WO1995004731A1 - Recovery of tocopherols - Google Patents

Recovery of tocopherols Download PDF

Info

Publication number
WO1995004731A1
WO1995004731A1 PCT/US1994/008481 US9408481W WO9504731A1 WO 1995004731 A1 WO1995004731 A1 WO 1995004731A1 US 9408481 W US9408481 W US 9408481W WO 9504731 A1 WO9504731 A1 WO 9504731A1
Authority
WO
WIPO (PCT)
Prior art keywords
sep
mixture
fatty acid
tocopherols
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1994/008481
Other languages
English (en)
French (fr)
Inventor
Tracy K. Hunt
Lutz Jeromin
Wilhelm Johannisbauer
Bernhard Gutsche
Volkmar Jordon
Herbert Wogatzki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
Original Assignee
Henkel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Corp filed Critical Henkel Corp
Priority to BR9407179A priority Critical patent/BR9407179A/pt
Priority to AT94924502T priority patent/ATE208769T1/de
Priority to DE69429093T priority patent/DE69429093T2/de
Priority to JP7506442A priority patent/JPH09502701A/ja
Priority to EP94924502A priority patent/EP0712399B1/en
Publication of WO1995004731A1 publication Critical patent/WO1995004731A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
    • C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
    • C07D311/72—3,4-Dihydro derivatives having in position 2 at least one methyl radical and in position 6 one oxygen atom, e.g. tocopherols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Pyrane Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Fats And Perfumes (AREA)
  • Steroid Compounds (AREA)
  • Cosmetics (AREA)
  • Catalysts (AREA)
PCT/US1994/008481 1993-08-06 1994-08-01 Recovery of tocopherols Ceased WO1995004731A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR9407179A BR9407179A (pt) 1993-08-06 1994-08-01 Processos de recuperação tocoferóis a partir de uma mistura gordurosa compreendida de ácidos graxos e tocoferóis de evaporação para a separação de alquil ésteres inferiores de ácido graxo de uma mistura que compreende adicionalmente tocoferóis e esteróis e de separação de um ou mais compostos de tocoferol de um ou mais compostos de esterol
AT94924502T ATE208769T1 (de) 1993-08-06 1994-08-01 Rückgewinnung von tocopherolen
DE69429093T DE69429093T2 (de) 1993-08-06 1994-08-01 Rückgewinnung von tocopherolen
JP7506442A JPH09502701A (ja) 1993-08-06 1994-08-01 トコフェロール類の回収
EP94924502A EP0712399B1 (en) 1993-08-06 1994-08-01 Recovery of tocopherols

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10362893A 1993-08-06 1993-08-06
US08/103,628 1993-08-06
US18059294A 1994-01-13 1994-01-13
US08/180,592 1994-01-13

Publications (1)

Publication Number Publication Date
WO1995004731A1 true WO1995004731A1 (en) 1995-02-16

Family

ID=26800669

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1994/008481 Ceased WO1995004731A1 (en) 1993-08-06 1994-08-01 Recovery of tocopherols

Country Status (8)

