WO1999009937A1 - Composition pour baton cosmetique hydratant - Google Patents

Composition pour baton cosmetique hydratant Download PDF

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Publication number
WO1999009937A1
WO1999009937A1 PCT/US1998/017664 US9817664W WO9909937A1 WO 1999009937 A1 WO1999009937 A1 WO 1999009937A1 US 9817664 W US9817664 W US 9817664W WO 9909937 A1 WO9909937 A1 WO 9909937A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
weight
nonvolatile
straight
branched chain
Prior art date
Application number
PCT/US1998/017664
Other languages
English (en)
Inventor
Joseph F. Calello
Janet E. Opel
Renee J. Ordino
Robert W. Sandewicz
Natividad R. Jose
Original Assignee
Revlon Consumer Products Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Revlon Consumer Products Corporation filed Critical Revlon Consumer Products Corporation
Priority to AU90352/98A priority Critical patent/AU9035298A/en
Priority to CA002301944A priority patent/CA2301944A1/fr
Priority to EP98942252A priority patent/EP1009364A1/fr
Publication of WO1999009937A1 publication Critical patent/WO1999009937A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00—Drug, bio-affecting and body treating compositions
    • Y10S424/05—Stick

Definitions

  • the invention is in the field of color cosmetic stick compositions such as lipstick,
  • Colored cosmetic stick compositions are most often anhydrous. They are formulated
  • moisturizing lipsticks should provide excellent color, shine,
  • Lipsticks with moisturizing properties generally contain high
  • oils tend to form a superficial layer on the lips and rubs off very easily. Water is often
  • the object of the invention is to formulate long wearing colored cosmetic stick
  • compositions which moisturize the skin and lips.
  • the object of the invention is to formulate long wearing colored cosmetic stick
  • compositions which provide shiny finish and good slip on application.
  • Another object of the invention is to formulate colored cosmetic sticks that exhibit
  • the cooling is achieved without including ingredients such as menthol in the formula.
  • the invention is directed to pigmented cosmetic stick compositions comprising, by:
  • a first nonvolatile oil which is a C 16 . 2 fatty ester of citric acid
  • stick refers to cosmetic compositions having a consistency such that they
  • compositions of the invention that are capable of being formed into sticks, but are poured into
  • pans or other types of cake or cream forms to deliver certain consumer benefits.
  • cake or cream forms to deliver certain consumer benefits.
  • an eyeshadow composition in accordance with the invention may be molded in the stick form
  • the colored cosmetic stick composition of the invention comprises 1-40%, preferably
  • volatile means that the
  • solvent has a vapor pressure of at least 2 mm. of mercury at 20° C.
  • volatile solvent is preferably 0.5 to 5 centipoise at 25° C.
  • volatile solvents include
  • volatile low viscosity silicone fluids such as cyclic silicones having the formula:
  • Volatile linear polydimethylsiloxanes are also suitable and generally have
  • octamethylcyclotetrasiloxane decamethylcyclopentasiloxane, hexamethyldisiloxane, or
  • volatile solvent component straight or branched chain
  • paraffinic hydrocarbons having 5-20 carbon atoms, more preferably 10-16 carbon atoms.
  • Suitable hydrocarbons are pentane. hexane. heptane, decane, dodecane, tetradecane,
  • hydrocarbons have a molecular weight of 70 to 190, more preferably 160-180. and a boiling
  • paraffinic hydrocarbons are available from EXXON under the
  • ISOPAR trademark as ISOPAR A, B, C, D, E, G, H, K, L, and M. Similar paraffinic
  • hydrocarbons are also available from Shell Oil under the Shellsol trademark, in particular
  • Shellsol 71 and from Phillips Petroleum under the tradename Solutrol 100, 130, and 220.
  • paraffinic hydrocarbons may be purchased from Permethyl Corporation under
  • the volatile solvent may be a mixture of volatile silicone and paraffinic hydrocarbons
  • the cosmetic stick compositions of the invention contain 20-80%, preferably 25-75%,
  • a first nonvolatile oil which is a C 12 . 22 fatty ester of
  • the fatty ester of citric acid is formed by the reaction of a C 12 . 22 fatty
  • citric acid alcohol with citric acid.
  • One, two, or three carboxylic acid groups of the citric acid may be
  • the fatty acid ester of citric acid generally exhibits the following generic formula:
  • R,, R 2 , and R 3 are each independently H, or a C 12 . 22 , preferably a C I6 . 22 alkyl. more
  • R,, R 2 . and R 3 are each a C 16 . 22 alkyl, preferably isostearyl and the
  • the cosmetic stick compositions of the invention contain 1-30%, preferably 2-25%,
  • nonvolatile means that the oil
  • oils are also suitable for use in the cosmetic sticks of the invention.
  • the nonvolatile oils are also suitable for use in the cosmetic sticks of the invention.
  • the nonvolatile oils are also suitable for use in the cosmetic sticks of the invention.
  • esters include isotridecyl isononanoate, PEG-4
  • diheptanoate isostearyl neopentanoate, tridecyl neopentanoate, cetyl octanoate, cetyl palmitate,
  • cetyl ricinoleate cetyl stearate, cetyl myristate, coco-dicaprylate/caprate, decyl isostearate,
  • the oil may also comprise naturally occuring glyceryl esters of fatty acids, or
  • triglycerides Both vegetable and animal sources may be used. Examples of such oils include
  • castor oil castor oil.
  • lanolin oil triisocetyl citrate, C I0 . lg triglycerides, caprylic/capric/triglycerides. coconut
  • soybean oil sunflower seed oil, walnut oil, and the like.
  • glyceryl esters e.g. fatty acid
  • acetylated castor oil glyceryl stearate, glyceryl dioleate, glyceryl distearate, glyceryl trioctanoate.
  • glyceryl distearate glyceryl linoleate, glyceryl myristate, glyceryl isostearate, PEG castor oils,
  • PEG glyceryl oleates PEG glyceryl stearates, PEG glyceryl tallowates, and so on.
  • nonvolatile hydrocarbons such as isoparaffins, hydrogenated
  • polyisobutene polyisobutene, mineral oil, squalene, petrolatum, and so on.
  • Such fatty alcohols include cetyl alcohol, stearyl alcohol, cetearyl alcohol, and the like.
  • lanolin derivatives such as acetylated lanolin
  • Nonvolatile silicones both water soluble and water insoluble, are also suitable as the oil
  • Such silicones preferably have a viscosity of 10 to 600,000 centistokes, preferably 20
  • Suitable water insoluble nonvolatile silicones include
  • trimethicone simethicone, dimethylhydrogensiloxane, stearoxytrimethylsilane, vinyldimethicone.
  • water soluble silicones such as dimethicone copolyol,
  • nonvolatile oil examples include various fluorinated oils such as fluorinated
  • silicones fluorinated esters, or perfluropoly ethers.
  • fluorosilicones such as
  • silicones such as those disclosed in U.S. patent no. 5,118,496 which is hereby incorporated by
  • Guerbet esters are also suitable oils.
  • guerbet ester means an ester which is
  • R 1 and R 2 are each independently a C 4 . 20 alkyl and R 3 is a substituted or unsubstiruted
  • fatty radical such as a C,. 50 straight or branched chain saturated or unsaturated alkyl or
  • alkylene or phenyl, wherein the substituents are halogen, hydroxyl, carboxyl, and
  • alkylcarbonylhydroxy Particularly preferred is a carboxylic acid wherein the R group is such
  • the guerbet ester is a
  • fluoro-guerbet ester which is formed by the reaction of a guerbet alcohol and carboxylic acid
  • n is from 3 to 40.
  • ester having the tentative CTFA name fluoro-octyldodecyl meadowfoamate. This ester is sold
  • the nonvolatile oil comprises naturally occuring glyceryl esters of fatty acids,
  • triglycerides either alone or in combination with a water insoluble nonvolatile silicone such that the triglyceride is present at about 5-25% by weight of the total composition. If the water
  • insoluble nonvolatile silicone is present, it is generally present from 0.5 to 8% by weight of the
  • the triglyceride is lanolin oil and the water insoluble nonvolatile
  • silicone is dimethicone.
  • the cosmetic stick compositions of the invention contain 1-30%, preferably 1-25%,
  • 135° C. will have a molecular weight ranging from about 100 and 2,000.
  • ethylene copolymers are comprised of ethylene monomer units in either repetitive or randon
  • R is a C,. 30 straight or branched chain saturated or unsaturated alkyl, aryl, or aralkyl
  • compositions of the invention comprise 0.1-25%, preferably 0.5-20%, more
  • the particulate matter may be colored or non-
  • Suitable powders include bismuth oxy chloride, titanated mica. fumed silica, spherical silica, polymethylmethacrylate, micronized teflon, boron nitride,
  • maltodextrin montmorillonite, microcrystalline cellulose, rice starch, silica, talc, mica,
  • titanium dioxide zinc laurate, zinc myristate, zinc rosinate, alumina, attapulgite, calcium
  • flour tin oxide, titanium hydroxide, trimagnesium phosphate, walnut shell powder, or
  • the above mentioned powders may be surface treated with lecithin, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids, amino acids
  • the particulate matter component also may comprise various organic and inorganic materials
  • the organic pigments are generally various aromatic types including azo, indigoid,
  • triphenylmethane, anthraquinone, and xanthine dyes which are designated as D&C and
  • Organic pigments generally consist
  • pigments include iron oxides, ultramarines, chromium, chromium hydroxide colors, and
  • composition may contain a mixture of both pigmented and non-pigmented
  • compositions of the invention may contain other ingredients which maximize the
  • the polymers are uncrosslinked synthetic polymers comprising a first
  • repeat unit selected from group consisting of methacrylate ester monomers which, if
  • ester monomers which, if polymerized, would yield a polymer having a glass transition
  • the first repeat unit comprises at least one
  • methacrylate ester monomer which, if polymerized to a molecular weight average of about
  • the second repeat unit comprises at least one methacrylate ester
  • polymer may contain, in addition to the first and second repeat units, other monomeric units
  • styrene ethylenically unsaturated monomer units such as ethylene, propylene,
  • vinyl monomers such as vinyl chloride, styrene, silicon repeat units, and so on,
  • the final polymer has at least one first repeat unit having a glass transition temperature ranging from about -10 to 75° C, and at least one second repeat unit having a
  • methacrylate ester monomers are suitable for use as first repeat unit.
  • the methacrylate ester monomers are aliphatic esters of methacrylic acid, such as
  • the aliphatic alcohol may-
  • the first repeat unit comprises
  • a variety of monomers are suitable for use as the second repeat unit.
  • the second repeat unit Preferably the
  • second repeat unit is methacrylic acid esterified with an aliphatic alcohol of 1 to 30 carbon
  • unsaturated monomer is isobornyl methacrylate or methylmethacrylate.
  • the first and second repeat units each independently have the following
  • R wherein R ⁇ is COOM wherein M is a substituted or unsubstituted C,. 30 straight or branched
  • substitutents are halogen or alkoxy; pyrrolidone; or a substituted or
  • first repeat unit R is COOM where M is C,. 30 alkyl, more preferably M
  • M is a C,., 0 alkyl, more preferably M is a C,. 5 alkyl, and most preferably M is a C 4 branched
  • R is COOM where M is H or C,. 30 alkyl or a
  • alicyclic or bicyclic ring is COOM where M is a C,. 5 alkyl or an alicyclic
  • R is COOM where M is CH 3 or an alicyclic ring which is
  • methacrylate comprising about 40-60% by weight of each monomer unit, wherein the
  • polymer has a glass transition temperature of about 20 to 105° C. and a molecular weight
  • polymer of the invention is a copolymer comprising a 50/50 ratio of isobutyl methacrylate
  • copolymers of acrylic acid or acrylic acid ester moieties Particularly preferred is a
  • two or more monomers consisting of acrylic acid, methacrylic acid, or their simple esters.
  • compositions of the invention contain one or more polymers, in
  • the composition may contain 0.0001-8%, preferably 0.001-6%, more preferably
  • preservatives 0.005-5% by weight of the total composition of preservatives.
  • preservatives are examples of preservatives.
  • Suitable including such as benzoic acid, benzyl alcohol, benzylhemiformal, benzylparaben, 5-
  • Hydantoin dilaurate dehydroacetic acid, diazolidinyl urea, dibromopropamidine
  • compositions of the invention may contain vitamins and/or coenzymes, as well as
  • antioxidants 0.001-10%, preferably 0.01-8%, more preferably 0.05-5% by weight of
  • Suitable vitamins include the B vitamins such as
  • thiamine riboflavin, pyridoxin, and so on, as well as coenzymes such as thiamine
  • Vitamin A and derivatives thereof are suitable. Examples are Vitamin A
  • Vitamin E and derivatives thereof such as Vitamin E acetate, nicotinate, or
  • Vitamins D, C, and K, as well as derivatives thereof are examples of Vitamins D, C, and K, as well as derivatives thereof.
  • vitamin C such as magnesium ascorbyl
  • Suitable antioxidants are ingredients which assist in preventing or retarding spoilage.
  • antioxidants suitable for use in the compositions of the invention are potassium
  • cysteine hydrochloride butylated hydroxytoluene, butylated hydroxyanisole, and so
  • sphingolipids such as natural and synthetic ceramides
  • compositions of the invention 0.0001-3%, preferably 0.0005-2%, more preferably
  • RI is a hydrocarbon group
  • R2-R8 are each independently H or CH3
  • XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon group of up to 24 carbon atoms; XI and X2 are each independently H or hydrocarbon
  • Yl and Y2 are H or OH. at least one of Yl and Y2 being OH;
  • Suitable plant extracts include
  • emollient-type effect on the skin If so, a range of 0.001-4%, preferably 0.005-3%, more
  • Suitable carbohydrates preferably 0.01-2% by weight of the total composition is suggested.
  • glucose, sucrose, and derivatives thereof such as methyl glucose dioleate, methyl glucose
  • glycosaminoglycans are glycosaminoglycans.
  • compositions of the invention may be desireable to include one or more sterols in the compositions of the invention.
  • Suitable sterols are animal or vegetable derived
  • the above skeleton may contain hydroxyl or keto groups, some ring unsaturation.
  • cholesterol lanasterol which are cholesterol and lanasterol esterified with a C,. 30 fatty acids
  • humectants preferably 0.001-3% by weight of one or more materials that act as humectants; such as
  • organic salts formed by the reaction of an organic base with either inorganic or organic acid.
  • organic salts that are ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ , ⁇ ,
  • humectant effect are sodium PCA, sodium lactate, sodium stearoyl lactate, and the
  • composition containing one or more of the above ingredients either
  • ingredients are pre-formed as a complex, and added
  • a cosmetic lipstick composition was made according to the following formula:
  • Titanium dioxide 2.37
  • the lipstick composition was made by combining the synthetic wax, paraffin wax.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention comprend une composition pigmentée pour bâton cosmétique. Cette composition comprend, en poids de la composition totale, 1 à 40 % d'un solvant non aqueux volatile présentant une viscosité comprise entre 0,5 et 5 centipoise à 25 °C, 20 à 80 % d'une première huile non volatile qui est un ester gras de C12-22 d'acide citrique, 1 à 35 % d'une deuxième huile non volatile, 1 à 30 % d'une cire dont le point de fusion est compris entre 30 et 135 °C, et qui est un homopolymère d'éthylène ou un copolymère d'éthylène, 0,1 à 25 % de matières particulaires, présentant une taille particulaire comprise entre 0,5 et 200 microns; et selon laquelle la quantité totale d'huile non volatile présente dans le bâton est supérieure à environ 31 % en poids de la composition totale.
PCT/US1998/017664 1997-08-27 1998-08-26 Composition pour baton cosmetique hydratant WO1999009937A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU90352/98A AU9035298A (en) 1997-08-27 1998-08-26 Moisturizing cosmetic stick compositions
CA002301944A CA2301944A1 (fr) 1997-08-27 1998-08-26 Composition pour baton cosmetique hydratant
EP98942252A EP1009364A1 (fr) 1997-08-27 1998-08-26 Composition pour baton cosmetique hydratant

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US91813497A 1997-08-27 1997-08-27
US08/918,134 1997-08-27

Publications (1)

Publication Number Publication Date
WO1999009937A1 true WO1999009937A1 (fr) 1999-03-04

Family

ID=25439865

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/017664 WO1999009937A1 (fr) 1997-08-27 1998-08-26 Composition pour baton cosmetique hydratant

Country Status (10)

Country Link
US (2) US6086859A (fr)
EP (1) EP1009364A1 (fr)
AR (2) AR016898A1 (fr)
AU (1) AU9035298A (fr)
CA (1) CA2301944A1 (fr)
IN (1) IN187860B (fr)
PE (2) PE110599A1 (fr)
TW (1) TW486371B (fr)
WO (1) WO1999009937A1 (fr)
ZA (2) ZA987798B (fr)

Cited By (5)

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WO2002051360A2 (fr) * 2000-12-22 2002-07-04 Basf Aktiengesellschaft Preparations cosmetiques, et leur utilisation, contenant des cires de polyethylene ayant des proprietes organoleptiques ameliorees
US6444212B1 (en) 1998-03-26 2002-09-03 L'oreal Moisturizing and long-wearing make-up composition
USRE38441E1 (en) 1995-12-19 2004-02-24 Maybelline, Inc. Solvent-based non-drying lipstick
EP1955692A1 (fr) * 2007-01-12 2008-08-13 L'oreal Utilisation d'actifs permettant d'augmenter la teneur en céramides dans les lèvres, à titre d'agent protecteur des lèvres fragiles
FR2918877A1 (fr) * 2007-07-16 2009-01-23 Oreal Utilisation de l'acide ascorbique ou de l'un de ses analogues a titre d'agent protecteur des levres fragiles

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DE20016826U1 (de) * 2000-09-29 2001-03-08 Schwan Stabilo Cosmetics Gmbh Stift
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US20070122507A1 (en) * 2005-05-26 2007-05-31 Palu Afa K Histone deacetylase and tumor necrosis factor converting enzyme inhibition
US20070025941A1 (en) * 2005-08-01 2007-02-01 L'oréal Liquid lip gloss compositions with enhanced shine
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US6086859A (en) 2000-07-11
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CA2301944A1 (fr) 1999-03-04
PE110599A1 (es) 1999-11-09
EP1009364A1 (fr) 2000-06-21
ZA987798B (en) 1999-03-01
PE110699A1 (es) 1999-11-08
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AR016898A1 (es) 2001-08-01
US6080390A (en) 2000-06-27

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