WO1999039187A1 - Procede et appareil de diagnostic de la deterioration des carburants - Google Patents
Procede et appareil de diagnostic de la deterioration des carburants Download PDFInfo
- Publication number
- WO1999039187A1 WO1999039187A1 PCT/JP1998/000427 JP9800427W WO9939187A1 WO 1999039187 A1 WO1999039187 A1 WO 1999039187A1 JP 9800427 W JP9800427 W JP 9800427W WO 9939187 A1 WO9939187 A1 WO 9939187A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- light
- oil
- deterioration
- transmission loss
- light transmission
- Prior art date
Links
- 230000006866 deterioration Effects 0.000 title claims abstract description 50
- 238000003745 diagnosis Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 10
- 230000005540 biological transmission Effects 0.000 claims abstract description 56
- 239000004065 semiconductor Substances 0.000 claims description 6
- 230000003287 optical effect Effects 0.000 abstract description 12
- 230000008859 change Effects 0.000 abstract description 10
- 239000003921 oil Substances 0.000 description 39
- 238000001228 spectrum Methods 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000010705 motor oil Substances 0.000 description 9
- 238000007689 inspection Methods 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000013307 optical fiber Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005375 photometry Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 210000000689 upper leg Anatomy 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/85—Investigating moving fluids or granular solids
- G01N21/8507—Probe photometers, i.e. with optical measuring part dipped into fluid sample
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/314—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
- G01N21/3151—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths using two sources of radiation of different wavelengths
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3577—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing liquids, e.g. polluted water
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/359—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2888—Lubricating oil characteristics, e.g. deterioration
Definitions
- the present invention relates to a method and an apparatus for diagnosing oil deterioration of an automobile engine, a compressor, a gear and the like.
- the optical sensor described above has a problem that the detection output of the optical sensor greatly fluctuates in response to a change in the temperature of the engine oil, which greatly changes depending on the operating condition of the engine.
- the two-wavelength diagnosis using visible light there was a problem that accurate judgment could not be made due to the influence of the color of the initial oil which was different due to the influence of various additives.
- An object of the present invention is to solve the above-mentioned problems and to provide an optical oil deterioration diagnosis method and apparatus which are not affected by a temperature change or an initial oil color. Disclosure of the invention
- the present inventors have studied the relationship between the degree of deterioration of oil in automobile engines and the like and the light transmission loss spectrum characteristics per unit length in the near infrared region, and found that the near infrared short wavelength side light The slope of the transmission loss spectrum and the light transmission on the near-infrared long wavelength side
- the present inventors have found that the increase in the baseline of the excess loss spectrum has a correlation with the values of the sludge amount (insoluble component amount), the kinematic viscosity, and the total acid value, and have reached the present invention. That is, the gist of the present invention is as follows.
- the irradiation light from at least two kinds of monochromatic light sources having different wavelengths is guided into the oil using the irradiation light guide, and the emission light from the irradiation light guide is transmitted through the oil at the transmission distance a. After passing through the light, it is incident on the light receiving light guide installed opposite to the light guide, then guided to the light receiving part, and the light transmission loss per unit length in the control and calculation part
- An oil deterioration diagnosis method and apparatus characterized in that the degree of deterioration is determined by comparing and calculating the relationship with the difference (master one curve).
- a semiconductor laser (LD) or a light emitting diode (LED) having a peak wavelength of 800 nm or more and 150 nm or less is easily available and has a long life and high performance. Stable and suitable. In particular, LEDs such as 800, 820, 830, 850, 940, 950, 1300, 1310, 1550111111, and the like are preferable. is there. With a light source having a wavelength outside the above range, the photodetector in the light receiving unit may have an overrange while the degree of oil deterioration is relatively small, and photometry may not be possible.
- the light guide for irradiation is installed in an oil level gauge of an automobile engine, it is not necessary to make a major change to a conventional engine system.
- the results can be displayed on the meter panel in the car as an alarm as part of the self-check function, or as part of the daily inspection imposed on the driver by installing a display plate on the grip part above the level gauge. It does not matter if you use it.
