WO1992020533A2 - Procede de production d'un stratifie flexible - Google Patents

Procede de production d'un stratifie flexible Download PDF

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Publication number
WO1992020533A2
WO1992020533A2 PCT/GB1992/000903 GB9200903W WO9220533A2 WO 1992020533 A2 WO1992020533 A2 WO 1992020533A2 GB 9200903 W GB9200903 W GB 9200903W WO 9220533 A2 WO9220533 A2 WO 9220533A2
Authority
WO
WIPO (PCT)
Prior art keywords
process according
foil
substrate
holographic
flexible
Prior art date
Application number
PCT/GB1992/000903
Other languages
English (en)
Other versions
WO1992020533A3 (fr
Inventor
Richard Alan Sharpe
Mia Josephine Manners
Original Assignee
Space Time Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Space Time Limited filed Critical Space Time Limited
Publication of WO1992020533A2 publication Critical patent/WO1992020533A2/fr
Publication of WO1992020533A3 publication Critical patent/WO1992020533A3/fr

Links

Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/02Layered materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/14Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0036Heat treatment
    • B32B38/004Heat treatment by physically contacting the layers, e.g. by the use of heated platens or rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10Applying flat materials, e.g. leaflets, pieces of fabrics
    • B44C1/14Metallic leaves or foils, e.g. gold leaf
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1712Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/1729Hot stamping techniques
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06QDECORATING TEXTILES
    • D06Q1/00Decorating textiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/02Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/12Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00Metals, their alloys or their compounds
    • B32B2311/24Aluminium

