WO2001051280A2 - Laminar articles containing layers of ethylene containing polymer elastomers containing aromatic resins - Google Patents

Laminar articles containing layers of ethylene containing polymer elastomers containing aromatic resins Download PDF

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Publication number
WO2001051280A2
WO2001051280A2 PCT/US2001/001157 US0101157W WO0151280A2 WO 2001051280 A2 WO2001051280 A2 WO 2001051280A2 US 0101157 W US0101157 W US 0101157W WO 0151280 A2 WO0151280 A2 WO 0151280A2
Authority
WO
WIPO (PCT)
Prior art keywords
article
ethylene
resin
norbornene
diene
Prior art date
Application number
PCT/US2001/001157
Other languages
English (en)
French (fr)
Other versions
WO2001051280A3 (en
WO2001051280A8 (en
Inventor
Kenneth Lewtas
Vincent B. Gallez
Eric P. Jourdain
Thomas J. Reynolds
Giandomenico Stella
Original Assignee
Exxonmobil Chemical Patents, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB0000674.2A external-priority patent/GB0000674D0/en
Application filed by Exxonmobil Chemical Patents, Inc. filed Critical Exxonmobil Chemical Patents, Inc.
Priority to BR0107623-0A priority Critical patent/BR0107623A/pt
Priority to EP01942270A priority patent/EP1259574A2/en
Priority to MXPA02006907A priority patent/MXPA02006907A/es
Priority to JP2001551682A priority patent/JP2004500997A/ja
Publication of WO2001051280A2 publication Critical patent/WO2001051280A2/en
Publication of WO2001051280A3 publication Critical patent/WO2001051280A3/en
Publication of WO2001051280A8 publication Critical patent/WO2001051280A8/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00Tubular articles, e.g. hoses, pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C08L57/02Copolymers of mineral oil hydrocarbons

Definitions

  • Natural and synthetic rubbers and elastomers are used extensively in the production of multi-layer articles such as V-belts, hoses, sheets such as those used for roofing, mats and tires
  • materials that are used are chloroprene, natural rubbers and synthetic rubbers such as neoprene, butyl rubber, styrene butadiene rubbers and polydiene rubbers
  • the rubber compounds are produced by calendaring and mixing to thoroughly disperse additives such as fillers, pigments, antioxidants and vulcanising agents throughout the rubber
  • the final articles are produced by forming layers, laying up and vulcanising or by co-extrusion and subsequent vulcanisation
  • Typical manufacturing processes for V-belts comprise producing laminated strips of the belting material, usually a laminar structure, laying the strips around a drum and then vulcanising It is therefore important that the layers in the laminar structure have sufficient green tack to adhere to each other and to firmly bond the two ends of the strips together Similarly
  • the ⁇ -olefin is generally incorporated into the ethylene containing elastomeric polymer in an amount of about 15 to about 85 wt %, more preferably at about 15 to about 70 wt % and even more preferably about 20 to about 60 wt %.
  • Illustrative of such substituted ⁇ -olefins are compounds of the formula
  • the molecular weight range of the ethylene containing polymers as measured by NMR will typically range from 5,000 to 5,000,000 weight average molecular weight (Mw), more typically from 10,000 to 500,000 Mw, most typically 15,000 to 350,000 Mw Mooney viscosity (ML 1+4 , 125°C) will typically range from 10 up to 90, more typically 20 to 75
  • the feedstream includes 50 wt % to 85 wt % of the C 9 monomers and 50 wt % to 15 wt % of a co-feed including at least one member selected form the group consisting of pure monomer, C 5 monomers, and terpenes
  • the layers used in the present invention can also contain other resins, such as rosin esters derived from tall oil, gum rosin and polyterpenes, which may be incorporated during the compounding operation
  • process oil ethylene- ⁇ -olefin oligomer, paraffin wax, liquid paraffin, white oil, petrolatum, petroleum, sultanate, gilsonite, asphalt, diene oligomer (including hydrogenated one), vegetable oil softener (caster oil, cotton seed oil, rapeseed oil, palm oil, peanut oil, pine oil, tall oil, etc), rubber substitute (vulcanised oil), fatty acid, fatty acid salt, and fatty acid ester. They may be used alone or in combination with one another.
  • the additives include reinforcing material and filler, such as carbon black (channel black, furnace black, thermal black or lamp black, acetylene black etc), silica (white carbon, etc), basic magnesium carbonate, calcium carbonate (e.g., light calcium carbonate, ground calcium carbonate, and surface-treated calcium carbonate), magnesium silicate (e.g., ultrafine magnesium silicate), clay, talc, wollastonite, zeolite, diatomaceous earth, silica sand, alumina sol, aluminium hydroxide, aluminium sulphate, barium sulphate, calcium sulphate, lithopone, molybdenum disulphide, rubber power, shellac, cork powder, and cellulose powder.
  • Adhesion promoters such as zinc methacrylate may be included where the rubber layers are required to stick to other materials such as the cords used in V-belt manufacture. These additives may be used alone or in commination with one another.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
PCT/US2001/001157 2000-01-13 2001-01-12 Laminar articles containing layers of ethylene containing polymer elastomers containing aromatic resins WO2001051280A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BR0107623-0A BR0107623A (pt) 2000-01-13 2001-01-12 Artigos laminares contendo camadas de resinas contendo elastÈmeros de polìmero contendo etileno
EP01942270A EP1259574A2 (en) 2000-01-13 2001-01-12 Laminar articles containing layers of ethylene containing polymer elastomers containing aromatic resins
MXPA02006907A MXPA02006907A (es) 2000-01-13 2001-01-12 Articulos laminares que contienen capas de resinas que contienen elastomeros de polimero que contiene etileno.
JP2001551682A JP2004500997A (ja) 2000-01-13 2001-01-12 樹脂を含むエチレン含有ポリマーエラストマーの層を含有する層状物品

