Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
  • B05C9/08—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
  • B05C11/02—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
  • B05C11/023—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface

Definitions

• the present invention relates to an acoustically assisted coating apparatus and a method for applying one or more layers of a coating material onto a moving web. More particularly, the present invention relates to using ultrasonic energy to improve the application of a smooth, uniform layer of coating material onto a moving web.
• Ultrasonically created fluid effects have been noted in the literature since the early 1900's. Since the 1960's, the development of improved transducers for generating ultrasonic energy increased activity in this field.
• Ultrasonic phenomena which relate to fluid processing or coating technologies include cavitation, viscous heating, increased shear, microturbulence, and acoustic streaming. These phenomena generate effects that include enhanced wettability, micromixing, dispersion, emulsification, deaeration, agglomeration, separation of components, viscosity reduction, polymer chain disentanglement, high polymer degradation, and increased chemical reaction rates.
• U.S. Patent No. 3,676,216 to Abitboul teaches applying ultrasonic energy to a previously coated web to more uniformly and consistently distribute the coating over the web and to smooth irregularities in the coating. However, the ultrasonic energy is transmitted through the air to excite the coated web after the web is completely coated.
• Japanese Patent No. 57-187071 discloses applying ultrasonic energy to the backside of a coated web.
• the ultrasonic source is too far from the point of coating for the ultrasonic energy to affect the liquid at the first contact between the liquid and the web or at the last contact between the liquid and the coating equipment.
• a nozzle for applying a liquid coating from a hopper onto a moving web is ultrasonically excited.
• a horn ultrasonically vibrates the nozzle to prevent the coating from sticking in and clogging the nozzle.
• the ultrasonic vibrations only affect the coating before it is placed on the web, and do not affect the process during the initial contact between the coating and the web or thereafter. Thus, the ultrasonic vibrations do not affect the uniformity of the thickness of the coating as the coating is applied.
• the Canadian patent is representative of a body of art which discloses applying ultrasonic energy to a nozzle during coating to improve flow through and from the nozzle. However, these apparatus are not practical for use in large scale production applications where wide coatings are being applied.
• None of the known apparatus or systems disclose metering the coating onto only one side of the web and using acoustic energy to improve the characteristics of an applied coating before the coating of the web is complete.
• the present invention overcomes these problems and uses acoustic energy to assist the coating of a smooth continuous or discontinuous layer of a metered quantity of liquid coating material having a substantially unifor crossweb thickness on one surface of a moving web.
• the apparatus includes a device which applies a coating material onto at least a portion of the surface of the web.
• the device may be any type of coating system in which the coating can be applied onto one side of the web, such as, for example, extrusion, curtain, slot-fed knife, hopper, fluid bearing, notch bar, blade, and roll coaters.
• a coating applicator meters and applies a controlled amount of coating material onto one surface of the web across the width of the web.
• An ultrasonic energy source excites the line of initial contact between the coating material and the web preferably at a uniform acoustic intensity, amplitude, and frequency in the low end of the ultrasonic, spectrum.
• the ultrasonic energy source can excite the line of final contact between the coating applicator device or downweb structure and the coated web.
• the ultrasonic energy can excite the area between the region of initial contact of the coating material and the web and the region of final contact between the coating applicator device or downweb structure and the coating material.
• the acoustic intensity is selected in combination with the properties of the coating material and the web to create a coated web having a substantially uniform crossweb thickness.
• the ultrasonic energy generator can apply ultrasonic energy to the coating material-web interface through " the die.
• ultrasonic energy is applied through the back surface of the web, through a backup horn which replaces a conventional support.
• the ultrasonic energy can also be transmitted through the air or other coupling fluid.
• Figure 1 schematically illustrates contact extrusion.
• Figure IA shows contact extrusion without acoustic excitation and
• Figures IB, 1C, ID, IE, IF, and 1G show contact extrusion with various ways of applying acoustic energy.
• Figure 2 schematically illustrates curtain coating.