Definitions

  • the present invention relates to the production of a laminate, in particular to a process for the production of a laminate in the form of a holographic image, typically displayed on an article of clothing.
  • the present invention relates to an improvement in and/or modification of the earlier process in which the outer layer of plastics material compatible with said size is a plastics material which has been provided e.g. by printing, as a pattern which gives a desired image on a surface of a flexible substrate, typically a textile material, and more typically one already made up into an article of clothing.
  • the present invention provides a process for the production of a flexible laminate, which process comprises applying to a surface of a flexible substrate a curable composition in fluid form and comprising a plastics material as a pattern which can provide a desired image or imaging effect, positioning a metal foil bearing a holographic image and having a layer of
  • the composition comprising a plastics material may be applied as a pattern by any suitable means.
  • the composition is applied by silk screen printing and the screen mesh is chosen to match the fineness of the image required.
  • compositions in fluid form comprising a plastics material.
  • plastics material Such compositions are known and generally are:
  • the process of the invention uses a composition which comprises a plastics material suspended in a plasticiser. More preferably, in such compositions the plastics material is PVC and the plasticiser is a plastisol ink.
  • a plastics material is PVC and the plasticiser is a plastisol ink.
  • a plastisol ink is sold as Metatran.
  • the metal foil bearing a holographic image may be any flexible metal foil, but preferably, is an aluminium foil.
  • Such foils are commercially available as hot stamping foils bearing a holographic pattern which are produced to provide a foil to be applied to a rigid substrate, typically a rigid plastics material.
  • the rigid substrate provides a support for the foil so that the holographic effect may be stabilized.
  • the size of a commercial foil is a PVC (polyvinyl chloride) , which is preferred for the foils used in the invention, but other plastics size layers may be employed in the present invention provided they can be adhered to a compatible plastics material in a composition as described above.
  • the foil used in the process of the invention preferably includes a release layer on that surface of the metal foil which does not carry the layer of plastics size. That release layer can serve to provide additional protection for the holographic pattern and is removed after treatment in the process of the invention and before the holographic effect is required.
  • a typical release layer may comprise a polymeric material, for example, a polyester.
  • the flexible substrate may be any such substrate provided only that it is flexible.
  • the substrate is a woven or non-woven web, typically a fabric, and more preferably one which is both flexible and stretchable.
  • the fabric is a natural fabric.
  • the fabric may be a silk, cotton, a cotton/synthetic mix, Lycra, acetate, satin, organza, chiffon, linen, icrofibre, viscose or a simulated suede or any other similar fabric.
  • the flexible substrate is one which has already been made up into a garment of clothing.
  • the substrate is a fabric forming part of a finished garment.
  • the foil and substrate are fed to a laminating station at which heat and pressure can be brought to bear on their combination.
  • the feeding to the laminating station may be on a continuous or batch basis depending on the requirements of the process being effected.
  • the foil or substrate may be supplied continuously or intermittently from rollers on which they may be stored.
  • the laminating station may comprise any form of apparatus or device which can supply heat and pressure under the general requirements stated herein. Furthermore, the construction and arrangement of the station may be varied to suit continuous or batch operation. Thus, in one preferred aspect of the invention the laminating station may comprise at least two rollers between which the foil and substrate may be fed to be pressed together and heated. Alternatively, in another preferred aspect the foil and substrate may be brought together in a heated press which typically may comprise upper and lower heated plates which can be brought together under pressure.
  • the process of the invention is effected under conditions of temperature and time which at least essentially avoid bubble formation.
  • the temperature is believed to be the determining factor and preferably the temperature used to effect adhesion or bonding is one in the range of from about 100°C to about 110°C and typically no higher than about 112°C.
  • a temperature in the given range should be used, and preferably about 100°C.
  • pressure it is preferred to use as high a pressure as is possible within the limits of the press or other apparatus employed, and subject to the requirements of the image or imaging effect to be produced. Typically,
  • a pressure of at or above about 200 gm/cm may be used I,, for example, a pressure of about 200 to about 210 gm/cm 2
  • the heat and pressure are applied for a sufficient time to enable laminate formation to take place,
  • a variety of dwell times may be employed, although a dwell time of about 20 to about 60 seconds is preferred, more preferably about 22 seconds, especially under the conditions mentioned above.
  • Fabric treated by the process of the invention is a fully flexible laminate which generally has the same or a similar high degree of flexure as the flexible substrate from which it is made.
  • the laminate should always be capable of a high degree of flexure and a treated fabric, for example, should be capable of behaving as a fabric essentially the same as the original fabric.
  • a 100% cotton tee-shirt was printed on its front face with a fine image involving half tones using a silk screen mesh 49T and a fluid composition comprising PVC suspended in a plastisol ink supplied as Metatran adhesive by Sericol of London, United Kingdom.
  • the tee- shirt was then while the adhesive was still in a fluid (or uncured) state laid adhesive side uppermost on a heat transfer press as supplied by Imagine Transfers of Braintree, United Kingdom.
  • a sheet of holographic foil EP49 with PVC 68 sizing
  • the laminate of tee-shirt front and foil was then subjected to a temperature of about 100°C for about 22 seconds in the press, after which the combination was allowed to cool. Finally, the foil was carefully peeled away to remove excess (unstuck) foil to leave a tee- shirt finely decorated with a holographic pattern in the image of the pattern of adhesive laid down with the silk screen.
  • the tee-shirt with the holographic image was machine washable at 40°C and could be tumble dried without destruction of the image or the holographic effect.
  • Example 1 was repeated except that an image was applied to the rear of a waistcoat made of a fleece fabric. Similar results were obtained and again the waistcoat was machine washable and able to be tumble dried without destruction of the image or the holographic effect.
  • Example 1 was repeated, this time with a tee-shirt made of 50% cotton and 50% polyester with essentially the same results.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention se rapporte à un procédé de production d'un stratifié souple. Le procédé consiste à appliquer sur la surface d'un substrat souple une composition, fluide, durcissable se composant de matières plastiques représentant un motif permettant d'obtenir une image souhaitée ou un effet d'image. Une feuille de métal supportant une image holographique et comportant une couche d'encollage plastique est positionnée de sorte que la couche d'encollage soit superposée au motif tandis que la composition reste fluide. On applique ensuite à ladite composition de la chaleur et de la pression à un niveau et pour une durée tels que l'on puisse faire adhérer la feuille au substrat par l'intermédiaire de matières plastiques tout en maintenant l'effet holographique. Par la suite, on enlève l'excédent de feuille qui n'avait pas adhéré au substrat afin d'exposer l'image souhaitée ou l'effet d'image. On obtient un stratifié souple, lavable en machine, comportant une image holographique souple.
PCT/GB1992/000903 1991-05-17 1992-05-18 Procede de production d'un stratifie flexible WO1992020533A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919110765A GB9110765D0 (en) 1991-05-17 1991-05-17 Laminate production
GB9110765.6 1991-05-17

Publications (2)

Publication Number Publication Date
WO1992020533A2 true WO1992020533A2 (fr) 1992-11-26
WO1992020533A3 WO1992020533A3 (fr) 1993-01-07

Family

ID=10695212

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1992/000903 WO1992020533A2 (fr) 1991-05-17 1992-05-18 Procede de production d'un stratifie flexible

Country Status (5)

