WO1994014404A1 - Tonifiant capillaire du type gel pouvant etre pulverise - Google Patents

Tonifiant capillaire du type gel pouvant etre pulverise Download PDF

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Publication number
WO1994014404A1
WO1994014404A1 PCT/US1992/010036 US9210036W WO9414404A1 WO 1994014404 A1 WO1994014404 A1 WO 1994014404A1 US 9210036 W US9210036 W US 9210036W WO 9414404 A1 WO9414404 A1 WO 9414404A1
Authority
WO
WIPO (PCT)
Prior art keywords
gel
vessel
mixing
until
hair
Prior art date
Application number
PCT/US1992/010036
Other languages
English (en)
Inventor
Stephanie Wong
Teresa Ferullo
Thomas M. Schultz
Original Assignee
Shiseido Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co., Ltd. filed Critical Shiseido Co., Ltd.
Priority to PCT/US1992/010036 priority Critical patent/WO1994014404A1/fr
Publication of WO1994014404A1 publication Critical patent/WO1994014404A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • This invention relates to hair conditioners and, more particularly, to viscous, gel-type hair conditioners formulated for being dispensed by spraying.
  • a hair conditioner should be capable of effectively grooming the hair and keeping it in place, thereby leaving the hair natural in appearance, without any evidence that a hair conditioner has been used.
  • no oily film should remain on the hair fibers which can act as a dirt catcher.
  • the hair conditioner must leave the hair with a high luster, gloss, sheen, as well as provide the entire head of hair with a full-bodied appearance, with the hair being easily managed and feeling soft and silky.
  • prior art hair conditioners are also typically difficult to thoroughly apply to all of the hair fibers. Furthermore, many prior art compositions are cumbersome to use. Recently, gel formulations of hair conditioners have become popular. However, due to the viscous nature of these prior art gel-type hair conditioners, these conditioners are typically dispensed directly through the portal of the con ⁇ tainer and are pumped through a large orifice. Regardless of which type of dispensing system is used, a large quantity of the gel is dispensed into the hands of the beautician or user followed by vigorous rubbing of the hands, in order to liquify the gel.
  • a hair conditioner having a gel formulation which is capable of being dispensed quickly and easily in a spray form through small diameter orifices.
  • Another object of the present invention is to provide a gel-type hair con ⁇ ditioner having the characteristic features described above which is capable of being applied directly to the head of hair quickly and easily by merely spraying the gel formulation on the hair.
  • Another object of the present invention is to provide a gel-type hair con- ditioner having the characteristic features described above which is capable of being sprayed through conventional, small-diameter pump spray nozzles repeatedly, without clogging the spray orifices, producing a mist-type spray.
  • the present invention overcomes the prior art difficulties typically en ⁇ countered with gel-type hair conditioners by attaining a viscous gel formulation which is capable of being dispensed by spraying.
  • the prior art difficulties and drawbacks commonly encountered with gel formulations for hair conditioners are totally eliminated and the gel formulation of the present invention is quickly and easily applied to the head of hair by spraying directly on the hair or into the user ' s hands.
  • the viscous gel hair conditioner is capable of being dispensed as a spray, passing easily through small diameter orifices.
  • alkyl polyols should have a carbon atom content ranging between 2 and 8, and a hydroxyl ion content ranging between 2 and 7.
  • the hydroxyl ions of the alkyl polyol not be vicinal. Furthermore, it has been found that the hydroxyl ions are preferably not spaced apart by more than 4 carbon atoms.
  • Alkyl polyols which have been found to be effective in attaining the sprayable hair conditioning gel include glycerin, propylene glycol, sorbitol, hydrogenated starch hydrolysate, 1,3-butylene glycol, and diethylene glycol. In Table I, these alkyl polyols are listed along with their empirical formulas. TABLE I
  • the gel formulation In order to obtain a hair conditioning gel capable of being dispensed as a liquid spray, the gel formulation must contain a water soluble or emulsifiable silicone-based compound in addition to the alkyl polyol.
  • a silicon-based compound provides the hair with added luster and sheen, as well as imparting added lubricity to the hair for increased slip and an increased silky feeling.
  • the silicone-based compound provides a synergistic effect, increasing the action of the other constituents used in the hair treatment com ⁇ position, and assisting in attaining sprayability of the viscous gel formulation.
  • the preferred silicone-based composition comprises amodimethicone.
  • Amodimethicone is a silicone polymer end blocked with amino functional groups. Its
  • dimethicone is a mixture of fully methylated linear siloxane polymers end blocked with trimethylsiloxy units.
  • the formula for dimethicone is (C 2 H 6 OSi) I C 4 H 12 Si, with the following being represen ⁇ tative of its general formula:
  • the silicone-based compound may comprise dimethicone copolyol, which is a polymer of dimethylsiloxane with polyoxyethylene and/or polyoxypropylene side chains.
