WO1992010546A1 - Completely inorganic, permanently anti-corrosive, innoxious anti-fouling paint - Google Patents

Completely inorganic, permanently anti-corrosive, innoxious anti-fouling paint Download PDF

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Publication number
WO1992010546A1
WO1992010546A1 PCT/KP1991/000010 KP9100010W WO9210546A1 WO 1992010546 A1 WO1992010546 A1 WO 1992010546A1 KP 9100010 W KP9100010 W KP 9100010W WO 9210546 A1 WO9210546 A1 WO 9210546A1
Authority
WO
WIPO (PCT)
Prior art keywords
sio
molar ratio
silicate
paint
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KP1991/000010
Other languages
English (en)
French (fr)
Inventor
Kim Gyu Hyong
Chae Jae Yun
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUNGSONG Corp
Original Assignee
HUNGSONG Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUNGSONG Corp filed Critical HUNGSONG Corp
Priority to DE9116748U priority Critical patent/DE9116748U1/de
Publication of WO1992010546A1 publication Critical patent/WO1992010546A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
    • C04B12/04—Alkali metal or ammonium silicate cements ; Alkyl silicate cements; Silica sol cements; Soluble silicate cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/003—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hybrid binders other than those of the polycarboxylate type
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/02—Polysilicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1618—Non-macromolecular compounds inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60—Agents for protection against chemical, physical or biological attack
    • C04B2103/67—Biocides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C04B2111/00525—Coating or impregnation materials for metallic surfaces
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C04B2111/0056—Coating or impregnation materials for ship decks