Country Link
EP (1) EP0585288A1 (fr)
CA (1) CA2103373A1 (fr)
GB (2) GB9110765D0 (fr)
HK (1) HK57396A (fr)
WO (1) WO1992020533A2 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0610721A1 (fr) * 1993-02-12 1994-08-17 LAPPE, Kurt Feuille de transfert pour imprimer des supports
WO1995017834A2 (fr) * 1993-12-30 1995-07-06 Bruno Roualdes Etoffe pour la confection et le decor
GB2290503A (en) * 1994-06-25 1996-01-03 Christopher Charles Rathbone Method of decoration, using a decal
FR2736649A1 (fr) * 1995-07-10 1997-01-17 Bordage Michel Procede et dispositif pour fixer au moins une matiere sur une base, notamment souple, telle que tissu ou cuir, et objet ainsi obtenu
WO1998039166A1 (fr) * 1997-03-06 1998-09-11 Focal Design Studios Limited Transferts d'images par application de pression et/ou de chaleur

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2342620B (en) * 1995-10-21 2000-06-07 Helen Louise Archer Making patterned foil products
DE29602370U1 (de) * 1996-02-10 1996-04-18 Hueck & Cie, 92637 Weiden Textiles Flächenelement

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4645555A (en) * 1985-01-25 1987-02-24 Asahi Screen Process Insatsu Kabushiki Kaisha Hot stamping method
EP0242457A1 (fr) * 1986-04-17 1987-10-28 Nihon Tokkyo Kanri Company Limited Méthode pour former un motif ou une représentation par enlèvement d'une ou de portions prédéterminées d'un film métallique
EP0294936A1 (fr) * 1987-05-06 1988-12-14 Reflex Promotion A/S Procédé et transfert pour décoration de textiles
US4838965A (en) * 1988-01-25 1989-06-13 Bussard Janice W Holographic art applied to T-shirts or other textile products
EP0328086A2 (fr) * 1988-02-12 1989-08-16 American Bank Note Holographics, Inc. Objets avec des hologrammes non continus intégrés et procédé de leur fabrication

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4645555A (en) * 1985-01-25 1987-02-24 Asahi Screen Process Insatsu Kabushiki Kaisha Hot stamping method
EP0242457A1 (fr) * 1986-04-17 1987-10-28 Nihon Tokkyo Kanri Company Limited Méthode pour former un motif ou une représentation par enlèvement d'une ou de portions prédéterminées d'un film métallique
EP0294936A1 (fr) * 1987-05-06 1988-12-14 Reflex Promotion A/S Procédé et transfert pour décoration de textiles
US4838965A (en) * 1988-01-25 1989-06-13 Bussard Janice W Holographic art applied to T-shirts or other textile products
EP0328086A2 (fr) * 1988-02-12 1989-08-16 American Bank Note Holographics, Inc. Objets avec des hologrammes non continus intégrés et procédé de leur fabrication

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0610721A1 (fr) * 1993-02-12 1994-08-17 LAPPE, Kurt Feuille de transfert pour imprimer des supports
WO1995017834A2 (fr) * 1993-12-30 1995-07-06 Bruno Roualdes Etoffe pour la confection et le decor
FR2714576A1 (fr) * 1993-12-30 1995-07-07 Roualdes Bruno Matériau pour la confection et le décor constitué d'une peau et/ou étoffe stratifiées avec une âme métallique.
WO1995017834A3 (fr) * 1993-12-30 1995-07-20 Bruno Roualdes Etoffe pour la confection et le decor
US5855980A (en) * 1993-12-30 1999-01-05 Roualdes; Bruno Fabric for clothing industry and interior furnishing
GB2290503A (en) * 1994-06-25 1996-01-03 Christopher Charles Rathbone Method of decoration, using a decal
FR2736649A1 (fr) * 1995-07-10 1997-01-17 Bordage Michel Procede et dispositif pour fixer au moins une matiere sur une base, notamment souple, telle que tissu ou cuir, et objet ainsi obtenu
WO1997002957A1 (fr) * 1995-07-10 1997-01-30 Ted Lapidus Procede et dispositif pour fixer des materiaux sur une base, et objet obtenu
WO1998039166A1 (fr) * 1997-03-06 1998-09-11 Focal Design Studios Limited Transferts d'images par application de pression et/ou de chaleur

Also Published As

Publication number Publication date
GB9110765D0 (en) 1991-07-10
GB9210401D0 (en) 1992-07-01
HK57396A (en) 1996-04-12
GB2255746B (en) 1994-10-05
WO1992020533A3 (fr) 1993-01-07
GB2255746A (en) 1992-11-18
EP0585288A1 (fr) 1994-03-09
CA2103373A1 (fr) 1992-11-18

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