WO1998040908A1 - Lampe fluorescente - Google Patents
Lampe fluorescente Download PDFInfo
- Publication number
- WO1998040908A1 WO1998040908A1 PCT/JP1998/000942 JP9800942W WO9840908A1 WO 1998040908 A1 WO1998040908 A1 WO 1998040908A1 JP 9800942 W JP9800942 W JP 9800942W WO 9840908 A1 WO9840908 A1 WO 9840908A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fluorescent lamp
- phosphor
- color
- green
- light
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/38—Devices for influencing the colour or wavelength of the light
- H01J61/42—Devices for influencing the colour or wavelength of the light by transforming the wavelength of the light by luminescence
- H01J61/44—Devices characterised by the luminescent material
Definitions
- the present invention relates to a fluorescent lamp having a low color rendering property but a high lamp efficiency.
- Discharge lamps utilizing the discharge phenomenon in the arc tube include a high-intensity discharge lamp and a fluorescent lamp.
- High-intensity discharge lamps are lamps that are highly economical because of their high lamp efficiency, high brightness, and long life. For this reason, high-intensity discharge lamps are widely used for outdoor lighting and the like that require large brightness in large-scale spaces.
- the lamp with the highest lamp efficiency is the low-pressure sodium lamp. Therefore, low-pressure sodium lamps are used for lighting where economics are important, especially in tunnels.
- the low-pressure sodium lamp is a lamp that utilizes discharge in sodium vapor, and emits orange yellow light near 59 O nm. Therefore, objects illuminated by low-pressure sodium lamps can hardly distinguish colors.
- the low-pressure sodium lamp emits monochromatic light, it is difficult to distinguish whether the lane on the road surface is white or yellow even in a tunnel, making it difficult to determine whether or not the lane change is possible. There was a problem that some objects seemed achromatic and uncomfortable.
- fluorescent lamps have many advantages compared to other lamps, such as easy lighting, excellent color rendering, long life, and abundant light colors. It is widely used in a wide range of fields.
- three-band emission fluorescent lamps have been widely used recently.
- This three-band fluorescent lamp emits light in three wavelengths: blue at about 450 nm, green at about 540 nm, and red at about 610 nm. It is a fluorescent lamp having a high color rendering property.
- the three narrow-band phosphors used in the three-band fluorescent lamps have been continually improved. Therefore, this phosphor has excellent characteristics such as higher quantum efficiency than other phosphors.
- an object of the present invention is to provide a fluorescent lamp which is equal to or higher than the efficiency of a low-pressure sodium lamp, and is capable of discriminating the minimum number of colors.
- the present invention according to claim 1 provides a green phosphor having an emission peak wavelength power of S530 nm to 560 nm, and 60 Onn!
- a fluorescent lamp which mainly emits light by using a red phosphor having a wavelength of from 630 nm to 630 nm, wherein the color rendering index No. for calculating a special color rendering index specified in the International Commission on Illumination CIE Publication No. 13.3 under the fluorescent lamp light is used.
- a fluorescent lamp characterized in that the four test colors of 9, 9, No. 10, No. ll, and No. 12 can be perceived as red, yellow, green, and blue-violet, respectively. It is.
- the present invention according to claim 2, wherein the correlated color temperature of the fluorescent lamp is 3200 K: to 450 K, and the chromaticity point of the light color is a blackbody locus on a CIE 1960 uv chromaticity diagram.
- the chromaticity deviation from is from 0.015 to 0.045.
- the green phosphor is a rare earth phosphor activated by terbium or terobium 'cerium' or terbium 'gadolinium' cerium, and the red phosphor is europium.
- the fluorescent lamp according to claim 2 wherein the fluorescent lamp is an activated rare earth phosphor.
- the present invention according to claim 4 is the fluorescent lamp according to claim 3, wherein a weight percentage of the green phosphor and the red phosphor in the phosphor is 70:30 to 50:50.
- the present invention according to claim 5 is the fluorescent lamp according to any one of claims 1 to 4, wherein the use of the fluorescent lamp is for external lighting.
