WO2001009051A1 - Revetement decoratif - Google Patents

Revetement decoratif Download PDF

Info

Publication number
WO2001009051A1
WO2001009051A1 PCT/CZ2000/000051 CZ0000051W WO0109051A1 WO 2001009051 A1 WO2001009051 A1 WO 2001009051A1 CZ 0000051 W CZ0000051 W CZ 0000051W WO 0109051 A1 WO0109051 A1 WO 0109051A1
Authority
WO
WIPO (PCT)
Prior art keywords
coating
decorative coating
decorative
substrate
protective layer
Prior art date
Application number
PCT/CZ2000/000051
Other languages
English (en)
Inventor
Jindřich MUSIL
Jaromír KUBIŠTA
Original Assignee
Zima A.S.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zima A.S. filed Critical Zima A.S.
Priority to AU61467/00A priority Critical patent/AU6146700A/en
Publication of WO2001009051A1 publication Critical patent/WO2001009051A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0605—Carbon
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
    • C03C17/09—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the vapour phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3605—Coatings of the type glass/metal/inorganic compound
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3684—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used for decoration purposes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0005—Other surface treatment of glass not in the form of fibres or filaments by irradiation
    • C03C23/0065—Other surface treatment of glass not in the form of fibres or filaments by irradiation by microwave radiation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02—Pretreatment of the material to be coated
    • C23C14/021—Cleaning or etching treatments
    • C23C14/022—Cleaning or etching treatments by means of bombardment with energetic particles or radiation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/25—Metals
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/154—Deposition methods from the vapour phase by sputtering
    • C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/30—Aspects of methods for coating glass not covered above
    • C03C2218/31—Pre-treatment

Definitions

  • This invention relates to the area of technology of creating a decorative coating on solid materials using a magnetron sputtering method, particularly on glass, producing textured glass in such a way
  • the substrate is divided from the decorative layer by an interlayer, e g by a titanic interlayer of Ti paint which is a metallic titanium colour, or by an interlayer of TiN -titanium nitride which is a golden colour
  • Deficiencies in the present state of technology have been solved by a method for creating a decorative coating on the solid substrate using a magnetron sputtering method according to the invention
  • the gist of the invention resides in pre-treating the substrate surface in a microwave discharge and consequently applying the decorative coating without heating the substrate up
  • the substrate is pre-treated in a microwave discharge, burning in oxygen, or a gas mixture containing oxygen, nitrogen, and/or fluorine, at a pressure ranging from 0 1 to 1000 Pa
  • the decorative coating is sputtered on the substrate, which has been pre- treated in this way, in an inert atmosphere, e g in argon, or in the presence of a reactive medium, from a cathode made of one element, or of an alloy of two or more elements, at a pressure ranging from 0 05 Pa to several Pa
  • a protective layer transparent in the optic range of the frequency spectrum, preferentially by a protective layer of Ti ⁇ 2, or Si ⁇ 2, or AI2O3, or Si3N4 or by a carbon-based protective layer
  • a protective layer transparent in the optic range of the frequency spectrum, may be used to control the resulting colour shade of the whole decorative layer consisting in this case of a decorative coating and protective layer
  • a decorative coating may be applied on the surface of a substrate, partially covered by a masking varnish, which has to be removed after a coating or, as the case may be, a protective optically transparent layer has been created.
  • textured glass with a decorative coating of stainless steel which may be covered by a protective layer made, for instance, of stainless steel nitride.
  • a protective layer made, for instance, of stainless steel nitride.
  • Another significant result is having textured glass with a decorative coating made of brass or aluminium bronze, which may be covered by a protective layer transparent in the optic range of the frequency spectrum.
  • the basic advantage of the method of this invention is the good adhesion of the coating applied on an unheated substrate. This is achieved by exposing the substrate surface to the influence of the plasma of a microwave discharge.
  • the microwave discharge is generated by microwave performance, usually at a frequency of 2.45 GHz in the working gas, i.e.
  • the activated atoms, excited molecules, and radicals are generated very effectively in comparison with other kinds of low-pressure discharges. They effectively interact with the surfaces of objects inserted into the microwave discharge. Their activation occurs when the plasma comes into contact with the surfaces of objects. The impact of their influence is manifested in a significant change of properties, particularly in the wet ability of the activated surface.
  • a layer which is transparent in the optic range e.g. of T1O2, or Si ⁇ 2, or AI2O3, or Si3N4, or one which is carbon-based.
  • This layer may be created by reactive magnetron sputtering in a mixture of argon and oxygen in the case of layers based on oxides.
  • the protective layer is sputtered from the same disk as a decorative coating and only oxygen or nitrogen is added to the argon. If a protective layer is thinner than - 4 -
  • Example of Invention Here is one example of this method being performed according to the invention described.
  • the technology for creating decorative coating consists in this example of the following three steps:
  • the invention can be applied in any industry where the decorative treatment of solid materials is required, particularly in the production of glass objects involving the decorative treatment of glass.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

