WO2002008512A1 - Procede d'impression de structures tissees, de structures tricotees et de structures a mailles - Google Patents

Procede d'impression de structures tissees, de structures tricotees et de structures a mailles Download PDF

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Publication number
WO2002008512A1
WO2002008512A1 PCT/DE2001/002665 DE0102665W WO0208512A1 WO 2002008512 A1 WO2002008512 A1 WO 2002008512A1 DE 0102665 W DE0102665 W DE 0102665W WO 0208512 A1 WO0208512 A1 WO 0208512A1
Authority
WO
WIPO (PCT)
Prior art keywords
substrate
coating
aqueous dispersion
self
disperse dye
Prior art date
Application number
PCT/DE2001/002665
Other languages
German (de)
English (en)
Inventor
Thomas Kerle
Original Assignee
Thomas Kerle
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thomas Kerle filed Critical Thomas Kerle
Priority to DE50110165T priority Critical patent/DE50110165D1/de
Priority to EP01953927A priority patent/EP1309753B1/fr
Publication of WO2002008512A1 publication Critical patent/WO2002008512A1/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001—Special chemical aspects of printing textile materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D06P1/20—Anthraquinone dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/043—Material containing basic nitrogen containing amide groups using dispersed dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/14—Wool
    • D06P3/143—Wool using dispersed dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/6033—Natural or regenerated cellulose using dispersed dyes

Definitions

  • the invention relates to a method for dyeing, printing, painting or the like of substrates made of fabrics, knitted fabrics, knitted fabrics or the like. With the features of the preamble of claim 1. Furthermore, it relates to a substrate made of fabrics, knitted fabrics, knitted fabrics or the like. With the features the preamble of claim 13.
  • azo dyes have been used in the printing of textiles, in particular textiles made of natural fibers, which are carcinogenic because of the amines and halogens contained therein and their diffusing properties. Due to these health-threatening properties, the azo dyes for printing on textiles are to be banned in the near future.
  • the invention is therefore based on the object of providing a method for dyeing, printing, painting or the like of substrates made from woven or knitted fabrics, with which a qualitatively improved color printing is achieved.
  • a method for dyeing, printing, painting or the like of substrates made of fabrics, knitted fabrics or the like in which the substrate surface is first coated with an aqueous dispersion of self-crosslinking polymers.
  • the dispersion applied to the substrate is then dried, in particular at elevated temperature.
  • the self-crosslinking polymers also harden increased temperature.
  • the disperse dye can be applied to the coated substrate surface.
  • the textured surface of the woven or knitted fabric is equalized by the coating, the surface properties remaining essentially unchanged.
  • the color printing with disperse dye applied to the coated substrate surface is characterized by its high resolution and line accuracy. Another advantage is the low dye consumption.
  • the dispersion is an aqueous system and is therefore biodegradable.
  • the aqueous dispersion can also be combined with other aqueous systems.
  • the process according to the invention also has the advantage that the natural surface of the fabric, knitted or crocheted fabric, in particular in the case of textiles made from natural fibers or with a predominant natural fiber content, is retained, the dispersion does not form a tactile plastic-like film and accordingly also the dimensioning, character and color of the Tissue (with a transparent dispersion) are not affected.
  • the dispersion is also completely solvent-free, requires only a low drying temperature and a short drying time, so that the fabrics or knitted fabrics can be processed quickly.
  • Anthraquinones, anthraquinone derivatives or quinolines can be used as disperse dyes.
  • the advantage of these groups is that they contain neither halogens nor amines and are therefore not carcinogenic or hazardous to health, which is extremely important especially for textiles which are processed into clothing.
  • Chemical and / or physical additives such as. B. defoamers, fillers, etc. are added to improve the processability of the dispersion, to increase the quality of the dye application or to consciously change the fabric or knitted fabric surface.
  • the substrate can be immersed in the dispersion for uniform and quick coating.
  • the aqueous dispersion it is also possible for the aqueous dispersion to be sprayed onto the substrate or applied with a brush.
  • a further coating of an aqueous dispersion of self-crosslinking polymers can be applied to the substrate, which at the same time creates a protective layer for color printing.
  • the drying process of the aqueous dispersion applied to the substrate can preferably take place at 100 ° C. to 150 ° C., in particular at approximately 130 ° C.
  • the relatively low temperatures required for drying are therefore associated with low energy consumption.
  • the self-crosslinking polymers can be cured at about 170 ° C. for about 1 minute, so that a permanent, fully cured coating is created.
  • the disperse dye can be applied either by screen printing, transfer printing or pad printing. It is therefore possible to use the usual methods of printing, which previously could only be carried out with azo dyes with high-quality results.
  • the disperse dye applied can preferably be dried at approx. 130 ° C for approx. 1 minute.
  • the substrate according to the invention made of woven fabric, knitted fabric, knitted fabric or the like, in particular textiles made of natural fibers or with a predominant proportion of natural fibers, are distinguished by a coating of an aqueous dispersion of self-crosslinking polymers, to which a color print or a color paint made from disperse dye is applied.
  • the coating leads to a leveling of the fabric or knitted surface, so that a high quality color print with disperse dyes is achieved.
  • the disperse dye can essentially consist of anthraquinones, anthraquinone derivatives or quinolines and is therefore not associated with carcinogenic dangers due to halogens or amines.
  • Color printing and color painting is characterized by high resolution, line accuracy and exact color gradients.
  • the coating is preferably transparent, so that the coloring takes place only through the disperse dye and there is no change in color of the disperse dye.
  • the coating can be mixed with chemical or physical additives in order to change the surface of the fabric or to optimize the function of the coating as a protective layer.
  • a further coating of an aqueous dispersion of self-crosslinking polymers which represents an additional protective function of the fabric surface or the color printing, can be provided on the color printing or the color painting.
  • Fig. 1 is a flow chart of the method according to the invention.
  • Fig. 2 shows a schematic diagram of the substrate according to the invention in section
  • the substrate made of fabric or knitted fabric provides z. B. is a natural fiber fabric made of wool, cotton, silk, linen or the like. That is to be printed with disperse dyes. But it can also be a synthetic fiber fabric.
  • the substrate surface is coated with an aqueous dispersion of self-crosslinking polymers.
  • the coating leads to an equalization of the usually textured fabric surface.
  • the coating is dried at about 130 ° C. for about 30 minutes.
  • the self-crosslinking polymers are then cured at approx.
  • anthraquinone derivatives are free of halogens and amines, so they are not carcinogenic and, in conjunction with the previously applied coating, ensure high-quality color printing with regard to color and light fastness, as well as resolution and line accuracy.
  • the applied disperse dye dries out at approx. 130 ° C.
  • anthraquinone derivatives anthraquinones or quinolines can also be used as disperse dyes, which also do not contain halogens or amines and are therefore not hazardous to health.
  • the dispersion Before coating, the dispersion can be chemical and / or physical additives such. B. defoamers, fillers and the like can be added. So z. B. the dispersion can be thickened with thickeners and thus adjusted for brush or squeegee application. For a uniform coating, the textile substrate can also simply be immersed in the dispersion. As an additional step, it is possible that, after the disperse dye has dried, a further coating of an aqueous dispersion of self-crosslinking polymers is applied to the substrate, which is a protective layer for the applied color print.
  • the disperse dye can e.g. B. in screen printing, transfer printing or pad printing.
  • a manual brush application is also possible.
  • reference numeral 1 denotes the substrate made of woven or knitted fabric, which is provided with a coating 2 made of an aqueous dispersion of self-crosslinking polymers.
  • a color print 3 is applied to the coating 2.
  • the color printing 3 from disperse dye consists essentially of anthraquinones, anthraquinone derivatives or quinolines. These groups have the advantage that they do not contain the carcinogenic halogens or amines. Because of the coating 2, a high-quality color print is possible using the dyes mentioned, d. H. color print 2 is characterized by high resolution, color and light fastness.
  • the coating is characterized in that it sinks into the substrate surface and seals it, but without closing the surface. The natural surface of the fabric is preserved. In order not to influence the color of the fabric or knitted fabric, the coating 2 is transparent.
  • the coating can be mixed with chemical or physical additives.

Abstract

La présente invention concerne un procédé pour teindre, imprimer, peindre ou réaliser une opération similaire sur des substrats constitués de structures tissées, de structures tricotées, de structures à mailles ou de structures similaires, notamment de matières textiles en fibres naturelles ou à fibres naturelles majoritaires ou de matières similaires, au moyen de colorants en dispersion. Ce procédé consiste a) à revêtir la surface du substrat avec une dispersion aqueuse de polymères auto-réticulants, b) à faire sécher la dispersion appliquée sur le substrat, c) à faire durcir les polymères auto-réticulants, puis d) à appliquer le colorant en dispersion sur la surface du substrat revêtue.
PCT/DE2001/002665 2000-07-22 2001-07-20 Procede d'impression de structures tissees, de structures tricotees et de structures a mailles WO2002008512A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE50110165T DE50110165D1 (de) 2000-07-22 2001-07-20 Verfahren zum färben von textilien
EP01953927A EP1309753B1 (fr) 2000-07-22 2001-07-20 Procédé de teinture de textiles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10035746A DE10035746A1 (de) 2000-07-22 2000-07-22 Verfahren zum Bedrucken von Geweben, Gestricken, Gewirken
DE10035746.6 2000-07-22