Country Link
US (3) US5616735A (cg-RX-API-DMAC7.html)
EP (3) EP0992500B1 (cg-RX-API-DMAC7.html)
JP (1) JPH09502701A (cg-RX-API-DMAC7.html)
AT (3) ATE289301T1 (cg-RX-API-DMAC7.html)
BR (1) BR9407179A (cg-RX-API-DMAC7.html)
CA (1) CA2168856A1 (cg-RX-API-DMAC7.html)
DE (3) DE69434277T2 (cg-RX-API-DMAC7.html)
WO (1) WO1995004731A1 (cg-RX-API-DMAC7.html)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997002890A1 (de) * 1995-07-08 1997-01-30 Basf Aktiengesellschaft Druckverlustarme gewebepackungen oder gewebeähnliche packungen mit geordneter struktur zur verwendung in stoffaustauschkolonnen und verfahren zur rektifikation unter verwendung dieser packungen
WO1997002880A1 (de) * 1995-07-08 1997-01-30 Basf Aktiengesellschaft Verfahren zur gewinnung reiner substanzen aus gemischen hochsiedender luft- und/oder temperaturempfindlicher substanzen, die eine hohe trennleistung erfordern, durch rektifikation im feinvakuum sowie für dieses verfahren geeignete kolonnen
US5703252A (en) * 1995-12-13 1997-12-30 Henkel Corporation Recovery of Tocopherols
WO2000064922A1 (en) * 1999-04-27 2000-11-02 Sterol Technologies Ltd. Alkanol, methyl ethyl ketone water solvent system for the separation of sterols
EP1081156A3 (en) * 1999-09-03 2002-01-16 Härting, Thomas Francis High efficiency process for the preparation of highly pure sterols
US6979743B1 (en) * 1999-02-13 2005-12-27 Cognis Deutschland Gmbh & Co. Kg Processes for preparing phytosterols and substantially citrostadienol-free phytosterols prepared thereby
CN108033938A (zh) * 2017-11-21 2018-05-15 合肥工业大学 一种采用酸性离子液体催化酯化和柱层析相结合从茶油脱臭馏出物提取生育酚的方法

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6706898B2 (en) * 1998-01-29 2004-03-16 Archer-Daniels-Midland Company Methods for separating a tocopherol from a tocopherol-containing mixture
JP2002501915A (ja) * 1998-01-29 2002-01-22 イーストマン ケミカル カンパニー トコール含有混合物からのトコールの分離方法
US6127560A (en) * 1998-12-29 2000-10-03 West Central Cooperative Method for preparing a lower alkyl ester product from vegetable oil
WO2000064923A1 (en) * 1999-04-27 2000-11-02 Sterol Technologies Ltd. Process for the isolation of phytosterols from neutral substances using hydrocarbon and alcohol based solvent systems
US6414166B1 (en) 1999-12-29 2002-07-02 National Science Council Process for preparing tocopherol concentrates
WO2001079400A2 (en) 2000-04-14 2001-10-25 Mars Incorporated Extraction of sterols from cocoa hulls
US6623604B1 (en) 2000-06-05 2003-09-23 Cognis Corporation Method of recovering free fatty acids having low ester content and high acid value
DE10038442A1 (de) * 2000-08-07 2002-02-21 Cognis Deutschland Gmbh Verfahren zur Gewinnung von Sterinen aus fettsäurehaltigen Rückständen
DE10038456A1 (de) * 2000-08-07 2002-02-21 Cognis Deutschland Gmbh Verfahren zur Gewinnung von Sterinen
US6838104B2 (en) * 2000-12-20 2005-01-04 Archer Daniels Midland Company Process for the production of tocotrienols
US20020107232A1 (en) * 2001-01-12 2002-08-08 Flickinger Brent D. Methods for producing sterol ester-rich compositions
ATE391135T1 (de) * 2001-09-07 2008-04-15 Raisio Staest Oy Verfahren zur isolierung von sterinen und/oder wachsalkoholen aus talölprodukten
US20040030166A1 (en) * 2002-03-18 2004-02-12 Dick Copeland Methods for treating deodorizer distillate
MY142319A (en) * 2002-08-20 2010-11-15 Malaysian Palm Oil Board Mpob Extraction of palm vitamin e, phytosterols and squalene from palm oil
TWI324592B (en) * 2002-11-28 2010-05-11 Sulzer Chemtech Ag A method for the esterification of a fatty acid
US8088183B2 (en) * 2003-01-27 2012-01-03 Seneca Landlord, Llc Production of biodiesel and glycerin from high free fatty acid feedstocks
US9725397B2 (en) 2003-01-27 2017-08-08 REG Seneca, LLC Production of biodiesel and glycerin from high free fatty acid feedstocks
US7871448B2 (en) 2003-01-27 2011-01-18 Seneca Landlord, Llc Production of biodiesel and glycerin from high free fatty acid feedstocks
DE60332053D1 (de) * 2003-02-21 2010-05-20 Cognis Ip Man Gmbh Verfahren zur gewinnung von fettsäurealkylestern, harzsäuren und sterinen aus rohtallöl
WO2005010136A2 (en) 2003-07-16 2005-02-03 Archer-Daniels-Midland Company Method for producing fats or oils
US20080015367A1 (en) * 2006-07-11 2008-01-17 Wiley Organics, Inc. Process for isolating phytosterols and tocopherols from deodorizer distillate
US20080282606A1 (en) * 2007-04-16 2008-11-20 Plaza John P System and process for producing biodiesel
BRPI0812609A2 (pt) * 2007-07-06 2019-02-19 Dow Global Technologies Inc método para separar pelo menos um componente de uma composição que compreenda pelo menos dois derivados de óleos de sementes
CN102574025B (zh) * 2009-07-30 2016-05-11 泰国研究基金 用于从脂肪酸馏出物中萃取维生素e的系统和方法
AU2014278303B2 (en) 2013-06-11 2016-12-08 Renewable Energy Group, Inc. Production of biodiesel and products obtained therefrom
WO2016028235A1 (en) * 2014-08-18 2016-02-25 Chiang Mai University A system and method for extracting and/or concentrating vitamin e
MY176376A (en) * 2015-02-06 2020-08-04 Ho Sue San David Recovery of tocopherols/tocotrienols, glycerine, sterols and fatty acid esters from vegetable oil distillate and the process thereof
CA3043521A1 (en) * 2017-02-08 2018-08-16 Nestec S.A. Creamers compositions
CN107955054A (zh) * 2017-11-30 2018-04-24 陕西海斯夫生物工程有限公司 一种薄膜反应与分离耦合制备植物甾醇酯的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335154A (en) * 1963-06-04 1967-08-08 Eastman Kodak Co Separation of tocopherols and sterols from deodorizer sludge and the like
US5190618A (en) * 1988-03-16 1993-03-02 Bioindustry Development Centre (Bidec) Production of high concentration tocopherols and tocotrienols from palm-oil by-products

