WO1994025801A1 - Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen - Google Patents

Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen Download PDF

Info

Publication number
WO1994025801A1
WO1994025801A1 PCT/EP1994/001153 EP9401153W WO9425801A1 WO 1994025801 A1 WO1994025801 A1 WO 1994025801A1 EP 9401153 W EP9401153 W EP 9401153W WO 9425801 A1 WO9425801 A1 WO 9425801A1
Authority
WO
WIPO (PCT)
Prior art keywords
oxygen
exhaust gases
furnace
nitrogen
flue gas
Prior art date
Application number
PCT/EP1994/001153
Other languages
German (de)
English (en)
French (fr)
Inventor
Peter Fritz
Gert Lautenschlager
Karl KÜRZINGER
Original Assignee
Noell-Krc Umwelttechnik Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Noell-Krc Umwelttechnik Gmbh filed Critical Noell-Krc Umwelttechnik Gmbh
Publication of WO1994025801A1 publication Critical patent/WO1994025801A1/de

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C9/00Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23BMETHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
    • F23B7/00Combustion techniques; Other solid-fuel combustion apparatus
    • F23B7/002Combustion techniques; Other solid-fuel combustion apparatus characterised by gas flow arrangements
    • F23B7/007Combustion techniques; Other solid-fuel combustion apparatus characterised by gas flow arrangements with fluegas recirculation to combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L2900/00Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
    • F23L2900/07001Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/32Direct CO2 mitigation

Definitions

  • the present invention relates to a method for reducing the amount of flue gas from combustion systems operating in the usual temperature range from 850 to 1100 ° C. and with excess oxygen by supplying oxygen.
  • DE-A-40 26 245 discloses a process for the thermal treatment of wastes and residues, in which pure oxygen without dilution is used as the oxidizing agent, the aim being to melt the mineral constituents and thus to glaze them to separate and store the form or to recycle it. It is therefore necessary to work with temperatures of at least 1200 to 1400 ° C, preferably even temperatures of 1600 ° C. Conventional incinerators are unsuitable for such high temperatures.
  • the method according to the invention allows for the first time to separate these two tasks from one another and to reduce the amount of flue gas by about 70%, so that flue gas cleaning can be carried out much more simply and efficiently, since the flue gases no longer contain the considerable amounts of atmospheric nitrogen as ballast
  • the acidic constituents to be removed subsequently by the flue gas cleaning such as SO / SO 3 , HCl and HF, are present in higher concentrations and can therefore be removed more easily and efficiently.
  • a particular advantage of the method according to the invention is that all conventional firing and boiler systems can be used.
  • the downstream flue gas cleaning systems can, however, be dimensioned much smaller or, if they already exist in the usual dimensioning, they can be operated more economically and ecologically.
  • the amount of oxygen admixed to the cooled partial flow of the exhaust gases is controlled by the oxygen content after the furnace and upstream of the boiler, which is measured in the usual way and is desired for the respective combustion material.
  • the amount of recirculated and cooled exhaust gases is controlled according to the invention by the temperature measured in the boiler in the usual way.
  • the amount of this partial flow is between 60 and 90% of the exhaust gases, while 10 to 40% of the flue gas cleaning is supplied. If desired, the ratio of these partial flows can be varied, especially if different wastes or fuels with different calorific values are used.
  • the method according to the invention it is entirely possible to add the oxygen to only a partial stream of the recirculated cooled exhaust gases, while the main quantity of the recirculated cooled exhaust gases is only circulated.
  • this measure permits easier and more reliable mixing of the recirculated cooled exhaust gases with the admixed oxygen and, on the other hand, the targeted introduction of oxygen to the material to be burned.
  • the exhaust gas stream is dedusted before being returned to the furnace.
  • the partial flow of the flue gases to be recirculated will preferably only be removed after the dedusting, mixed with oxygen and returned to the furnace.
  • the amount of flue gas is reduced by this nitrogen content.
  • Another advantage of the method according to the invention is that the efficiency of the overall system is significantly increased, since the lower amounts of flue gas also result in a reduction in energy losses due to exhaust gases.
  • there is better heat transfer in the boiler since the exhaust gases predominantly consist of C0 2 and H 0, which emit the energy more strongly than nitrogen.
  • the formation of nitrogen oxides is completely avoided or suppressed to such an extent that it is not necessary to de-nitrogenize the flue gases.
  • the method according to the invention can be used in practically all conventional firing and boiler systems, in particular in those with a grate furnace, rotary tube furnace or with burner systems.
  • High-calorific and low-calorific wastes and fuels such as garbage can thus also be used, since it is now possible for the first time to provide the oxygen required for the combustion regardless of how much gas must be made available as a coolant in order to Avoid excessive temperatures.
  • the amount of flue gas is reduced to a maximum, since the flue gases only contain the optimally required excess amount of oxygen in addition to the combustion product CO 2, H 0 and the oxidizable impurities.
  • the air nitrogen previously carried as ballast is no longer contained in the smoke gases produced according to the invention.
  • Acidic impurities such as S0 “, HCl, HF can be used in the usual way Remove way. If necessary, denitrification can be dispensed with entirely.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chimneys And Flues (AREA)
  • Treating Waste Gases (AREA)
PCT/EP1994/001153 1993-04-29 1994-04-14 Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen WO1994025801A1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE4314080 1993-04-29
DEP4314080.7 1993-04-29
DE4344821 1993-12-28
DEP4344821.6 1993-12-28