- the present invention according to claim 6 is the fluorescent lamp according to any one of claims 1 to 4, wherein the use of the fluorescent lamp is for road lighting and tunnel lighting.
- FIG. 1 is a relative spectral distribution diagram of a fluorescent lamp according to one embodiment of the present invention.
- FIG. 2 is a diagram illustrating a method for evaluating color characteristics according to the present invention.
- FIG. 3 is a division diagram of the Munsell hue, which is a basic concept of the present invention.
- FIG. 4 is a diagram showing the chromaticity deviation SP. BEST MODE FOR CARRYING OUT THE INVENTION
- mercury emits a bright line due to electrons discharged into the tube, and a phosphor excited by the bright line emits light.
- the light emitted from the fluorescent lamp is a mixture of the light emitted by the phosphor and the light of the visible mercury emission line.
- the visible mercury emission line mainly emits light in the short wavelength region of 405 mn, 436 mn, etc., and the visible mercury emission dose contained in the fluorescent lamp is said to be about 5 lra / W.
- fluorescent lamps inherently have some blue emission.
- blue light emission improves color rendering with a small amount
- blue phosphor light emission efficiency is not as good as green and red phosphor light emission efficiency
- danger indications use red text or pictures. Therefore, it is desirable not to use blue phosphors.
- the red phosphor is 600 ⁇ ! Centered on a wavelength of about 610nm, where humans can feel the color efficiently and efficiently, as demonstrated by a three-band fluorescent lamp.
- a phosphor with good luminous efficiency having a luminescence peak at ⁇ 630 ⁇ .
- the green phosphor and the red phosphor must be adjusted. There is a problem of how to set the ratio.
- the color calculation method for finding the optimum blending ratio was determined as follows. In other words, at least the basic color can be almost perceived as the original color of the object. D For the color perception, the color adaptation state of the human eye is improved. In addition, the original color of the object must be the color under standard light that you often see everyday. In addition, we consider that hue is the most important factor in color perception of objects.
- test colors No. 9, No. 10, No. 11, and No. 12 of the test colors for special color rendering evaluation of CIE Publication No. 13.3 of the International Commission on Illumination were used as basic colors. .
- test colors are four high-saturation test colors selected to evaluate the color rendering properties of light sources both in Japan and worldwide.
- Table 1 shows the spectral radiance factors of the four test colors.
- the Munsell color system is a display system proposed by the US painter A. H. Munsel, which classifies colors into three attributes: Munsell hue, Munsell brightness, and Munsell saturation.
- the Munsell hue consists of five basic hues R, Y, G, B, and P, plus YR, GY, BG, PB, and RP. Divide the adjacent hues into 10 equal parts, and graduate the total of 100 types with psychologically equal hues.
- a 40 ⁇ 1: tube single-color fluorescent lamp was fabricated to obtain the spectral distribution of the lamp that was the basis for the color calculation.
- Green monochromatic fluorescent lamps are proven three-wave length region emitting fluorescent lamp LaPO Ce 3 +,.
- Red monochromatic fluorescent lamp proven equally three band fluorescent lamp Y 2 0 3: using the phosphor represented by the Eu 3 + formula.
- the luminous flux ratio of both fluorescent lamps was changed by light mixing calculation to calculate the spectral distribution of various mixed light.
- the spectral distribution of the illumination light, the spectral radiance factor of the four test colors, the CIE 2 ° field of view, etc. Enter the color function.
- Standard light C light is used as the reference light, the illuminance of each illumination light and the reference light is set to 10001x, and the reflectance of the background is set to 20%. The color corresponding to the light is determined by the xyY value.
- the hues of the 4 test colors are referred to as red in the Munsell hue, R in the Munsell hue, yellow in the Munsell hue, and G in the Munsell hue. It is located almost in the center of the green region, which is to be referred to, and the blue-violet region, which is called PB in Munsell hue.
- the range in which the test color of No. 9 of the CIE Publication No. 13.3, which can be almost perceived as red is 9RP to R to 1YR in Munsell hue.
