WO1997028246A1 - Procede pour la production d'une composition detergente - Google Patents
Procede pour la production d'une composition detergente Download PDFInfo
- Publication number
- WO1997028246A1 WO1997028246A1 PCT/EP1997/000118 EP9700118W WO9728246A1 WO 1997028246 A1 WO1997028246 A1 WO 1997028246A1 EP 9700118 W EP9700118 W EP 9700118W WO 9728246 A1 WO9728246 A1 WO 9728246A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bulk density
- process according
- detergent
- low
- granules
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000003599 detergent Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 27
- 239000007858 starting material Substances 0.000 claims abstract description 19
- 239000008187 granular material Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 12
- 239000011236 particulate material Substances 0.000 claims abstract description 10
- 238000001694 spray drying Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- 239000002243 precursor Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000010457 zeolite Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 150000005323 carbonate salts Chemical class 0.000 claims description 2
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 239000012530 fluid Substances 0.000 abstract description 10
- 239000000843 powder Substances 0.000 description 25
- 238000005469 granulation Methods 0.000 description 9
- 230000003179 granulation Effects 0.000 description 9
- 235000019832 sodium triphosphate Nutrition 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- -1 potassium alkyl sulphates Chemical class 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- VSXGXPNADZQTGQ-UHFFFAOYSA-N oxirane;phenol Chemical compound C1CO1.OC1=CC=CC=C1 VSXGXPNADZQTGQ-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
Definitions
- the present invention relates to a process for the production of a detergent composition.
- the invention is concerned with a process for the production of a detergent composition having a medium bulk density without the use of a spray-drying step involving a high shear mixing step and a very low shear mixing step and to detergent compositions thereby produced.
- detergent compositions have been produced by a spray-drying process in which the components of the composition are mixed with water to form an aqueous crutcher slurry which is then sprayed into a spray-drying tower and contacted with hot air to remove water whereby detergent particles, often referred to as a "base" powder are obtained.
- the particles so obtained have a high porosity.
- powders produced by this method typically have a bull- density of 300 to 550 g/1 or even up to 650 g/1.
- Spray-dried powders generally provide good powder delivery characteristics such as dispensing and dissolution. However, the capital and operating costs of the spray-drying process are high. Nevertheless there remains a significant consumer demand for such low density powders.
- detergent powders having a high bulk density have been produced by mechanical mixing processes. Bulk densities of 700 to 900 g/1 and even higher have been obtained. Typically such powders are produced by densifying a spray-dried base powder in one or more mechanical mixers, optionally with the addition of further components, or by mixing the components of the composition in a continuous or batch mixing process without the use of a spray-drying step.
- EP 367 339 discloses a process for the production of a detergent composition having a high bulk density in which a particulate starting material is treated in a high speed mixer, a moderate speed mixer wherein the material is brought into or maintained in a deformable state, and then dried and/or cooled.
- the starting material may be a spray-dried base powder or the components of the composition may be employed without a prior spray-drying step in the detergent production process.
- Powders having a high bulk density have a low packing volume which is advantageous for storage and distribution operations and also for the consumer. Furthermore, if a spray-drying step is not employed, the capital and operating costs are typically much lower and the process uses less energy and so provides an environmental benefit. The avoidance of a spray-drying step in the detergent production process is therefore desirable.
- EP 544 365 (Unilever) is concerned with the production of a high bulk density detergent composition and refers to the bulk density of a detergent powder being dependent upon the bulk density of the starting materials in the case of a mixing process.
- Treating a porous spray-dried material in a mechanical mixing process typically leads to an increase in bulk density as the powder porosity is reduced.
- a powder having a surprisingly low bulk density for example less than 700 g/1, may be obtained by a process in which a spray-drying step is not employed, involving a high shear mixing step and a very low shear mixing step if a component having a low bulk density is incorporated in the very low shear mixing step. Further, such a powder exhibits good powder properties.
- a first aspect of the invention provides a process for the production of a detergent composition or component having a bulk density of less than 700 g/1 which does not comprise a spray-drying step and which process comprises mixing a particulate starting material with a liquid binder in a mixer granulator, preferably having both a stirring and a cutting action, to form granules wherein the starting material and/or binder comprises a non-soap detergent active or a precursor thereof, feeding the said granules to a very low shear mixing zone and contacting the granules with a particulate material having a bulk density of not more than 700g/l to produce a detergent composition or component having a bulk density of less than 700 g/1.
- a second aspect of the invention provides a detergent composition or component having a bulk density of less than 700 g/1 obtainable by a process which does not comprise a spray-drying step and which comprises mixing a particulate starting material with a liquid binder in a mixer/granulator, preferably having both a stirring and cutting action, to form granules and feeding the said granules to a very low shear mixing zone and contacting the granules with a particulate material having a bulk density of not more than 700g/l.
