WO1994025801A1 - Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen - Google Patents
Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen Download PDFInfo
- Publication number
- WO1994025801A1 WO1994025801A1 PCT/EP1994/001153 EP9401153W WO9425801A1 WO 1994025801 A1 WO1994025801 A1 WO 1994025801A1 EP 9401153 W EP9401153 W EP 9401153W WO 9425801 A1 WO9425801 A1 WO 9425801A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oxygen
- exhaust gases
- furnace
- nitrogen
- flue gas
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000002912 waste gas Substances 0.000 title abstract 2
- 239000001301 oxygen Substances 0.000 claims abstract description 31
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 239000003546 flue gas Substances 0.000 claims description 30
- 239000007789 gas Substances 0.000 claims description 30
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 21
- 238000002485 combustion reaction Methods 0.000 claims description 21
- 239000003517 fume Substances 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 238000004140 cleaning Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- 239000012535 impurity Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000004056 waste incineration Methods 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- -1 S0 “ Substances 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23B—METHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
- F23B7/00—Combustion techniques; Other solid-fuel combustion apparatus
- F23B7/002—Combustion techniques; Other solid-fuel combustion apparatus characterised by gas flow arrangements
- F23B7/007—Combustion techniques; Other solid-fuel combustion apparatus characterised by gas flow arrangements with fluegas recirculation to combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07001—Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/32—Direct CO2 mitigation
Definitions
- the present invention relates to a method for reducing the amount of flue gas from combustion systems operating in the usual temperature range from 850 to 1100 ° C. and with excess oxygen by supplying oxygen.
- DE-A-40 26 245 discloses a process for the thermal treatment of wastes and residues, in which pure oxygen without dilution is used as the oxidizing agent, the aim being to melt the mineral constituents and thus to glaze them to separate and store the form or to recycle it. It is therefore necessary to work with temperatures of at least 1200 to 1400 ° C, preferably even temperatures of 1600 ° C. Conventional incinerators are unsuitable for such high temperatures.
- the method according to the invention allows for the first time to separate these two tasks from one another and to reduce the amount of flue gas by about 70%, so that flue gas cleaning can be carried out much more simply and efficiently, since the flue gases no longer contain the considerable amounts of atmospheric nitrogen as ballast
- the acidic constituents to be removed subsequently by the flue gas cleaning such as SO / SO 3 , HCl and HF, are present in higher concentrations and can therefore be removed more easily and efficiently.
- a particular advantage of the method according to the invention is that all conventional firing and boiler systems can be used.
- the downstream flue gas cleaning systems can, however, be dimensioned much smaller or, if they already exist in the usual dimensioning, they can be operated more economically and ecologically.
- the amount of oxygen admixed to the cooled partial flow of the exhaust gases is controlled by the oxygen content after the furnace and upstream of the boiler, which is measured in the usual way and is desired for the respective combustion material.
- the amount of recirculated and cooled exhaust gases is controlled according to the invention by the temperature measured in the boiler in the usual way.
- the amount of this partial flow is between 60 and 90% of the exhaust gases, while 10 to 40% of the flue gas cleaning is supplied. If desired, the ratio of these partial flows can be varied, especially if different wastes or fuels with different calorific values are used.
- the method according to the invention it is entirely possible to add the oxygen to only a partial stream of the recirculated cooled exhaust gases, while the main quantity of the recirculated cooled exhaust gases is only circulated.
- this measure permits easier and more reliable mixing of the recirculated cooled exhaust gases with the admixed oxygen and, on the other hand, the targeted introduction of oxygen to the material to be burned.
- the exhaust gas stream is dedusted before being returned to the furnace.
- the partial flow of the flue gases to be recirculated will preferably only be removed after the dedusting, mixed with oxygen and returned to the furnace.
- the amount of flue gas is reduced by this nitrogen content.
- Another advantage of the method according to the invention is that the efficiency of the overall system is significantly increased, since the lower amounts of flue gas also result in a reduction in energy losses due to exhaust gases.
- there is better heat transfer in the boiler since the exhaust gases predominantly consist of C0 2 and H 0, which emit the energy more strongly than nitrogen.
- the formation of nitrogen oxides is completely avoided or suppressed to such an extent that it is not necessary to de-nitrogenize the flue gases.
- the method according to the invention can be used in practically all conventional firing and boiler systems, in particular in those with a grate furnace, rotary tube furnace or with burner systems.
- High-calorific and low-calorific wastes and fuels such as garbage can thus also be used, since it is now possible for the first time to provide the oxygen required for the combustion regardless of how much gas must be made available as a coolant in order to Avoid excessive temperatures.