- the range that can be almost perceived as yellow is 9YR to Y to 1GY in the Munsell hue
- the range in which the test color of No. 11 can be almost perceived as green is 9GY to G to 1BG in the Munsell hue
- the test of No. 12 The range in which the color can be almost perceived as bluish purple is the Munsell hue 9B ⁇ PB ⁇ : LP.
- each test color Under each illumination, if the Munsell hue of each test color obtained based on the calculation steps of (1) to) is within the above-mentioned range, each test color is almost changed to red, yellow, green, and blue-violet. You should be able to perceive.
- the Munsell hue value of each test color under each illumination light calculated in (Table 2) is shown in FIG.
- the black squares in Figure 3 are the four test colors under standard light C light, that is, the color of the color chart itself.
- the reference black circle
- ⁇ open circle
- the illuminating light that renders the No. 9 test color almost in the red area called R in the Mansenore hue has a luminous flux ratio of about 8: 2 to 2: 8.
- the illumination light that renders the test color of No. 10 almost in the yellow region called Y in the Munsell hue has a luminous flux ratio of about 8: 2 to 0:10 for the monochromatic green fluorescent lamp and the monochromatic red fluorescent lamp.
- the illumination light that renders the test color of No. 11 almost in the green area called G in the Munsell hue has a luminous flux ratio of about 10: 0 to 6: 4 between the green monochromatic fluorescent lamp and the red monochromatic fluorescent lamp.
- the illumination light that renders the test color of No. 12 almost in the blue-violet region called PB in the Munsell hue has a luminous flux ratio of about 10: 0 to 0:10 between the green monochromatic fluorescent lamp and the red monochromatic fluorescent lamp. You.
- the illuminating light in which the test color of No. 11 almost renders in the green region called G in Munsell hue and the test color of No. 12 almost in the blue-purple region called PB in Munsell hue, is a monochromatic green fluorescent lamp. And the luminous flux ratio of the red monochromatic fluorescent lamp is about 8: 2 to 6: 4.
- Table 3 shows characteristics of various illumination lights calculated by changing the luminous flux ratio of both fluorescent lamps by the light mixing calculation.
- Characteristics of illumination light [Table 3] Luminous flux ratio Correlation Lamp efficiency Illumination light uV
- Illumination light with a luminous flux ratio of 8: 2 between a green monochromatic fluorescent lamp and a red monochromatic fluorescent lamp has a correlated color temperature of 4175 °, ⁇ of +0.0356, and a lamp efficiency of about 120 lm / W.
- Illumination light with a luminous flux ratio of 7: 3 between a green monochromatic fluorescent lamp and a red monochromatic fluorescent lamp has a correlated color temperature of 3466 K, an Auv of +0.0189, and a lamp efficiency of about 110 lm / W .
- Illumination light with a luminous flux ratio of 6: 4 between a green monochromatic fluorescent lamp and a red monochromatic fluorescent lamp has a correlated color temperature of 2852 2, ⁇ of +0.061, and a lamp efficiency of about 100 lm / W. It is. Therefore, the lamp efficiency of illumination light with a luminous flux ratio of 6: 4 between a green monochromatic fluorescent lamp and a red monochromatic fluorescent lamp is approximately 9 O lm / W, which is the current 40 W straight tube three-wavelength fluorescent lamp. Does not have a particularly significant advantage.
- the lamp efficiency is highest when the monochromatic green fluorescent lamp has the largest light amount among these illumination lights, and the luminous flux ratio of the light emitted from the monochromatic green fluorescent lamp and the monochromatic red fluorescent lamp is about 8: 2.
- a fluorescent lamp having a minimum color rendering property can be manufactured.
- the correlated color temperature of the illumination light of the present invention was determined as follows.
- the remarkable effect of the present invention is that the luminous flux ratio between the green monochromatic fluorescent lamp and the red monochromatic fluorescent lamp is in the range of about 8: 2 to about 7: 3, but also in the surrounding range of 9: 1 to 6: 4. There is an equivalent effect.
- the present invention was obtained by rounding the numerical value of 0 45 to the narrower side.
- the correlated color temperature of the illumination light of the present invention that is, the fluorescent lamp is about 3200 K to 450 OK
- the chromaticity point of the light color is the blackbody locus on the CIE 1960 uv chromaticity diagram. Is from 0.015 to 0.045.
