WO1996000565A1 - Agent de fixation capillaire - Google Patents

Agent de fixation capillaire Download PDF

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Publication number
WO1996000565A1
WO1996000565A1 PCT/EP1995/001728 EP9501728W WO9600565A1 WO 1996000565 A1 WO1996000565 A1 WO 1996000565A1 EP 9501728 W EP9501728 W EP 9501728W WO 9600565 A1 WO9600565 A1 WO 9600565A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
degree
composition according
percent
agent
Prior art date
Application number
PCT/EP1995/001728
Other languages
German (de)
English (en)
Inventor
Günther LANG
Wolfgang Keil
Michael Franzke
Harald Wendel
Original Assignee
Wella Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella Aktiengesellschaft filed Critical Wella Aktiengesellschaft
Priority to JP8502736A priority Critical patent/JPH09502456A/ja
Priority to EP95919419A priority patent/EP0715513A1/fr
Priority to BR9506005A priority patent/BR9506005A/pt
Publication of WO1996000565A1 publication Critical patent/WO1996000565A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/736—Chitin; Chitosan; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the invention relates to an agent for setting the hair on an aqueous, alcoholic or aqueous-alcoholic basis, which contains 50 to 100 percent neutralized shellac in combination with hydroxypropylchitosan, hydroxybutylchitosan, hydroxypropylcellulose and / or hydroxybutylcellulose.
  • the temporary reshaping of the hair is generally based on the use of hair-setting agents, the essential component of which are solutions of film-forming natural or synthetic polymers.
  • synthetic polymers are anionic polymers such as acrylic acid or methacrylic acid homopolymers or copolymers, copolymers of acrylic acid and acrylamides and copolymers based on alkyl vinyl ethers and maleic acid monoalkyl esters, amphoteric polymers such as copolymers of octylacrylamide, acrylate and butylaminoethyl methacrylate and nonionic polymers such as vinylpyrrolidone homopolymers, vinylpyrrolidone-vinyl acetate copolymers and copolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate.
  • Synthetic hair-fixing polymers are preferred by radical polymerization of monomeric petro- chemical products, i.e. from non-renewable raw materials.
  • synthetic polymers can contain contaminants from monomers, polymerization stoppers and polymerization regulators, which can be toxicologically unsafe.
  • Natural polymers do not have the disadvantages of synthetic polymers described above.
  • the most suitable natural hair-setting polymers are Schel varnish, polysaccharides or derivatives of polysaccharides, in particular cellulose derivatives, chitosan or chitosan derivatives.
  • Hair fixatives the hair-setting effect of which is based on shellac as a film-forming agent, generally adhere strongly to the hair, making the hair difficult to style. In addition, such hair fixatives leave residues on the hair which are difficult to remove.
  • Hair-setting agents containing polysaccharides are generally difficult to spray due to the thickening effect of polysaccharides. Furthermore, these agents have the disadvantage that when combing out the hair, dandruff formation and the formation of a gray coating on the hair can occur.
  • Polymers suitable for use in hair setting agents must have a multitude of properties. For example, they have to Dissolve alcohols and alcohol-water mixtures well and be contracted with the commonly used aerosol propellants.
  • a general problem with setting products is the durability of the hairstyles created with them. For example, washing the hair loses the setting effect of the products.
  • the object was therefore to provide a means for setting the hair that does not have the disadvantages of the previously known means.
  • the middle is said to make the hair easy to style, to give the hair shine and to ensure good hair strengthening beyond washing. Furthermore, with good sprayability and resistance to atmospheric humidity, it should dry quickly and act less stressfully on the hair.
  • the present invention therefore relates to an agent for setting the hair on an aqueous, alcoholic or aqueous-alcoholic basis, which is characterized in that it
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • the hair fixative preferably contains.
  • shellac component (A) can handels ⁇ conventional shellac, such as the commercial product shellac MHP210 ® from Pennig, Hamburg / Germany, are used.
  • the organic or inorganic bases customary in cosmetics such as primary, secondary or tertiary amines, amino alcohols, alkali metal hydroxides or ammonia in the form of aqueous ammonia solutions, can be used.
  • Preferred neutralizing agents are 2-amino-2-methylpropanol, triisopropanolamine, sodium hydroxide or ammonia as an aqueous ammonia solution.
  • partial neutralization of the shellac is possible by means of the hydroxypropylchitosan and / or hydroxybutylchitosan used in the agent.
