WO2000054287A1 - Imprägniervergussmassen, ihre verwendung sowie ein verfahren zur imprägnierung von zündspulen - Google Patents
Imprägniervergussmassen, ihre verwendung sowie ein verfahren zur imprägnierung von zündspulen Download PDFInfo
- Publication number
- WO2000054287A1 WO2000054287A1 PCT/EP2000/000325 EP0000325W WO0054287A1 WO 2000054287 A1 WO2000054287 A1 WO 2000054287A1 EP 0000325 W EP0000325 W EP 0000325W WO 0054287 A1 WO0054287 A1 WO 0054287A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- impregnating
- range
- fillers
- compounds
- ignition coils
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/28—Coils; Windings; Conductive connections
- H01F27/32—Insulating of coils, windings, or parts thereof
- H01F27/327—Encapsulating or impregnating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F38/00—Adaptations of transformers or inductances for specific applications or functions
- H01F38/12—Ignition, e.g. for IC engines
Definitions
- Impregnating casting compounds, their use and a method for impregnating ignition coils are Impregnating casting compounds, their use and a method for impregnating ignition coils
- the invention relates to thermosetting casting compounds for impregnating electrical and electronic components.
- the components are overmolded with these materials.
- the masses are then hardened and protect the components from mechanical and chemical influences.
- epoxy resin-based compounds are preferred for this area of application.
- compositions accordingly contain one or more epoxy compounds with more than one epoxy group per molecule, hardener and generally 20 to 70% by weight of fine-grained fillers.
- the purpose of these fillers is to improve both the mechanical and electrical properties of the hardened masses and to reduce the shrinkage that occurs during hardening.
- DE-C 3229558 chalk is claimed as the optimal filler.
- EP-A 0348 193 and DE-C 42 06 733 also disclose fillers from the group consisting of aluminum or magnesium hydroxide, red phosphorus, dolomite, alumina, titanium dioxide, calcium silicates, aluminum silicates (clays), finely ground mica (mica) or glass powder, Flakes, fibers or whiskers.
- fillers have the same problems: if they are very fine, such as precipitated chalk or highly disperse silica, they impair the impregnability of the mass. If the fillers are coarse-grained, they sediment very easily, especially since epoxy compounds with low viscosity are used if possible. This creates inhomogeneities in the impregnation layer and cracks under mechanical or thermal loads.
- the object is achieved by impregnating casting compounds according to claims 1 to 5, by using the compositions for impregnating ignition coils according to claim 6 and by a method for impregnating ignition coils by impregnating with an impregnating casting compound according to claims 1 to 5.
- non-sedimenting, homogeneous impregnating casting compounds with a very good impregnating action are obtained if they contain an epoxy resin and hardener as binders and a filler mixture of one or more fillers from the group of calcium carbonate or dolomite and aluminum hydroxide.
- the masses can also other, conventional additives such as curing accelerators, adhesion promoters, reactive diluents, modifiers such.
- B. contain polyether polyols or silicones, wetting agents and pigments. These masses are used in a manner known per se to impregnate electrical or electronic components, in particular ignition coils. After casting the masses, which is preferably done under vacuum, the masses are hardened at elevated temperature. They then form a homogeneous coating with good chemical, mechanical and electrical properties and high resistance to temperature changes.
- the filler content of the compositions according to the invention is in the range from 10 to 70% by weight, preferably in the range from 50 to 60% by weight, based on the respective overall mixture.
- these fillers are a mixture of aluminum hydroxide and either calcium carbonate or dolomite or a mixture of calcium carbonate and dolomite in any ratio.
- the proportion of aluminum hydroxide is in the range from 5 to 30, preferably in the range from 10 to 20,% by weight, based on the total amount of the fillers.
- the fillers of the impregnating casting compounds according to the invention can also be present in the entire range of particle sizes from 0.01 to 100 ⁇ m.
- hardeners All compounds known for the curing of epoxy resins can be used as hardeners. Preference is given to latent epoxy resin hardeners which generally only lead to rapid hardening above a certain light-off temperature.
- latent epoxy resin hardeners which generally only lead to rapid hardening above a certain light-off temperature.
- the common representatives of these hardeners are dicarboxylic acid anhydrides, which may also be used
- Imidazole or alkyl-substituted imidazoles can be accelerated.
- hardeners are novolaks, especially novolaks which are liquid at temperatures in the range from 30-50 ° C., as are known from EP-B 0 248 980. These hardeners increase the toughness of the hardened impregnating compounds.
- Particularly preferred hardeners are metal complex compounds of the general
- L is a chelating ligand
- PHal is an ion of a pseudohalogen
- N is a nitrogen base
- x is a number in the range from 1 to 8
- y is a number in the range from 1 to 5
- z is a number in the range from 7 to 8
- m is a number in the range from 2 to 3
- n is a number in the range from 1 to 2.
