WO1998025295A1 - Low-pressure discharge lamp - Google Patents

Low-pressure discharge lamp Download PDF

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Publication number
WO1998025295A1
WO1998025295A1 PCT/IB1997/001344 IB9701344W WO9825295A1 WO 1998025295 A1 WO1998025295 A1 WO 1998025295A1 IB 9701344 W IB9701344 W IB 9701344W WO 9825295 A1 WO9825295 A1 WO 9825295A1
Authority
WO
WIPO (PCT)
Prior art keywords
lamp
mesh body
lamp vessel
electrodes
pressure discharge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB1997/001344
Other languages
English (en)
French (fr)
Inventor
Hui-Meng Chow
Jose Azevedo
Susan Mcgee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke Philips NV
Philips Norden AB
Original Assignee
Koninklijke Philips Electronics NV
Philips Electronics NV
Philips Norden AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koninklijke Philips Electronics NV, Philips Electronics NV, Philips Norden AB filed Critical Koninklijke Philips Electronics NV
Priority to DE69731374T priority Critical patent/DE69731374T2/de
Priority to EP97945037A priority patent/EP0883895B1/en
Priority to JP10525385A priority patent/JP2000504482A/ja
Publication of WO1998025295A1 publication Critical patent/WO1998025295A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/06Main electrodes
    • H01J61/067Main electrodes for low-pressure discharge lamps
    • H01J61/0675Main electrodes for low-pressure discharge lamps characterised by the material of the electrode
    • H01J61/0677Main electrodes for low-pressure discharge lamps characterised by the material of the electrode characterised by the electron emissive material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/06Main electrodes
    • H01J61/067Main electrodes for low-pressure discharge lamps
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/06Main electrodes
    • H01J61/09Hollow cathodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/36Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors

Definitions

  • Such a low-pressure discharge lamp is known from EP-A 0 562 679 (PHN 14.189).
  • the known lamp is of a simple construction which is easy to realise.
  • the lamp vessel has a tubular main part and spherical auxiliary parts at both sides which are connected to the main part by metal tubes. These metal tubes serve as current conductors. End portions thereof protruding inside the main part of the discharge vessel form electrodes.
  • the lamp vessel can be cleaned and be provided with its filling, through the metal tubes.
  • the auxiliary parts can be obtained by fusing a glass tube to each of the metal tubes and subsequently closing the glass tubes free ends, for example by fusion.
  • the construction of the known lamp renders it easy to realise lamps of a comparatively small internal diameter, for example 1.5 to 7 mm, and of a comparatively great length of, for example, 1 m or more.
  • the ionizable filling may comprise a rare gas or a mixture of rare gases, or in addition a component capable of evaporation such as, for example, mercury.
  • the lamp vessel wall may be provided with a fluorescent material.
  • the lamp may be used for lighting purposes, or as a signal lamp, for example with a neon filling as a tail lamp or stop lamp in vehicles. In the latter application the lamp has the advantage over an incandescent lamp that it emits its full light after 10 ms already, instead of 300 ms after being energized.
  • High current narrow diameter (ND) fluorescent and neon lamps are highly desirable yet are non-existent. The requirement for such lamps, among others, is a low cathode fall of, for example, less than 80 volts. There is therefore a need in the art for high current and high efficacy ND lamps. Such higher current ND fluorescent lamps may be used in automobile interior lighting or as backlights in laptop computers.
  • the cathode fall of an electrode in a lamp can be reduced by promoting electron emission.
  • a tungsten coil coated with triple carbonates for example a mixture of barium, strontium and calcium carbonates
  • these lamps have four terminals, two for each electrode on either side.
  • the carbonates are thermally converted into oxides in the lamp by passing a current through the tungsten coil.
  • these oxides [(Ba,Sr,Ca)O] promote electron emission via thermionic emission when the electrode is heated to 1000-1300° C, either by passing a heating current through the tungsten coil or by ion-bombardment. It would be desirable to have novel electrodes which do not require the extra thermal in-lamp processing step during manufacture, particularly since this step requires expensive processing time.
  • An ND lamp requires single-lead electrodes because of geometrical constraints and therefore ion-bombardment is the only source of cathode heating. Due to the absence of a coil the use of carbonates in single-lead ND lamps would require external RF heating to convert them to oxides during manufacturing. This adds an additional, even more costly step to the manufacturing process.
  • this object is realised in that at least one of the electrodes is a mesh body and in that the electron emitter comprises at least one mixed oxide of at least one of the elements Ba and Sr with at least one metal from the group comprising Ta, Ti, Zr, Sc, Y, La and the lanthanids, wherein electron emitters of the composition Ba x Sr 1 . x Y 2 O 4 , x being in the range of 0 to 1 , are excluded.
  • the non-prepublished Application IB 95/00951 (PHN 15023) describes a narrow diameter lamp according to the above mentioned kind in which the electrodes are a mesh body.
  • the mesh body may be covered with Ba x Sr 1 . x Y 2 O 4 as an emitter, wherein x is, for example, 0.75.
  • the electrode is formed by a mesh body carrying an electron emitter material.
  • a mesh body of the same material and geometry has a significantly lower mass and therefore a significantly lower heat capacity.
  • Such a mesh body will have a lower heat loss to its surroundings at a given temperature than a corresponding continuous walled electrode.
  • the mesh body can be operated at a significantly higher temperature than an electrode having a continuous wall. The higher temperature promotes greater emission from the electron emitter material and leads to lower cathode fall. With a lower cathode fall, the lamp can have a higher lamp current and greater light output without increasing the temperature in the seal area of the lamp.
  • the mesh body has the capability of reducing sputtering of metal from the electrode onto the wall of the lamp vessel and the consequent darkening of the inner wall of the lamp vessel. This is the result of faster heating of the tip portion of the mesh body to its operating temperature by ion bombardment during the ignition phase, due to the lower mass of the mesh body, providing faster glow-to-arc transition. Reduced sputtering can also be attributed to the capability of improved adhesion of the emitter material to the mesh body.
  • the mesh body is hollow and circular cylindrical and extends at least substantially parallel to the lamp axis. Such a shape is advantageous for narrow diameter lamps because within a narrow diameter the length can be selected to carry a sufficient quantity of emitter material. Such a shape is easy to form by rolling a length of the mesh material about a cylindrical jig, welding, and then cutting to length.
  • the electron emitter comprises one or more mixed oxides selected from the group consisting of Ba 4 Ta 2 O 9 , Ba 5 Ta 4 O 15 , BaY 2 O 4 , BaCeO 3 , Ba 2 TiO 4 , BaZrO 3 , Ba x Sr ! . x TiO 3 , and Ba x Sr ⁇ _ x ZrO 3 , wherein x ranges from a value of 0 to 1.
  • the electron emitter comprises one or more mixed oxides selected from the group consisting of Ba 4 Ta 2 O 9 , BaCeO 3 , Ba 2 TiO 4 , BaZrO 3 , Ba 5 Sr 5 TiO 3 and Ba 5 Sr 5 ZrO 3
  • the lamp which has only one electrode provided with a mesh body is highly suitable for DC operation.
  • the electrode with the mesh body is the cathode then. It is favourable, however, for example for AC operation, when both electrodes are fitted with such a mesh body.
  • the mesh body may be fixed directly to a hollow cylindrical ferrule or other conductive element serving as the current conductor for the electrode.
  • an electrically conductive thermal isolator is preferably interposed between the current conductor and the mesh body.
  • the thermal isolator may be a length of wire as in the above described embodiments.
  • the wire may be mounted to the current conductor and to the mesh body with welds, for example with resistance welds or laser welds.
  • the electrically conductive thermal isolator may comprise two or more wires. This embodiment may be preferable in lamps which are subjected to accelerations during operation, for example owing to shocks or vibrations.
  • the thermal isolator may be an integral elongate extension of the ferrule formed, for example, by removing material from the inwardly protruding end of the ferrule by cutting, grinding, sawing, etc.
  • the current conductor may be made of a metal which has a coefficient of expansion which corresponds to that of the glass of the lamp vessel, for example a CrNiFe alloy in the case of lime glass, for example Cr 6% by weight, Ni 42% by weight, and the rest Fe.
  • a current conductor may be used, for example made of Ni/Fe or NiCoFe, for example Ni 29% by weight, Co 17% by weight, the rest Fe, for example with a diameter of 1.5 mm and a wall thickness of 0.12 mm.
  • the current conductor may consist of, for example, CrNiFe with 18% Cr by weight, 10% Ni by weight, and the rest Fe, or of Ni.
  • the electrically conducting thermal isolator may then be, for example, NiCr, for example Ni80Cr20 (weight/ weight), for example in the form of wire of 0.125 or 0.250 mm diameter.
  • the current conductor is solid.
  • the lamp vessel may be manufactured in a chamber proces.
  • a favorable embodiment is characterised in that the current conductor connected to the mesh body is a tube and in that the lamp vessel has a main part and an auxiliary part which parts are connected to each other by the tube.
  • the tube can be used to evacuate the lamp and to provide it with its filling, which renders the manufacturing proces more easy.
  • An attractive embdodiment is characterised in that the mesh body is arranged in the auxiliary part of the lamp vessel.
  • This has the advantage that material detached from the mesh body during operation will end up substantially outside the main part of the lamp vessel, so that this part itself remains clear. The lumen output accordingly remains high during lamp life.
  • This embodiment is of particular importance for lamps whose filling comprises a component capable of evaporation. Since the discharge arc applies itself mainly to the mesh body during normal operation, the space outside the lamp vessel, where the mesh body is accommodated, assumes a comparatively high temperature. The evaporation component can thus have a comparatively high vapour pressure.
  • FIG. 1 shows schematically an embodiment of the low-pressure discharge lamp according to the invention
  • Figure 2 shows a portion of the lamp of Figure 1 in more detail;
  • Figure 3 shows a corresponding portion of a second embodiment; and
  • Figure 4 shows a corresponding portion of a third embodiment.
  • the low-pressure discharge lamp has a tubular glass lamp vessel 60.
  • the lamp vessel has a main part 61 and auxiliary parts 62. It has an ionizable filling comprising rare gas, such as for example argon or neon, or it may contain mercury vapor, depending on the lamp type.
  • a luminescent layer 2 may cover the inner surface or at least a major portion thereof.
  • the lamp vessel is made of glass which transmits the visible radiation generated in the luminescent layer 2.
  • Current conductors in the form of tubes 30 enter the main part of the lamp vessel each at a respective end portion B and connect the main part to a respective auxiliary part.
  • the current conductors 30 have a surface 31 outside the lampvessel.
  • a mesh body 20, shown in detail in Fig.2, has been laser or resistance welded onto the current conductor 30 with a thermal isolator, for example, a Ni or Ni-Cr wire 40.
  • the mesh body 20 is coated with an electron emitter material 50 on at least one of its surfaces, and preferably on an internal surface.
  • the cylindrical mesh body 20 is easily formed by wrapping a mat of the mesh material around a rod and welding the opposing edges together, with or without overlap.
  • a long mesh cylinder is easily formed which can be then be cut to obtain a protrusion, or electrode tip, 20 of the desired length.
  • the mesh protrusion is then connected to the wire 40 via welding.
  • the mesh body 20 is coated with emitter material by dipping the mesh body in a suspension of the emitter material.
  • the emitter material may also be applied to the screen by other methods, for example, by spraying.
  • 100 x 100 mesh material having an opening size of 0.14 mm and an open area of about 30% was rolled into a hollow tube, welded, and cut into 3 mm lengths.
  • a NiCr wire was welded to the mesh body, and the mesh body was dip coated with emitter materials (eg. Ba 4 Ta 2 O 9 ) mixed with a binder (nitrocellulose) and an appropriate solvent (butyl acetate). The coated mesh was then heated to 1000°C to burn off the binder. For Ni and Mo mesh, the binder was burned off in He-H 2 . While for Ta mesh, binder burnoff was carried out in Ar.
  • FIG 3 shows another embodiment, in which the thermal isolator 40 is an integral elongate extension of the ferrule 30 having a length "1" and a width "w" obtained by removing material from the ferrule 30, such as by sawing, grinding, etc.
  • the hollow ferrule 30 serves both as a current conductor to connect the electrode to a source of electric potential outside of the lamp envelope and as a conduit to evacuate and fill the lamp vessel.
  • Such a seal structure is useful for lamps having a narrow diameter, for example less than 5 mm.
  • other seal structures are used, such as a lamp stem. With a lamp stem, a glass tube is used to evacuate and fill the lamp vessel, and the current conductor is in that case a wire.
  • Figure 4 illustrates an embodiment of an electrode for a lamp having a lamp stem in which the mesh cylinder body is connected directly to a current conductor formed by a wire feed- through.
  • the wire has an offset to maintain the mesh body aligned with the lamp axis.
  • the Table shows the cathode fall for a group of test lamps having the geometry described with respect to Figure 4 and having mesh material Ni, Mo or Ta.
  • the lamps were fluorescent lamps with mercury, argon at 40 mbar and 40 a current.
  • the emitter material was Ba 4 Ta O 9 .
  • the results include lamps operated continuously and lamps cycled on/off. TABLE

Landscapes

  • Discharge Lamp (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)
PCT/IB1997/001344 1996-12-04 1997-10-27 Low-pressure discharge lamp Ceased WO1998025295A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE69731374T DE69731374T2 (de) 1996-12-04 1997-10-27 Niederdruckentladunglampe
EP97945037A EP0883895B1 (en) 1996-12-04 1997-10-27 Low-pressure discharge lamp
JP10525385A JP2000504482A (ja) 1996-12-04 1997-10-27 低圧放電ランプ

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/764,700 US5905339A (en) 1995-12-29 1996-12-04 Gas discharge lamp having an electrode with a low heat capacity tip
US08/764,700 1996-12-04

Publications (1)

Publication Number Publication Date
WO1998025295A1 true WO1998025295A1 (en) 1998-06-11

Family

ID=25071505

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB1997/001344 Ceased WO1998025295A1 (en) 1996-12-04 1997-10-27 Low-pressure discharge lamp

Country Status (6)

Country Link
US (1) US5905339A (enExample)
EP (1) EP0883895B1 (enExample)
JP (1) JP2000504482A (enExample)
CN (1) CN1139101C (enExample)
DE (1) DE69731374T2 (enExample)
WO (1) WO1998025295A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003504792A (ja) * 1997-07-23 2003-02-04 ジョージア テック リサーチ コーポレイション ガス放電装置内の動作電圧を減少させる装置及び方法
WO2004025692A1 (en) * 2002-09-12 2004-03-25 Philips Intellectual Property & Standards Gmbh Low-pressure gas discharge lamp with electron emitter substances similar to batio3

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Publication number Priority date Publication date Assignee Title
US6300722B1 (en) * 1997-11-05 2001-10-09 Jorge M. Parra Non-thermionic ballast-free energy-efficient light-producing gas discharge system and method
US6465971B1 (en) * 1999-06-02 2002-10-15 Jorge M. Parra Plastic “trofer” and fluorescent lighting system
US6411041B1 (en) * 1999-06-02 2002-06-25 Jorge M. Parra Non-thermionic fluorescent lamps and lighting systems
US6384534B1 (en) * 1999-12-17 2002-05-07 General Electric Company Electrode material for fluorescent lamps
DE10062974A1 (de) * 2000-12-16 2002-06-20 Philips Corp Intellectual Pty Hochdruckgasentladungslampe und Verfahren zu ihrer Herstellung
US6921878B2 (en) * 2003-02-04 2005-07-26 Ado Enterprise Co., Ltd. Warmth-keeping structure of cold cathode lamp
JP2005209382A (ja) 2004-01-20 2005-08-04 Sony Corp 放電灯および放電灯用電極
DE102004004655A1 (de) * 2004-01-29 2005-08-18 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Niederdruckentladungslampe
CN101297452A (zh) * 2005-09-14 2008-10-29 力特保险丝有限公司 充气式电涌放电器、激活化合物、点火条及相应方法
GB0523478D0 (en) * 2005-11-18 2005-12-28 Lg Philips Displays B V Improvements in and relating to electrodes
US7893617B2 (en) * 2006-03-01 2011-02-22 General Electric Company Metal electrodes for electric plasma discharge devices
DE102007021384A1 (de) * 2007-05-04 2008-11-13 Neon Products Lichttechnik Gmbh Elektrode für Niederdruckentladungslichtquellen sowie Niederdruckentladungslichtquelle
CN104091740A (zh) * 2014-01-24 2014-10-08 朱惠冲 高强度稀土钼管冷阴极及其制备工艺
JP6691317B2 (ja) * 2015-10-06 2020-04-28 ウシオ電機株式会社 ショートアーク型放電ランプ
CN117383950B (zh) * 2023-12-11 2024-03-05 中国航发北京航空材料研究院 用于镍基高温合金脱硫的非钙质耐火材料坩埚及制备方法

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EP0562679A1 (en) * 1992-03-27 1993-09-29 Koninklijke Philips Electronics N.V. Low pressure discharge lamp and luminaire provided with such a lamp
US5675214A (en) * 1994-09-21 1997-10-07 U.S. Philips Corporation Low-pressure discharge lamp having hollow electrodes

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US4866339A (en) * 1987-12-21 1989-09-12 Gte Laboratories Incorporated Beam mode fluorescent lamp
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US5675214A (en) * 1994-09-21 1997-10-07 U.S. Philips Corporation Low-pressure discharge lamp having hollow electrodes

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003504792A (ja) * 1997-07-23 2003-02-04 ジョージア テック リサーチ コーポレイション ガス放電装置内の動作電圧を減少させる装置及び方法
WO2004025692A1 (en) * 2002-09-12 2004-03-25 Philips Intellectual Property & Standards Gmbh Low-pressure gas discharge lamp with electron emitter substances similar to batio3

Also Published As

Publication number Publication date
CN1214797A (zh) 1999-04-21
CN1139101C (zh) 2004-02-18
US5905339A (en) 1999-05-18
JP2000504482A (ja) 2000-04-11
EP0883895A1 (en) 1998-12-16
EP0883895B1 (en) 2004-10-27
DE69731374D1 (de) 2004-12-02
DE69731374T2 (de) 2005-11-10

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