WO2002014215A3 - Membranreaktor und verfahren zur herstellung von hochreinem wasserstoffgas - Google Patents

Membranreaktor und verfahren zur herstellung von hochreinem wasserstoffgas Download PDF

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Publication number
WO2002014215A3
WO2002014215A3 PCT/EP2001/009528 EP0109528W WO0214215A3 WO 2002014215 A3 WO2002014215 A3 WO 2002014215A3 EP 0109528 W EP0109528 W EP 0109528W WO 0214215 A3 WO0214215 A3 WO 0214215A3
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WO
WIPO (PCT)
Prior art keywords
production
highly pure
hydrogen gas
pure hydrogen
membrane reactor
Prior art date
Application number
PCT/EP2001/009528
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English (en)
French (fr)
Other versions
WO2002014215A2 (de
Inventor
Franz Fuder
Original Assignee
Bp Benzin Und Petroleum Ag
Franz Fuder
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10040539A external-priority patent/DE10040539A1/de
Application filed by Bp Benzin Und Petroleum Ag, Franz Fuder filed Critical Bp Benzin Und Petroleum Ag
Priority to AU2001295480A priority Critical patent/AU2001295480A1/en
Priority to JP2002519319A priority patent/JP2004509042A/ja
Priority to EP01976106A priority patent/EP1373134A2/de
Priority to BR0113349-7A priority patent/BR0113349A/pt
Priority to US10/344,415 priority patent/US20040237406A1/en
Publication of WO2002014215A2 publication Critical patent/WO2002014215A2/de
Publication of WO2002014215A3 publication Critical patent/WO2002014215A3/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B01D63/062—Tubular membrane modules with membranes on a surface of a support tube
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B01J10/007—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2425—Tubular reactors in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B01J35/59—Membranes
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2313/22—Cooling or heating elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
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    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/041—In-situ membrane purification during hydrogen production
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Gegenstand der Erfindung ist ein Membranreaktor zur Herstellung von hochreinem Wasserstoff aus einem Kohlenwasserstoffstrom und Wasserdampf umfassend eine für Wasserstoff durchlässige Diffusionsmembran und gegebenenfalls einen Katalysator zur Umwandlung von Kohlenwasserstoffen in Wasserstoff und zur Abtrennung des Wasserstoffgases vom Restgas, wobei die Membran und gegebenenfalls der Reaktor mit Mitteln zum Aufheizen ausgestattet ist. Ein weiterer Gegenstand der Erfindung ist ein Verfahren zur Herstellung von hochreinem Wasserstoffgas mit einem Vorbehandlungsschritt.
PCT/EP2001/009528 2000-08-18 2001-08-17 Membranreaktor und verfahren zur herstellung von hochreinem wasserstoffgas WO2002014215A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2001295480A AU2001295480A1 (en) 2000-08-18 2001-08-17 Membrane reactor and method for the production of highly pure hydrogen gas
JP2002519319A JP2004509042A (ja) 2000-08-18 2001-08-17 膜型反応器および高純度水素の生成法
EP01976106A EP1373134A2 (de) 2000-08-18 2001-08-17 Membranreaktor und verfahren zur herstellung von hochreinem wasserstoffgas
BR0113349-7A BR0113349A (pt) 2000-08-18 2001-08-17 Reator de membrana e processo para a produção de gás de hidrogênio de alta pureza
US10/344,415 US20040237406A1 (en) 2000-08-18 2001-08-17 Membrane reactor and method for the production of highly pure hydrogen gas

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10040539.8 2000-08-18
DE10040539A DE10040539A1 (de) 2000-08-18 2000-08-18 Membranreaktor und Verfahren zur Herstellung von hochreinem Wasserstoffgas
DE10118248A DE10118248A1 (de) 2000-08-18 2001-04-11 Verfahren zur Herstellung von hochreinem Wasserstoffgas mit einem Membranreaktor und einem Vorbehandlungschritt
DE10118248.1 2001-04-11

Publications (2)

Publication Number Publication Date
WO2002014215A2 WO2002014215A2 (de) 2002-02-21
WO2002014215A3 true WO2002014215A3 (de) 2003-10-23

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PCT/EP2001/009528 WO2002014215A2 (de) 2000-08-18 2001-08-17 Membranreaktor und verfahren zur herstellung von hochreinem wasserstoffgas

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Country Link
US (1) US20040237406A1 (de)
EP (1) EP1373134A2 (de)
JP (1) JP2004509042A (de)
AU (1) AU2001295480A1 (de)
BR (1) BR0113349A (de)
DE (1) DE10118248A1 (de)
WO (1) WO2002014215A2 (de)

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US7648566B2 (en) * 2006-11-09 2010-01-19 General Electric Company Methods and apparatus for carbon dioxide removal from a fluid stream
US7966829B2 (en) * 2006-12-11 2011-06-28 General Electric Company Method and system for reducing CO2 emissions in a combustion stream
JP5415109B2 (ja) * 2009-03-12 2014-02-12 川崎重工業株式会社 ハイブリッド水素供給ステーション
JP5412232B2 (ja) * 2009-03-30 2014-02-12 東京瓦斯株式会社 二酸化炭素分離回収装置を伴う水素分離型水素製造システム
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AU2001295480A1 (en) 2002-02-25
EP1373134A2 (de) 2004-01-02
JP2004509042A (ja) 2004-03-25

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