WO1992008361A1 - Produits alimentaires stabilises a l'acide - Google Patents
Produits alimentaires stabilises a l'acide Download PDFInfo
- Publication number
- WO1992008361A1 WO1992008361A1 PCT/US1991/008359 US9108359W WO9208361A1 WO 1992008361 A1 WO1992008361 A1 WO 1992008361A1 US 9108359 W US9108359 W US 9108359W WO 9208361 A1 WO9208361 A1 WO 9208361A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- foodstuff
- acid
- food
- puddings
- acceptable acid
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/10—Preserving with acids; Acid fermentation
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/154—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C19/00—Cheese; Cheese preparations; Making thereof
- A23C19/06—Treating cheese curd after whey separation; Products obtained thereby
- A23C19/068—Particular types of cheese
- A23C19/076—Soft unripened cheese, e.g. cottage or cream cheese
- A23C19/0765—Addition to the curd of additives other than acidifying agents, dairy products, proteins except gelatine, fats, enzymes, microorganisms, NaCl, CaCl2 or KCl; Foamed fresh cheese products
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C19/00—Cheese; Cheese preparations; Making thereof
- A23C19/06—Treating cheese curd after whey separation; Products obtained thereby
- A23C19/09—Other cheese preparations; Mixtures of cheese with other foodstuffs
- A23C19/0912—Fried, baked or roasted cheese products, e.g. cheese cakes; Foamed cheese products, e.g. soufflés; Expanded cheese in solid form
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/42—Preservation of non-alcoholic beverages
- A23L2/44—Preservation of non-alcoholic beverages by adding preservatives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/256—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan
Definitions
- Methods of preservation involve the application of scientific and engineering principles to control food deterioration. Modern processes to achieve food preservation are aimed primarily at controlling the growth of microorganisms.
- Drying is one of the oldest methods of food preservation known. Sun drying of fruits, nuts and grains, meats and vegetables is an important method of food preservation. However, since the natural elements are unpredictable, mechanical dehydration equipment is used to maximize heat transfer into the product and afford greater control of the drying variables.
- Commercially used dried foods include apples, apricots,, figs, prunes, raisins, carrots, potatoes, bananas, eggs, and milk. Most dried foods have excellent shelf life, are reasonably inexpensive, and, because of convenience, have widespread use in the food service industry.
- Fresh food products also have been prepared or even precooked and provided in cans.
- Canned products such as vegetables typically are prepared as follows: blanching the vegetables in boiling water to soften the vegetables; filling the blanched vegetables into a can together with a sauce or syrup if desired; sealing the can; and retorting the sealed can under time-temperature conditions sufficient to provide a sterile product - typically about one hour at 115°C. Since the canned product and its environment typically have a water content which will support the growth of spoilage organisms, the canned product must be subjected to relatively severe heat processing conditions in order to produce a sterile product. The product is then maintained in the sterile state, by sealing it in the can.
- sulfating agents such as sulphur dioxide, sodium and potassium bisulfite, sodium and potassium metabisulfite and sodium sulfite, have been successfully used for controlling or reversing discoloration of a wide variety of foodstuffs, including fruits and vegetables, potatoes, hominy, mushrooms and soup mixes.
- these sulfating agents has not been without problems. They tend to produce sulfurous odors and flavors, and though they heretofore have been generally regarded as safe, recently they have been implicated as potential health hazards (for example, as initiators of asthmatic attack and other adverse reactions in sensitive people) .
- the sodium containing agents are contraindicated with respect to hypertensive individuals.
- the art has long been searching for an alternative to the foregoing.
- the alternative should provide a product which has an extended life at room temperature or under normal conditions of refrigeration, is easily prepared and stored, has substantially no off-flavor in a state suitable for consumption, and (when in a state suitable for consumption) is at least palatable and pleasing in appearance.
- Microorganisms are sensitive to acids in various degrees.
- the preserving effect of acid is due to the hydrogen ion concentration and its destabilization effect on bacterial cells.
- Acids may be found in foods as a natural component, produced in foods by fermentation, or added to foods directly as a ' chemical. Since acid enhances the lethality of heat, acid foods (pH 4.6 or below) need only be heated generally up to about 95°C which is much lower than the heat needed for more alkaline foods (low acid; pH above 4.6) to render them free of spoilage organisms.
- the acids commonly added to foods create a distinct l, pickled ,, flavor, which in many instances detracts from the natural home-cooked flavor.
- the foods to which they have been added are technically termed acidified.
- the foodstuffs treated in these patents include such items as fruits, vegetables, meats, slurries of vegetable seed fiber, salad dressings, sauces, beverages including juices, and egg yolks.