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1170126A (fr) * 1954-09-23 1959-01-09 Eastman Kodak Co Procédé d'obtention de concentrés de tocophérol à partir de boues de désodorisation et produits obtenus
GB1008767A (en) * 1961-06-01 1965-11-03 Eastman Kodak Co Improvements in or relating to sterols and tocopherols
DE3126110A1 (de) * 1980-07-04 1982-04-01 The Nisshin Oil Mills, Ltd., Tokyo Verfahren zur gewinnung von tocopherol-konzentraten
JPS6042495A (ja) * 1983-08-17 1985-03-06 日清製油株式会社 油脂脱臭留出物のメチルエステル化法
JPS60178883A (ja) * 1984-02-27 1985-09-12 Riken Vitamin Co Ltd トコフエロ−ルの精製濃縮法
JPS60185776A (ja) * 1984-03-05 1985-09-21 Riken Vitamin Co Ltd トコフエロ−ルの精製濃縮法
EP0171009B1 (en) * 1984-08-02 1991-05-22 HENKEL CORPORATION (a Delaware corp.) Purification of tocopherols by extraction
JPS6193178A (ja) * 1984-10-12 1986-05-12 Agency Of Ind Science & Technol トコトリエノ−ル類の分離方法
JPS61178883A (ja) * 1984-12-21 1986-08-11 株式会社日立製作所 梱包装置
US4594437A (en) * 1985-02-21 1986-06-10 Uc Unitas Corporation Process for recovering tocopherols from deodorizer sludge
DE4228476C2 (de) * 1992-08-27 2002-05-02 Cognis Deutschland Gmbh Verfahren zum Gewinnen von Tocopherol und/oder Sterin
US5487817A (en) * 1993-02-11 1996-01-30 Hoffmann-La Roche Inc. Process for tocopherols and sterols from natural sources