Definitions

  • Present invention relates to a completely inorganic
  • water glass system paint has been considered to give an anti-corrosive effect for heavy duty, special purpose steel structure, especially in deserts and ocean environment. But, in most cases, it is used as a
  • Phosphoric acid and phosphate such as silicon polyphosphate, titanium phosphate and metal oxides such as calcium oxide, alumina, etc. are known as curing agent of water glass paint already
  • the object of this invention is to provide a completely inorganic, permanently anti-corrosive, innoxious anti-fouling paint based upon the study of corrosion machanism of iron and the property of adhesively inhabitating organisms in the sea environment.
  • Another object of this invention is to provide a paint for coating inside and outside of structures and colors for pictures which have excellent adhesiveness, waterresistance, humidity control, anti-static, anti-bacterial property and permanently unfading colors.
  • the latter object of the invention relates directly to a noble work for inheriting and developing more the valuable cultural heritages of our ancestors (everlasting, unfading colors) displayed in the mural of tombs and pictures of many colors and designs in the historic relics of Koguryo dinasty of our country.
  • the paint is manufactured by various method in accordance with their uses.
  • the silicagel obtained by above mentioned reaction is matu for a certain period of time and washed to get gel-state denatu ammonia silicagel (xH 2 SiO 3 ⁇ NH 4 OH ⁇ yH 2 O) which absorbed ammonia g
  • Its molar ratio (NH 4 OH/SiO 2 ) is preferably 0,25-0,5.
  • This mixtu is mixed with silicate solution of molar ratio (M 2 O/SiO 2 ) 0,25- at the ratio of 1-50:100 by weight.
  • MX/Si0 2 can reach 0,01-6,05 to get denatured silicate solution of high viscosity (vehicle) (where, M: K, Na, Li, Rb, Ba, Zn, Ca; X: Cl, P, Br).
  • the alumosilicate is M(I) 2 O ⁇ M(II)O ⁇ Al 2 O 5 ⁇ nSiO 2 ⁇ mH 2 O (M(I) and M(II) are monovalent a bivalent metallic cations, n is molar ratio of SiO 2 /Al 2 O 3 , m is number of mol of water). Molar ratio (SiO 2 /Al 2 O 3 )
  • the grain size of the filler is prefe ably 250-300 mesh.
  • the vehicle is added preferably with alumosilicate, one or two_kinds of metal oxides of among ZnO, TiO 2 , Fe 2 O 3 , BaO, Al 2 O 3 , one or two kinds of metallic powders of amon Zn, Pe, Al and Cu at the proportion of 30-40, 0-20, 0-20 weight respectively.
  • the ion absorbing capacity of film changes in the ra of 90-110 mg equivalent/100 g, iron exchanging capacity being 10-30 mg equivalent/100 g. If a paint is made in this way and applied to the bottom of a ship, inorganic film is obtained, which is prooved to have an absorbing capacity 3 times higher than natural zeolite in terms of absorption amount of cation, in particular Ca 2+ (see table 1).
  • the film As the surface of the film comprises very active alkali metal cations, it is able to easily exchange with other metallic cations. Therefore, the film absorbos Ca 2+ away from amino acid calcium colloid solution of adhesive secretion product of sea adhesive organisms, thus weakening the adhesive strength of the adhesive organisms and making them unable to inhabitate.
  • the film has the capacity to absorb any amount of calcium secreted by sea adhesive organisms, including epiphytes, but also disorption-absorption process of calcium and sodium continues due to the constant reverse reaction in the sea water. Therefore, as long as film exists, the anti-fouling capacity against sea adhesive organisms, including epiphytes is permanent.
  • the vehicle is obtained according to the first method. This vehicle is mixed with filler of following composition and the resulting paint is applied to specimens and bottom of a ship and cured for a week, followed by exposure test and actual test.
  • composition (by weight %)
  • the former causes a neutralization and polysilicate elastomer (PSE) is obtained.
  • Precipitated PSE is dispersed into silicate solution so that molar ratio (PSE/SiO 2 ) can be 0,1-10,0and then aluminium salt solution is added thereto so that molar ratio(Al 2 O 3 /SiO 2 ) can be 0,01-5,0 and heated at 100 o0 to get vehicle.
  • This vehicle is mixed with barium sulphate, calcium phosphate, 1-2 kinds of metal oxides such as alumina, titanium white, zinc oxide etc. at the proportion of 5:1-10 by weight, which is made paste state, thus obtaining excellent smokeless, humidity controlling, anti-bacterial, anti-static paint needed for painting inside and outside of structures or colors for pictures.
  • the paint thus made is applicable to fabrics, concrete plate, glass, iron, slate and stone etc., excluding resin and oil colors, under-coating plate.
  • the vehicle obtained according to the second method is mixed with dispersoid of following composition and applied to cement plate and cured for one week:
  • Titanium oxide 5-10 % " "
  • the paint for decoration of insid and outside of building and structure has excellent humidity control, anti-bacterial, anti-static properties and is waterproof and smokeless. Therefore, its servise time is very long and it provides a good hygenic environment. Further, it is of completely inorganic, so it has an anti-aging property, too.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Composite Materials (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Paints Or Removers (AREA)
PCT/KP1991/000010 1990-12-05 1991-10-24 Completely inorganic, permanently anti-corrosive, innoxious anti-fouling paint Ceased WO1992010546A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE9116748U DE9116748U1 (de) 1990-12-05 1991-10-24 Vollstaendig anorganischer, dauerhafter korrosionsverhindernder, unschaedlicher faeulnisverhindernder farbanstrich

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KP287990 1990-12-05
KP90-2879 1990-12-05

Publications (1)

Publication Number Publication Date
WO1992010546A1 true WO1992010546A1 (en) 1992-06-25

Family

ID=19198155

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KP1991/000010 Ceased WO1992010546A1 (en) 1990-12-05 1991-10-24 Completely inorganic, permanently anti-corrosive, innoxious anti-fouling paint

Country Status (4)

Country Link
EP (1) EP0526594A1 (cg-RX-API-DMAC7.html)
CN (1) CN1062151A (cg-RX-API-DMAC7.html)
DE (1) DE9116748U1 (cg-RX-API-DMAC7.html)
WO (1) WO1992010546A1 (cg-RX-API-DMAC7.html)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2284822A (en) * 1993-12-14 1995-06-21 Daiei Kikai Kabushiki Kaisha Anti-corrosive, non-toxic coating compositions
AU661923B2 (en) * 1993-02-17 1995-08-10 Kabushiki Kaisha Daiei Kikai Water-glass, non-zinc multifunctional paint and its manufacturing method
CN102584090A (zh) * 2012-01-18 2012-07-18 厦门理工学院 一种海工混凝土防止污损生物腐蚀的外加剂及其制备方法
WO2016005397A1 (en) * 2014-07-07 2016-01-14 University College Dublin, National University Of Ireland, Dublin Thermal control coatings

