WO2001017936A3 - Procede et installation pour la production de methanol - Google Patents

Procede et installation pour la production de methanol Download PDF

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Publication number
WO2001017936A3
WO2001017936A3 PCT/EP2000/008486 EP0008486W WO0117936A3 WO 2001017936 A3 WO2001017936 A3 WO 2001017936A3 EP 0008486 W EP0008486 W EP 0008486W WO 0117936 A3 WO0117936 A3 WO 0117936A3
Authority
WO
WIPO (PCT)
Prior art keywords
methanol reactor
gas mixture
methanol
arrangement
catalyst
Prior art date
Application number
PCT/EP2000/008486
Other languages
German (de)
English (en)
Other versions
WO2001017936A2 (fr
Inventor
Hans-Joachim Baehnisch
Original Assignee
Krupp Uhde Gmbh
Baehnisch Hans Joachim
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19948585A external-priority patent/DE19948585A1/de
Application filed by Krupp Uhde Gmbh, Baehnisch Hans Joachim filed Critical Krupp Uhde Gmbh
Priority to EP00964071A priority Critical patent/EP1210309B1/fr
Priority to US10/070,407 priority patent/US6686398B1/en
Priority to DE50004668T priority patent/DE50004668D1/de
Priority to JP2001521683A priority patent/JP4837213B2/ja
Priority to AT00964071T priority patent/ATE255552T1/de
Priority to DK00964071T priority patent/DK1210309T3/da
Publication of WO2001017936A2 publication Critical patent/WO2001017936A2/fr
Publication of WO2001017936A3 publication Critical patent/WO2001017936A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B01J2208/00061—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

L'invention concerne un procédé pour la synthèse de méthanol à partir d'hydrogène, de monoxyde de carbone et de dioxyde de carbone sous pression, qui comporte au moins une phase de synthèse contenant au moins un réacteur de méthanol rempli de catalyseur, au moins une phase pour plusieurs phases étant équipée d'un compresseur. L'invention concerne également une installation pour l'exécution de ce procédé. L'invention vise à surmonter les inconvénients cités et, notamment, à économiser de la surface d'échangeur thermique ou à augmenter le rendement tout en tenant particulièrement compte de l'activité catalysatrice variable. A cet effet, dans au moins une phase de synthèse, le mélange gazeux destiné à être utilisé dans un réacteur de méthanol rempli de catalyseur est chauffé, juste avant d'être ajouté dans ce réacteur de méthanol, dans un réchauffeur d'appoint supplémentaire. L'installation correspondante selon l'invention est caractérisée en ce que, dans une phase de synthèse au moins, un réchauffeur d'appoint (5) chauffe le mélange gazeux alimentant directement le réacteur de méthanol (10).
PCT/EP2000/008486 1999-09-07 2000-08-31 Procede et installation pour la production de methanol WO2001017936A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP00964071A EP1210309B1 (fr) 1999-09-07 2000-08-31 Procede et installation pour la production de methanol
US10/070,407 US6686398B1 (en) 1999-09-07 2000-08-31 Method and arrangement for producing methanol
DE50004668T DE50004668D1 (de) 1999-09-07 2000-08-31 Verfahren und anlage zur methanolherstellung
JP2001521683A JP4837213B2 (ja) 1999-09-07 2000-08-31 メタノールを製造する方法と設備
AT00964071T ATE255552T1 (de) 1999-09-07 2000-08-31 Verfahren und anlage zur methanolherstellung
DK00964071T DK1210309T3 (da) 1999-09-07 2000-08-31 Fremgangsmåde og anlæg til methanolfremstilling

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19942736.4 1999-09-07
DE19942736 1999-09-07
DE19948585.2 1999-10-08
DE19948585A DE19948585A1 (de) 1999-09-07 1999-10-08 Verfahren und Anlage zur Methanolherstellung

Publications (2)

Publication Number Publication Date
WO2001017936A2 WO2001017936A2 (fr) 2001-03-15
WO2001017936A3 true WO2001017936A3 (fr) 2002-02-28

Family

ID=26054870

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2000/008486 WO2001017936A2 (fr) 1999-09-07 2000-08-31 Procede et installation pour la production de methanol

Country Status (7)

