WO1998033880A1 - Nettoyeur de blanchiment produisant de la mousse - Google Patents

Nettoyeur de blanchiment produisant de la mousse Download PDF

Info

Publication number
WO1998033880A1
WO1998033880A1 PCT/US1998/001744 US9801744W WO9833880A1 WO 1998033880 A1 WO1998033880 A1 WO 1998033880A1 US 9801744 W US9801744 W US 9801744W WO 9833880 A1 WO9833880 A1 WO 9833880A1
Authority
WO
WIPO (PCT)
Prior art keywords
cleaner
acid
hypochlorite
group
carbonate
Prior art date
Application number
PCT/US1998/001744
Other languages
English (en)
Inventor
George J. Svoboda
Mark M. Gipp
Original Assignee
S. C. Johnson & Son, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by S. C. Johnson & Son, Inc. filed Critical S. C. Johnson & Son, Inc.
Priority to AU62560/98A priority Critical patent/AU6256098A/en
Publication of WO1998033880A1 publication Critical patent/WO1998033880A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2082—Polycarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines

Definitions

  • the present invention relates to a cleaner that foams for cleaning piping systems such as sink drains. More particularly, it relates to binary peroxide cleaning systems.
  • liquid drain cleaners While such liquids have some advantages, they can be less effective than the granular drain cleaners in removing certain types of clogs. Moreover, such liquids also often do not sufficiently clean vertical surfaces. This can lead to premature reclogging.
  • the invention provides a liquid cleaner having two parts, Parts
  • Part A contains a peroxide (e.g. hydrogen peroxide).
  • Part B is a compound selected from the group consisting of a hypochlorite, a manganese containing material (e.g. a manganese salt), a carbonate, and a hypochlorite generator. At least one of Part A and Part B is a liquid, and at least one of Part A and Part B also has a surfactant.
  • Part A also has an organic acid such as one selected from glycolic acid, citric acid, lactic acid, boric acid, adipic acid, fumaric acid, malic acid, succinic acid, and tartaric acid. Other acids may also be used, but it is preferred to use relatively mild acids that keep hydrogen peroxide stable in storage without generating noxious smells.
  • the hypochlorite is preferably sodium hypochlorite, calcium hypochlorite or other alkali metal and alkaline earth metal hypochlorites.
  • the surfactant is preferably an anionic or nonionic foaming surfactant.
  • the carbonate is preferably an alkali metal carbonate, alkali metal bicarbonate, or alkaline earth metal carbonate. Water is preferably the majority of one of Part A and Part B.
  • a hypochlorite generator is a compound that generates a hypochlorite and is preferably an alkali metal dichloroisocyanurate.
  • Other suitable hypochlorite generators are those described in U.S. patent 4,664,836.
  • the invention has the advantage over completely solid systems of not requiring water from an outside source.
  • the invention provides a method of removing an organic material from an interior surface of a piping system (e.g. a drain pipe). One mixes Part A and Part B to thereby create foam. One then exposes the organic material to the resulting foam. The foam helps the cleaning active(s) contact the organic material.
  • a piping system e.g. a drain pipe
  • Part A and Part B e.g. a drain pipe
  • One mixes Part A and Part B to thereby create foam.
  • One exposes the organic material to the resulting foam.
  • the foam helps the cleaning active(s) contact the organic material.
  • other peroxide generators besides hydrogen peroxide are substituted for hydrogen peroxide.
  • Peroxide “generators” are compounds such as a perborate, a percarbonate, a peroxyurea compound, persilic acid and hydrogen peroxide adducts of pyrophosphates, citrates, sodium sulfate, and sodium silicate, which readily release a peroxide in aqueous solution.
  • the surfactant is in Part A, the surfactant should be stable in the presence of hydrogen peroxide.
  • the surfactant is between .01 % and 10% of Part A, with .05% to 6% being especially preferred.
  • Foaming surfactants that may be employed in the present invention include anionic, nonionic and amphoteric surfactants, and mixtures thereof.
  • Suitable anionic surfactants include alpha olefin sulfonates, the alkyl aryl sulfonic acids and their alkali metal and alkaline earth metal salts such as sodium dodecyl benzene sulfonate, magnesium dodecyl benzene sulfonate, disodium dodecyl benzene disulfonate and the like, as well as the alkali metal salts of fatty alcohol esters of sulfuric and sulfonic acids, the alkali salts of alkyl aryl (sulfothioic acid) esters, alkyl thiosulfuric acid and soaps such as coco or tallow, etc.
  • Preferred anionics include sodium dodecyl benzene sulfonate available under the tradename Nacconal 40-G from Stepan Company, Northfield, Illinois, and sodium lauryl sulfate ("SLS") because of its foam enhancing properties, and to a lesser degree because of its detergency, wetting, and emulsifying properties.
  • SLS is available in dry form under the trade designation Stephanol ME-Dry from the Stepan Chemical Company.
  • Suitable nonionic surfactants include the ethylene oxide esters of alkyl phenols such as (nonylphenoxy) polyoxyethylene ether, the ethylene oxide esters of fatty alcohols such as tridecyl alcohol polyoxyethylene ether, the propylene oxide ethers of fatty alcohols, the ethylene oxide ethers of alkyl mercaptans such as dodecyl mercaptan polyoxyethylene thioester, the ethylene oxide esters of acids such as the lauric ester of methoxy polyethylene glycol, the ethylene oxide ethers of fatty acid amides, the condensation products of ethylene oxide with partial fatty acid esters of sorbitol such as the lauric ester of sorbitan polyethylene glycol ether, and other similar materials.