- hardeners are known from EP-B 0518 908 and from an earlier application by the applicant (file number 198 48329.5). They have the advantages that they enable the production of storage-stable one-component systems in which there is almost no curing below the light-off temperature of the hardening reaction, that they are used without accelerators, have low light-off temperatures for the hardening reaction and lead to hardened products with high T g values.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00902601A EP1080474A1 (de) | 1999-03-10 | 2000-01-18 | Imprägniervergussmassen, ihre verwendung sowie ein verfahren zur imprägnierung von zündspulen |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19910711.4 | 1999-03-10 | ||
DE1999110711 DE19910711A1 (de) | 1999-03-10 | 1999-03-10 | Imprägniervergußmassen, ihre Verwendung sowie ein Verfahren zur Imprägnierung von Zündspulen |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000054287A1 true WO2000054287A1 (de) | 2000-09-14 |
Family
ID=7900503
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2000/000325 WO2000054287A1 (de) | 1999-03-10 | 2000-01-18 | Imprägniervergussmassen, ihre verwendung sowie ein verfahren zur imprägnierung von zündspulen |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1080474A1 (de) |
DE (1) | DE19910711A1 (de) |
TW (1) | TW573302B (de) |
WO (1) | WO2000054287A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10057111C1 (de) * | 2000-11-16 | 2002-04-11 | Bosch Gmbh Robert | Wärmeleitfähige Vergußmasse |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3317197C1 (de) * | 1983-05-11 | 1984-10-11 | SEMIKRON Gesellschaft für Gleichrichterbau u. Elektronik mbH, 8500 Nürnberg | Elektrisch isolierende Einkapselungsmasse für Halbleiterbauelemente |
US4923908A (en) * | 1988-10-14 | 1990-05-08 | Zenith Electronics Corporation | Epoxy compositions, and method of making same |
WO1991013925A1 (de) * | 1990-03-09 | 1991-09-19 | Rütgerswerke Aktiengesellschaft | Verfahren zur polymerisation von epoxidverbindungen |
EP0544618A1 (de) * | 1991-11-27 | 1993-06-02 | Ciba-Geigy Ag | Hochgefüllte Epoxid-Giessharzmassen |
JPH07286092A (ja) * | 1994-02-28 | 1995-10-31 | Shinko Electric Co Ltd | 無機フィラー沈降防止型注型樹脂組成物及びプレミックス組成物 |
WO1996001481A1 (en) * | 1994-07-01 | 1996-01-18 | Ciba Sc Holding Ag | Epoxy resin casting composition |
-
1999
- 1999-03-10 DE DE1999110711 patent/DE19910711A1/de not_active Withdrawn
-
2000
- 2000-01-18 EP EP00902601A patent/EP1080474A1/de not_active Ceased
- 2000-01-18 WO PCT/EP2000/000325 patent/WO2000054287A1/de not_active Application Discontinuation
- 2000-02-03 TW TW89101894A patent/TW573302B/zh active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3317197C1 (de) * | 1983-05-11 | 1984-10-11 | SEMIKRON Gesellschaft für Gleichrichterbau u. Elektronik mbH, 8500 Nürnberg | Elektrisch isolierende Einkapselungsmasse für Halbleiterbauelemente |
US4923908A (en) * | 1988-10-14 | 1990-05-08 | Zenith Electronics Corporation | Epoxy compositions, and method of making same |
WO1991013925A1 (de) * | 1990-03-09 | 1991-09-19 | Rütgerswerke Aktiengesellschaft | Verfahren zur polymerisation von epoxidverbindungen |
EP0544618A1 (de) * | 1991-11-27 | 1993-06-02 | Ciba-Geigy Ag | Hochgefüllte Epoxid-Giessharzmassen |
JPH07286092A (ja) * | 1994-02-28 | 1995-10-31 | Shinko Electric Co Ltd | 無機フィラー沈降防止型注型樹脂組成物及びプレミックス組成物 |
WO1996001481A1 (en) * | 1994-07-01 | 1996-01-18 | Ciba Sc Holding Ag | Epoxy resin casting composition |
Non-Patent Citations (1)
Title |
---|
CHEMICAL ABSTRACTS, vol. 124, no. 18, 29 April 1996, Columbus, Ohio, US; abstract no. 234025, YAMAMOTO, AKIRA ET AL: "Cast molding epoxy resin compositions without inorganic filler deposition and premixes therefor" XP002137420 * |
Also Published As
Publication number | Publication date |
---|---|
EP1080474A1 (de) | 2001-03-07 |
TW573302B (en) | 2004-01-21 |
DE19910711A1 (de) | 2000-09-14 |
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