- the acids used include ascorbic, acetic, citric, lactic, malic.
- JP-A-6 307 770 apparently describes the preparation of a noodle which contains an acid preservative in its dough.
- the preservative includes a food-acceptable organic acid, a salt of such an acid and a water-soluble macromolecular polysaccharide or chitosan.
- the organic acid may be citric, tartaric, malic, fumaric, lactic, acetic or gluconic acid.
- the polysaccharide may be alginic acid or sodium alginate. However, the polysaccharide appears to be used solely as a texturizing agent.
- the invention is a method for the preparation of an acid-stabilized food product, which comprises treating the food product with a polymeric food-acceptable acid under conditions such that the product's life is extended without introducing foreign acid flavor notes.
- the invention is a method for the preparation of an acid-stabilized food product, which comprises treating a food product with at least one polymeric food-acceptable acid in an amount, for a time, and at a temperature sufficient to effect the product's acid-stabilization.
- the invention is a method for the preparation of an acid-stabilized food product, which comprises treating a food product in an aqueous solution or suspension of at least one polymeric food- acceptable acid, and packaging the food product in a container.
- the invention is an acid-stabilized food product prepared by any of the methods described above.
- the invention is an acid-stabilized food product which is substantially free of foreign acid flavor notes.
- the invention is an acid-stabilized food product, which comprises a food product having a pH below about 4.6, and at least one polymeric food-acceptable acid component.
- the invention is a system, which comprises an acid-stabilized food product having a pH below about 4.6, at least one polymeric food-acceptable acid component, and a container in which the product resides.
- the food products in accordance with the present invention are advantageous in that they have the full complement of features required of a premium product, in contrast to prior products which are deficient in one or more important respects.
- the products of the present invention are easily prepared and stored. Further, they have an extended life, and thus lend themselves to distribution, display and sale in a wide range of commercial settings, for instance in high-volume supermarkets, in convenience stores and in food-service establishments. Because of the unique attributes of the present invention, there is no need to sacrifice the taste and texture of a premium product in order to secure the versatility in adaptation to the different marketing environments described above.
- the invention is advantageous in eliminating the need for specialized delivery and storage conditions which result in considerable cost savings.
- the products of the present invention in these embodiments, can be held at ambient temperature for long periods of time without damaging the product, or affecting its acceptability.
- the substantial economies resulting from obviating the need for refrigeration make the product commercially appealing from a cost standpoint.
- the products of the present invention can be held under refrigeration and will resist microorganism spoilage for substantially longer periods of time than are achieved with currently available conventional refrigerated products.
- the acid-stabilized products of the invention and the methods of preparing them, provide a product having the attributes of a premium product. They are preserved food products with enhanced- resistance to microorganism spoilage.
- any food product is considered to be usable in accordance with the invention.
- vegetables and fruits whether or not they are processed in any way
- fruit gels including casseroles, omelettes and quiches
- sauces including tomato-based sauces, teriyaki, wine sauces, purees, gravies and sauces containing meat whether or not the meat is also acid- stabilized before being added to the sauce
- grain products including soups, salad dressings, dairy-based products (cream sauces, cheeses, cheesecake, and custard)
- puddings including rice puddings, noddle puddings and breakfast puddings with cereal grains
- Examples of vegetables which are particularly well suited to use in accordance with the invention include carrots, zucchini, red bell peppers, onions and corn.
- Examples of fruits which are particularly well suited to use in accordance with the invention are cherries, blueberries, strawberries, apples, pears and peaches.
- the term "acid-stabilized food products” means food products treated with a suitable acid or acids, either in the free or dissociated state, under conditions (e.g., amount of acid, time of treatment, pH of treatment medium, temperature, etc.) such that the number of microbes destroyed in the food product is sufficient, at least under conditions of refrigeration, to result in the food product's maintaining its resistance to microorganism-spoilage for 90 days or more.
- to "treat" with acid(s) refers to treatment in any way suitable for effecting intimate contact between the food product and the acid(s), for example, by boiling the food product in acidified water, by incorporating the acid(s) directly in the food product during formulation, by soaking the food product in acidified water, some combination of two or more of those measures, or the like.
- a product is considered to be “shelf-stable" when that product remains of acceptable quality from the time of manufacture until the anticipated time of consumption without means of preservation such as refrigeration. While a shelf-life of even 3 or 4 months would be acceptable under certain circumstances, typically, ready-to-eat products are considered to be shelf-stable if they remain of acceptable quality for at least 9 months, preferably at least 12 months, and especially at least 14 months. Sensory attributes of particular interest in assessing shelf-stability are color, texture, aroma, flavor, rancidity and tartness. A product is shelf-stable when these attributes are of acceptable quality after passage of the desired time.