- LaPC Ce 3 +, Tb 3 + and Y 2 0 3: Eu 3 + phosphors about in weight% 6 having the formula: is a spectral distribution of a fluorescent lamp in a mixing ratio of 4.
- This fluorescent lamp was manufactured so that the luminous flux ratio of the green monochromatic fluorescent lamp of No. 3 and the monochromatic red fluorescent lamp of Table 3 (Table 3) was almost equivalent to the spectral distribution of illumination light of about 8: 2.
- the lamp efficiency is about 120 lra / W.
- the fluorescent lamp of the present invention was installed on the ceiling surface, measuring 170 cm in depth, 150 cm in width, and 180 cra in height.
- the wall of the observation booth is N8.5, the floor is N5, and the desk is N7.On the desk, the test colors for special color rendering evaluation No.9 and No. Red, yellow, green and blue-violet color charts according to 10, No. 11, No. 12 were placed. Prior to the observation, chromatic adaptation was performed for 5 minutes.
- the color chart according to No. 9 of the CIE Publication No. 13.3 can be almost perceived as red, and the color chart according to No. 10 can be almost perceived as yellow.
- the color chart conforming to No. 12 can be almost perceived as green, and the color chart according to No. 12 can be almost perceived as bluish purple, confirming that it has the minimum color rendering properties.
- the characteristics of a fluorescent lamp having the minimum color rendering properties can be applied to a fluorescent lamp actually manufactured by this calculation method.
- FIG. 1 As shown in FIG. 1 described above, an example of the embodiment is shown, but it goes without saying that it can be manufactured by various combinations of phosphors.
- LaP0 4 Ce 3+ , Tb 3 + , La 2 O 3 ⁇ 0.2 Si 0 2 ⁇ 0.9 P 2 0: Ce 3+ , Tb 3 + , CeMgAl i i0i 9 : Tb 3+ and GdMgBsC. : Ce 3+, Tb 3 +, (La, Ce, Tb) 2 0 3 '0.2SiO, represented by the chemical formula such as -0.9P 2 0s.
- the said red phosphor 630nm emission peak wavelength from 600 nm there is a rare earth phosphor activated with europium, Y 2 0 3: Eu 3+ , (Y, Gd) 2 0 3: Eu 3+, Y 2 0 3 : represented by a chemical formula such as Pr 3+ .
- the present invention can be achieved by satisfying claim 1. It goes without saying that a fluorescent lamp having substantially the same characteristics as the fluorescent lamp of the present invention can be manufactured.
- the weight% of the mixture of the green phosphor and the red phosphor is determined by the luminous efficiency of each phosphor, the particle size, weight, surface shape of each phosphor, and the medium in which the phosphor is dissolved when producing a fluorescent lamp. It changes under various conditions such as temperature, temperature and drying conditions.
- the luminous flux ratios of the monochromatic green fluorescent lamps and the monochromatic red fluorescent lamps Nos. 3 and 4 in Table 3 are approximately
- the weight percentage ratio of the green phosphor to the red phosphor which is almost equal to the characteristic of the illumination light of 8: 2 to about 7: 3, is 70:30 to 50:50.
- the fluorescent lamp made with a 40 W straight tube is shown.
- the fluorescent lamp of the present invention can be made regardless of the lamp output (W) or the shape of the fluorescent lamp. Needless to say.
- the fluorescent lamp of the present invention having the highest lamp efficiency can be manufactured.
- the fluorescent lamp of the present invention has a minimum color rendering property and is a high-efficiency fluorescent lamp, it has many advantages such as easy lighting and low cost compared to a high-intensity discharge lamp. Have.
- the chromaticity deviation A u, v is the chromaticity point of the light color of the light source as S (u, v).
- P uo, vo
- the chromaticity point S is on the upper left side (greenish light side) of the blackbody locus
- the chromaticity deviation is positive ( ⁇ ⁇ , ⁇ > 0) and the lower right side (reddish light side).
- the chromaticity deviation was negative (u, ⁇ ⁇ 0).