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB0000674.2A GB0000674D0 (en) 2000-01-13 2000-01-13 Laminar articles containing layers of ethylene containing polymer elastomers containing resins
GB0000674.2 2000-01-14
US18460900P 2000-02-24 2000-02-24
US60/184,609 2000-02-24

Publications (3)

Publication Number Publication Date
WO2001051280A2 true WO2001051280A2 (en) 2001-07-19
WO2001051280A3 WO2001051280A3 (en) 2001-12-20
WO2001051280A8 WO2001051280A8 (en) 2002-10-03

Family

ID=26243386

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/001157 WO2001051280A2 (en) 2000-01-13 2001-01-12 Laminar articles containing layers of ethylene containing polymer elastomers containing aromatic resins

Country Status (6)

Country Link
EP (1) EP1259574A2 (ja)
JP (1) JP2004500997A (ja)
CN (1) CN1419592A (ja)
BR (1) BR0107623A (ja)
MX (1) MXPA02006907A (ja)
WO (1) WO2001051280A2 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112566796A (zh) * 2018-08-14 2021-03-26 大陆轮胎德国有限公司 具有至少一个发送和/或接收设备的技术用橡胶制品和用于将至少一个发送和/或接收设备紧固在技术用橡胶制品的面上的粘合剂组合物的用途

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7471129B2 (ja) 2020-04-02 2024-04-19 三井化学株式会社 エチレン系共重合体組成物およびその用途

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4657958A (en) * 1985-03-05 1987-04-14 The Firestone Tire & Rubber Company Contact adhesive and adhesive system for EPDM elastomers
DE19734035A1 (de) * 1996-08-07 1998-02-12 Sumitomo Chemical Co Harzmasse, vernetzte Harzmasse und Laminat
WO1998012251A1 (en) * 1996-09-20 1998-03-26 Exxon Chemical Patents Inc. Metal salts of acrylic or methacrylic acid as curatives for compositions containing halogenated isomonoolefin/para-alkylstyrene copolymers
WO1999040160A1 (en) * 1998-02-03 1999-08-12 Montell Technology Company B.V. Polyolefin based hot melt adhesive composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4657958A (en) * 1985-03-05 1987-04-14 The Firestone Tire & Rubber Company Contact adhesive and adhesive system for EPDM elastomers
DE19734035A1 (de) * 1996-08-07 1998-02-12 Sumitomo Chemical Co Harzmasse, vernetzte Harzmasse und Laminat
WO1998012251A1 (en) * 1996-09-20 1998-03-26 Exxon Chemical Patents Inc. Metal salts of acrylic or methacrylic acid as curatives for compositions containing halogenated isomonoolefin/para-alkylstyrene copolymers
WO1999040160A1 (en) * 1998-02-03 1999-08-12 Montell Technology Company B.V. Polyolefin based hot melt adhesive composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112566796A (zh) * 2018-08-14 2021-03-26 大陆轮胎德国有限公司 具有至少一个发送和/或接收设备的技术用橡胶制品和用于将至少一个发送和/或接收设备紧固在技术用橡胶制品的面上的粘合剂组合物的用途

Also Published As

Publication number Publication date
WO2001051280A3 (en) 2001-12-20
CN1419592A (zh) 2003-05-21
JP2004500997A (ja) 2004-01-15
BR0107623A (pt) 2002-11-26
MXPA02006907A (es) 2003-05-23
WO2001051280A8 (en) 2002-10-03
EP1259574A2 (en) 2002-11-27

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