- % figures are on a weight basis and based on the total weight of the detergent composition or component prior to the optional addition of post-dosed ingredients .
- the detergent composition has a bulk density of 400 to 680 g/1, preferably 450 to 680 g/1 and more preferably 500 to less than 650 g/1. It is further preferred that the detergent composition has a particle porosity of at least 0.2 and more preferably at least 0.25. The porosity may be determined by a mercury porosimetry method.
- the component incorporated in the very low shear zone has a bulk density of not more than 700 g/1, and suitably has a bulk density of 200 to 600 g/1, preferably 250 to 550 g/1 and especially 350 to 500 g/1.
- This low bulk density component is desirably an aluminosilicate, for example zeolite 4A or zeolite A24 or a salt, preferably an inorganic salt. Salts, preferably sodium, of phosphates, for example tripolyphosphate, carbonate, bicarbonate and sulphate are especially suitable. Desirably the low bulk density component constitutes the detergency builder, or part thereof in the composition. If desired, this component may be a non-builder material, in which case the particulate starting material will suitably comprise a builder.
- the low bulk density component comprises sodium tripolyphosphate having a bulk density of 380 to 500 g/1. This compares to a typical bulk density of 800 to 1000 g/1 for tripolyphosphate conventionally employed in detergent compositions.
- the level of the low bulk density component is selected according to the desired density of the detergent composition. Preferably it is present at a level of 5 to 65 wt %, preferably 10 to 40 wt % and optimally 10 to 30 wt % of the composition.
- part of the low bulk density component may be introduced into the high speed mixer/granulator.
- the level of this component in the very low shear mixing zone is at least 10% by ' weight based on the detergent composition and additionally up to 80% of the total amount of the low bulk density component may be dosed into the high speed mixer/granulator although it is preferred that up to 60%, more preferably 5 to 50%, especially 20 to 45% of the low density material (as a percentage of the total amount of this material) be dosed into the high speed mixer granulator.
- the process may be continuous but is preferably batch- wise.
- a preferred type of mixer/granulator for use in the process of the invention is bowl-shaped and preferably has a substantially vertical stirrer axis.
- mixers of the Fukae (Trade Mark) FS-G series manufactured by Fukae Powtech Kogyo Co. , Japan are essentially in the form of a bowl-shaped vessel accessible via a top port, provided near its base with a stirrer having a substantially vertical axis, and a cutter positioned on a side wall.
- the stirrer and cutter may be operated independently of one another, and at separately variable speeds.
- Another mixer found to be suitable for use in the process of the invention is the L ⁇ dige (Trade Mark) FM series batch mixer ex Morton Machine Co. Ltd., Scotland. This differs from the mixers mentioned above in that its stirrer has a horizontal axis.
- Granulation is preferably effected by running the mixer using both stirrer and cutter; a relatively short residence time (for example, 5-8 minutes for a 35 kg batch) is generally sufficient.
- the final bulk density can be controlled by choice of residence time.
- the stirrer is operated at a rate of 25 to 80 rpm, preferably 30 to 75 rpm.
- the cutter is suitably operated at a rate of 200 to 2500 rpm, preferably 300 to 2200 rpm.
- a batch process typically involves pre- mixing of solid components, addition of liquids, granulation, optional addition of a layering material suitable for controlling the granulation end-point, and product discharge.
- the rate of stirring and/or cutting is suitably adjusted according to the stage of the process.
- the binder comprises one or more of the following: liquid detergent-active compound(s) , precursors thereof, water, solutions, non-aqueous or aqueous, of other ingredients or mixtures thereof. If water is employed the level is desirably controlled so that the moisture content of the detergent composition is not more than 10% by weight and preferably not more than 6%.
- the mixing step is preferably carried out at a controlled temperature somewhat above ambient, preferably above 30°C.
- the temperature is within the range 30 to 55°C although higher temperatures may be suitable, for example, where heat of reaction is generated by in situ neutralisation.
- the very low shear mixing zone may be located within the same apparatus as the high speed mixer granulation but desirably is in a separate apparatus for example a rotating bowl mixer and preferably a fluid bed.
- the fluid bed is suitably operated at a temperature of 30 to 90°C and at a superficial air velocity of about 0.25 to 1.2 ms "1 .
- Suitable fluid beds are available from, for example NIRO.
- the air flow in the fluid bed may be adjusted according to the desired level of shear and agitation of the low bulk density component.