- precooked is meant that the food product can be prepared for consumption merely by heating it, for instance in a conventional oven or a microwave oven, or by steaming it or immersing it in hot or boiling water, to elevate the food product to a desired temperature for consumption.
- a precooking step the product is cooked for a sufficient time such that no prolonged heat treatment will be necessary in order to complete the cooking for consumption. This step can be carried out either in water or in an aqueous solution or suspension of acid.
- the precooked product is reheated for a time of 30 seconds to 3 minutes.
- the product is heated in a microwave oven for a short time, e.g., about two minutes. In this way, if the product is heated in final preparation for dining, so little heating is necessary that essentially no further cooking occurs.
- the precooked product since the precooked product is already fully cooked and ready to eat from the container, it can be used at room- temperature or in a cold salad with no heating.
- the product simulates fresh, refrigerated product and is not fully cooked.
- the food product is pre-cooked or at least cooked partially during preparation for storage and display pursuant to marketing.
- the acid-stabilization of the product typically renders it shelf-stable.
- the food product simulates a fresh refrigerated product, and there is no cooking prior to distribution into marketing channels.
- the food products in such cases is advantageously refrigerated, and under those conditions exhibits an extended life vis-a-vis conventional refrigerated products.
- An essential feature of the present invention is the utilization of at least one polymeric, typically macromolecular, food-acceptable acid.
- these acids are of high molecular weight, for example, having a subunit molecular weight of about 190, and can be copolymeric substances if desired.
- they are non-toxic, and additionally are materials which have the capability of retarding growth of spoilage micro ⁇ organisms without imparting a foreign acidic or other undesirable "off" flavor to the product.
- the preferred polymeric food-acceptable acids have a cellulosic or saccharide-derived backbone with pendent carboxyl groups.
- a preferred polymeric acid in accordance with the invention is alginic acid; also preferred are the non-alginic polymeric food-acceptable acids such as carrageenic acid, pectinic acid, and carboxymethyl cellulose acid. Combinations of two or more of the foregoing acids can also be utilized.
- the acid is used in an amount sufficient to attain conditions which result in the treated product's exhibiting the desired shelf-life or extended life, and one or more other attributes of a premium product without imparting foreign acid flavor notes.
- the precise quantity of acid utilized in any particular embodiment will often depend on other considerations, such as the nature of the final product desired (for example, refrigerated but not necessarily shelf-stable, or non-refrigerated and substantially shelf-stable, etc.), the amount and type of food product, the pH desired, other substances present, etc.
- the acid can be present in an amount of from about .05 to 2 wt.% of the cooking medium or brine.
- the quantity can vary from one embodiment to another, and its determination is empirical. It is, in any event, within the capability of one ordinarily skilled in the art, once equipped with the teachings set forth herein, to determine the amount of acid which is needed.
- the polymeric food-acceptable acid may be introduced as such, it can alternatively be generated in situ, for instance, by reaction between a salt of the polymeric acid and an inorganic acid.
- alginic acid may be generated by reacting sodium alginate with hydrochloric acid.
- derivatives of the acid may be used in place of the acid, or derivatives of the acid may be formed during cooking and be present in the product. All these embodiments are contemplated herei .
- alginates have been used as stabilizers in ice cream, water ices, sherbets and cheese, as gelling agents in water dessert gels and milk puddings, as suspending and thickening agents in fruit drinks and beverages, as foam stabilizers in beer, as emulsifiers in salad dressings and as film forming agents in coatings for meat and fish.
- U.S. Patent No. 3,332,786 apparently discloses that propylene glycol alginate "stabilizes" starch. (The specific starches mentioned are natural or modified starches derived from corn, wheat, potatoes, waxy maize and tapioca) .
- this stabilization relates to the ability to withstand freeze-thaw cycles or gelling problems. It does not relate to, nor was it recognized as having any ability to providing, shelf-stability or other extension of product life as discussed herein.
- these polymeric acids are generally only sparingly soluble in water. For this reason, it is surprising that they can act as acidulants at all. It is further unexpected that they can produce the required acidification to produce a stable product without the use of undesirably large quantities of the acid.
- one or more conventional acidulants is utilized in addition to the polymeric acid.
- the conventional acidulants will be used to assist in controlling the pH of the product at the desired level.
- the conventional acidulant is present in a brine for cooking the product, in an amount of about .25%.
- the conventional acidulant is incorporated in the product formulation.
- the conventional acidulant replaces some of the polymeric food-acceptable acid which would otherwise be needed.
- the amount of conventional acidulant used is not so large as to impart an unacceptable flavor to the product, and that the amount of polymeric food-acceptable acid is not decreased to the extent that the advantages of the invention are lost.
- Suitable conventional acidulants include inorganic acids, such as phosphoric, sulfuric and hydrochloric acids, and organic acids, such as citric, malic, acetic, fumaric, tartaric, adipic, lactic, ascorbic, sorbic, propionic and erythrobic acids. Citric acid is especially preferred, but malic and ascorbic acids are also preferred.
- a known amount of the product for example a 100 gram sample, is combined with an equivalent weight of distilled water in a blender until a homogeneous paste is achieved. Electrode tips are immersed in the paste while the paste is stirred. The electrode is allowed to stabilize for one minute before the pH reading is taken.
- the food product is precooked, typically by boiling it to bring it to the desired state of preparation.
- boiling is not necessary and the product may be precooked at temperatures below 100°C.
- the temperature is between 90 °C and 100°C, preferably about 95°C.
- the product is precooked (including any pasteurization or other stabilization) for about 5-30 minutes, especially 7-16 minutes, for instance by boiling in an aqueous solution or suspension of at least one polymeric food-acceptable acid.
- the aqueous solution or suspension typically has a pH from about 2.0-4.0, especially 2.4-2.8.
- the exact time, pH, temperature and other conditions of precooking can vary from one embodiment to another, and the skilled artisan will be able to derive the particular precooking parameters best suited to the situation empirically, based on his level of skill and the teachings set forth herein.
- the cooking times of the product will vary depending on the size, thickness and shape of the product and the degree to which it is precooked. Further guidance regarding suitable conditions to be used can be obtained from a study of the examples set forth hereinafter. Given the above disclosure and the examples, one skilled in the art will be able to determine appropriate conditions for processing the food products.
- Salt and/or sugar, and other flavorings can also be used in the cooking medium or brine.
- the product can be quenched after the initial treatment, typically at room temperature. It is preferred that the product be quenched, in an aqueous solution or suspension of at least one polymeric food-acceptable acid as already described, after heating in connection with precooking or partial cooking.
- a quenching liquid can also advantageously contain one or more conventional acidulants (also as already described) besides the polymeric acid. Whether or not a quenching liquid is used, the product can be washed (for instance in water) between steps and separated from, e.g. drained of, all free liquid prior to packaging or at least prior to sealing the container.
- the foodstuff can be contacted with an amount of edible oil sufficient to prevent the foodstuff from sticking together.
- the edible oil is used in an amount of from about 0.5 to 1% by weight of the product.
- the oils include rice oil, sunflower oil, soybean oil, cottonseed oil, or rapeseed oil.
- the pH of the product in the preferred embodiments should be below about 4.6. This is the generally recognized maximum pH which ensures that the pasteurized product remains shelf-stable.
- the pH of the product is in the range of about 3.8 to 4.6, preferably 3.8 to 4.2. In one preferred embodiment, the pH of the product is about 4.0.
- the pH can be below 3.8. However, the lower the pH, the more acid must be used and the more difficult it is to avoid acid flavor in the product. As a practical matter, the skilled person given the instant disclosure will be able to balance the pH level and amount of acid used to ensure that the product is shelf-stable and has substantially no foreign acid flavor notes.
- a product simulating a fresh product especially fresh fruits and vegetables.
- This can be achieved, for example, by soaking the product in an aqueous solution or suspension of acid to effect a product-pH low enough to result in the product's maintaining its resistance to microorganism spoilage for 90 days or more.
- the pH of the product can be less than about 4.6, but can alternatively be higher, for example as high as 6.0, if the product is refrigerated or some analogous preservative measure is taken. It is within the skill of the art to derive the parameters best suited to the situation. For example, a higher pH could be employed if the life of the product need not be greatly extended.
- the product typically is also pasteurized by passing it through a steam tunnel so that its center temperature is held at about 95°C for about 5 minutes.
- the acid is incorporated into the product formulation in an amount sufficient to effect a product-pH low enough to result in the product's maintaining its resistance to microorganism spoilage for 90 days or more.
- the pH of these products also can be less than about 4.6, but can alternatively be higher, for example as high as 6.0, if the product is to be refrigerated or some analogous preservative measure is taken. It is within the skill of the art to derive the parameters best suited to the situation.
- the products of the present invention are then typically packaged in a container having a configuration, construction and constituent material such that it is capable of maintaining the acid- stabilized product - i.e., providing an environment in which the product's shelf-stability or extended life due to acid-stabilization is not appreciably diminished by extraneous influences for substantially the entire period of its shelf-stability or extended life.
- the product is first cooled.