- the degree of deterioration of automobile engine oil and the light transmission loss spectrum per unit length in the near infrared region are represented by changes as shown in FIG.
- the light transmission loss spectrum is not affected by the measurement temperature, the same value can be obtained during the start-up inspection before operation and during the operation.
- the light transmission loss in the visible region shows a remarkable increase with deterioration, so the oil turns black, and the photodetector in the light receiving section becomes overrange while the progress of deterioration is relatively small. I will. Therefore, as a result of the examination, it was concluded that the evaluation using visible light was not suitable for oil deterioration.
- This increase in spectrum from the short wavelength side is mainly due to an increase in electron transition absorption loss due to thermal oxidation degradation.
- looking at the difference in light transmission loss between the two wavelengths the slope between A and A 'in the beginning, the slope between B and B'
- Fig. 4 shows the light transmission loss spectrum of the actual engine oil and the initial product (new oil) 14 with different usage conditions, but the four types shown here are affected by the additives.
- the initial oil has a different color, but in the region above 700 nm, the light transmission loss spectrum shows exactly the same value.
- the use of near-infrared light enables diagnosis without being affected by different types of oil.
- Fig. 9 shows the relationship between the light transmission loss at 1310 nm and the kinematic viscosity at 40 ° C of engine oil of various actual vehicles with different mileage, vehicle type, and usage conditions.
- Fig. 10 shows the relationship between the light transmission loss difference between 9500 nm and 1310 ⁇ m and the total acid value
- Fig. 11 similarly shows the light transmission loss at 1310 nm.
- the figure which shows the relationship between a transmission loss and a pentane insoluble matter is shown. It can be seen that each parameter has a good correlation with light transmission loss and light transmission loss difference.
- the degree of deterioration is generally represented by a conversion time ⁇ ⁇ .
- the conversion time ⁇ is defined by equation (1).
- ⁇ E the apparent activation energy of degradation (JZmol)
- R is the gas constant
- JZKZmol T is the absolute temperature of degradation (K)
- t is the deterioration time (h)
- Oil degradation ⁇ E can be easily calculated by the Arrhenius plot, and the conversion time at the oil life point obtained in advance is ⁇ .
- the difference ⁇ 0 from the conversion time 0 is the conversion time corresponding to the remaining life, and serves as a measure of the degree of deterioration determination, that is, the remaining life ⁇ ⁇ (h) is expressed by equation (2).
- Fig. 1 is a schematic diagram showing an application form of an oil deterioration diagnosis system for an automobile engine. Expression diagram.
- Figure 2 shows the internal structure of the optical sensor in the level gauge.
- Fig. 3 shows the change in the light transmission loss spectrum due to deterioration of the engine oil
- Fig. 4 shows the light transmission loss spectrum of the actual engine oil and the new oil in various usage situations.
- Fig. 5 shows an example of a diagnostic master curve with light transmission loss difference as a parameter.
- ⁇ Fig. 6 shows an example of a diagnostic master curve with light transmission loss as a parameter.
- Fig. 7 is a flowchart of a diagnosis for judging the degree of oil deterioration.
- Fig. 8 shows the internal structure of the optical sensor in the level gauge.
- Fig. 9 shows the relationship between light transmission loss and kinematic viscosity of actual engine oils in various usage situations.
- Fig. 10 shows the relationship between the light transmission loss and the total acid value of actual engine oils in various usage situations.
- Fig. 11 shows the relationship between the light transmission loss and the pentane-insoluble content of actual engine oils in various usage situations.
- Fig. 12 shows an example of a level gauge grip display type sensor.
- FIG. 1 is a schematic diagram showing an application form of an oil deterioration diagnosis device for an automobile engine.
- Fig. 7 shows a flowchart for calculating the degree of deterioration.
- the control / calculation unit 7 consists of a microprocessor with a built-in memory for storing measurement data and a read-only memory. Performs wavelength switching, received light intensity measurement, and calculations. In the present embodiment, description will be made on an apparatus using two wavelengths.
