WO2002042380A1 - Utilisation de pigments en cosmetique, en particulier dans le maquillage - Google Patents

Utilisation de pigments en cosmetique, en particulier dans le maquillage Download PDF

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Publication number
WO2002042380A1
WO2002042380A1 PCT/IB2001/001784 IB0101784W WO0242380A1 WO 2002042380 A1 WO2002042380 A1 WO 2002042380A1 IB 0101784 W IB0101784 W IB 0101784W WO 0242380 A1 WO0242380 A1 WO 0242380A1
Authority
WO
WIPO (PCT)
Prior art keywords
pigment
formula
substituted
composition
branched
Prior art date
Application number
PCT/IB2001/001784
Other languages
English (en)
Other versions
WO2002042380A8 (fr
Inventor
Bansi Lal Kaul
Bruno Piastra
Original Assignee
Clariant Finance (Bvi) Limited
Clariant International Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Finance (Bvi) Limited, Clariant International Ltd. filed Critical Clariant Finance (Bvi) Limited
Priority to AU2001287995A priority Critical patent/AU2001287995A1/en
Publication of WO2002042380A1 publication Critical patent/WO2002042380A1/fr
Publication of WO2002042380A8 publication Critical patent/WO2002042380A8/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/02—Nail coatings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B19/00—Oxazine dyes
    • C09B19/02—Bisoxazines prepared from aminoquinones
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes

Definitions

  • the present invention relates to the use of pigments in cosmetics, to cosmetic compositions containing them and to cosmetic treatment processes using them.
  • the Applicant has just discovered pigments that are particularly advantageous to use in cosmetics, and in particular for use in make-up compositions, especially foundations, tinted creams, mascaras, face powders, eye shadows, lipsticks, nail varnishes and temporary hair dyes. These pigments produce a very wide range of reproducible colorations, which is highly desirable in the cosmetics field, ranging from yellow to brown and passing through orange-yellow, orange and bright red. They are also stable at pHs of between 6 and 8 and insoluble in most cosmetic m ⁇ dia.
  • One subject of the invention is the use of compounds of formulae (I) and (II)
  • Ri and R 2 denote, independently of each other, the atoms required to form a substituted or unsubstituted aromatic ring or an aliphatic ring or a heterocycle
  • R 3 and R 4 independently of each other, denote a hydrogen atom, a substituted or unsubstituted phenyl radical, a branched or unbranched, saturated or unsaturated alkyl radical or a carbamate group (III)
  • R 5 denotes a substituted or unsubstituted phenyl radical or a branched or unbranched saturated or unsaturated alkyl radical
  • nuclei denoted by A and B independently of each other, include aromatic rings linearly substituted on positions 2, 3 and 9, 10, or angularly substituted on positions 1 , 2 and 8, 9 or on 3, 4 and 10, 11 with heterocyclic groups allowing the formation of the following species (1) to (3)
  • R 3 and R 4 independently of each other, denote, as in formula (I), a hydrogen atom, a substituted or unsubstituted phenyl radical, a branched or unbranched saturated or unsaturated alkyl radical, or a carbamate group (III)
  • R 5 denotes a substituted or unsubstituted phenyl radical or a branched or unbranched, saturated or unsaturated alkyl radical
  • pigments in cosmetic compositions for treating and/or coloring keratin materials such as the skin, the nails and the hair.
  • these pigments are used more particularly in foundation, tinted cream, mascara, face powder, eye shadow, lipstick and nail varnish compositions and temporary hair dyeing compositions. They may be used alone or mixed with other conventional mineral or organic pigments.
  • the pigments of formula (I) and the process for preparing them are described in publication WO 98/32800.
  • the pigments of formula (II) and the process for preparing them are described in publication EP 0 889 046 A1.
  • R T and R 2 are, independently of each other, preferably chosen from the following groups
  • Hal denotes a halogen atom of Cl, F, Br or I type
  • R denotes a C C 4 alkyl radical, preferably methyl or ethyl a has the value 1 , 2, 3 or 4 b has the value 1 , 2, 3 or 4
  • R 3 denotes a substituted or unsubstituted phenyl radical and R 4 denotes a hydrogen atom.
  • compositions which constitute another subject of the invention are characterized in that they contain at least one compound corresponding to formula (I) or (II) defined above, in a cosmetically acceptable medium.
  • the pigments of formulae (I) and (II) are generally used at a concentration which can range between 0.1% and 80% by weight and preferably between 1 % and 30% by weight relative to the total weight of the composition.
  • the cosmetically acceptable medium is a medium that is essentially a non-solvent for the pigment.
  • essentially non-solvent medium means a medium that dissolves less than 1% of the said pigment.
  • compositions may be in the form of a lotion, a thickened lotion, a gel, emulsions (creams, milks or ointments), vesicular dispersions, a powder or a stick. They may optionally be packaged as an aerosol and may be in the form of a mousse or spray.
  • compositions are preferably emulsions of oil-in-water or water-in-oil type or liposo- mal dispersions or alternatively solid preparations.
  • surfactants that are well known in the prior art, such as anionic, nonionic, cationic or amphoteric surfactants or mixtures thereof.
  • compositions may also contain fatty substances, organic solvents, silicones, thickeners, softeners, sun screens, free-radical scavengers, antifoams, moisturizers, fragrances, preserving agents, antioxidants, fillers, sequestering agents, treating agents such as nonionic, cationic, anionic or amphoteric polymers or mixtures thereof, propellants and acidifying or basifying agents.
  • the fatty substances may consist of an oil or a wax or mixtures thereof, fatty acids, fatty alcohols, fatty acid esters, petroleum jelly, paraffin, lanolin, hydrogenated lanolin or acetylated lanolin.
  • oils are chosen from animal oils, plant oils, mineral oils, synthetic oils and in particular hydrogenated palm oil, hydrogenated castor oil, liquid petroleum jelly, liquid paraffin, purcellin oil and silicone oils.
  • the waxes are chosen from animal waxes, fossil waxes, plants waxes, mineral waxes and synthetic waxes. Mention may be made more particularly of bees waxes, carnauba wax, candelilla wax, sugar cane wax, Japan wax, ozokerites, montan wax, microcry- stalline waxes and paraffins.
  • the compositions are used for coloring the nails, they are in the form of "nail varnish" products containing the pigment in accordance with the invention dispersed in a cosmetically acceptable solvent containing one or more resins and ingredients usually used in products of this type.
  • compositions When used for coloring the hair, they preferably comprise a medium which is suitable for temporary dyeing, consisting of water, a solvent or a mixture of water and one or more cosmetically acceptable solvent(s), containing at least one pigment in accordance with the invention, in dispersed form.
  • the solvents are chosen more particularly from C C 6 lower alcohols, alkylene glycols, for instance ethylene glycol or propylene glycol, glycol ethers, for instance ethylene glycol monomethyl ether, monoethyl ether or monobutyl ether, ethylene glycol mono- ethyl ether acetate, propylene glycol monomethyl ether and dipropylene glycol mono- methyl ether, and methyl lactate.
  • alkylene glycols for instance ethylene glycol or propylene glycol
  • glycol ethers for instance ethylene glycol monomethyl ether, monoethyl ether or monobutyl ether, ethylene glycol mono- ethyl ether acetate, propylene glycol monomethyl ether and dipropylene glycol mono- methyl ether, and methyl lactate.
  • the solvents that are particularly preferred are ethyl alcohol and propylene glycol.
  • compositions in accordance with the invention may also contain, in addition to the pigment defined above, other pigments generally used in cosmetics, in particular white or colored pigments, nacreous and/or purlescent pigments for varying the colorations or for increasing the protection against ultraviolet radiation.
  • pigments which may be used are nanopigments of metal oxides, such as titanium oxide, zinc oxide, cerium oxide and/or zirconium oxide with a mean diameter of less than 100 nm and preferably between 1 and 50 nm. These pigments may be coated.
  • Another subject of the invention consists of a process for coloring or making up keratin materials such as the skin, the nails, the eyelashes, the eyebrows and the hair, using a composition containing, in a cosmetically acceptable medium, at least one pigment corresponding to formula (I) or (II) as defined above.
  • Insoluble pigment consisting of a dye from the 0.65 g indigo family deposited on a filler, known as DC Red 30 LAKE in the CTFA dictionary Ultramarine blue 0.15 g Titanium mica 5.00 g
  • Titanium dioxide 0.77 g