Publications (1)

Publication Number Publication Date
WO2002008512A1 true WO2002008512A1 (fr) 2002-01-31

Family

ID=7649859

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2001/002665 WO2002008512A1 (fr) 2000-07-22 2001-07-20 Procede d'impression de structures tissees, de structures tricotees et de structures a mailles

Country Status (5)

Country Link
EP (1) EP1309753B1 (fr)
AT (1) ATE330057T1 (fr)
DE (2) DE10035746A1 (fr)
ES (1) ES2265436T3 (fr)
WO (1) WO2002008512A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004070109A1 (fr) * 2003-01-28 2004-08-19 Sara Lee Corporation Tampographie sur substrats textiles
EP1762395A1 (fr) * 2005-09-12 2007-03-14 PAM Berlin GmbH & Co. KG Procédé d'impression sérigraphique en trois étapes et produits ainsi obtenus
CN106079945A (zh) * 2016-08-01 2016-11-09 太仓市鑫泰针织有限公司 一种竹纤维针织品的印花方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019215939A1 (de) 2019-10-16 2021-04-22 Adidas Ag Einfärben einer Textilschicht und eine Textilschicht

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2708235A1 (de) * 1976-02-26 1977-09-01 Toppan Printing Co Ltd Verfahren zum bedrucken von cellulosefaser- und polyester/cellulose-mischfasermaterial
US4171404A (en) * 1977-02-22 1979-10-16 Milliken Research Corporation Polymer-modified, acid dyeable polyester and polyolefin textile materials and method for producing same
JPS564785A (en) * 1979-06-20 1981-01-19 Emori Shoji Kk Three dimensional pattern coloring method of polyester fiber material
US4421826A (en) * 1980-05-08 1983-12-20 W. R. Grace & Co. Polyurethane polymer amine salt as a dyeing aid, particularly for polyolefin fibers

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4207110A1 (de) * 1992-03-06 1993-09-09 Sandoz Ag Polykationische polymerpraeparate und deren verwendung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2708235A1 (de) * 1976-02-26 1977-09-01 Toppan Printing Co Ltd Verfahren zum bedrucken von cellulosefaser- und polyester/cellulose-mischfasermaterial
US4171404A (en) * 1977-02-22 1979-10-16 Milliken Research Corporation Polymer-modified, acid dyeable polyester and polyolefin textile materials and method for producing same
JPS564785A (en) * 1979-06-20 1981-01-19 Emori Shoji Kk Three dimensional pattern coloring method of polyester fiber material
US4421826A (en) * 1980-05-08 1983-12-20 W. R. Grace & Co. Polyurethane polymer amine salt as a dyeing aid, particularly for polyolefin fibers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 198111, Derwent World Patents Index; Class A23, AN 1981-18348D, XP002183132 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004070109A1 (fr) * 2003-01-28 2004-08-19 Sara Lee Corporation Tampographie sur substrats textiles
US7498277B2 (en) 2003-01-28 2009-03-03 Hbi Branded Apparel Enterprises, Llc Pad printing on textile substrates
US8342088B2 (en) 2003-01-28 2013-01-01 Hbi Branded Apparel Enterprises, Llc Pad printing on textile substrates
US10377127B2 (en) 2003-01-28 2019-08-13 HBI Branded Apparel Enterprises, LLC Corporation Pad printed apparel
EP1762395A1 (fr) * 2005-09-12 2007-03-14 PAM Berlin GmbH & Co. KG Procédé d'impression sérigraphique en trois étapes et produits ainsi obtenus
CN106079945A (zh) * 2016-08-01 2016-11-09 太仓市鑫泰针织有限公司 一种竹纤维针织品的印花方法

Also Published As

Publication number Publication date
DE10035746A1 (de) 2002-02-21
EP1309753A1 (fr) 2003-05-14
ES2265436T3 (es) 2007-02-16
EP1309753B1 (fr) 2006-06-14
ATE330057T1 (de) 2006-07-15
DE50110165D1 (de) 2006-07-27

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