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
- Luminescent Compositions (AREA)
- Led Device Packages (AREA)
- Developing Agents For Electrophotography (AREA)
- Glass Compositions (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002254114A CA2254114A1 (en) | 1997-03-10 | 1998-03-06 | Fluorescent lamp |
AT98905801T ATE268504T1 (de) | 1997-03-10 | 1998-03-06 | Leuchtstofflampe |
US09/180,596 US6242857B1 (en) | 1997-03-10 | 1998-03-06 | High efficiency fluorescent lamp with low color rendering property |
DE69824259T DE69824259T2 (de) | 1997-03-10 | 1998-03-06 | Leuchtstofflampe |
EP98905801A EP0917182B1 (en) | 1997-03-10 | 1998-03-06 | Fluorescent lamp |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9/54531 | 1997-03-10 | ||
JP5453197 | 1997-03-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998040908A1 true WO1998040908A1 (fr) | 1998-09-17 |
Family
ID=12973261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1998/000942 WO1998040908A1 (fr) | 1997-03-10 | 1998-03-06 | Lampe fluorescente |
Country Status (10)
Country | Link |
---|---|
US (1) | US6242857B1 (ja) |
EP (1) | EP0917182B1 (ja) |
KR (1) | KR20000010909A (ja) |
CN (1) | CN1219284A (ja) |
AT (1) | ATE268504T1 (ja) |
CA (1) | CA2254114A1 (ja) |
DE (1) | DE69824259T2 (ja) |
ID (1) | ID20992A (ja) |
TW (1) | TW357243B (ja) |
WO (1) | WO1998040908A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011091441A (ja) * | 1999-02-18 | 2011-05-06 | Philips Lumileds Lightng Co Llc | 赤の不足を補償する蛍光体を使用したled |
US9840666B2 (en) | 2013-09-30 | 2017-12-12 | Panasonic Intellectual Property Management Co., Ltd. | Phosphor having inorganic oxide with cerium and terbium activators, light-emitting device illumination light source, and illumination device using same |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6525460B1 (en) * | 2000-08-30 | 2003-02-25 | General Electric Company | Very high color rendition fluorescent lamps |
US7091656B2 (en) * | 2001-04-20 | 2006-08-15 | Nichia Corporation | Light emitting device |
WO2002086978A1 (fr) * | 2001-04-20 | 2002-10-31 | Nichia Corporation | Dispositif photoemetteur |
JP4013657B2 (ja) * | 2002-06-03 | 2007-11-28 | セイコーエプソン株式会社 | 画像表示装置、画像表示方法および画像表示プログラムが記録されたコンピュータ読み取り可能な記録媒体 |
US7179402B2 (en) * | 2004-02-02 | 2007-02-20 | General Electric Company | Phosphors containing phosphate and/or borate of metals of group IIIA, group IVA, and lanthanide series, and light sources incorporating the same |
CN1725435B (zh) * | 2005-07-21 | 2010-09-22 | 北京世纪卓克能源技术有限公司 | 道路照明无极灯 |
JP4941370B2 (ja) * | 2008-03-18 | 2012-05-30 | 富士通株式会社 | 画像補正プログラム、画像補正装置および画像補正方法 |
EP2444713A1 (en) | 2010-10-19 | 2012-04-25 | University College Cork | A light source |
CN104537217B (zh) * | 2014-12-17 | 2017-04-26 | 青岛海信电器股份有限公司 | 照明体及显示器背光光谱功率分布的优化方法 |
Citations (8)
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JPS58225552A (ja) * | 1982-06-23 | 1983-12-27 | Matsushita Electric Works Ltd | けい光ランプ |
JPS642246A (en) * | 1987-06-24 | 1989-01-06 | Matsushita Electron Corp | Fluorescent lamp of electric bulb type |
JPH0298035A (ja) * | 1988-10-05 | 1990-04-10 | Iwasaki Electric Co Ltd | 蛍光高圧水銀灯 |
WO1997011480A1 (fr) * | 1995-09-21 | 1997-03-27 | Matsushita Electric Industrial Co., Ltd. | Source lumineuse |
JPH1021883A (ja) * | 1996-07-04 | 1998-01-23 | Matsushita Electric Ind Co Ltd | 一般照明用ランプ |
JPH10112286A (ja) * | 1996-10-04 | 1998-04-28 | Matsushita Electric Ind Co Ltd | 蛍光ランプ |
JPH10116592A (ja) * | 1996-10-11 | 1998-05-06 | Matsushita Electric Ind Co Ltd | 蛍光ランプ |
JPH10116589A (ja) * | 1996-10-11 | 1998-05-06 | Matsushita Electric Ind Co Ltd | 照明光源 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5714836A (en) * | 1992-08-28 | 1998-02-03 | Gte Products Corporation | Fluorescent lamp with improved phosphor blend |
-
1998
- 1998-03-06 KR KR1019980709056A patent/KR20000010909A/ko not_active Application Discontinuation
- 1998-03-06 EP EP98905801A patent/EP0917182B1/en not_active Expired - Lifetime
- 1998-03-06 US US09/180,596 patent/US6242857B1/en not_active Expired - Lifetime
- 1998-03-06 CN CN98800261A patent/CN1219284A/zh active Pending
- 1998-03-06 DE DE69824259T patent/DE69824259T2/de not_active Expired - Fee Related
- 1998-03-06 AT AT98905801T patent/ATE268504T1/de not_active IP Right Cessation
- 1998-03-06 CA CA002254114A patent/CA2254114A1/en not_active Abandoned
- 1998-03-06 WO PCT/JP1998/000942 patent/WO1998040908A1/ja not_active Application Discontinuation
- 1998-03-09 ID IDP980342A patent/ID20992A/id unknown
- 1998-03-09 TW TW087103391A patent/TW357243B/zh active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS58225552A (ja) * | 1982-06-23 | 1983-12-27 | Matsushita Electric Works Ltd | けい光ランプ |
JPS642246A (en) * | 1987-06-24 | 1989-01-06 | Matsushita Electron Corp | Fluorescent lamp of electric bulb type |
JPH0298035A (ja) * | 1988-10-05 | 1990-04-10 | Iwasaki Electric Co Ltd | 蛍光高圧水銀灯 |
WO1997011480A1 (fr) * | 1995-09-21 | 1997-03-27 | Matsushita Electric Industrial Co., Ltd. | Source lumineuse |
JPH1021883A (ja) * | 1996-07-04 | 1998-01-23 | Matsushita Electric Ind Co Ltd | 一般照明用ランプ |
JPH10112286A (ja) * | 1996-10-04 | 1998-04-28 | Matsushita Electric Ind Co Ltd | 蛍光ランプ |
JPH10116592A (ja) * | 1996-10-11 | 1998-05-06 | Matsushita Electric Ind Co Ltd | 蛍光ランプ |
JPH10116589A (ja) * | 1996-10-11 | 1998-05-06 | Matsushita Electric Ind Co Ltd | 照明光源 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011091441A (ja) * | 1999-02-18 | 2011-05-06 | Philips Lumileds Lightng Co Llc | 赤の不足を補償する蛍光体を使用したled |
US9840666B2 (en) | 2013-09-30 | 2017-12-12 | Panasonic Intellectual Property Management Co., Ltd. | Phosphor having inorganic oxide with cerium and terbium activators, light-emitting device illumination light source, and illumination device using same |
Also Published As
Publication number | Publication date |
---|---|
EP0917182A1 (en) | 1999-05-19 |
EP0917182B1 (en) | 2004-06-02 |
CN1219284A (zh) | 1999-06-09 |
DE69824259T2 (de) | 2004-09-23 |
ID20992A (id) | 1999-04-01 |
DE69824259D1 (de) | 2004-07-08 |
KR20000010909A (ko) | 2000-02-25 |
ATE268504T1 (de) | 2004-06-15 |
EP0917182A4 (ja) | 1999-05-26 |
TW357243B (en) | 1999-05-01 |
CA2254114A1 (en) | 1998-09-17 |
US6242857B1 (en) | 2001-06-05 |
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