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention se rapporte à l'utilisation comme pigment dans des compositions cosmétiques de composés répondant à la formule (1) ou (2) dans lesquelles les substituants sont tels que définis dans la revendication 1, à des compositions cosmétiques contenant au moins un pigment tel que défini, et également à des procédés permettant de maquiller la peau, de colorer les ongles ou de teinter des fibres de kératine en appliquant la composition précitée.
PCT/IB2001/001784 2000-11-24 2001-09-27 Utilisation de pigments en cosmetique, en particulier dans le maquillage WO2002042380A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001287995A AU2001287995A1 (en) 2000-11-24 2001-09-27 Use of pigments in cosmetic, in particular in make-up

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH20002286/00 2000-11-24
CH22862000 2000-11-24

Publications (2)

Publication Number Publication Date
WO2002042380A1 true WO2002042380A1 (fr) 2002-05-30
WO2002042380A8 WO2002042380A8 (fr) 2004-02-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2001/001784 WO2002042380A1 (fr) 2000-11-24 2001-09-27 Utilisation de pigments en cosmetique, en particulier dans le maquillage

Country Status (2)

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AU (1) AU2001287995A1 (fr)
WO (1) WO2002042380A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9889080B2 (en) 2015-05-07 2018-02-13 Celeb LLC Color depositing shampoo
US10245221B2 (en) 2015-05-07 2019-04-02 Celeb LLC Stabilized color depositing shampoo

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998032800A1 (fr) * 1997-01-29 1998-07-30 Clariant Finance (Bvi) Limited Pigments thiazine indigo, solution solides de ceux-ci et procede de preparation associe
EP0889046A1 (fr) * 1997-06-25 1999-01-07 Clariant Finance (BVI) Limited Triphénedioxazines et leur utilisation comme pigments
EP0919597A2 (fr) * 1997-11-25 1999-06-02 Clariant GmbH Nouvelle modification cristalline de thiazine-indigo
EP1036821A1 (fr) * 1999-03-18 2000-09-20 Clariant Finance (BVI) Limited Procédé pour la préparation de composés thiazine-indigo et de nouveaux intermédiaires pour ceux-ci
EP1046681A2 (fr) * 1999-04-22 2000-10-25 Clariant Finance (BVI) Limited Pigments hybrides
EP1125986A2 (fr) * 2000-02-10 2001-08-22 Clariant Finance (BVI) Limited Nouveaux pigments du type triphénédioxazine

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998032800A1 (fr) * 1997-01-29 1998-07-30 Clariant Finance (Bvi) Limited Pigments thiazine indigo, solution solides de ceux-ci et procede de preparation associe
EP0889046A1 (fr) * 1997-06-25 1999-01-07 Clariant Finance (BVI) Limited Triphénedioxazines et leur utilisation comme pigments
EP0919597A2 (fr) * 1997-11-25 1999-06-02 Clariant GmbH Nouvelle modification cristalline de thiazine-indigo
EP1036821A1 (fr) * 1999-03-18 2000-09-20 Clariant Finance (BVI) Limited Procédé pour la préparation de composés thiazine-indigo et de nouveaux intermédiaires pour ceux-ci
EP1046681A2 (fr) * 1999-04-22 2000-10-25 Clariant Finance (BVI) Limited Pigments hybrides
EP1125986A2 (fr) * 2000-02-10 2001-08-22 Clariant Finance (BVI) Limited Nouveaux pigments du type triphénédioxazine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9889080B2 (en) 2015-05-07 2018-02-13 Celeb LLC Color depositing shampoo
US10245221B2 (en) 2015-05-07 2019-04-02 Celeb LLC Stabilized color depositing shampoo

Also Published As

Publication number Publication date
AU2001287995A1 (en) 2002-06-03
WO2002042380A8 (fr) 2004-02-19

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