  • dimethicone copolyol is a polymer of dimethylsiloxane with polyoxyethylene and/or polyoxypropylene side chains. The following represents the general formula for dimethicone copolyol:
  • PE ( H 4 0 — ) x ( H 6 0 ),H.
  • Another silicone compound which can be employed is stearoxytrimethylsilane which is an organo-silicon compound having the empirical formula of ⁇ H ⁇ Osi. Its formula generally conforms to the following:
  • stearoxy dimethicone can be employed, which is a polymer of dimethylpolysiloxane end blocked with stearoxy groups.
  • the resulting gel composition is capable of being dispensed through small diameter spray nozzles, achieving the delivery of the gel composition as a liquid spray.
  • the delivery of viscous gels has only been through large diameter pump means or directly through the container orifice or portal.
  • the resulting viscous composition is capable of being dispensed through apertures ranging in size between 0.010 and 0.030 mm with complete ease. Furthermore, by employing a plurality of orifices, a substantially liquid, mist spray pattern is attained, even though the gel composition comprises a viscosity previously incapa ⁇ ble of being dispensed in this manner.
  • the preferred alkyl polyols have a viscosity generally ranging between about 9,000 cps and 12,000 cps, and the hair conditioning gel formula ⁇ tions made in accordance with the present invention have viscosities ranging between 1,000 cps and 15,000 cps
  • the gel formulations of this invention are able to be dispensed as a liquid mist spray, delivered through apertures having a diameter of 0.030 mm or less.
  • the concentration of the alkyl polyol is preferably maintained between about 0.10% and 10% by weight of the gel formulation.
  • the water soluble or emulsifiable silicone concentration may range between about 0.02% and 5% by weight of the gel for ⁇ mulation. However, a range of between 0.02% and 1.5% by weight is preferred.
  • the hair conditioning gel formulations of the present invention re-congeal when intermixed after spraying, with the viscosity of the re-congealed gel being between 2% and 15% less than the viscosity of the original hair conditioning gel formulation.
  • This reduction in viscosity provides a further advantage over prior art formulations by providing a dispensed gel-type hair conditioner which is more easily thoroughly spread throughout the entire head of hair.
  • the present invention provides a viscous hair conditioning gel which is easily and consistently delivered through a conventional small diametered apertured pump in a liquid mist spray.
  • a typical hair conditioning gel base formulation is provided.
  • glycerin and dimethicone copolyol were added in the ranges detailed in Table III to produce a plurality of sample products.
  • Dimethicone Copolyol 0.02 - 5 In preparing each hair conditioning gel formulation sample, the following procedure was employed. Initially, a first vessel suitable for making thick slurries and equipped with a variable speed mixer and side scrapers was selected and deionized water was added to the first vessel and agitated rapidly. Then, the carbomer 940 was carefully sifted into the water and mixed until completely hydrated and free of lumps. Typically, this took at least three hours. Once completed, the methylchloroisothiazolinone or the methylisothiazolinone was added and mixed until homogeneous.
  • the solution in the second vessel was homogeneous, a portion of the triethanolamine was added and mixed until homogeneous. This solution was then allowed to stand until it became clear. Typically, this took at least twenty minutes. Once the solution in the second vessel was clear, the solution was added to the first vessel under moderate to strong mixing. However, care was taken to incorporate as little air as possible. In addition, the second vessel was rinsed with deionized water and added to the composition in the first vessel. Mixing continued until the batch product was clear and a moderately viscous gel was attained. Typically, this required a minimum of forty-five minutes. The batch product was then completed by adding deionized water to attain a desired batch product size, and by adding additional triethanolamine to adjust the pH.
  • each sample for- mulation ' was placed in a container for being dispensed by a finger actuated p ⁇ mp " sprayer.
  • the finger actuated pump sprayer incorporated orifices having a diameter of 0.013 inches.
  • compositions containing dimethicone copolyol ranging between 0.02% and 1.5% by weight provided superior sprayable product formulations, as opposed to those products in which the dimethicone copolyol exceeded 1.5%. Although such products were effective in providing a spray mist pattern, a more effective spray was obtained with the dimethicone copolyol at or below 1.5%.
  • Table IV the preferred hair conditioning gel formulation is provided. In preparing this composition, the process detailed above in reference to Tables II and III was employed. TABLE IV
  • each sample consisted of the formula detailed in Table IV, while each of the other samples were identical in each and every ingredient and quantity, except for the glycerin. Instead of glycerin, each sample incorporated an iden ⁇ tical quantity of one alkyl polyol selected from the group consisting of propylene glycol, sorbitol, hydrogenated starch hydrolysate, 1,3-butylene glycol, and diethylene glycol.
  • one alkyl polyol selected from the group consisting of propylene glycol, sorbitol, hydrogenated starch hydrolysate, 1,3-butylene glycol, and diethylene glycol.
  • each of the samples experienced a reduction in the viscosity after spraying. This shows that each gel product experienced liquification during the spraying process and recongealed after spraying at a lower viscosity. As a result, a more easily managed product was realized, which was able to be applied more quickly and easily onto the hair fibers. was realized, which was able to be applied more quickly and easily onto the hair fibers.
  • each sample provided an easily dispensed gel formulation, with each sample, with each sample was dispensed easily, quickly, repeatedly and conveniently, while also being readily spread onto the hair once dispensed.
  • a conventional gel-type hair conditioner was tested to determine its ability to be dispensed through a pump-type sprayer of the nature detailed above.
  • the gel formulation employed as the base consisted of a commercially available gel product sold under the trade name ULTRA BOND® WELDING GELTM, sold by Zotos International of Darien, Connecticut.
  • a viscous, gel-type hair conditioning product capable of being dispensed in a liquified mist spray through a conventional finger-actuated pump, said product comprising a gel base composition incorporating:
  • A. hair conditioning ingredients B. an alkyl polyol having a. a carbon content ranging between 2 and 8, and b. a hydroxyl ion content ranging between 2 and 7; and C. a water soluble or emulsifiable silicone based compound; whereby a viscous gel-type hair conditioning product is attained which is capable of being dispensed through small diametered orifices of a pump delivery system and producing a liquified mist spray, thereby realizing an easily dispensed product which can be quickly and easily rubbed into the hair.
  • the viscous, gel-type hair conditioning product defined in Claim 3 wherein the alkyl polyol is further defined as comprising at least one selected from the group consisting of glycerin, propylene glycol, sorbitol, hydrogenated starch hydrolysate, 1, 3-butylene glycol, and diethylene glycol.
  • the viscous, gel-type hair conditioning product defined in Claim 1 wherein the water soluble emulsifiable silicone based compound is further defined as comprising one selected from the group consisting of amodimethicone, dimethicone, dimethicone copolyol, stearoxytrimethyl- silane and stearoxy dimethicone.
  • a viscous, gel-type hair conditioner capable of being dispensed in a liquified mist spray through a conventional finger actuated pump and comprising
  • A between about 0.10% and 10% by weight of an alkyl polyol selected from the group consisting of glycerin, propylene glycol, sorbitol, hydrogenated starch hydrolysate, 1, 3-butylene glycol, and diethylene glycol;
  • a water soluble or emul ⁇ sifiable silicone-based compound selected from the group consisting of amodimethicone, dimethicone, dimethicone copolyol, stearoxytrimethylsilane and stearoxy dimethicone;
  • said hair conditioning ingredients are further defined as comprising a. 1.50% by weight of PVP/VA, b. 0.28% by weight of Oleth-20, c. 0.22% by weight of carbomer 940, d. 0.20% by weight of panthenol, e.
  • a product delivery system for dispensing a viscous, hair conditioning gel product in a spray mist form comprising
  • a viscous hair conditioning gel product comprising a. hair conditioning ingredients, b. an alkyl polyol having 1. a carbon content ranging between 2 and 8, and
  • a hydroxyl ion content ranging between 2 and 7, and c. a water soluble or emulsifiable silicone based compound; whereby a dispensing system is achieved for delivering a viscous hair conditioning gel product in an easily used spray mist form.
  • alkyl polyol is further defined as comprising between about 0.10% and 10% by weight of one selected from the group consisting of glycerin, propylene glycol, sorbitol, hydrogenated starch hydrolysate, 1, 3-butylene glycol, and diethylene glycol.
  • the water soluble or emulsifiable silicone-based compound is further defined as comprising between about 0.02% and 5% by weight of one selected from the group consisting of amodimethicone, dimethicone, dimethicone copolyol, stearoxytrimethylsilane and stearoxy dimethicone.
  • hair conditioning ingredients are further defined as comprising a. 1.50% by weight of PVP/VA, b. 0.28% by weight of Oleth-20, c. 0.22% by weight of carbomer 940, d. 0.20% by weight of panthenol, e. 0.06% by weight of at least one selected from the group consisting of methylchloroisothiazolinone and methylisothiazolinone, f. 0.16% by weight of triethanolamine, and g. 0.04% by weight of a fragrance.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention se rapporte à des tonifiants capillaires et en particulier à des tonifiants capillaires visqueux du type gel, formulés de façon à pouvoir être pulvérisés.
PCT/US1992/010036 1992-12-21 1992-12-21 Tonifiant capillaire du type gel pouvant etre pulverise WO1994014404A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/US1992/010036 WO1994014404A1 (fr) 1992-12-21 1992-12-21 Tonifiant capillaire du type gel pouvant etre pulverise