• Figure 2A shows curtain coating without acoustic excitation and
• Figures 2B, 2C, 2D, and 2E show curtain coating with various ways of applying acoustic energy.
• Figure 3 schematically illustrates slot-fed knife coating.
• Figure 3A shows slot-fed knife coating without acoustic excitation and
• Figures 3B, 3C, and 3D show slot-fed knife coating with various ways of applying acoustic energy.
• Figure 4 schematically illustrates slide coating.
• Figure 4A shows slide coating without acoustic excitation and
• Figure 4B shows slide coating with acoustic excitation.
• Figure 5 schematically illustrates roll coating.
• Figure 5A shows roll coating without acoustic excitation and
• Figure 5B shows roll coating with acoustic excitation.
• Figure 6 schematically illustrates non-contact extrusion coating.
• Figure 6A shows extrusion coating without acoustic excitation and
• Figures 6B and 6C show extrusion coating with acoustic excitation.
• Figure 7A is a graph of a cross web coating thickness profile without ultrasonics and Figure 7B is a graph of the cross web coating thickness profile coated with ultrasonics.
• Figure 8A is a graph comparing the average percentage coating thickness range variation for test runs with ultrasonics and for test runs without ultrasonics.
• Figure 8B is a graph comparing the coating thickness standard deviation variation as a percentage for test runs with ultrasonics and for test runs without ultrasonics.
• the apparatus and coating method of the present invention apply acoustic energy to the interface between a web and a liquid coating material . . applied on the web.
• acoustic energy can be applied at various locations in all coating systems, improved coating is best achieved in systems which coat the web on one surface. With this system acoustic energy is used to improve coating thickness uniformity on the coated web, increase wettability
• the increased coating uniformity reduces distortion, peaking and gapping, high spots, and telescoping of wound rolls of coated webs.
• ultrasonic energy can be used with the coating of a web having a macrostructure such as voids which are filled with a coating but there is not continuity between the coating in adjacent voids.
• the web can be any material such as polyester, polypropylene, paper, or nonwoven materials.
• the improved wetting of the coating is particularly useful in rough textured or porous webs, regardless of whether the pore size is microscopic or macroscopic.
• the web and the coating material are excited at a preferably uniform ultrasonic intensity across the width of the coated web.
• the intensity is selected in combination with the coating material properties to maximize crossweb coating thickness uniformity.
• the frequency and amplitude can be varied while maintaining a uniform ultrasonic intensity, ultrasonic waves having uniform amplitude and frequency are preferred.
• Acoustic waves are longitudinal waves caused by periodic compression and rarefaction of the medium through which they travel. These waves also can generate other acoustic waves such as surface transverse acoustic waves. Acoustic waves contain both kinetic energy of motion and potential energy of compressed matter.
• the acoustic energy density, E is a measure of the energy per volume in an longitudinal acoustic wave and is represented by:
• the ultrasonic energy intensity, I is a function of the amplitude and frequency of the waves and the properties of the medium and is represented by:
• c is the speed of the acoustic waves in the medium.
• the characteristic acoustic impedance, R is as follows:
• Roll coaters include gravure and kiss coaters and are generically represented in Figure 5. Although other types of coaters are also enhanced by the application • of acoustic energy, the systems described below are representative. The operation of the invention is generally similar with all of these coating methods.
• a contact extrusion coating system is shown.
• a coating system 10 includes an extrusion die 12 located adjacent a backup roller 14.
• a web 16 of material to be coated travels from left to right in the figure.
• Coating material 18 is extruded onto and across the web 16 as shown. The coating material 18 may be applied across the entire width of the web 16 or across any fraction of the width in the known manner.
• ultrasonic energy is applied to the system 10 such that the energy acts on the web 16 and coating 18 in the region of initial contact between the web 16 and coating 18.
• the details of this ultrasonic excitation are described below.
• a resonant sonotrode or ultrasonic horn 20 replaces the backup roller 14.
• the ultrasonic horn 20 is a specially designed horn which can vibrate at selected frequencies or amplitudes of vibration.