L'invention porte sur un procédé de création d'un revêtement décoratif appliqué sur un substrat solide selon une technique de pulvérisation au magnétron. Ce procédé consiste à prétraiter la surface du substrat dans une décharge de micro-ondes et à appliquer, par conséquent, un revêtement décoratif sur le substrat sans réchauffer le substrat. Une couche protectrice, transparente dans la plage optique du spectre de fréquences, peut recouvrir le revêtement décoratif. L'épaisseur de la couche de protection optique peut être utilisée pour stabiliser la teinte obtenue de la couche décorative. Le verre texturé avec un revêtement créé selon ce procédé, le revêtement étant, par exemple, en acier inoxydable ou en laiton ou en bronze d'aluminium, peut, si besoin, être recouvert d'une couche protectrice transparente.
PCT/CZ2000/000051 1999-07-29 2000-07-26 Revetement decoratif WO2001009051A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU61467/00A AU6146700A (en) 1999-07-29 2000-07-26 Decorative coating

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZPV2693-99 1999-07-29
CZ19992693A CZ287571B6 (cs) 1999-07-29 1999-07-29 Způsob vytváření dekorativního povlaku a dekorativně upravené sklo

Publications (1)

Publication Number Publication Date
WO2001009051A1 true WO2001009051A1 (fr) 2001-02-08

Family

ID=5465415

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CZ2000/000051 WO2001009051A1 (fr) 1999-07-29 2000-07-26 Revetement decoratif

Country Status (3)

Country Link
AU (1) AU6146700A (fr)
CZ (1) CZ287571B6 (fr)
WO (1) WO2001009051A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2876370A1 (fr) * 2004-10-11 2006-04-14 Saint Gobain Emballage Sa Procede de depot sur un verre sodocalcique comprenant une etape de fluoration prealable
WO2010103097A1 (fr) * 2009-03-12 2010-09-16 Centre National De La Recherche Scientifique (Cnrs) Decoration par pulverisation plasma magnetron sur des contenants en verre pour les secteurs de la cosmetique
US20110047175A1 (en) * 2004-04-21 2011-02-24 Kong Eng Cheng Querying Target Databases Using Reference Database Records
EP2097357B1 (fr) 2006-12-14 2018-01-10 Vitro, S.A.B. de C.V. Feuille non métallique enduite présentant un aspect de métal brossé

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63118066A (ja) * 1986-11-05 1988-05-23 Hitachi Ltd スパツタ装置
US5030503A (en) * 1989-09-01 1991-07-09 Ppg Industries, Inc. Reflective patterned glass product and coating method
US5135775A (en) * 1990-11-02 1992-08-04 Thyssen Edelstalhwerke Ag Process for plasma-chemical cleaning prior to pvd or pecvd coating
JPH09255367A (ja) * 1996-03-18 1997-09-30 Gunma Toobi:Kk 装飾ガラス容器とその装飾加工方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63118066A (ja) * 1986-11-05 1988-05-23 Hitachi Ltd スパツタ装置
US5030503A (en) * 1989-09-01 1991-07-09 Ppg Industries, Inc. Reflective patterned glass product and coating method
US5135775A (en) * 1990-11-02 1992-08-04 Thyssen Edelstalhwerke Ag Process for plasma-chemical cleaning prior to pvd or pecvd coating
JPH09255367A (ja) * 1996-03-18 1997-09-30 Gunma Toobi:Kk 装飾ガラス容器とその装飾加工方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 012, no. 365 (C - 532) 29 September 1988 (1988-09-29) *
PATENT ABSTRACTS OF JAPAN vol. 1998, no. 01 30 January 1998 (1998-01-30) *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110047175A1 (en) * 2004-04-21 2011-02-24 Kong Eng Cheng Querying Target Databases Using Reference Database Records
US8346794B2 (en) * 2004-04-21 2013-01-01 Tti Inventions C Llc Method and apparatus for querying target databases using reference database records by applying a set of reference-based mapping rules for matching input data queries from one of the plurality of sources
FR2876370A1 (fr) * 2004-10-11 2006-04-14 Saint Gobain Emballage Sa Procede de depot sur un verre sodocalcique comprenant une etape de fluoration prealable
WO2006040495A1 (fr) * 2004-10-11 2006-04-20 Saint-Gobain Emballage Procede de depot sur un verre sodocalcique comprenant une etape de fluoration prealable
EP2097357B1 (fr) 2006-12-14 2018-01-10 Vitro, S.A.B. de C.V. Feuille non métallique enduite présentant un aspect de métal brossé
WO2010103097A1 (fr) * 2009-03-12 2010-09-16 Centre National De La Recherche Scientifique (Cnrs) Decoration par pulverisation plasma magnetron sur des contenants en verre pour les secteurs de la cosmetique
FR2943072A1 (fr) * 2009-03-12 2010-09-17 Centre Nat Rech Scient Decoration par pulverisation plasma magnetron sur des contenants en verre pour les secteurs de la cosmetique.

Also Published As

Publication number Publication date
AU6146700A (en) 2001-02-19
CZ287571B6 (cs) 2000-12-13
CZ269399A3 (cs) 2000-09-13

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