- the low bulk density component is dosed into the bed and gently agitated using a small air flow which is then increased prior to feeding in the granules from the high speed mixer/granulator.
- the detergent composition suitably comprises anionic detergent active.
- anionic detergent active This may be incorporated as a pre- neutralised material, desirably as a component of the particulate starting material, or may be neutralised in situ.
- the acid precursor of the active is preferably neutralised using a solid neutralising agent, for example carbonate (preferably sodium carbonate) , which is desirably a component of the particulate starting material.
- the detergent active material present in the composition may be selected from anionic, ampholytic, zwitterionic or nonionic detergent active materials or mixtures thereof.
- suitable synthetic anionic detergent compounds are sodium and potassium (C 9 -C 20 ) benzene sulphonates, particularly sodium linear secondary alkyl (C 10 -C 15 ) benzene sulphonates; sodium or potassium alkyl sulphates; and sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum.
- Suitable nonionics which may be employed include, in particular the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
- Specific nonionic detergent compounds are alkyl (C 6 - C 22 ) phenol ethylene oxide condensates, generally having 5 to 25 EO, ie 5 to 25 units of ethylene oxide per molecule, and the condensation products of aliphatic (C 8 -C 18 ) primary or secondary linear or branched alcohols with ethylene oxide, generally 5 to 40 EO.
- the level of detergent active material present in the composition may be in the range from 1 to 50% by weight depending on the desired applications.
- Nonionic material may be present in the particulate starting material at a level which is preferably less than 10% by weight, more preferably less than 5% by weight and/or employed as the liquid binder optionally with another liquid component, for example water.
- the particulate starting material comprises one or more of a carbonate salt at a level of 5 to 60 wt %, a zeolite at a level of 5 to 60 wt % and, if present as the low bulk density component, a phosphate salt at a level of 5 to 20% by weight of the total quantity of starting material.
- the particulate starting material constitutes 30 to 70% of the detergent composition.
- a layering material may be employed during the high speed mixing step to control granule formation and reduce or prevent over-agglomeration.
- a layering material is introduced into the very low shear mixing step.
- Suitable materials include aluminosilicates, for example zeolite 4A and A24.
- the layering material is suitability present at a level of 1 to 4 wt % based on the composition.
- the composition may be used as a complete composition in its own right or may be mixed with other components or mixtures and thus may form a major or minor part of a final product.
- the composition may be blended with for example a spray-dried base powder.
- a detergent composition was prepared by dosing the following components into a Fukae FS3500 mixer (in the following sequence) :
- the mixer was operated at a temperature of 30-35°C.
- the mixer was operated for sufficient time to effect granulation in the granulation step (end point 60 amps) and the product was discharged over 240 seconds.
- 130kg of sodium tripolyphosphate (bd 400-440g/l) was dosed into a NIRO fluid bed and 'bubbled' at a low air velocity. Prior to discharge of the granules from the Fukae mixer, the air flow was increased to about 11000 m 3 /hr and the granules were fed into the fluid bed. 20kg of zeolite 4A was then dosed into the fluid bed as a layering material. The detergent composition was then discharged from the fluid bed at a temperature below 30°C.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002242420A CA2242420C (fr) | 1996-01-31 | 1997-01-06 | Procede pour la production d'une composition detergente |
DE69701731T DE69701731T2 (de) | 1996-01-31 | 1997-01-06 | Verfahren zur herstellung einer waschmittelzusammensetzung |
PL97328022A PL184656B1 (pl) | 1996-01-31 | 1997-01-06 | Sposób wytwarzania kompozycji detergentowej lub jej komponentu |
EA199800668A EA001314B1 (ru) | 1996-01-31 | 1997-01-06 | Способ получения моющего состава |
AU14409/97A AU1440997A (en) | 1996-01-31 | 1997-01-06 | Process for the production of a detergent composition |
EP97901008A EP0882126B1 (fr) | 1996-01-31 | 1997-01-06 | Procede pour la production d'une composition detergente |