- LED light-emitting diode
- LD semiconductor laser
- the incident light 11 from the ⁇ 1 force passes through the optical fiber cable 4 and is guided to the level gauge 3.
- the level gauge 3 has an internal structure as shown in Fig. 2, and the incident light 11 passes through the light guide 15 formed in the level gauge 3 and is reflected by the mirror 10 Change the traveling direction of the optical path and reach slit 13.
- the slit 13 has a light path length of 1.0, which is set to the thigh, and is variable from 0.5 to 2.Omin.
- the transmitted light 12 After passing through the oil fill 1 filled in the slit, the transmitted light 12 re-enters the opposing light guide 15 and is guided to the light receiving unit 6.
- the transmitted light intensity at ⁇ 1 is detected by the light receiving unit 6, and calculated and stored as the light transmission loss by the control and calculation unit 7.
- the transmitted light intensity with respect to the incident light 11 from ⁇ 2 is measured, and the control / calculation unit 7 calculates and stores it as the light transmission loss of ⁇ 2.
- the control / calculation unit 7 the deterioration of the oil from the stored relationship between the oil deterioration and the light transmission loss and the light transmission loss difference (master curve) as shown in FIGS. 5 and 6 is shown.
- the degree is calculated as the conversion time, and the result is displayed on the warning light installed inside the vehicle.
- This inspection is a system that operates as a self-check function after the engine is started.
- the level gauge 3 having the internal structure shown in FIG. 8 is used in the same manner as in the first embodiment.
- the reference light quantity (I ..,.) Of each light source wavelength was measured.
- the incident light 11 from ⁇ 1 passes through the optical fiber cable 4 and is guided to the level gauge 3.
- the level gauge 3 has an internal structure as shown in FIG. 2, and the incident light 11 transmits through the light guide 15 formed in the level gauge 3 and is reflected by the mirror 10. Change the traveling direction of the optical path, and
- the slit 13 has an optical path length of 0.5 nim in this embodiment. After passing through oil 1 filled in the slit, the transmitted light
- the light 12 enters the light guide 15 placed opposite to the light guide 15 again, and is guided to the light receiving unit 6.
- the transmitted light intensity at ⁇ 1 is detected by the light receiving unit 6, and calculated and stored as the light transmission loss by the control and calculation unit 7.
- the transmitted light intensity with respect to the incident light 11 from ⁇ 2 is measured, and the control / calculation unit 7 calculates and stores it as the light transmission loss of ⁇ 2.
- the control / calculation unit 7 determines the degree of oil deterioration from the relationship diagram (master curve) between the oil deterioration and the light transmission loss and the light transmission loss difference stored in advance as shown in FIGS. 5 and 6. It is calculated as the conversion time, and the result is displayed on the warning light installed in the vehicle.
- This inspection is a system that operates as a self-check function after the engine is started.
- the level gauge 3 having the internal structure shown in FIG. 8 is used in the same manner as in the first embodiment.
- the reference light amounts (I., J) of each light source wavelength are measured.
- the incident light 11 from ⁇ 1 passes through the optical fiber cable 4 and is guided to the level gauge 3.
- the level gauge 3 is the second
- the incident light 11 transmits through the light guide 15 formed in the level gauge 3 and is reflected by the mirror 10 to change the traveling direction of the optical path, as shown in the figure.
- the slit 13 has an optical path length of 1.5 mm in this embodiment.
- the transmitted light 12 After passing through the oil 1 filled in the slit, the transmitted light 12 reenters the opposing light guide 15 and is guided to the light receiving section 6.
- the transmitted light intensity at ⁇ 1 is detected by the light receiving unit 6, and calculated and stored as the light transmission loss by the control and calculation unit 7.
- the transmitted light intensity with respect to the incident light 11 from ⁇ 2 is measured, and the control / calculation unit 7 calculates and stores it as the light transmission loss of f 2.
- the control / calculation unit 7 the deterioration of the oil from the stored relationship between the oil deterioration and the light transmission loss and the difference in the light transmission loss (master one curve) as shown in FIGS.
- the degree is calculated as the conversion time, and the result is displayed on the warning light installed inside the vehicle.
- This inspection is a system that operates as a self-check function after the engine is started.
- Example 4 In the same system as in Example 1, an example was shown in which the result display was displayed on a display plate installed on a grip portion above the level gauge shown in FIG. This inspection will be used as part of the daily inspections imposed on the driver before driving.
- the degree of deterioration of oil used in an automobile engine, a compressor, a gear, and the like can be diagnosed without being affected by the measured temperature or the initial oil color.
- a diagnostic device that can be operated as an on-board type or a portable type.
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- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Physics & Mathematics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Toxicology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN98801011A CN1239546A (zh) | 1998-02-02 | 1998-02-02 | 油变质诊断方法和装置 |
EP98901092A EP1054251A4 (en) | 1998-02-02 | 1998-02-02 | METHOD AND APPARATUS FOR DIAGNOSING FUEL DETERIORATION |
PCT/JP1998/000427 WO1999039187A1 (fr) | 1998-02-02 | 1998-02-02 | Procede et appareil de diagnostic de la deterioration des carburants |
US09/974,887 US20020069021A1 (en) | 1998-02-02 | 2001-10-12 | Automobile oil deterioration diagnosing apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP1998/000427 WO1999039187A1 (fr) | 1998-02-02 | 1998-02-02 | Procede et appareil de diagnostic de la deterioration des carburants |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09269108 A-371-Of-International | 1999-03-19 | ||
US09/974,887 Continuation US20020069021A1 (en) | 1998-02-02 | 2001-10-12 | Automobile oil deterioration diagnosing apparatus |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999039187A1 true WO1999039187A1 (fr) | 1999-08-05 |
Family
ID=14207531
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1998/000427 WO1999039187A1 (fr) | 1998-02-02 | 1998-02-02 | Procede et appareil de diagnostic de la deterioration des carburants |
Country Status (4)
Country | Link |
---|---|
US (1) | US20020069021A1 (ja) |
EP (1) | EP1054251A4 (ja) |
CN (1) | CN1239546A (ja) |
WO (1) | WO1999039187A1 (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10105793B4 (de) * | 2001-02-07 | 2010-03-04 | Iav Gmbh Ingenieurgesellschaft Auto Und Verkehr | Verfahren zur Bewertung der Schmierstoffqualität |
US7339657B2 (en) * | 2001-10-11 | 2008-03-04 | Sentelligence, Inc. | Low-cost on-line and in-line spectral sensors based on solid-state source and detectors combinations for monitoring lubricants and functional fluids |
DE10325537B4 (de) | 2003-06-04 | 2006-08-17 | Fuchs Petrolub Ag | Vorrichtung und Verfahren zum automatischen Detektieren von wenigstens einem in einem flüssigen Betriebsstoff enthaltenen fluoreszierenden und/oder lichtabsorbierenden Indikator während des Einfüllvorgangs des Betriebsstoffs in eine Maschine |
US7459713B2 (en) | 2003-08-14 | 2008-12-02 | Microptix Technologies, Llc | Integrated sensing system approach for handheld spectral measurements having a disposable sample handling apparatus |
FR2888323B1 (fr) * | 2005-07-05 | 2008-07-18 | Peugeot Citroen Automobiles Sa | Procede d'evaluation d'un melange de produits petroliers et de biocarburants |
FR2888326B1 (fr) * | 2005-07-05 | 2007-10-05 | Peugeot Citroen Automobiles Sa | Procede d'evaluation du vieillissement d'une huile moteur |
FI20065575A0 (fi) * | 2006-09-20 | 2006-09-20 | Moventas Oy | Menetelmä ja laite voiteluöljyn kunnon valvomiseksi |
DE102006060138B4 (de) * | 2006-12-18 | 2009-01-22 | Airbus France | Online-Sensor zum Überwachen chemischer Verunreinigungen in hydraulischen Flüssigkeiten |
FR2940448B1 (fr) * | 2008-12-23 | 2011-10-14 | Continental Automotive France | Guide d'onde perfectionne et spectrometre associe embarque dans un vehicule automobile |
KR101356176B1 (ko) * | 2011-08-30 | 2014-01-28 | 한국화학연구원 | 엔진오일열화 감지방법 및 시스템 |
CN108931502B (zh) * | 2018-06-01 | 2020-09-08 | 西安交通大学 | 红外点状激光发射器在线监测润滑脂衰变程度系统及方法 |
JP2022078595A (ja) * | 2020-11-13 | 2022-05-25 | 日本ピラー工業株式会社 | 液体センサ |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62180753U (ja) * | 1986-05-08 | 1987-11-17 | ||
JPH02236440A (ja) * | 1989-03-10 | 1990-09-19 | Komatsu Ltd | 潤滑油の劣化検出方法及び装置 |
JPH0249644B2 (ja) * | 1983-02-08 | 1990-10-30 | Tokyo Tatsuno Kk | |
JPH0712723A (ja) * | 1992-09-30 | 1995-01-17 | Mitsubishi Heavy Ind Ltd | 潤滑油劣化度測定装置 |
JPH07140074A (ja) * | 1993-11-18 | 1995-06-02 | Hitachi Ltd | 機器の劣化監視システム |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3829217A (en) * | 1971-05-19 | 1974-08-13 | C Johnson | Oil condition indicator |
US4637729A (en) * | 1983-12-14 | 1987-01-20 | Carrier Corporation | Fiber optic moisture analysis probe |
JPH0249141A (ja) * | 1988-05-09 | 1990-02-19 | Cosmo Oil Co Ltd | スラッジ濃度迅速定量方法および装置 |
US5049742A (en) * | 1989-11-16 | 1991-09-17 | Kyodo Oil Technical Research Co., Ltd. | Apparatus for detecting deterioration of engine oil |
US5194910A (en) * | 1990-07-31 | 1993-03-16 | Gas Research Institute | Use of optical spectrometry to evaluate the condition of used motor oil |
US5404015A (en) * | 1993-09-21 | 1995-04-04 | Exxon Research & Engineering Co. | Method and system for controlling and optimizing isomerization processes |
JP2963346B2 (ja) * | 1994-08-22 | 1999-10-18 | 株式会社ジャパンエナジー | 潤滑油の劣化検知方法 |
TW343281B (en) * | 1996-06-28 | 1998-10-21 | Hitachi Ltd | Method and apparatus for diagnosing degradation of an electric machine |
-
1998
- 1998-02-02 WO PCT/JP1998/000427 patent/WO1999039187A1/ja not_active Application Discontinuation
- 1998-02-02 EP EP98901092A patent/EP1054251A4/en not_active Withdrawn
- 1998-02-02 CN CN98801011A patent/CN1239546A/zh active Pending
-
2001
- 2001-10-12 US US09/974,887 patent/US20020069021A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0249644B2 (ja) * | 1983-02-08 | 1990-10-30 | Tokyo Tatsuno Kk | |
JPS62180753U (ja) * | 1986-05-08 | 1987-11-17 | ||
JPH02236440A (ja) * | 1989-03-10 | 1990-09-19 | Komatsu Ltd | 潤滑油の劣化検出方法及び装置 |
JPH0712723A (ja) * | 1992-09-30 | 1995-01-17 | Mitsubishi Heavy Ind Ltd | 潤滑油劣化度測定装置 |
JPH07140074A (ja) * | 1993-11-18 | 1995-06-02 | Hitachi Ltd | 機器の劣化監視システム |
Non-Patent Citations (1)
Title |
---|
See also references of EP1054251A4 * |
Also Published As
Publication number | Publication date |
---|---|
EP1054251A1 (en) | 2000-11-22 |
EP1054251A4 (en) | 2001-05-02 |
CN1239546A (zh) | 1999-12-22 |
US20020069021A1 (en) | 2002-06-06 |
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