Publications (1)

Publication Number Publication Date
WO1994025801A1 true WO1994025801A1 (de) 1994-11-10

Family

ID=25925377

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1994/001153 WO1994025801A1 (de) 1993-04-29 1994-04-14 Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen

Country Status (2)

Country Link
TW (1) TW247927B (enrdf_load_stackoverflow)
WO (1) WO1994025801A1 (enrdf_load_stackoverflow)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996004507A1 (en) * 1994-08-02 1996-02-15 N.V. Kema Process and combuster for carrying out oxygen enriched combustion
FR2822721A1 (fr) * 2001-03-28 2002-10-04 Inst Francais Du Petrole Procede et installation de reduction des oxydes d'azote presents dans les fumees de combustion d'un gaz issu d'un processus de thermolyse

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2360873A1 (de) * 1972-12-06 1974-06-12 Denyo Kagaku Kogyo Kk Verfahren zur verhinderung der ausbildung schaedlicher verbrennungsgase in einer verbrennungskammer
US4405587A (en) * 1982-02-16 1983-09-20 Mcgill Incorporated Process for reduction of oxides of nitrogen
EP0204059A1 (en) * 1985-06-03 1986-12-10 SSAB Svenskt Stal AB Method to control a combustion progress
DE3546465A1 (de) * 1985-11-02 1987-05-14 Helmut Kohler Verfahren und anordnung zum betrieb eines verbrennungskraftwerkes
FR2651301A1 (fr) * 1989-08-23 1991-03-01 Bertin & Cie Procede de destruction de dechets indesirables par incineration sous pression et installation pour la mise en óoeuvre du procede.
DE4026245A1 (de) * 1990-08-18 1992-02-20 Hpm Technocommerz Technologie Verfahren zur thermischen behandlung von abfaellen und reststoffen

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2360873A1 (de) * 1972-12-06 1974-06-12 Denyo Kagaku Kogyo Kk Verfahren zur verhinderung der ausbildung schaedlicher verbrennungsgase in einer verbrennungskammer
US4405587A (en) * 1982-02-16 1983-09-20 Mcgill Incorporated Process for reduction of oxides of nitrogen
EP0204059A1 (en) * 1985-06-03 1986-12-10 SSAB Svenskt Stal AB Method to control a combustion progress
DE3546465A1 (de) * 1985-11-02 1987-05-14 Helmut Kohler Verfahren und anordnung zum betrieb eines verbrennungskraftwerkes
FR2651301A1 (fr) * 1989-08-23 1991-03-01 Bertin & Cie Procede de destruction de dechets indesirables par incineration sous pression et installation pour la mise en óoeuvre du procede.
DE4026245A1 (de) * 1990-08-18 1992-02-20 Hpm Technocommerz Technologie Verfahren zur thermischen behandlung von abfaellen und reststoffen

