlling black sigatoka in bananas using pongamia oil and formulations thereof |
Also Published As
Publication number | Publication date |
---|---|
DE10101326A1 (de) | 2002-07-25 |
CA2434395A1 (en) | 2002-07-18 |
EP1351581A1 (de) | 2003-10-15 |
US20040047972A1 (en) | 2004-03-11 |
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