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1992/010036 WO1994014404A1 (fr) 1992-12-21 1992-12-21 Tonifiant capillaire du type gel pouvant etre pulverise

Publications (1)

Publication Number Publication Date
WO1994014404A1 true WO1994014404A1 (fr) 1994-07-07

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PCT/US1992/010036 WO1994014404A1 (fr) 1992-12-21 1992-12-21 Tonifiant capillaire du type gel pouvant etre pulverise

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5674478A (en) * 1996-01-12 1997-10-07 The Procter & Gamble Company Hair conditioning compositions
US5750122A (en) * 1996-01-16 1998-05-12 The Procter & Gamble Company Compositions for treating hair or skin
US5847179A (en) * 1997-10-02 1998-12-08 Pcr, Inc. High purity alkoxytrimethylsilane fluids
US6106814A (en) * 1996-01-16 2000-08-22 The Procter & Gamble Company Hair conditioning compositions
US6322778B1 (en) 1998-02-10 2001-11-27 Johnson & Johnson Consumer Companies, Inc. Hair conditioning compositions comprising a quaternary ammonium compound
EP1287808A2 (fr) * 2001-08-30 2003-03-05 Clariant Life Science Molecules (Florida) Inc. Emulsion aqueuse stable des fluides alkoxytriméthylsilane
EP1293194A1 (fr) * 2001-09-18 2003-03-19 Johnson & Johnson Consumer Companies, Inc. Gel pulvérisable stable
US10123966B2 (en) 2013-05-16 2018-11-13 The Procter And Gamble Company Hair thickening compositions and methods of use

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3246850A (en) * 1964-05-20 1966-04-19 Corn Products Co Dual spray head
US3724763A (en) * 1971-04-05 1973-04-03 A Braun Spray device
US4563347A (en) * 1982-05-20 1986-01-07 Dow Corning Corporation Compositions used to condition hair
US4591076A (en) * 1983-05-24 1986-05-27 Yoshino Kogyosho Co., Ltd. Manual liquid dispenser
US4749732A (en) * 1987-01-02 1988-06-07 Dow Corning Corporation Hair care composition containing modified aminoalkyl substituted polydiorganosiloxane
US4838490A (en) * 1987-03-26 1989-06-13 Berthoud S.A. Rotatable nozzle assembly for sprayers

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3246850A (en) * 1964-05-20 1966-04-19 Corn Products Co Dual spray head
US3724763A (en) * 1971-04-05 1973-04-03 A Braun Spray device
US4563347A (en) * 1982-05-20 1986-01-07 Dow Corning Corporation Compositions used to condition hair
US4591076A (en) * 1983-05-24 1986-05-27 Yoshino Kogyosho Co., Ltd. Manual liquid dispenser
US4749732A (en) * 1987-01-02 1988-06-07 Dow Corning Corporation Hair care composition containing modified aminoalkyl substituted polydiorganosiloxane
US4838490A (en) * 1987-03-26 1989-06-13 Berthoud S.A. Rotatable nozzle assembly for sprayers

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5674478A (en) * 1996-01-12 1997-10-07 The Procter & Gamble Company Hair conditioning compositions
US5750122A (en) * 1996-01-16 1998-05-12 The Procter & Gamble Company Compositions for treating hair or skin
US6106814A (en) * 1996-01-16 2000-08-22 The Procter & Gamble Company Hair conditioning compositions
US5847179A (en) * 1997-10-02 1998-12-08 Pcr, Inc. High purity alkoxytrimethylsilane fluids
US6322778B1 (en) 1998-02-10 2001-11-27 Johnson & Johnson Consumer Companies, Inc. Hair conditioning compositions comprising a quaternary ammonium compound
EP1287808A2 (fr) * 2001-08-30 2003-03-05 Clariant Life Science Molecules (Florida) Inc. Emulsion aqueuse stable des fluides alkoxytriméthylsilane
EP1287808A3 (fr) * 2001-08-30 2004-01-02 Clariant Life Science Molecules (Florida) Inc. Emulsion aqueuse stable des fluides alkoxytriméthylsilane
EP1293194A1 (fr) * 2001-09-18 2003-03-19 Johnson & Johnson Consumer Companies, Inc. Gel pulvérisable stable
US10123966B2 (en) 2013-05-16 2018-11-13 The Procter And Gamble Company Hair thickening compositions and methods of use

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