BR9707474A BR9707474A (pt) | 1996-01-31 | 1997-01-06 | Processo para a produção de uma composição ou componente detergente e composição ou componente detergente |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9601920.3A GB9601920D0 (en) | 1996-01-31 | 1996-01-31 | Process for the production of a detergent composition |
GB9601920.3 | 1996-01-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997028246A1 true WO1997028246A1 (fr) | 1997-08-07 |
Family
ID=10787857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/000118 WO1997028246A1 (fr) | 1996-01-31 | 1997-01-06 | Procede pour la production d'une composition detergente |
Country Status (16)
Country | Link |
---|---|
EP (1) | EP0882126B1 (fr) |
CN (1) | CN1191351C (fr) |
AR (1) | AR005576A1 (fr) |
AU (1) | AU1440997A (fr) |
BR (1) | BR9707474A (fr) |
CA (1) | CA2242420C (fr) |
DE (1) | DE69701731T2 (fr) |
EA (1) | EA001314B1 (fr) |
ES (1) | ES2145567T3 (fr) |
GB (1) | GB9601920D0 (fr) |
HU (1) | HUP9901180A3 (fr) |
IN (1) | IN188387B (fr) |
PL (1) | PL184656B1 (fr) |
TR (1) | TR199801444T2 (fr) |
WO (1) | WO1997028246A1 (fr) |
ZA (1) | ZA97255B (fr) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5990073A (en) * | 1995-06-30 | 1999-11-23 | Lever Brothers Company | Process for the production of a detergent composition |
US6056905A (en) * | 1997-06-16 | 2000-05-02 | Lever Brothers Company Division Of Conopco, Inc. | Production of detergent granulates |
US6077820A (en) * | 1995-12-20 | 2000-06-20 | Lever Brothers Company Division Of Conopco, Inc. | Process for preparing a granular detergent |
WO2000037605A1 (fr) * | 1998-12-22 | 2000-06-29 | The Procter & Gamble Company | Procede de preparation d'une composition detergente a faible masse volumique apparente par agglomeration |
US6121229A (en) * | 1996-10-04 | 2000-09-19 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6133223A (en) * | 1997-06-27 | 2000-10-17 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6136777A (en) * | 1996-10-04 | 2000-10-24 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6143711A (en) * | 1996-10-04 | 2000-11-07 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6150323A (en) * | 1996-10-04 | 2000-11-21 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
WO2000077147A1 (fr) * | 1999-06-10 | 2000-12-21 | Unilever Plc | Procede relatif a l'elaboration de compositions detergentes granuleuses |
US6172034B1 (en) | 1996-10-04 | 2001-01-09 | The Procter & Gamble | Process for making a detergent composition by non-tower process |
US6211138B1 (en) | 1996-10-04 | 2001-04-03 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6211137B1 (en) | 1996-10-04 | 2001-04-03 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6274544B1 (en) | 1997-06-16 | 2001-08-14 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6391844B1 (en) | 1996-10-04 | 2002-05-21 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6455490B1 (en) | 1999-06-10 | 2002-09-24 | Unilever Home & Personal Care Usa Division Of Conopco, In.C | Granular detergent component containing zeolite map and laundry detergent compositions |
US6555514B1 (en) | 1998-10-26 | 2003-04-29 | The Procter & Gamble Company | Processes for making granular detergent composition having improved appearance and solubility |
US6596683B1 (en) | 1998-12-22 | 2003-07-22 | The Procter & Gamble Company | Process for preparing a granular detergent composition |
US6858572B1 (en) | 1999-03-09 | 2005-02-22 | The Procter & Gamble Company | Process for producing coated detergent particles |
US6894018B1 (en) | 1999-06-21 | 2005-05-17 | The Procter & Gamble Company | Process for making granular detergent in a fluidized bed granulator having recycling of improperly sized particles |
WO2011005803A1 (fr) * | 2009-07-09 | 2011-01-13 | The Procter & Gamble Company | Procédé continu de fabrication d'une composition de détergent pour le linge |
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- 1997-01-06 PL PL97328022A patent/PL184656B1/pl not_active IP Right Cessation
- 1997-01-06 CA CA002242420A patent/CA2242420C/fr not_active Expired - Fee Related
- 1997-01-06 HU HU9901180A patent/HUP9901180A3/hu unknown
- 1997-01-06 EA EA199800668A patent/EA001314B1/ru not_active IP Right Cessation
- 1997-01-06 ES ES97901008T patent/ES2145567T3/es not_active Expired - Lifetime
- 1997-01-06 WO PCT/EP1997/000118 patent/WO1997028246A1/fr not_active Application Discontinuation
- 1997-01-06 AU AU14409/97A patent/AU1440997A/en not_active Abandoned
- 1997-01-06 DE DE69701731T patent/DE69701731T2/de not_active Revoked
- 1997-01-06 TR TR1998/01444T patent/TR199801444T2/xx unknown
- 1997-01-06 BR BR9707474A patent/BR9707474A/pt not_active IP Right Cessation
- 1997-01-06 CN CNB971919607A patent/CN1191351C/zh not_active Expired - Fee Related
- 1997-01-06 EP EP97901008A patent/EP0882126B1/fr not_active Revoked
- 1997-01-13 ZA ZA97255A patent/ZA97255B/xx unknown
- 1997-01-28 AR ARP970100333A patent/AR005576A1/es unknown
- 1997-01-31 IN IN61BO1997 patent/IN188387B/en unknown
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Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5990073A (en) * | 1995-06-30 | 1999-11-23 | Lever Brothers Company | Process for the production of a detergent composition |
US6077820A (en) * | 1995-12-20 | 2000-06-20 | Lever Brothers Company Division Of Conopco, Inc. | Process for preparing a granular detergent |
US6211137B1 (en) | 1996-10-04 | 2001-04-03 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6211138B1 (en) | 1996-10-04 | 2001-04-03 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6136777A (en) * | 1996-10-04 | 2000-10-24 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6143711A (en) * | 1996-10-04 | 2000-11-07 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6150323A (en) * | 1996-10-04 | 2000-11-21 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6172034B1 (en) | 1996-10-04 | 2001-01-09 | The Procter & Gamble | Process for making a detergent composition by non-tower process |
US6391844B1 (en) | 1996-10-04 | 2002-05-21 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6121229A (en) * | 1996-10-04 | 2000-09-19 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
US6056905A (en) * | 1997-06-16 | 2000-05-02 | Lever Brothers Company Division Of Conopco, Inc. | Production of detergent granulates |
US6274544B1 (en) | 1997-06-16 | 2001-08-14 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6429184B1 (en) | 1997-06-16 | 2002-08-06 | Lever & Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6133223A (en) * | 1997-06-27 | 2000-10-17 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6555514B1 (en) | 1998-10-26 | 2003-04-29 | The Procter & Gamble Company | Processes for making granular detergent composition having improved appearance and solubility |
US6784151B2 (en) * | 1998-10-26 | 2004-08-31 | The Procter & Gamble Company | Processes for making granular detergent composition having improved appearance and solubility |
WO2000037605A1 (fr) * | 1998-12-22 | 2000-06-29 | The Procter & Gamble Company | Procede de preparation d'une composition detergente a faible masse volumique apparente par agglomeration |
US6596683B1 (en) | 1998-12-22 | 2003-07-22 | The Procter & Gamble Company | Process for preparing a granular detergent composition |
US6858572B1 (en) | 1999-03-09 | 2005-02-22 | The Procter & Gamble Company | Process for producing coated detergent particles |
US6455490B1 (en) | 1999-06-10 | 2002-09-24 | Unilever Home & Personal Care Usa Division Of Conopco, In.C | Granular detergent component containing zeolite map and laundry detergent compositions |
EA003404B1 (ru) * | 1999-06-10 | 2003-04-24 | Унилевер Нв | Способ получения гранулированных моющих составов |
AU768795B2 (en) * | 1999-06-10 | 2004-01-08 | Unilever Plc | Process for preparing granular detergent compositions |
WO2000077147A1 (fr) * | 1999-06-10 | 2000-12-21 | Unilever Plc | Procede relatif a l'elaboration de compositions detergentes granuleuses |
US6894018B1 (en) | 1999-06-21 | 2005-05-17 | The Procter & Gamble Company | Process for making granular detergent in a fluidized bed granulator having recycling of improperly sized particles |
WO2011005803A1 (fr) * | 2009-07-09 | 2011-01-13 | The Procter & Gamble Company | Procédé continu de fabrication d'une composition de détergent pour le linge |
Also Published As
Publication number | Publication date |
---|---|
BR9707474A (pt) | 1999-07-27 |
HUP9901180A2 (hu) | 1999-08-30 |
DE69701731T2 (de) | 2000-08-10 |
TR199801444T2 (xx) | 1998-10-21 |
CN1191351C (zh) | 2005-03-02 |
AR005576A1 (es) | 1999-06-23 |
CN1209835A (zh) | 1999-03-03 |
PL184656B1 (pl) | 2002-11-29 |
ZA97255B (en) | 1998-07-14 |
DE69701731D1 (de) | 2000-05-25 |
HUP9901180A3 (en) | 2002-04-29 |
PL328022A1 (en) | 1999-01-04 |
IN188387B (fr) | 2002-09-14 |
EA199800668A1 (ru) | 1999-02-25 |
EP0882126A1 (fr) | 1998-12-09 |
EA001314B1 (ru) | 2001-02-26 |
GB9601920D0 (en) | 1996-04-03 |
AU1440997A (en) | 1997-08-22 |
EP0882126B1 (fr) | 2000-04-19 |
CA2242420A1 (fr) | 1997-08-07 |
CA2242420C (fr) | 2005-08-30 |
ES2145567T3 (es) | 2000-07-01 |
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