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100633177B1 (ko) * 2005-03-24 2006-10-12 김정하 ｐＨ 조절을 이용한 상온건조 무기도료 조성물과 그제조방법 및 용도
DE102005059757A1 (de) * 2005-12-12 2007-06-14 Beharrysingh-Pracejus, Ramona Brenda Ökologische Schimmelbekämpfung durch natürlichen Massenrohstoff (Zeolith) als Fungizidersatz
CN103881431B (zh) * 2014-03-24 2016-04-13 浙江大学 一种硅烷偶联剂改性硅酸锂基涂料及其制备方法
CN115849868B (zh) * 2022-12-07 2023-11-07 山东电盾科技股份有限公司 自洁干挂硅瓷板幕墙

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3893864A (en) * 1973-12-20 1975-07-08 Exxon Research Engineering Co Quick-curing water resistant silica-alkali metal coatings and processes therefor
JPS54133523A (en) * 1978-04-07 1979-10-17 Kansai Paint Co Ltd Inorganic paint containing zinc powder
JPS5714783B2 (cg-RX-API-DMAC7.html) * 1978-09-14 1982-03-26
JPS58108257A (ja) * 1981-12-21 1983-06-28 Toshiba Corp 自己浄化型被覆層の製造方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0295834A1 (en) * 1987-06-16 1988-12-21 Minnesota Mining And Manufacturing Company High temperature resistant inorganic composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3893864A (en) * 1973-12-20 1975-07-08 Exxon Research Engineering Co Quick-curing water resistant silica-alkali metal coatings and processes therefor
JPS54133523A (en) * 1978-04-07 1979-10-17 Kansai Paint Co Ltd Inorganic paint containing zinc powder
JPS5714783B2 (cg-RX-API-DMAC7.html) * 1978-09-14 1982-03-26
JPS58108257A (ja) * 1981-12-21 1983-06-28 Toshiba Corp 自己浄化型被覆層の製造方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Obzornaya informatsia "Silikatnye lakokrasochnye materialy", 1989, NIITEXIM (Moscow), p. 25. *
See also references of EP0526594A4 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU661923B2 (en) * 1993-02-17 1995-08-10 Kabushiki Kaisha Daiei Kikai Water-glass, non-zinc multifunctional paint and its manufacturing method
GB2284822A (en) * 1993-12-14 1995-06-21 Daiei Kikai Kabushiki Kaisha Anti-corrosive, non-toxic coating compositions
AU670986B2 (en) * 1993-12-14 1996-08-08 Kabushiki Kaisha Daiei Kikai Method of preparing multifunctional coatings containing water-soluble silicate
GB2284822B (en) * 1993-12-14 1997-07-16 Daiei Kikai Kabushiki Kaisha Method of preparing multi-functional coatings containing water-soluble silicate
CN102584090A (zh) * 2012-01-18 2012-07-18 厦门理工学院 一种海工混凝土防止污损生物腐蚀的外加剂及其制备方法
CN102584090B (zh) * 2012-01-18 2013-12-18 厦门理工学院 一种海工混凝土防止污损生物腐蚀的外加剂及其制备方法
WO2016005397A1 (en) * 2014-07-07 2016-01-14 University College Dublin, National University Of Ireland, Dublin Thermal control coatings
CN106661345A (zh) * 2014-07-07 2017-05-10 爱尔兰国立大学都柏林大学学院 热控制涂料
US10100203B2 (en) 2014-07-07 2018-10-16 University College Dublin, National University Of Ireland Thermal control coatings

Also Published As

Publication number Publication date
CN1062151A (zh) 1992-06-24
EP0526594A4 (cg-RX-API-DMAC7.html) 1994-01-26
EP0526594A1 (en) 1993-02-10
DE9116748U1 (de) 1993-09-23

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