  • the agent according to the invention preferably contains hydroxypropylchitosan or hydroxybutylchitosan with a degree of propoxylation or butoxylation of 1.0 to 5.0 with a ratio of N / O substitution of 99: 1 to 1:99 and an intrinsic viscosity ( ⁇ ) of 10 up to 150 ml per gram (1 percent solution in 0.2 mol acetic acid and 0.1 mol sodium chloride at 20 degrees Celsius).
  • Suitable hydroxypropylchitosans are listed for example in EP-PS 0 224 045; Suitable Hydroxy ⁇ butylchitosane are described for example in EP-PS 0 243 822.
  • the agent according to the invention preferably contains hydroxypropyl cellulose or hydroxybutyl cellulose with a degree of propoxylation or butoxylation of 2.0 to 4.0 and a kinematic viscosity of 0.1 to 25 mm 2 per second, measured with an Ubbelohde viscometer type 501 103 (capillary 2) at 20 degrees Celsius, 3 percent solution in 96 percent ethanol.
  • a hydroxypropyl cellulose or hydroxybutyl cellulose with a degree of propoxylation or degree of butoxylation of 2.3 to 3.8 and a kinematic viscosity of 0.2 to 12 mm 2 per second is particularly preferred.
  • Suitable hydroxypropyl include the commercial products Nisso HPC ® Nippon Soda, Tokyo, Japan or Klucel ® EF Aqualon, Dusseldorf, Germany.
  • the agent for setting the hair preferably contains component (B) in an amount of 0.5 to 10 percent by weight.
  • the agent according to the invention can be in the form of an aqueous, alcoholic or aqueous-alcoholic solution.
  • Suitable alcohols are, in particular, the lower alcohols with 1 to 5 carbon atoms usually used for cosmetic purposes, the boiling point of which is below 300 ° Celsius; alcohols with 1 to 3 carbon atoms are particularly preferred.
  • the agent according to the invention for setting the hair can be filled with a propellant in a pressure vessel and sprayed as an aerosol or foam. It can also be in the form of a non-aerosol hairspray, non-aerosol foam or non-aerosol hair lacquer that can be sprayed with the aid of a suitable mechanically operated spraying device.
  • Mechanical spraying devices are to be understood as devices which enable the spraying of a liquid without using a liquefied propellant.
  • a suitable mechanical spray device can be, for example, a spray pump or an elastic container provided with a spray valve, into which the above-described cosmetic agent is filled under pressure, the elastic container expanding and from which the agent expands as a result of the contraction of the elastic one Can be removed continuously when opening the spray valve.
  • the agent according to the invention is in the form of an aerosol hairspray, aerosol foam or aerosol hair lacquer, then it additionally contains 2 to 80 percent by weight of a propellant and is filled into a pressure container.
  • blowing agents such as N 2 , N 2 0 and C0 2 , and mixtures of the above-mentioned compounds are suitable.
  • blowing agents mentioned above dimethyl ether and mixtures of lower alkanes with dimethyl ether are preferred, the use of dimethyl ether as blowing agent being particularly preferred.
  • composition according to the invention for hair fixatives can furthermore contain customary cosmetic additives, such as, for example, anionic, cationic, amphoteric or non-anionic wetting agents and emulsifiers, such as, for example, d 2 - to C -.
  • customary cosmetic additives such as, for example, anionic, cationic, amphoteric or non-anionic wetting agents and emulsifiers, such as, for example, d 2 - to C -.
  • the agent for strengthening the hair according to the invention can optionally dye or tone the hair at the same time through a content of cosmetic dyes.
  • Such preparations are known in the trade, inter alia, as color fixers or tinting fixers. They additionally contain customary cosmetic dyes known for hair fixatives, for example aromatic nitro dyes such as 1,4-diamino-2-nitrobenzene, picramic acid, 1-hydroxy-2-amino-4, which are known to be hair-absorbing -nitrobenzene and 1,4-bis - [(2-hydroxyethyl) amino] -2-nitro-5-chlorobenzene, azo dyes, such as for example Acid Brown 4 (CI 14 805), anthraquinone dyes, such as, for example, Disperse Violet 4 (CI 61 105) or triphenylmethane dyes, such as, for example, Basic Violet I (CI 42 535), the dyes of these classes depending on the nature of their substituents, they can have an acidic, nonionic or basic character
  • the agent according to the invention has a low residue on the hair and does not give the hair a high shine. In addition to good hairdosability, the agent brings about lasting strengthening beyond washing the hair.
  • the agent is easy to spray and resistant to atmospheric moisture.
  • the agent is also characterized by comparatively shorter drying times.
  • hydroxypropyl cellulose e.g. Klucel EF ® der
  • Example 5 Aerosol hairspray for normal hold
  • Example 6 Spray fixer with birch extract
  • birch extract for example Extrapon® birch from Dragoco, Holzminden, Germany 15.00 g ethanol 80.45 g water 100.00 g
  • Example 7 Firming mousse for a strong hold
  • hydroxypropyl cellulose e.g. Klucel EE * der
  • hydroxypropyl cellulose e.g. Klucel EF ® der