- the amount of flue gas is reduced to a maximum, since the flue gases only contain the optimally required excess amount of oxygen in addition to the combustion product CO 2, H 0 and the oxidizable impurities.
- the air nitrogen previously carried as ballast is no longer contained in the smoke gases produced according to the invention.
- Acidic impurities such as S0 “, HCl, HF can be used in the usual way Remove way. If necessary, denitrification can be dispensed with entirely.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chimneys And Flues (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4314080 | 1993-04-29 | ||
DEP4314080.7 | 1993-04-29 | ||
DE4344821 | 1993-12-28 | ||
DEP4344821.6 | 1993-12-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994025801A1 true WO1994025801A1 (de) | 1994-11-10 |
Family
ID=25925377
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1994/001153 WO1994025801A1 (de) | 1993-04-29 | 1994-04-14 | Verfahren zur reduzierung der rauchgasmenge von verbrennungsanlagen |
Country Status (2)
Country | Link |
---|---|
TW (1) | TW247927B (enrdf_load_stackoverflow) |
WO (1) | WO1994025801A1 (enrdf_load_stackoverflow) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996004507A1 (en) * | 1994-08-02 | 1996-02-15 | N.V. Kema | Process and combuster for carrying out oxygen enriched combustion |
FR2822721A1 (fr) * | 2001-03-28 | 2002-10-04 | Inst Francais Du Petrole | Procede et installation de reduction des oxydes d'azote presents dans les fumees de combustion d'un gaz issu d'un processus de thermolyse |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2360873A1 (de) * | 1972-12-06 | 1974-06-12 | Denyo Kagaku Kogyo Kk | Verfahren zur verhinderung der ausbildung schaedlicher verbrennungsgase in einer verbrennungskammer |
US4405587A (en) * | 1982-02-16 | 1983-09-20 | Mcgill Incorporated | Process for reduction of oxides of nitrogen |
EP0204059A1 (en) * | 1985-06-03 | 1986-12-10 | SSAB Svenskt Stal AB | Method to control a combustion progress |
DE3546465A1 (de) * | 1985-11-02 | 1987-05-14 | Helmut Kohler | Verfahren und anordnung zum betrieb eines verbrennungskraftwerkes |
FR2651301A1 (fr) * | 1989-08-23 | 1991-03-01 | Bertin & Cie | Procede de destruction de dechets indesirables par incineration sous pression et installation pour la mise en óoeuvre du procede. |
DE4026245A1 (de) * | 1990-08-18 | 1992-02-20 | Hpm Technocommerz Technologie | Verfahren zur thermischen behandlung von abfaellen und reststoffen |
-
1994
- 1994-04-14 WO PCT/EP1994/001153 patent/WO1994025801A1/de active Application Filing
- 1994-04-27 TW TW083103816A patent/TW247927B/zh active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2360873A1 (de) * | 1972-12-06 | 1974-06-12 | Denyo Kagaku Kogyo Kk | Verfahren zur verhinderung der ausbildung schaedlicher verbrennungsgase in einer verbrennungskammer |
US4405587A (en) * | 1982-02-16 | 1983-09-20 | Mcgill Incorporated | Process for reduction of oxides of nitrogen |
EP0204059A1 (en) * | 1985-06-03 | 1986-12-10 | SSAB Svenskt Stal AB | Method to control a combustion progress |
DE3546465A1 (de) * | 1985-11-02 | 1987-05-14 | Helmut Kohler | Verfahren und anordnung zum betrieb eines verbrennungskraftwerkes |
FR2651301A1 (fr) * | 1989-08-23 | 1991-03-01 | Bertin & Cie | Procede de destruction de dechets indesirables par incineration sous pression et installation pour la mise en óoeuvre du procede. |
DE4026245A1 (de) * | 1990-08-18 | 1992-02-20 | Hpm Technocommerz Technologie | Verfahren zur thermischen behandlung von abfaellen und reststoffen |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996004507A1 (en) * | 1994-08-02 | 1996-02-15 | N.V. Kema | Process and combuster for carrying out oxygen enriched combustion |
FR2822721A1 (fr) * | 2001-03-28 | 2002-10-04 | Inst Francais Du Petrole | Procede et installation de reduction des oxydes d'azote presents dans les fumees de combustion d'un gaz issu d'un processus de thermolyse |
Also Published As
Publication number | Publication date |
---|---|
TW247927B (enrdf_load_stackoverflow) | 1995-05-21 |
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