  • alkyl phenols such as (nonylphenoxy) polyoxyethylene ether
  • the ethylene oxide esters of fatty alcohols such as tridecyl alcohol polyoxyethylene ether
  • Suitable amphoteric surfactants include the fatty imidazolines, such as 2- coco-1 hydroxyethyl-1 carboxymethyl-lhydroxylimidazoline and similar compounds made by reacting monocarboxylic fatty acids having chain lengths of 10 to 24 carbon atoms with 2-hydroxy ethyl ethylene diamine and with monohalo monocarboxylic fatty acids.
  • An additional class of suitable foaming surfactants are amine oxides which demonstrate cationic surfactant properties in acidic pH and nonionic surfactant properties in alkaline pH.
  • Example amine oxides include alkyl dimethyl amine oxide, dihydroxy ethyl cocamine oxide, tallowamidopropylamine oxide and lauramine oxide.
  • One mode of forming the foam is to have hypochlorite in (or from) Part B react with hydrogen peroxide in Part A to release oxygen in an alkaline environment, e.g.: NaOCI+H 2 O 2 6 NaCI+O 2 +H 2 O.
  • the released oxygen causes the surfactant to foam, thereby providing very effective surface contact properties.
  • An excess of hypochlorite is preferred as it will act to dissolve hair, while also bleaching.
  • manganese containing material such as a salt of manganese (e.g. manganese citrate derived via manganese sulfate and sodium citrate) can be included in Part B.
  • a releasing compound e.g. an alkali metal or alkaline earth metal halide such as calcium chloride
  • the calcium readily displaces the manganese from the citrate complex, and the Mn ++ reacts with H 2 0 2 .
  • oxygen causes the foaming.
  • the reaction time is slower than that when hypochlorite is used.
  • a third mode of operation uses a carbonate to release carbon dioxide when exposed to the acid from Part A.
  • the hydrogen peroxide in this formulation acts as a bleach, with the foaming due to the carbon dioxide.
  • Part A can be sold as an additive for existing drain cleaners (e.g. a solid sodium perborate tablet to be used with a liquid drain cleaner containing sodium hypochlorite and surfactant).
  • existing drain cleaners e.g. a solid sodium perborate tablet to be used with a liquid drain cleaner containing sodium hypochlorite and surfactant.
  • the drain cleaner creates foam very rapidly when hydrogen peroxide itself is in Part A. Note that the problem of the instability of hydrogen peroxide during storage in an alkaline environment is overcome.
  • a stabilizer/chelating agent such as Monsanto's Dequest, an aminophosphonate
  • chelating agents sequester metals.
  • enzymes and/or bacteria can also be added to the cleaner system.
  • Suitable enzymes for use in the present invention include, for example, protease, amylase, cellulase, lipase and mixtures thereof.
  • the enzyme is a mixture of the above listed enzymes available under the tradename Otimase from Novo Nordisk Bioindustrials Inc., Danbury, Connecticut.
  • Enzymes, in commercially available forms, are typically present in amounts from about 0.1% to about 50%, preferably from about 0.1% to about 10%, and most preferably from about 1 % to about 5% by weight of the cleaner.
  • bacteria is typically present in a commercially available form in amounts from about 0.1% to about 50%, preferably from about 0.1% to about 20%, and most preferably from about 1% to about 10% by weight of the cleaner. Suitable bacteria are those which are specially developed for waste and sewer treatment.
  • the objects of the present invention therefore include providing a cleaner of the above kind:
  • liquid cleaner we mean that at least one of Part A or Part B is a liquid.
  • Final pH's in the 6-10 range are preferred, with pH 8-9 being particularly preferred.
  • Non-caustic compositions, with less than 5% excess NaOH or KOH, can be created.
  • l-lll a 1 :1 mixture of Part A and Part B (by volume) can be made.
  • Hair Dissolving Test A cylinder was used to measure the invention's ability to dissolve hair (one of the most difficult clog components typically encountered).
  • the Example IV 510 g was added to 150 ml of 100 degree Fahrenheit water along with 5 g of human hair clippings. The solution was then left overnight. The remaining hair was then strained out, rinsed, dried in an oven, and then weighed. This dissolved 3.4 g more of the hair than a control without the cleaning solution. Note that heat when the hypochlorite is in excess with respect to the hydrogen peroxide the foam will have good bleaching properties.
  • a liquid drain cleaner that foams can be prepared from the cleaners of the present invention.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Cette invention concerne des nettoyants liquides qui moussent et qui sont constitués de deux parties. Dans une forme de réalisation, une partie contient un peroxyde tel que du peroxyde d'hydrogène et peut contenir un acide faible. L'autre partie contient un carbonate, un hypochlorite, un générateur d'hypochlorite ou une matière contenant du manganèse. Au moins une de ces deux parties contient également un tensio-actif.
PCT/US1998/001744 1997-02-05 1998-01-30 Nettoyeur de blanchiment produisant de la mousse WO1998033880A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU62560/98A AU6256098A (en) 1997-02-05 1998-01-30 Bleaching cleaner that foams