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Zoology (AREA)
  • Insects & Arthropods (AREA)
  • Cosmetics (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention concerne un agent de fixation capillaire à base aqueuse, alcoolique ou aqueuse-alcoolique, qui se caractérise en ce qu'il contient: (A) entre 0,1 et 20 % en poids de gomme-laque neutralisée à entre 50 et 100 % et (B) entre 0,1 et 20 % en poids de chitosane d'hydroxypropyle, de chitosane d'hydroxybutyle, de cellulose d'hydroxypropyle et/ou de cellulose d'hydroxybutyle. Cet agent n'altère pas les cheveux dans la mesure où il laisse peut de dépôt et leur confère beaucoup de brillance. Outre qu'il facilite le coiffage, cet agent conserve un bon pouvoir fixatif au-delà d'un shampooing, est aisé à vaporiser et résiste à l'humidité atmosphérique. Cet agent se caractérise en outre par le fait qu'il permet de parvenir à des temps de séchage plus cours.
PCT/EP1995/001728 1994-06-28 1995-05-06 Agent de fixation capillaire WO1996000565A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP8502736A JPH09502456A (ja) 1994-06-28 1995-05-06 毛髪固化剤
EP95919419A EP0715513A1 (fr) 1994-06-28 1995-05-06 Agent de fixation capillaire
BR9506005A BR9506005A (pt) 1994-06-28 1995-05-06 Agente para fixaçao dos cabelos

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4422593.8 1994-06-28
DE19944422593 DE4422593A1 (de) 1994-06-28 1994-06-28 Mittel zur Festigung der Haare

Publications (1)

Publication Number Publication Date
WO1996000565A1 true WO1996000565A1 (fr) 1996-01-11

Family

ID=6521706

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/001728 WO1996000565A1 (fr) 1994-06-28 1995-05-06 Agent de fixation capillaire

Country Status (6)

Country Link
EP (1) EP0715513A1 (fr)
JP (1) JPH09502456A (fr)
BR (1) BR9506005A (fr)
DE (1) DE4422593A1 (fr)
ES (1) ES2087054T1 (fr)
WO (1) WO1996000565A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0841060A2 (fr) * 1996-11-07 1998-05-13 Wella Aktiengesellschaft Produit de soins capillaires pour la fixation des cheveux
GB2326889A (en) * 1997-06-30 1999-01-06 Procter & Gamble Hair styling composition
US6475475B2 (en) 1999-12-02 2002-11-05 Wella Aktiengesellschaft Polymer ingredient combinations for hair treatment compositions
KR100416929B1 (ko) * 1996-11-25 2004-06-04 주식회사 엘지생활건강 에어졸 헤어 스프레이 조성물
DE102004009158A1 (de) * 2004-02-26 2005-09-15 Beiersdorf Ag Polymerkombination für Stylingmittel
US7597898B2 (en) 2002-05-15 2009-10-06 Wella Ag Aerosol foam or pump foam product for hair treatment