• the ultrasonic energy is applied directly to the web 16 and excites the web 16 and coating 18 at the location of initial contact between the coating 18 and the web 16.
• both an ultrasonic horn 20 and a backup roller 14 are used in the coating system 10'.
• the backup roller 14 is located opposite the extrusion die 12, and the ultrasonic horn 20 is located downweb from this location.
• the ultrasonic energy is applied directly to the coated web 16 and the energy travels through the web 16 and coating 18 to excite the line of initial contact between the coating 18 and the web 16.
• the horn 20 is shown downweb of the die 12, it also could be located upweb of the die 12. Additionally, although the ultrasonic energy is not applied directly to the line of initial contact between the coating 18 and the web 16, the energy is applied with a sufficient intensity such that when it reaches the initial contact line it has sufficient energy.
• the coating system 10' of Figure ID includes similar components to the known system 10 of Figure IA.
• the web 16 passes around a backup roller 14 and the coating material 18 is extruded onto and across the desired- width of the web 16.
• An extrusion die 22 applies the coating material 18 onto the web 16.
• the die 22 is ultrasonically excited to excite the coating 18 within the die 22 and the excited coating 18 is extruded onto the web 16.
• the ultrasonic die 22 is a specially designed die connected to an ultrasonic energy generator, either in a single housing as shown, or by externally securing the two together as with a mounting bracket. The ultrasonic energy travels through the coating 18 to excite the region of initial contact between the coating 18 and the web 16. Referring to Figure 2, a curtain coating system is shown.
• the curtain coating die 28 is spaced above the backup roller 14.
• the web 16 travels from left to right in the figure.
• the coating material 18 is extruded from the die 28 and falls in a curtain onto the web 16 across the desired width of the web 16.
• ultrasonic energy is applied to the coating system 26' such that the energy acts on the web 16 and coating 18 in the region of initial contact between the web 16 and coating 18.
• the ultrasonic horn 20 replaces the backup roller 14.
• the ultrasonic energy is applied directly to the web 16 and excites the web 16 and coating 18 at the location of initial contact between the coating 18 and the web 16.
• both an ultrasonic horn 20 and a backup roller 14 are used.
• the ultrasonic energy is applied directly to the coated web 16 and the energy travels upweb through the web 16 and coating 18 to excite the line of initial contact between the coating 18 and the web 16.
• an ultrasonic die (not shown) can be used in a manner similar to the system 10' of Figure ID.
• a downweb structure such as a rigid leveling bar 30 shown in Figure 2D, or a flexible leveling pad 32 shown in Figure 2E may be used to smooth or level the coating material 18 after it is applied to improve the thickness uniformity.
• a downstream element such as the leveling bar 30 or leveling pad 32 is used as part of the coating system 26'
• application of ultrasonic energy can be beneficially applied in the region of final contact between the coated web 16 and the downweb leveling structure.
• the ultrasonic energy need not reach the region of initial contact between the web 16 and the coating 18 as long as it reaches the region of final contact between the coated web 16 and the leveling bar 30 or leveling pad 32.
• the web beneath the leveling bar 30 and the leveling pad 32 can be supported (as shown) or unsupported. These devices can be directly ultrasonically excited. An ultrasonically excited unsupported structure could also be used to meter the fluid.
• a slot-fed knife die coating system 36 is shown.
• the coating system 36 includes a slot-fed knife die 38 located adjacent to the backup roller 14.
• the web 16 of material to be coated travels from left to right in the. igure, and the coating material 18 is deposited onto the web 16 across the desired web width as shown.
• ultrasonic energy is applied to the system 36' such that the energy acts on the web 16 and coating 18 in the region of initial contact between the web 16 and coating 18.
• the ultrasonic horn 20 replaces the backup roller 14.
• the ultrasonic energy is applied directly to the web 16 and excites the web 16 and coating 18 at the location of initial contact between the coating 18 and the web 16, as well as the coating 18 between the die 38 and the horn 20.
