WO1998023808A1 - Compositions assouplissantes liquides et limpides - Google Patents

Compositions assouplissantes liquides et limpides Download PDF

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Publication number
WO1998023808A1
WO1998023808A1 PCT/KR1997/000244 KR9700244W WO9823808A1 WO 1998023808 A1 WO1998023808 A1 WO 1998023808A1 KR 9700244 W KR9700244 W KR 9700244W WO 9823808 A1 WO9823808 A1 WO 9823808A1
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WIPO (PCT)
Prior art keywords
weight
compositions
composition
softner
liquid fabric
Prior art date
Application number
PCT/KR1997/000244
Other languages
English (en)
Inventor
Chul Woo Kim
Eul Kyu Lee
Dong Tak Lee
Original Assignee
Cheil Jedang Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cheil Jedang Corporation filed Critical Cheil Jedang Corporation
Priority to AU50694/98A priority Critical patent/AU5069498A/en
Publication of WO1998023808A1 publication Critical patent/WO1998023808A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2048—Dihydric alcohols branched
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/388—Amine oxides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • the present invention relates to liquid fabric softner compositions. More particularly, it relates to liquid fabric softner compositions which have water-like appearance and are crystal-clear while providing sufficient fabric softening efficacy and exhibiting good storage stability.
  • U.S. Patent No. 5,427,697 describes clear or translucent textile softening compositions which contain imidazoline, imidazolinium, di(2-amido- ethyl)methyl quaternary ammonium compounds, mono long-chain alkyl cationic quaternary ammonium compounds and non-aqueous solvents.
  • U.S. Patent No. 5,399,272 describes clear or translucent fabric softner compositions which contain ester quaternary ammonium compounds, mono long-chain alkyl cationic quaternary ammonium compounds and non-aqueous solvents.
  • U.S. Patent No. 5,490,944 discloses liquid fabric softner compositions which includes a blend of dialkyl quaternary ammonium salt and imidazolinium quaternary ammonium salt in the ratio of 8: 1 to 3.6: 1, and meets the required clarity.
  • U.S. Patent No. 5,492,636 teaches that the desired clarity of the fabric softner composition is obtained by using cationic surfactant and 10 to 25% by weight of butyl carbitol.
  • the aforementioned patent literature and other art do not specify methodology to meet with the clarity for the fabric softner composition.
  • the present invention provides clear liquid fabric softner compositions comprising:
  • n is the number of 2 to 4; R and R' are independently Cio-Cig alkenyl; and X " is selected from an anion group consisting of chloride, methylsulfate and ethylsulfate;
  • R is C ⁇ 0 -C 2 alkyl
  • R' is selected from a group consisting of methyl, ethyl, hydroxyethyl and benzyl
  • X " is selected from an anion group consisting of chloride, methylsulfate and ethylsulfate
  • R is Cs-Cis alkyl or alkylphenyl; n is the number of 9 to 60; and
  • (E) purified water provided that 1) if B/E is more than 0.08, then (B+C)/A is more than 1.2; 2) if B/E is more than 0.06, then (B+C)/A is more than 1.4; 3) if B/E is more than 0.04, then (B+Q/A is more than 2.0; 4) if B/E is more than 0.03, then (B+C)/A is more than 2.5; 5) if B/A is more than 0.9, then (B+C)/A is more than 1.1; 6) if B/A is more than 0.5, then (B+C)/A is more than 3.3; or 7) if B/A is more than 0.7, then (B+C)/A and B/E is more than 0.9 and 0.07, respectively.
  • the clear liquid fabric softner composition of the present invention contains as a fabric softner active component from 2% to 40%> by weight of the composition, imidazolinium salt of the formula:
  • n is the number of 2 to 4; R and R are independently do-Cig alkenyl; and X is selected from an anion group consisting of chloride, methylsulfate and ethylsulfate.
  • the clear liquid fabric softner composition of the present invention contains from 2% to 30% by weight of the composition, mono long-chain alkyl quaternary ammonium salts as a dispersibility aid which functions to disperse fabric softner cationic surfactants in water.
  • mono long-chain alkyl quaternary ammonium compounds are represented by the following formula:
  • R is C ⁇ o-C 22 alkyl
  • R is selected from a group consisting of methyl, ethyl, hydroxyethyl and benzyl
  • X " is selected from an anion group consisting of chloride, methylsulfate and ethylsulfate.
  • the clear liquid fabric softner composition of the present invention contains from 2% to 60% by weight of the composition, a solubilizer which enhances the solubility of cationic components in an aqueous solution.
  • a solubilizer which enhances the solubility of cationic components in an aqueous solution.
  • the possible solubilizer to be used in the present composition includes ethanol, propanol, ethylene glycol, propylene glycol, isopropyl glycol, dipropylene glycol, 2-methyl-l,3-propanediol, diethylene glycol monobutylether, propylene carbonic salt or mixtures thereof.
  • the clarity of the present liquid fabric softner compositions depends on the correlative ratios of imidazolinium salt (A) as softner active, mono long-chain alkyl quaternary ammonium salt (B) as dispersibility aid, solubilizer (C) as solubility aid, and purified water (E).
  • A imidazolinium salt
  • B mono long-chain alkyl quaternary ammonium salt
  • C solubility aid
  • purified water E
  • the ratio of imidazolinium salt to purified water (A/E) is higher, the clarity of the composition is increased.
  • the higher the ratio of mono long-chain alkyl quaternary ammonium salt and/or solubilizer to imidazolinium salt or purified water (B/E, B/A, (B+C)/A) is, the clearer the composition.
  • the above components A, B, C and E should be strictly used in compliance with any one of the following ratio requirements: 1) if B/E is more than 0.08, then (B+C)/A is more than 1.2;
  • the clear liquid fabric softner compositions of the present invention contains from 0.3% to 5.0% by weight of the composition, polyoxyethylene alkylether which can serve as the stability aid for the composition.
  • polyoxyethylene alkylether of the present invention is represented by the following formula:
  • these clear liquid fabric softner compositions contain polyoxyethylene alkylether wherein R is C ⁇ 4 -C ⁇ 6 alkylphenyl and n is the number of 40 to 60.
  • the clear liquid fabric softner compositions of the present invention optionally contain less than 3%> by weight of the composition, amine oxides of the formula:
  • R is Cio-is alkyl; and R is selected from a group consisting of methyl, ethyl, propyl and hydroxyethyl.
  • These amine oxide compounds can function to improve the clarity of the liquid fabric softner composition of the present invention and the aqueous solution of the softner.
  • the amine oxide compound is used in an amount of more than 3%> by weight of the composition, excessive foams disadvantageously generate during a laundering operation.
  • Optional additives such as pH regulator (for example, citric aicd, boric aicd and hydrochloric acid, etc.), organic solvent, polymer (for example, hydroxyethyl cellulose), hydrocarbon oil, perfume can be included in the clear liquid fabric softner composition of the present invention. These additives can aid for assuring the function and stability of the softner composition.
  • the liquid fabric softner compositions of the present invention are prepared by the following procedure:
  • a water phase is prepared as follows: (a) adding purified water;
  • An oil phase is prepared as follows:
  • oil soluble additives perfumes, organic solvents, hydrocarbon oils
  • compositions were made by the following:
  • Ethanol was poured into a separate bath.
  • Variquat 80 MC and Varisoft 3690 were added in sequence, and the solution was mixed at the temperature of 20 °C to 40 ° C to form an oil phase.
  • the previously obtained water phase was added to the oil phase with stirring over 30 rpm.
  • the remaining portion of purified water was added to the solution, mixed for 10-20 minutes, and filtrated to obtain the desired liquid fabric softner composition.
  • the liquid fabric softner composition was visually observed by a panel of 20. If all panelists consented that the appearance of the softner composition is crystal-clear, then the product was defined as "clear.” In addition, after the liquid fabric softner composition was incorporated into water, the resulting aqueous solution was visually observed by a panel of 20. Likewise, the aqueous solution was defined as "clear” when all panelists consented that the aqueous solution has crystal-clear appearance. The results are shown in Table 2 below.
  • a control standard liquid softner was formulated from 5.7% by weight of distearyl dimethylammonium chloride (75%>), 5.0% by weight of ethylene glycol and the remaining purified water to adjust 100% by weight.
  • This control composition was used in a same manner as the present compositions, and comparison between the two was made on softness results. If the softness result from the present test composition is superior to that from the control composition, then the present test composition was recorded as three (3) points. If the softness result from the present test composition is equal to that from the control composition, then the present test composition was recorded as two (2) points. If the softness result of the present test composition is inferior to that from the control composition, then the present test composition was recorded as one (1) point. The results were indicated as average scores in Table 2 below.
  • compositions were made by the following: An appropriate amount of purified water was poured into a bath and heated to 45 °C-60 ° C . Polyoxyethylene alkylether was added to the warm water and mixed until the solution was clear. Amine oxide was added to the solution and throughly mixed at 20 ° C-40 ° C with stirring over 30 rpm to form a water phase.
  • Ethanol was poured into a separate bath.
  • Variquat 80 MC and Varisoft 3690 were added in sequence, and the solution was mixed at the temperature of 20 ° C to 40 ° C to form an oil phase.
  • the previously obtained water phase was added to the oil phase with stirring over 30 rpm.
  • the remaining portion of purified water was added to the solution, mixed for 10-20 minutes, and filtrated to obtain the desired liquid fabric softner composition.
  • compositions were made in the same manner as described in Examples 1 to 5, but using the ingredients and amounts (% by weight) shown in Table 5 below.
  • compositions were made by the following: An appropriate amount of purified water was poured into a bath and heated to 45°C-60 ° C . Polyoxyethylene alkylether was added to the warm water and mixed until the aqueous solution was clear. Amine oxide was added to the solution and then pigment and citric acid were added. The solution was throughtly mixed at 20 ° C-40 ° C with stirring over 30 rpm to form a water phase.
  • Ethylene glycol was poured into a separate bath. Variquat 80 MC and Varisoft 3690 were added in sequence, and the solution was stirred. Perfume and hydrocarbon oil were then added, and the solution was mixed at the temperature of 20 °C to 40 "C to form an oil phase.
  • the previously obtained water phase was added to the oil phase with stirring over 30 rpm.
  • the remaining portion of purified water was added to the solution, mixed for 10-20 minutes and filtrated to obtain the desired liquid fabric softner composition.
  • compositions were made in the same manner as described in Examples 6 to 10, except for the ingredients and amounts (% by weight) shown in Table 13 below.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Cette invention a trait à des compositions assouplissantes liquides et limpides ayant l'apparence de l'eau, efficaces en tant qu'adoucisseur de tissu et restant stables une fois stockées. Ces compositions comportent de 2 à 40 % en poids d'un sel d'imidazolinium (composant A), de 2 à 30 % en poids d'un sel d'ammonium quaternaire d'alkyle mono à chaîne longue (composant B), de 2 à 60 % en poids d'un agent de solubilisation (composant C) et de 0.3 à 5 % en poids d'un alkyléther de polyoxyéthylène (composant D), le reste étant constitué d'eau purifiée (composant E), pourvu que, 1), si la valeur de B/E est supérieure à 0,08, celle de (B + C)/A est alors supérieure à 1,2, 2), si la valeur de B/E est supérieure à 0,06, celle de (B + C)/A est alors supérieure à 1,4, 3), si la valeur de B/E est supérieure à 0,04, celle de (B + C)/A est alors supérieure à 2,0, 4), si la valeur de B/E est supérieure à 0,03, celle de (B + C)/A est alors supérieure à 2,5, 5), si la valeur de B/A est supérieure à 0,9, celle de (B + C)/A est alors supérieure à 1,1, 6), si la valeur de B/A est supérieure à 0,5, celle de (B + C)/A est alors supérieure à 3,3, ou 7), si la valeur de B/A est supérieure à 0,7, celles de (B + C)/A sont alors supérieures à 0,9 et à 0,07, respectivement.
PCT/KR1997/000244 1996-11-28 1997-11-27 Compositions assouplissantes liquides et limpides WO1998023808A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU50694/98A AU5069498A (en) 1996-11-28 1997-11-27 Clear liquid fabric softner compositions

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR1996/58821 1996-11-28
KR19960058821 1996-11-28
KR1019970028381A KR100259266B1 (ko) 1996-11-28 1997-06-27 액체 섬유유연제 조성물
KR1997/28381 1997-06-27

Publications (1)

Publication Number Publication Date
WO1998023808A1 true WO1998023808A1 (fr) 1998-06-04

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AU (1) AU5069498A (fr)
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001002522A2 (fr) * 1999-07-02 2001-01-11 The Dow Chemical Company Formulation adoucissantes limpides renfermant des additifs alcoxyles
GB2353807A (en) * 1999-09-02 2001-03-07 Mcbride Robert Ltd Clear fabric conditioning fluid
WO2001096510A1 (fr) * 2000-06-16 2001-12-20 Unilever Plc Compositions adoucissantes pour tissus
US7012059B2 (en) * 2002-06-10 2006-03-14 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Fabric detergent compositions
EP2592134A3 (fr) * 2011-11-13 2013-07-10 Compad Consulting GmbH Détersifs et nettoyants durables
WO2019048556A1 (fr) * 2017-09-06 2019-03-14 Evonik Degussa Gmbh Microémulsion comprenant un composé d'ammonium quaternaire, en particulier pour la production de formulations d'assouplissant
US11312926B2 (en) 2017-09-25 2022-04-26 Evonik Operations Gmbh Polysiloxane-containing concentrates with improved storage stability and use thereof in textile care compositions
US11692153B2 (en) 2018-07-05 2023-07-04 Evonik Operations Gmbh Long-chain alkyl esterquats for highly viscous laundry and cleaning formulations

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101215488B1 (ko) 2011-05-06 2012-12-26 (재)한국섬유소재연구소 저온안정성이 우수한 소핑유연제 조성물 및 이의 제조방법
KR101876314B1 (ko) * 2018-02-07 2018-07-09 강인숙 저황변 유연제 및 이의 제조방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01192873A (ja) * 1988-01-22 1989-08-02 Kenjiro Kato 濃厚布類柔軟化組成物
US5427697A (en) * 1993-12-17 1995-06-27 The Procter & Gamble Company Clear or translucent, concentrated fabric softener compositions
US5490944A (en) * 1994-08-11 1996-02-13 Colgate-Palmolive Company Liquid fabric softener compositions
US5492636A (en) * 1994-09-23 1996-02-20 Quest International Fragrances Company Clear concentrated fabric softener

Patent Citations (4)

* Cited by examiner, † Cited by third party
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WO2001002522A2 (fr) * 1999-07-02 2001-01-11 The Dow Chemical Company Formulation adoucissantes limpides renfermant des additifs alcoxyles
WO2001002522A3 (fr) * 1999-07-02 2002-09-26 Dow Chemical Co Formulation adoucissantes limpides renfermant des additifs alcoxyles
GB2353807A (en) * 1999-09-02 2001-03-07 Mcbride Robert Ltd Clear fabric conditioning fluid
WO2001096510A1 (fr) * 2000-06-16 2001-12-20 Unilever Plc Compositions adoucissantes pour tissus
US7015188B2 (en) 2000-06-16 2006-03-21 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Fabric conditioning compositions
US7012059B2 (en) * 2002-06-10 2006-03-14 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Fabric detergent compositions
EP2592134A3 (fr) * 2011-11-13 2013-07-10 Compad Consulting GmbH Détersifs et nettoyants durables
WO2019048556A1 (fr) * 2017-09-06 2019-03-14 Evonik Degussa Gmbh Microémulsion comprenant un composé d'ammonium quaternaire, en particulier pour la production de formulations d'assouplissant
CN111051485A (zh) * 2017-09-06 2020-04-21 赢创运营有限公司 特别用于生产织物柔软剂配制物的包含季铵化合物的微乳剂
US11485938B2 (en) 2017-09-06 2022-11-01 Evonik Operations Gmbh Microemulsion comprising quaternary ammonium compound, especially for production of fabric softener formulations
US11312926B2 (en) 2017-09-25 2022-04-26 Evonik Operations Gmbh Polysiloxane-containing concentrates with improved storage stability and use thereof in textile care compositions
US11692153B2 (en) 2018-07-05 2023-07-04 Evonik Operations Gmbh Long-chain alkyl esterquats for highly viscous laundry and cleaning formulations

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KR19980041772A (ko) 1998-08-17
AU5069498A (en) 1998-06-22
KR100259266B1 (ko) 2000-06-15

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