Country Link
US (1) US6686398B1 (fr)
EP (1) EP1210309B1 (fr)
CN (1) CN1181023C (fr)
AT (1) ATE255552T1 (fr)
DK (1) DK1210309T3 (fr)
ES (1) ES2211610T3 (fr)
WO (1) WO2001017936A2 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA05006692A (es) * 2002-12-21 2005-10-05 Haldor Topsoe As Proceso para la sintesis de metanol.
CN1310862C (zh) * 2005-04-30 2007-04-18 四川天一科技股份有限公司 甲醇合成塔
WO2007021393A1 (fr) * 2005-08-18 2007-02-22 Exxonmobil Chemical Patents Inc. Synthese du methanol et systeme de reaction
US20070282021A1 (en) * 2006-06-06 2007-12-06 Campbell Gregory A Producing ethanol and saleable organic compounds using an environmental carbon dioxide reduction process
US20090077892A1 (en) * 2007-07-27 2009-03-26 Shulenberger Arthur M Biomass energy conversion apparatus and method
WO2009052764A1 (fr) * 2007-10-19 2009-04-30 Ren Lou Appareillage de réaction composite et procédé chimique de production utilisant celui-ci
CN101519336B (zh) * 2008-02-29 2012-11-14 杭州林达化工技术工程有限公司 合成气制烃类的方法和设备
DE102008049622B4 (de) 2008-09-30 2012-10-31 Lurgi Gmbh Verfahren und Anlage zur Herstellung von Methanol
CN102012125B (zh) * 2010-10-19 2012-04-25 四川天一科技股份有限公司 焦炉气制甲醇转化废水汽提塔废水热量回收的方法
CN103910604B (zh) * 2014-03-31 2015-10-28 神华集团有限责任公司 甲醇合成塔出口高温气体的处理工艺和甲醇合成系统
EP3401299B1 (fr) 2017-05-12 2021-11-03 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Réacteur destiné à effectuer des réactions d'équilibre exothermiques
EP3401300B1 (fr) * 2017-05-12 2021-06-23 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Procédé pour la production du méthanol
CN107382665B (zh) * 2017-07-13 2023-06-30 南京国昌化工科技有限公司 一种甲醇合成的工艺和装置
CN110026134A (zh) * 2019-05-23 2019-07-19 河北金牛旭阳化工有限公司 一种串联合成塔以及使用其制备甲醇的方法
DE102020120879A1 (de) 2020-08-07 2022-02-10 Karlsruher Institut für Technologie, Körperschaft des öffentlichen Rechts Vorrichtung und Verfahren zur Herstellung von Methanol aus Kohlendioxid

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997031707A1 (fr) * 1996-03-01 1997-09-04 Imperial Chemical Industries Plc Procede chimique catalytique exothermique

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2904575A (en) 1957-11-21 1959-09-15 Exxon Research Engineering Co Production of methanol
DE2117060A1 (en) 1971-04-07 1972-10-26 Methanol synthesis with improved reboiler heating
GB1484366A (en) 1974-07-02 1977-09-01 Ici Ltd Methanol
DE3220995A1 (de) 1982-06-03 1983-12-08 Linde Ag, 6200 Wiesbaden Verfahren zur gewinnung von methanol
DE3518362A1 (de) 1985-05-22 1986-11-27 Linde Ag, 6200 Wiesbaden Verfahren zur herstellung von methanol
DE4004862A1 (de) 1990-02-16 1991-08-22 Uhde Gmbh Methanolsynthese mit frischgaszufuhr
DE4028750A1 (de) 1990-09-11 1992-03-12 Uhde Gmbh Verfahren und anlage zur nutzung der energie einer methanol-synthese
US5179129A (en) * 1991-03-01 1993-01-12 Air Products And Chemicals, Inc. Staged liquid phase methanol process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997031707A1 (fr) * 1996-03-01 1997-09-04 Imperial Chemical Industries Plc Procede chimique catalytique exothermique

Also Published As

Publication number Publication date
EP1210309A2 (fr) 2002-06-05
US6686398B1 (en) 2004-02-03
ES2211610T3 (es) 2004-07-16
ATE255552T1 (de) 2003-12-15
CN1372535A (zh) 2002-10-02
DK1210309T3 (da) 2004-03-15
CN1181023C (zh) 2004-12-22
WO2001017936A2 (fr) 2001-03-15
EP1210309B1 (fr) 2003-12-03

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