• both an ultrasonic horn 20 and a backup roller 14 are used.
• the ultrasonic energy is applied directly to the coated web 16 and the energy travels through the web 16 and coating 18 to excite the line of initial contact between the coating 18 and the web 16.
• the knife die is ultrasonically excited and is shown as knife die 40.
• the coating 18 is excited while still within the knife die 40 and the energy travels through the coating 18 to the region of initial contact between the coating 18 and the web 16. Additionally, the ultrasonic energy can excite the area between the region of initial contact of the coating material and the web and the region of final contact between the coating applicator device or downweb structure and the coating material. This applies to all discussed coating methods when downweb structures are used.
• a slide coating system 44 is shown.
• the coating system 44 is a slide die 46, and is located adjacent the backup roller 14.
• the web 16 of material to be coated travels from left to right in the figure and the coating material 18 is coated onto the web 16 as shown. The coating is applied across the desired width of the web 16.
• ultrasonic energy is applied to the system 44' such that the energy acts on the web 16 and coating 18 in the region of initial contact between the web 16 and coating 18.
• the ultrasonic horn 20 replaces the backup roller 14 and the ultrasonic energy is applied directly to the web 16 and excites the web 16 and coating 18 at the location of initial contact between the coating 18 and the web 16.
• an ultrasonic slide die (not shown) in which the coating 18 is excited while still within the slide die and the energy travels through the coating 18 to the region of initial contact between the coating 18 and the web 16 can be used.
• a roll coating system Referring to Figure 5
• the coating system 50 includes a pan 52 containing liquid coating material 18 and a roll 54 mounted for rotation within the pan 52.
• the backup roller 14 is located adjacent the roll 54.
• the web 16 of material to be coated travels from left to right in the figure.
• the coating material 18 is applied to the web 16 across the desired width and a smoother or doctor blade 56 may be used to wipe off excess coating 18 and level or smooth the coating 18 on the web 16.
• ultrasonic energy is applied to the system 50' such that the energy acts on the web 16 and coating 18 in the region of initial contact between the web 16 and coating 18. This is accomplished by replacing the backup roller 14 with an ultrasonic horn 20.
• the ultrasonic energy is applied directly to the web 16 and excites the web 16 and coating 18 at the location of initial contact between the coating 18 and the web 16.
• a doctor blade 56 is used as part of the coating applicator device 10 to level or smooth the coating 18 on the web 16
• application of ultrasonic energy can be beneficially applied in the region of final contact between the coated web 16 and the downweb doctor blade.
• the doctor blade is used, the ultrasonic energy need not reach the region of initial contact between the web 16 and the coating 18 as long as it reaches the region of final contact between the coated web 16 and the doctor blade.
• Ultrasonic energy also performs well with other coating systems including those with a plurality of rolls.
• Figures 6A, 6B, and 6C correspond to Figures IA, IB, and 1C, respectively, and illustrate non-contact extrusion coating systems 60, 60'.
• the ultrasonic source is located at the line of initial contact between the coating material and the web.
• the ultrasonic energy is applied at the backside of the web through an ultrasonic horn used in place of a backup roll or other support.
• the ultrasonic source can be located remotely from the initial contact line to apply energy to the coated or uncoated web as long as sufficient ultrasonic energy reaches the line of initial contact. The maximum distance is about 15 cm although the best results have been found to occur within 8 cm.
• the ultrasonic energy can be applied within 15 cm of the location of any downweb leveling or smoothing structure.
• the ultrasonic energy can excite the area between the region of initial contact of the coating material and the web and the region of final contact between the coating applicator device or downweb structure and the coating material.
• the ultrasonic energy can be applied at any one or a combination of these areas.
• the ultrasonic energy adds energy to the coating liquid.
• the coating quality and processability improves until an optimum acoustic intensity level is reached.
• Acoustic energy preferably is applied near this optimum level which is at intensity levels between 0.1 W/cm 2 and 40 W/cm 2 , depending on the kind of coater and the type of material being coated.