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996004507A1 (en) * 1994-08-02 1996-02-15 N.V. Kema Process and combuster for carrying out oxygen enriched combustion
FR2822721A1 (fr) * 2001-03-28 2002-10-04 Inst Francais Du Petrole Procede et installation de reduction des oxydes d'azote presents dans les fumees de combustion d'un gaz issu d'un processus de thermolyse

Also Published As

Publication number Publication date
TW247927B (enrdf_load_stackoverflow) 1995-05-21

Similar Documents

Publication Publication Date Title
EP2344810B1 (de) Verfahren und vorrichtung zur reduzierung von schadstoffemissionen in verbrennungsanlagen
EP3055266B1 (de) Verfahren zur entstickung von bypassabgasen in einer anlage zur herstellung von zementklinker
DE4312820C2 (de) Verfahren zum Verbrennen von Brennstoffen, insbesondere Abfall
EP0162215A1 (de) Verfahren zur Entsorgung von brennbaren Abfällen
DE3240373A1 (de) Verfahren und vorrichtung zur rauchgasentschwefelung von kohlenfeuerungen
DE2624971C2 (de) Verfahren zur Verwertung industrieller Abfälle
EP0694147A1 (de) Verfahren zur reduzierung der emissionen bei der verbrennung von abfällen
CH661112A5 (de) Verfahren zur abfallbeseitigung durch vergasung, insbesondere von haushaltmuell.
DE3603054A1 (de) Verfahren zur vergasung von klaerschlamm
WO2007090510A1 (de) Verfahren zur primärseitigen stickoxidminderung in einem zweistufigen verbrennungsprozess
DE3444073A1 (de) Verfahren und anlage zum verbrennen von abfaellen wie haus-, industrie- und sondermuell
EP0340644B1 (de) Verfahren zur Beseitigung und zum Recycling von Abfallstoffen
EP0338103B1 (de) Verfahren zum Vermindern der Schadstoffemissionen beim Betrieb von Kohleverbrennungseinrichtungen
EP0302910B1 (de) Verbrennung von kohle mit einer wirbelschichtfeuerung
DE4308388A1 (de) Verfahren zur Reduzierung des Schadstoffgehaltes im Rohgas von Verbrennungsanlagen
WO1986006151A1 (en) Process and installation for burning refuse materials
DE3520447A1 (de) Verfahren und anlage zur thermischen behandlung von feinkoernigem gut wie zementrohmehl, unter verwendung von brennstoffhaltigen abfaellen und/oder minderwertigen brennstoffen
WO1994025801A1 (de) Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen
DE4027908C2 (de) Verbrennungsverfahren und Vorrichtung dafür
EP1918015B1 (de) Rauchgas-Äquilibrierung in Müllverbrennungsanlagen
DE69304214T2 (de) Verfahren zur Verbrennung von festen Brennstoffen mit einem hohen Gehalt an schmelzbaren Aschen und Schwermetallen
EP0496101B1 (de) Verfahren zur thermischen Aufarbeitung ammoniumsulfathaltiger Rückstände insbesondere ammoniumsulfathaltiger Abwässer
DE3329342A1 (de) Behandlungsverfahren fuer rauchgase aus einer dampferzeugungsanlage mit mehreren kesseleinheiten und jeder kesseleinheit zugeordneter schmelzkammer-feuerung
DE3900977A1 (de) Verfahren zum verbrennen von brennstoffen sowie verbrennungsanlage zum durchfuehren dieses verfahrens
WO1995027872A1 (de) Verfahren zur reduzierung der emission bei der verbrennung von abfällen

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA JP KR US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA