Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J11/00—Recovery or working-up of waste materials
  • C08J11/04—Recovery or working-up of waste materials of polymers
  • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
  • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
  • C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
  • C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
  • C08G63/88—Post-polymerisation treatment
  • C08G63/90—Purification; Drying
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
  • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
  • Y02W30/00—Technologies for solid waste management
  • Y02W30/50—Reuse, recycling or recovery technologies
  • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

• the present invention is directed to a novel process for recycling post- consumer polyester.
• the process of the present invention involves depolymerization of the post-consumer polyester by way of glycolysis.
• Polyesters are used to form a wide variety of articles. In order to conserve resources and reduce the amount of pollution resulting from discarded polyester articles, it has become important to recycle discarded polyester articles. Polyester may be recycled by depolymerizing high molecular weight polyester into monomers and oligomers that are then repolymerized to an appropriate molecular weight for formation into new articles. Since discarded polyester may be contaminated with foreign materials, early polyester recycling efforts were geared toward producing relatively low-grade recycled products that do not require high purity polyester. An example of such low-grade product commonly made from recycled polyester is the "fiber fill" used in comforters, coats, pillows, and such. Polyester recycling technology has recently developed to include depolymerization and purification of discarded polyester waste to produce recycled polyester having high purity. High purity recycled polyester is required for sensitive uses such as producing containers for food use.
• Post-consumer polyester waste may contain a variety of foreign materials in addition to materials typically present in a polyester through polycondensation. Examples of such foreign materials include polyesters with different compositions, catalyst metals, colorants, other polymers such as polyvinyl chloride and polyethylene, aluminum, sand, paper, glue, and chemicals or residues absorbed from anything stored in the container. If post-consumer polyester is to be recycled for sensitive applications such as food containers, beverage containers, medical devices, and the like, it is critical that such contaminants are removed from the polyester.
• a method of recycling high molecular weight polyester, especially polyethylene terephthalate (“PET”) involves depolymerizing ground or crushed flakes of polyester via glycolysis. This process includes contacting the high molecular weight polyester with a glycol such as ethylene glycol to produce oligomers and/or monomers of the polyester. These materials are subsequently repolymerized as part of the preparation of new polyester articles. In the glycolysis of PET, the scrap PET is reacted with ethylene glycol, thus producing bis-(2- hydroxyethyl) terephthalate (“BHET”) and/or its oligomers.
• BHET bis-(2- hydroxyethyl) terephthalate
• Glycolysis is an especially useful reaction for depolymerizing PET due to the fact that the BHET produced can be used as a raw material for both dimethyl terephthalate (“DMT”)- based and terephthalic acid (“TPA”)- based PET production processes without major modification of the production facility.
• DMT dimethyl terephthalate
• TPA terephthalic acid
• U.S. Pat. No. 5,223,544 discloses a process whereby the foreign material present in post-consumer PET is removed by a process of first depolymerizing the polyester in a reactor via glycolysis to provide a mixture of PET oligomers, monomers, and various immiscible contaminants.
• the reaction mixture is then fed to an unstirred separation device whereby the contaminants are allowed to migrate away from the polyester on the basis of density, thereby forming an upper layer of low density contaminants, a middle layer of polyester material, and a lower layer of high density contaminants.
• the middle polyester layer is thereafter separated from the contaminants by being removed from the separation device through a draw-off pipe.
• the polyester depolymerization and purification process of the present invention includes the steps of contacting a contaminated polyester with an effective amount of a glycol to provide a molar ratio of greater than about 1 to about 5 total glycol units to total dicarboxylic acid units at a temperature between about 150 to about 300°C and an absolute pressure of about 0.5 to about 3 bars.
• This process is conducted in an agitated reactor vessel for a time sufficient to produce, in the reactor, an upper layer having a relatively low density contaminant floating above a lower layer of a depolymerized oligomer of the polyester.
• the process further includes separating the layers from each other by removing the upper layer from the reactor in a first stream and the second layer from the reactor in a second stream.
• the process of the present invention is a simpler and less expensive way of effectively removing contaminants from post-consumer polyester.
• separation of contaminants from polyester could be achieved under agitated glycolysis conditions, and that the lower density contaminants form a distinct upper layer in the reactor vessel that can be readily separated from the lower layer containing the remainder of the glycolysis reaction mixture.
• any immiscible contaminants which may have a relatively high density can be effectively removed by filtration or straining. This simple process requires less residence time in the vessel, fewer vessels and reduced costs, thereby producing less unwanted by-products.
• the depolymerization and purification process of the present invention comprises contacting a contaminated polyester with an amount of a glycol to provide a molar ratio of greater than about 1 to about 5 total glycol units to total dicarboxylic acid units at a temperature between about 150 to about 300°C and an absolute pressure of about 0.5 to about 3 bars in an agitated reactor vessel for a time sufficient to form, in the reactor, an upper layer of a relatively low density contaminant floating above a lower layer comprising a depolymerized oligomer of the polyester.
• oligomer includes both monomers and oligomers of polyester.
• the present process further includes the step of separating the upper and lower layers by removing the upper layer from the reactor in a first stream and removing the lower layer from the reactor in a second stream.
• the entire reaction mixture does not need to be transferred to a dedicated separation vessel.
• the process of the present invention is useful for recycling polyester.
• the present process is especially beneficial in recycling contaminated polyester which is used in packaging, preferably food packaging.
• polyesters are generally known in the art and may be formed from aromatic dicarboxylic acids, esters of aromatic dicarboxylic acids, glycol and mixtures thereof.
• the polyesters are formed from terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, dimethyl terephthalate, dimethyl isophthalate, and dimethyl-2,6- naphthalenedicarboxylate, ethylene glycol, diethylene glycol, cyclohexanedimethanol and mixtures thereof.
• terephthalic acid isophthalic acid
• 2,6-naphthalenedicarboxylic acid dimethyl terephthalate, dimethyl isophthalate
• dimethyl-2,6- naphthalenedicarboxylate ethylene glycol, diethylene glycol, cyclohexanedimethanol and mixtures thereof.
• PET polyethylene naphthalate
• PEN polyethylene naphthalate
• the dicarboxylic acid component of the polyester may contain up to about 50 mole % of one or more modifying dibasic acids.
• Such modifying dibasic acids include dicarboxylic acids preferably having from about 2 to about 40 carbon atoms, more preferably including aromatic dicarboxylic acids having about 8 to about 14 carbon atoms, aliphatic dicarboxylic acids having about 4 to about 12 carbon atoms, and cycloaliphatic dicarboxylic acids having about 8 to about 12 carbon atoms.
• Examples of modifying dibasic acids include terephthalic, isophthalic, adipic, glutaric, azelaic, sebacic, fumaric, cis- or trans- 1,4-cyclohexanedicarboxylic, the various isomers of naphthalene dicarboxylic acids and mixtures thereof.
• naphthalene dicarboxylic acids include the 2,6-, 1,4-, 1,5-, or 2,7- isomers but the 1,2-, 1,3-, 1,6-, 1,7-, 1,8-, 2,3-, 2,4-, 2,5-, and/or 2,8- isomers may also be used.
• the dibasic acids may be used in acid form or as their esters such as the dimethyl esters for example.
• the glycol component of the polyester may contain up to about 50 mole % of one or more modifying diols.
• Typical modifying glycols may contain from about 2 to about 10 carbon atoms and include ethylene glycol, propylene glycol, 1,3- propanediol, 1,4-butanediol, 1,6-hexanediol, diethylene glycol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, and the like.
• the 1,4-cyclohexanedimethanol may be in the cis or the trans form or as cis/trans mixtures.
• the post-consumer polyester treated by the depolymerization and purification process of the present invention contains contaminants that may have originated from manufacturing of the end article or from goods stored in or used with the polyester article.
• Contaminated polyester is defined herein as a polyester material containing, having attached thereto, or admixed with a substance that would be deleterious in the recycling or reuse of the polyester.
• the present process is especially useful for treating post-consumer polyester contaminated with substances such as polymers other than polyesters, particularly polymers of poly vinyl chloride and polyolefins. Examples of other contaminants effectively removed using the process of the invention include aluminum, sand, paper, glue, and chemicals absorbed and residues from materials stored in the container.
• post-consumer polyester articles are typically washed and ground into flakes or other particles suitable for rapid dissolution prior to being charged to the glycolysis reactor along with the glycol.
• the size of the polyester particle fed to the reactor is dependent on the reactor feed system. A system run at atmospheric pressure would have little limitation on the particle size.
• a preferable particle diameter of polyester charged to the reactor is less than about 1 inch.
• the present process can be conducted either as a continuous process or as a batch process.
• a continuous process typically includes the continual or intermittent charge of post- consumer polyester and glycol to the reactor vessel and the continuous or intermittent removal of a stream of the lower layer drained from the reactor.
• the polyester oligomer/monomer in the reactor serves as a solvent to dissolve the high molecular weight polyester flakes so that the glycolysis reaction proceeds at a reasonably rapid rate.
• Other examples of continuous processes which may be utilized in accordance with the present invention include co-current and counter-current extraction. Such processes are well known to those skilled in the separation art.
• a solvent may be charged to the reactor to dissolve the polyester flake. It is preferred to use an oligomer/monomer of the polyester as the only solvent.
• post-consumer polyester may contain catalysts which may be adequate to produce an oligomeric mixture at an acceptable rate
• transesterification catalysts known in the art such as salts of Mn, Zn, Sb, Ti, Sn, or Ge may be included to increase the rate of glycolysis.
• glycolysis reaction will proceed with most glycols (diprotic alcohols).
• glycols diprotic alcohols
• the glycol used in the glycolysis reaction should be substantially the same glycol upon which the diol component of the post-consumer polyester is based. Therefore, in the preferred process wherein either PET homopolymer or PET copolymer wherein PET is modified as described above with only a minor amount of modifying acid and/or diol units, ethylene glycol, including mixtures thereof, is the preferable glycol for glycolysis.
• the post-consumer polyester and glycol are introduced into the glycolysis reactor in amounts sufficient to provide a molar ratio of from greater than about 1 to about 5 total glycol units to total dicarboxylic acid units, preferably a molar ratio of from about 1.5 to about 2.5.
• the total glycol units include the glycol units incorporated in the post-consumer polyester as well as the glycol charged to the reactor for glycolysis.
• the proper molar ratio range of glycol to post- consumer polyester is important so that the viscosity of the resulting reaction mixture allows for migration of the lower density contaminants away from the polyester mixture.
• the viscosity of the reaction mixture should be less than about 1,000 poise, preferably less than about 100 poise, with a viscosity less than about 50 poise being more preferable.
• the glycolysis reaction of the present process should be conducted at a temperature between about 150 to about 300°C, preferably between about 190 and about 250°C.
• the reaction time should be sufficient to produce an oligomeric material, usually from about 10 minutes to about 4 hours. It is a critical aspect of the present invention that the low-density contaminants released from the post-consumer polyester during glycolysis be separated from the polyester while still in the reactor, even while maintaining an agitation rate acceptable for promoting glycolysis in the reactor.
• the reactor agitator is preferably operated to produce a turbulent flow in the reactor.
• the low-density materials floating on the surface of the reaction mixture can be continuously or intermittently pulled off of the lower layer by means such as siphoning, vacuuming, absorbing or skimming the upper layer of contaminants off of the relatively high density layer of polyester and/or oligomer.
• the build up of low- density contaminant materials is small, it may be sufficient to allow an upper layer of low-density contaminants to accumulate until the reaction is stopped. At which point, all of the lower polyester-containing layer would be drained, leaving only the upper layer of low-density contaminants in the reactor to be separately removed from the reactor.
• the process of the present invention is preferably conducted as a continuous process wherein at least a portion or stream of the upper layer is continuously or at least intermittently removed from the reactor and a stream of the lower layer intermittently or continuously flows out of the reactor, preferably to a filtration area where solid and relatively high density contaminants are filtered out of the polyester and/oligomers.
• the process of the present invention may be used to recycle PET contaminated with a polyolefin such as low density polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene (HDPE), and ultra-high density polyethylene (UHDPE), and polyvinyls such as polyvinyl chloride (PNC) and polyvinylidene chloride (PVDC).
• LDPE low density polyethylene
• LLDPE linear low density polyethylene
• HDPE high density polyethylene
• UHDPE ultra-high density polyethylene
• PNC polyvinyl chloride
• PVDC polyvinylidene chloride
• the process of the present invention is conducted continuously and polyester and glycol are continuously fed into a stirred reactor, or extraction vessels, and a stream of polyester material is continuously withdrawn out of the bottom of the reactor, a flake of post-consumer polyester may occasionally get channeled through the reactor without sufficient contact time to depolymerize or dissolve. In such case, the flake would be filtered out of the polyester material along with the high-density contaminants.
• the discharge pipe connecting the lower layer discharge point of the reactor with the filtration area be long enough to provide a sufficient residence time to assure dissolution of all post-consumer polyester. Residence time in the pipe is preferably from less than about 1 minute up to about 60 minutes, and more preferably between about 1 minute to about 30 minutes.
• Another optional step following separation of the upper layer from the lower layer is the batchwise treatment of the lower layer with from about 0.0001 to about 2 parts of an adsorbent per part of product or continuously over a bed of adsorbent with an empty tube residence time of about 0.01 to about 2 hours.
• Suitable adsorbents include activated carbon, activated clay, silica, and alumina and mixtures thereof, with activated carbon being preferred.
• the depolymerization process of the present invention unexpectedly produces a monomer/oligomer mixture of suitable quality for introduction into a process for the production of high quality polyesters.
• the major contaminants in the scrap are removed through filtration, floatation, volatilization, or thermal destruction during the process.
• Containers formed from post-consumer polyester recycled according to the process of the present invention are suitable for food contact.
• the monomer/oligomer mixture recovered from the lower layer of the glycolysis reactor may optionally be introduced into a second reactor.
• excess glycol may be removed from the monomer/oligomer mixture to give the desired degree of polymerization for a product suitable for use as a reactant in repolymerization. Adjustment of the pressure or temperature of the reactor is among the means to control the removal of glycol.
• the final purified monomer/oligomer product of the process of the present invention may be stored or transported as a liquid in a heated (if necessary) container. Alternately, it may be solidified by cooling, grinding, and storing and transporting as a solid. The product may be introduced into a polyester production process for repolymerization.
• Such processes are well known in the art, and include esterification of dicarboxylic acid(s) or transesterification of esters of dicarboxylic acid(s) with diol(s) followed by polycondensation under reduced pressure.
• the monomer/oligomer product of the process of the present invention can be fed at any desired point in the polyester manufacturing process. Feed rates of the glycolysis product and a virgin raw material cab be adjusted to give a product containing from less than about 1% to 100% post-consumer recycle content polyester. It may further be desirable to add a colorant to the polyester production process to improve the color of the polyester containing post-consumer recycle content.
• the scrap primarily contained clear PET.
• a 1:1 molar ratio of ethylene glycol to post-consumer PET (based on repeat unit) were fed to a glycolysis reactor to provide a total glycol units to total carboxylic acid units of about 2 to 1.
• the reactants were charge to the reactor at a rate of 32 pounds of PET per hour.
• the reactor was run at 230 °C and atmospheric pressure.
• the batch residence time was about 65 minutes.
• the lower layer of the reaction mixture was transferred through a pipe allowing a residence time of about 20 minutes, and was filtered through a 40-mesh strainer.
• the depolymerized PET was fed to a first reactor in a DMT-based PET production process at a ratio of one part recycle per three parts DMT, based on moles of terephthalate.
• Post-consumer PET was intentionally spiked with 1000 ppm (by weight) of four contaminants: lindane, diazinon, toluene, and chloroform. These compounds represent nonvolatile nonpolar, nonvolatile polar, volatile nonpolar, and volatile polar substances, respectively. It is unlikely that commercial quantities of post-consumer PET would contain as much as 1,000 ppm of any such contaminant.
• the contaminated post-consumer PET was depolymerized via glycolysis, and fed to a PET production process to make 100% recycle content PET as described in this invention. The resulting PET was analyzed for the contaminants. The PET was found to contain less than 0.100 ppm of each of these materials. This very efficient removal of contaminants indicates that the process described in this invention produces PET safe for food contact.
• Example 1 The continuous process in Example 1 was used to produce PET with 25% content from manufacturing scrap (the scrap was not contaminated). Process conditions and catalyst additives were as in Example 1. High-density polyethylene was added (110 grams) as a contaminant to the manufacturing scrap being fed to the process. After conducting the continuous process for forty-eight hours without removing any of the upper layer from the reactor, the process was stopped, the lower layer was drained, and the upper layer was removed from the glycolysis reactor. The upper layer contained 108 g of polyethylene. No polyethylene was detected in the lower layer PET product. This illustrates that very good separation of the low density contaminants from polyester is attained in the process of the present invention, even when the low density contaminants are allowed to build up under the agitated reactor conditions for a long period of time. Modifications of this invention will be readily apparent to those skilled in the art and it is intended that all such modifications be included within the scope of the appended claims.

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• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Life Sciences & Earth Sciences (AREA)
• Sustainable Development (AREA)
• Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
• Polyesters Or Polycarbonates (AREA)
• Saccharide Compounds (AREA)

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• 2000
  • 2000-01-05 US US09/478,018 patent/US6410607B1/en not_active Expired - Fee Related
  • 2000-02-04 JP JP2000598569A patent/JP4531988B2/ja not_active Expired - Fee Related
  • 2000-02-04 ES ES00907128T patent/ES2179021T3/es not_active Expired - Lifetime
  • 2000-02-04 EP EP20000907128 patent/EP1153070B1/en not_active Expired - Lifetime
  • 2000-02-04 BR BR0008127A patent/BR0008127A/pt active Search and Examination
  • 2000-02-04 CN CNB008036276A patent/CN1149254C/zh not_active Expired - Fee Related
  • 2000-02-04 DE DE60000414T patent/DE60000414T2/de not_active Expired - Lifetime
  • 2000-02-04 AT AT00907128T patent/ATE223456T1/de not_active IP Right Cessation
  • 2000-02-04 WO PCT/US2000/002813 patent/WO2000047659A1/en not_active Ceased
  • 2000-02-04 CA CA 2359727 patent/CA2359727C/en not_active Expired - Fee Related

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