• the application of ultrasonic energy can create web vibrations such as surface acoustic waves which apply energy to the coating. Depending on the magnitude of the vibration, this can improve or degrade the coating quality. Care must be taken to avoid adverse affects such as lower frequency standing waves which yield coating nonuniformity.
• the application of ultrasonic energy through a backup horn that generally replaces a backup roller is the preferred arrangement in all coating configurations.
• the ultrasonic energy can be applied to the web by direct contact or through any medium which transmits a sufficient amount of energy such as a coupling fluid.
• the working surface of the horn itself, and also the web in contact with the horn is at or near a pressure node in the acoustic standing wave.
• the ultrasonic energy is transmitted and reflected by the web and the coating material, the combined waves pull coating material toward the horn pressure node and toward the web. This improves drawdown in extrusion coating and provides a more stable liquid contact line in both extrusion and curtain coating.
• the coating material is urged to the web and reduces the tendency for air entrainment between the coating and the web.
• Other desirable effects that improve wettability include phenomena such as ultrasonic viscosity reduction and contact line and bulk fluid dynamics with the associated fluid momentum contributions.
• the horn is a rigidly mounted, nonrotating, low friction surface, backup roll runout and the associated downweb variations are eliminated.
• a carrier we could be used to shield the moving coated web from the stationary ultrasonic horn. If the region of initial contact between the coating material and web is confined by another structure, as with the slot-fed knife system of Figures 3B and 3D, additional effects may occur.
• the coating material forms a thin layer between two acoustically-matched materials, the transmission of acoustic energy is greatly enhanced.
• the acoustic energy density in the coating material between the die and the web is much greater than that outside this region.
• the acoustic energy density in this area is lower and an increased fluid crossflow occurs which fills in the streak.
• the increased energy density of the fluid in the coating area increases the crossweb flow, reduces streaks, reduces the tendency for air entrainment, and results in better crossweb uniformity and a flow configuration which is more resistant to external disturbances.
• the system can operate with larger gaps between the die and the web.
• the preferred frequency of vibration for the acoustic energy is at the low end of the ultrasonic spectrum at 20,000 Hz.
• a broad range of high and low frequencies is functional.
• lower frequencies are audible and present noise control problems, they can be used when higher amplitudes are required as with more viscous liquids or for scale-up of larger systems.
• Higher frequency ultrasonic systems present scale-up problems because they are smaller due to the shorter wavelengths that accompany higher frequencies.
• high frequency systems may be preferred for lower viscosity (less than 500 cps) liquids as they generate fewer low frequency resonances.
• Peak-to-peak amplitudes of ultrasonic vibration between 0.002 mm and 0.20 mm have been tested in ultrasonically-assisted coating. The higher amplitudes are more useful for highly viscous liquids or thin layers whereas lower viscosity liquids or thick layers require lower amplitudes. For example, in a slot-fed knife system with a 5,000 cps solvent-based rubber coating, a peak-to-peak amplitude of 0.03 mm at 20,000 Hz is sufficient to observe the desired improvements in coating quality. If the amplitude is too large, coating uniformity can be disrupted by localized nonuniformities such as rippling effects.
• the angle of input of the ultrasonic waves preferably is perpendicular to the direction of web travel, as shown in Figures IB and IC. However, while this orientation is preferred, the angle of input can range from perpendicular to parallel to the plane of the web 16.
• Figures IE and IF show systems similar to Figures IB and IC in which the ultrasonic energy is transmitted through an ultrasonic horn 20 and an ultrasonic die 22, respectively. In these embodiments, the horn 20 and the die 22 transmit the ultrasonic energy at an angle between 0° and 90°.
• the ultrasonic horn 20 transmits the ultrasonic energy in a direction parallel to the plane of the web 16 such that the amplitude of vibration of the ultrasonic energy lies in the direction of web 16 travel.