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335154A (en) * 1963-06-04 1967-08-08 Eastman Kodak Co Separation of tocopherols and sterols from deodorizer sludge and the like
US5190618A (en) * 1988-03-16 1993-03-02 Bioindustry Development Centre (Bidec) Production of high concentration tocopherols and tocotrienols from palm-oil by-products

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997002890A1 (de) * 1995-07-08 1997-01-30 Basf Aktiengesellschaft Druckverlustarme gewebepackungen oder gewebeähnliche packungen mit geordneter struktur zur verwendung in stoffaustauschkolonnen und verfahren zur rektifikation unter verwendung dieser packungen
WO1997002880A1 (de) * 1995-07-08 1997-01-30 Basf Aktiengesellschaft Verfahren zur gewinnung reiner substanzen aus gemischen hochsiedender luft- und/oder temperaturempfindlicher substanzen, die eine hohe trennleistung erfordern, durch rektifikation im feinvakuum sowie für dieses verfahren geeignete kolonnen
US6111117A (en) * 1995-07-08 2000-08-29 Basf Aktiengesellschaft Process for isolation of pure substances from mixtures of high-boiling air and/or temperature-sensitive substances which require a high separation efficiency by rectification under medium vacuum, and columns suitable for this process
EP1209156A3 (de) * 1995-07-08 2002-10-30 Basf Aktiengesellschaft Verfahren zur Gewinnung von reinem Vitamin-E-acetat oder reinen Tocopherolen durch Rektifikation zwecks Reinigung von leichter siedenden und höher siedenden Verunreinigungen
US5703252A (en) * 1995-12-13 1997-12-30 Henkel Corporation Recovery of Tocopherols
EP0866789A4 (en) * 1995-12-13 1999-04-07 Henkel Corp RECOVERY OF TOCOPHEROLS
US6979743B1 (en) * 1999-02-13 2005-12-27 Cognis Deutschland Gmbh & Co. Kg Processes for preparing phytosterols and substantially citrostadienol-free phytosterols prepared thereby
WO2000064922A1 (en) * 1999-04-27 2000-11-02 Sterol Technologies Ltd. Alkanol, methyl ethyl ketone water solvent system for the separation of sterols
EP1081156A3 (en) * 1999-09-03 2002-01-16 Härting, Thomas Francis High efficiency process for the preparation of highly pure sterols
CN108033938A (zh) * 2017-11-21 2018-05-15 合肥工业大学 一种采用酸性离子液体催化酯化和柱层析相结合从茶油脱臭馏出物提取生育酚的方法

Also Published As

Publication number Publication date
EP0992499B1 (en) 2005-02-16
CA2168856A1 (en) 1995-02-16
US5670669A (en) 1997-09-23
EP0992500B1 (en) 2002-02-13
DE69429884D1 (de) 2002-03-21
EP0992500A2 (en) 2000-04-12
EP0992499A2 (en) 2000-04-12
EP0992500A3 (en) 2000-04-26
DE69434277T2 (de) 2005-10-13
US5616735A (en) 1997-04-01
ATE213239T1 (de) 2002-02-15
US5646311A (en) 1997-07-08
JPH09502701A (ja) 1997-03-18
DE69429093D1 (de) 2001-12-20
ATE208769T1 (de) 2001-11-15
EP0712399A4 (cg-RX-API-DMAC7.html) 1996-05-29
ATE289301T1 (de) 2005-03-15
EP0712399B1 (en) 2001-11-14
EP0712399A1 (en) 1996-05-22
DE69429093T2 (de) 2002-07-11
EP0992499A3 (en) 2002-12-11
DE69429884T2 (de) 2002-08-14
DE69434277D1 (de) 2005-03-24
BR9407179A (pt) 1996-09-17

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