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US79561897A 1997-02-05 1997-02-05
US08/795,618 1997-02-05

Publications (1)

Publication Number Publication Date
WO1998033880A1 true WO1998033880A1 (fr) 1998-08-06

Family

ID=25166018

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/001744 WO1998033880A1 (fr) 1997-02-05 1998-01-30 Nettoyeur de blanchiment produisant de la mousse

Country Status (3)

Country Link
AU (1) AU6256098A (fr)
WO (1) WO1998033880A1 (fr)
ZA (1) ZA98935B (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001000765A1 (fr) * 1999-06-28 2001-01-04 The Procter & Gamble Company Compositions liquides de detergent aqueux comprenant un systeme effervescent
EP1109885A1 (fr) * 1998-08-31 2001-06-27 The Clorox Company Produit moussant pour deboucher les tuyaux d'ecoulement
EP1130082A1 (fr) * 2000-03-03 2001-09-05 Unilever Plc Compositions de nettoyage
US6479444B1 (en) 1999-07-08 2002-11-12 The Clorox Company Foaming drain cleaner
US6583103B1 (en) 2002-08-09 2003-06-24 S.C. Johnson & Son, Inc. Two part cleaning formula resulting in an effervescent liquid
US6660702B2 (en) 2000-12-08 2003-12-09 The Clorox Company Binary foaming drain cleaner
WO2004024861A1 (fr) * 2002-09-10 2004-03-25 Reckitt Benckiser Inc Compositions pour traiter des surfaces dures
US6758411B2 (en) 2002-08-09 2004-07-06 S. C. Johnson & Son, Inc. Dual bottle for even dispensing of two flowable compositions
GB2410032A (en) * 2004-01-17 2005-07-20 Reckitt Benckiser Inc Foaming two-component hard surface cleaning compositions
EP2060622A1 (fr) * 2007-11-13 2009-05-20 The Procter & Gamble Company Composition de nettoyage de surface dure
US9789216B2 (en) 2012-12-14 2017-10-17 Saban Ventures Pty Limited Synergistic disinfection enhancement
US10206404B2 (en) 2012-12-14 2019-02-19 Saban Ventures Pty Limited Disinfectant

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58191800A (ja) * 1982-04-30 1983-11-09 甲陽化成株式会社 ガス発生による高膨脹性洗浄剤
JPS5924798A (ja) * 1982-07-31 1984-02-08 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPS59164399A (ja) * 1983-03-09 1984-09-17 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPS6013897A (ja) * 1983-07-01 1985-01-24 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPS6038497A (ja) * 1983-08-12 1985-02-28 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPH0718298A (ja) * 1993-02-15 1995-01-20 Noriko Hoshi 化学反応利用による泡状万能洗浄剤
WO1995016023A1 (fr) * 1993-12-07 1995-06-15 Unilever Plc Composition de nettoyage a deux parties comprenant au moins un compose de peroxyde
JPH08120299A (ja) * 1994-10-24 1996-05-14 Lion Corp 漂白剤組成物及び漂白方法
WO1997031087A1 (fr) * 1996-02-23 1997-08-28 The Clorox Company Composition pour nettoyage de surfaces et appareil correspondant