• ultrasonic energy is applied through the coating die (as in Figures ID and 3D) it also effects the flow of coating material in the die. It has been found that in some instances when the pumping force is held constant, the flow rate through the die is doubled when ultrasonic energy is applied parallel to the liquid motion and the flow rate is improved by a factor of five when it is applied in the perpendicular direction.
• ultrasonic excitation of the die increases the temperature of the coating material which improves the natural flow of coating from the die. Also, debris stuck in die crevices can be coaxed out of the die by ultrasonic excitation, thus eliminating the presence of streaks in the coated web due to trapped debris.
• the die is preferably excited as a standing wave. Alternatively, the ultrasonic vibrations can be applied as a traveling wave propagating through the die, either with or without the use of a coupling material.
• FIG. 7A shows coating without ultrasonics. A streak at area A was caused by the plug in the die orifice and a dip at area B was a naturally occurring thin coating area in the web. When the ultrasonics was turned on, the area A filled in to within 92% of the overall coating thickness and the area B dip was essentially eliminated, as shown in Figure 7B.
• Pilot plant data also was obtained.
• a run of 24,689 (81,000 ft) of 61 cm (24 in) wide rubber-based adhesive tape was made at 15.24 to 30.48 m/min (50 to 100 ft/min) using a slot fed knife die with an ultrasonic backup horn.
• the ultrasonic amplitude was varied between 0.015 and 0.025 mm (0.0006 and 0.001 in) peak-to-peak.
• the coating was 0.030 mm (0.0012 in) thick and crossweb profiles were measured.
• Ten consecutive scans of 230 data points each were taken noting the range of the coating thickness and the standard deviation of the last scan, and the average range and standard deviation of all ten scans. (The range is the minimum to maximum crossweb coating thickness.)
• the ten scan groups were performed 17 times with ultrasonics and 9 times without ultrasonics.
• An indication of transient coating thickness variation can be determined by considering how much the range of a single scan varies from the average range of several scans before it.
• the coating range variations that occur with time therefore can be indicated by subtracting the average range of the ten scans from the tenth scan of a group of ten scans, taking the absolute value, and dividing by the average range. This is performed for all of the groups of ten scans, then averaged.
• Figure 8 compares the average range variation as a percentage for the scan groups with ultrasonics with the scan groups without ultrasonics. Ultrasonics reduces the percent variation from 47% to 15%, a three-fold reduction.
• Figure 8B compares the standard deviation variations of the runs with and without ultrasonics.
• eccentric cams or white noise generators can be used to improve coatings.
• acoustic energy can be applied to both sides of the web.

Landscapes

• Application Of Or Painting With Fluid Materials (AREA)
• Coating Apparatus (AREA)
• Treatment Of Fiber Materials (AREA)
• Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
• Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)

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• 1992
  • 1992-09-09 WO PCT/US1992/007610 patent/WO1993007969A1/en not_active Application Discontinuation
  • 1992-09-09 KR KR1019940701198A patent/KR100215322B1/ko not_active IP Right Cessation
  • 1992-09-09 AU AU26425/92A patent/AU663116B2/en not_active Ceased
  • 1992-09-09 EP EP92920236A patent/EP0608265B1/de not_active Expired - Lifetime
  • 1992-09-09 DE DE69212329T patent/DE69212329T2/de not_active Expired - Fee Related
  • 1992-09-09 CZ CS94670A patent/CZ67094A3/cs unknown
  • 1992-09-09 HU HU9401022A patent/HUT68044A/hu unknown
  • 1992-09-09 CA CA002116962A patent/CA2116962A1/en not_active Abandoned
  • 1992-09-09 BR BR9206633A patent/BR9206633A/pt not_active IP Right Cessation
  • 1992-09-09 JP JP50644493A patent/JP3302016B2/ja not_active Expired - Fee Related
  • 1992-09-16 ZA ZA927084A patent/ZA927084B/xx unknown
  • 1992-09-21 TW TW081107436A patent/TW216404B/zh active
  • 1992-10-07 MX MX9205742A patent/MX9205742A/es not_active IP Right Cessation

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Non-Patent Citations (4)

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