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE258419T1 (de) * 1996-09-12 2004-02-15 Kpss Kao Gmbh Verwendung einer amin enthaltenden aerosolzusammensetzung

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0224045A2 (fr) * 1985-11-22 1987-06-03 Wella Aktiengesellschaft Compositions cosmétiques à base de chitosanes N-hydroxypropylés, chitosanes N-hydroxypropylés modifiés et leur méthode de préparation
US5053218A (en) * 1989-07-17 1991-10-01 Cosmosol, Ltd. Pressurized hair spray composition
EP0469232A1 (fr) * 1990-08-03 1992-02-05 Kabushiki Kaisha Japan Happy Matériaux pour produits cosmétiques capillaires et produits cosmétiques capillaires
EP0580514A1 (fr) * 1992-07-24 1994-01-26 L'oreal Laque aérosol capillaire à base de N-carboxybutyl chitosane
US5304368A (en) * 1993-02-19 1994-04-19 American Telecast Corporation Non-foaming, non-viscous, alcohol-free, water-based, pressurized hair spray product
DE4234743A1 (de) * 1992-10-15 1994-04-21 Wella Ag Mittel zur Festigung der Haare

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0224045A2 (fr) * 1985-11-22 1987-06-03 Wella Aktiengesellschaft Compositions cosmétiques à base de chitosanes N-hydroxypropylés, chitosanes N-hydroxypropylés modifiés et leur méthode de préparation
US5053218A (en) * 1989-07-17 1991-10-01 Cosmosol, Ltd. Pressurized hair spray composition
EP0469232A1 (fr) * 1990-08-03 1992-02-05 Kabushiki Kaisha Japan Happy Matériaux pour produits cosmétiques capillaires et produits cosmétiques capillaires
EP0580514A1 (fr) * 1992-07-24 1994-01-26 L'oreal Laque aérosol capillaire à base de N-carboxybutyl chitosane
DE4234743A1 (de) * 1992-10-15 1994-04-21 Wella Ag Mittel zur Festigung der Haare
US5304368A (en) * 1993-02-19 1994-04-19 American Telecast Corporation Non-foaming, non-viscous, alcohol-free, water-based, pressurized hair spray product

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0841060A2 (fr) * 1996-11-07 1998-05-13 Wella Aktiengesellschaft Produit de soins capillaires pour la fixation des cheveux
EP0841060A3 (fr) * 1996-11-07 2000-08-09 Wella Aktiengesellschaft Produit de soins capillaires pour la fixation des cheveux
US6214319B1 (en) 1996-11-07 2001-04-10 Wella Aktiengesellschaft Aqueous-alcoholic hair fixing composition containing a combination of shellac and synthetic hair fixing polymer
KR100416929B1 (ko) * 1996-11-25 2004-06-04 주식회사 엘지생활건강 에어졸 헤어 스프레이 조성물
GB2326889A (en) * 1997-06-30 1999-01-06 Procter & Gamble Hair styling composition
US6475475B2 (en) 1999-12-02 2002-11-05 Wella Aktiengesellschaft Polymer ingredient combinations for hair treatment compositions
US7597898B2 (en) 2002-05-15 2009-10-06 Wella Ag Aerosol foam or pump foam product for hair treatment
DE102004009158A1 (de) * 2004-02-26 2005-09-15 Beiersdorf Ag Polymerkombination für Stylingmittel

Also Published As

Publication number Publication date
EP0715513A1 (fr) 1996-06-12
BR9506005A (pt) 1997-08-19
ES2087054T1 (es) 1996-07-16
DE4422593A1 (de) 1996-01-04
JPH09502456A (ja) 1997-03-11

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