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58191800A (ja) * 1982-04-30 1983-11-09 甲陽化成株式会社 ガス発生による高膨脹性洗浄剤
JPS5924798A (ja) * 1982-07-31 1984-02-08 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPS59164399A (ja) * 1983-03-09 1984-09-17 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPS6013897A (ja) * 1983-07-01 1985-01-24 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPS6038497A (ja) * 1983-08-12 1985-02-28 ライオン株式会社 発泡性硬表面洗浄剤組成物
JPH0718298A (ja) * 1993-02-15 1995-01-20 Noriko Hoshi 化学反応利用による泡状万能洗浄剤
WO1995016023A1 (fr) * 1993-12-07 1995-06-15 Unilever Plc Composition de nettoyage a deux parties comprenant au moins un compose de peroxyde
JPH08120299A (ja) * 1994-10-24 1996-05-14 Lion Corp 漂白剤組成物及び漂白方法
WO1997031087A1 (fr) * 1996-02-23 1997-08-28 The Clorox Company Composition pour nettoyage de surfaces et appareil correspondant

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PATENT ABSTRACTS OF JAPAN vol. 096, no. 009 30 September 1996 (1996-09-30) *

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1109885A1 (fr) * 1998-08-31 2001-06-27 The Clorox Company Produit moussant pour deboucher les tuyaux d'ecoulement
EP1109885A4 (fr) * 1998-08-31 2002-06-12 Clorox Co Produit moussant pour deboucher les tuyaux d'ecoulement
WO2001000765A1 (fr) * 1999-06-28 2001-01-04 The Procter & Gamble Company Compositions liquides de detergent aqueux comprenant un systeme effervescent
US6479444B1 (en) 1999-07-08 2002-11-12 The Clorox Company Foaming drain cleaner
EP1130082A1 (fr) * 2000-03-03 2001-09-05 Unilever Plc Compositions de nettoyage
US6900164B2 (en) * 2000-12-08 2005-05-31 The Clorox Company Binary foaming drain cleaner
US6660702B2 (en) 2000-12-08 2003-12-09 The Clorox Company Binary foaming drain cleaner
US6916771B2 (en) 2000-12-08 2005-07-12 The Clorox Company Binary foaming drain cleaner
US6583103B1 (en) 2002-08-09 2003-06-24 S.C. Johnson & Son, Inc. Two part cleaning formula resulting in an effervescent liquid
US6758411B2 (en) 2002-08-09 2004-07-06 S. C. Johnson & Son, Inc. Dual bottle for even dispensing of two flowable compositions
WO2004015052A1 (fr) * 2002-08-09 2004-02-19 S. C. Johnson & Son, Inc. Composition de nettoyage a deux constituants
WO2004024861A1 (fr) * 2002-09-10 2004-03-25 Reckitt Benckiser Inc Compositions pour traiter des surfaces dures
GB2410032A (en) * 2004-01-17 2005-07-20 Reckitt Benckiser Inc Foaming two-component hard surface cleaning compositions
WO2005068595A1 (fr) * 2004-01-17 2005-07-28 Reckitt Benckiser Inc. Compositions de nettoyage pour surfaces dures a deux constituants moussants
US7488708B2 (en) 2004-01-17 2009-02-10 Reckitt Benckiser Inc. Foaming two-component hard surface cleaning compositions
AU2005205232B2 (en) * 2004-01-17 2010-05-13 Reckitt Benckiser Llc Foaming two-component hard surface cleaning compositions
EP2060622A1 (fr) * 2007-11-13 2009-05-20 The Procter & Gamble Company Composition de nettoyage de surface dure
WO2009063393A1 (fr) * 2007-11-13 2009-05-22 The Procter & Gamble Company Composition de nettoyage de surface dure
US9789216B2 (en) 2012-12-14 2017-10-17 Saban Ventures Pty Limited Synergistic disinfection enhancement
US9872930B2 (en) 2012-12-14 2018-01-23 Saban Ventures Pty Limited Synergistic disinfection enhancement
US10206404B2 (en) 2012-12-14 2019-02-19 Saban Ventures Pty Limited Disinfectant

Also Published As

Publication number Publication date
ZA98935B (en) 1998-08-06
AU6256098A (en) 1998-08-25

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