- the package is advantageously a container made of a microorganism-impermeable and/or waterproof material, for example glass, foil or a suitable plastic, and in some embodiments it is a container (for example, a pouch) made of oxygen-impermeable material.
- a container for example, a pouch
- Such containers include, for example, cans, jars, bottles,. foil trays, plastic trays, foil pouches and plastic pouches.
- the containers may be flexible or rigid.
- a particularly preferred container is a plastic tray, advantageously used with a foil or plastic lid.
- the plastic may be a single layer or, preferably a laminated material comprising a reinforcing layer, such as a nylon or polyester layer, and a sealing layer such as a polyethylene, polyvinylidene chloride or EVOH layer, for instance nylon/polyethylene or polyester/polyethylene,
- the package can be a laminate of board and plastics material, such as that sold by Combibloc.
- the products are packaged in the container under vacuum prior to pasteurization or other processing in connection with partial cooking (in which case the container is capable of withstanding heating attendant to such pasteurization or other processing) .
- the products of the present invention are preferably packed in the container under an inert gas atmosphere, for example, to avoid any discoloration of the product by oxidation during pasteurization, other processing, storage or display.
- the container is flushed with an inert gas, and then the container is sealed and sterilized. Any suitable, non-toxic inert gas can be used, but nitrogen and especially carbon dioxide or mixtures of nitrogen and carbon dioxide are preferred.
- the atmosphere within the container is substantially free of oxygen.
- the package can be hermetically sealed.
- carbon dioxide is particularly advantageous in certain embodiments because it should provide further protection against spoilage.
- the product of the present invention is subjected to such conditions as would allow water to gather in the package, such water could provide a breeding ground for microorganisms.
- the gas will dissolve in free water present. This makes the water a much less conducive environment for growth of microorganisms.
- food grade diatomic nitrogen is advantageously employed.
- the packaging often includes substantially evacuating the container for holding the product, i.e., so that the air content in the container does not exceed 5%.
- pasteurization is effected by holding the product in the sealed container at a temperature of about 85'C, for example, about six minutes in steam for a pack 20mm thick, followed by drying and cooling.
- reheating to the temperature mentioned above can be effected with steam or in hot water.
- the product may be pasteurized or otherwise processed in connection with partial cooking before the package is sealed.
- the minimum requirements are that the center temperature of the food should be held for a time sufficient to achieve killing of microorganisms.
- the center temperature of the food is held at a minimum of about 85 °C for at least about five minutes, and the food should have a pH less than 4.6. If higher temperatures or lower pHs are used, then the treatment time may be reduced.
- the pasteurization step whatever the pH, should hold a center temperature of 85°C for five minutes. More preferably, a center temperature of 93°C should be held for 10 minutes.
- the pasteurization step is carried out at a temperature of 100°C or less, it is not necessary to use a pressurized heating system.
- the pasteurization step can be carried out under atmospheric pressure using hot water or steam to heat the product. If the pasteurization step is carried out at a temperature above 100°C, then the use of a pressurized system will prevent water from being driven off. In any event, the product is pasteurized while it is maintained at a pH of less than 4.6 by the use of the aqueous solution or suspension of at least one polymeric food-acceptable acid.
- the finished product in the preferred embodiments of the invention typically have a pH below about 4.6.
- the products have a pH from about 3.8 to 4.2.
- the products have a pH of about 4.0.
- the products typically contain a characteristic acid component. This component preferably is included in an amount of approximately 0.05% -2% (w/w) , and especially 0.6% (w/w) .
- the acid component in the product includes any residue or moiety of the acid molecule which is present in the treated product and is a reflection of the fact that the product has been treated.
- the product of the invention has the full complement of advantages and features that should be demanded of a premium product, namely (i) extended life at room temperature or normally prevailing refrigeration temperatures, (ii) ease of preparation and storage, (iii) substantially no off- flavors when in a condition suitable for consumption, and (iv) palatability and a fresh, pleasant appearance.
- the present invention is further described and illustrated in the following examples. It will be appreciated that these examples are provided solely for the purposes of illustrating the invention and not for the purpose of limitation. It will further be appreciated that variations and modifications to the product and process can be made by the skilled person without departing from the spirit or scope of the invention as defined in the appended claims. Examples l and 2
- a 500 gram sample of a vegetable blend which includes chopped zucchini, carrots and red bell peppers in the relative ratios of 55:45:10 is used in these examples. Each sample is blanched at 90°F for 5 minutes.
- the blanching solution contains (in grams) :
- each sample is quenched in the blanchi solution at room temperature for 20 minutes, and then rinsed with water for 1 minute.
- the pH of the treated vegetable blend in Example 1 is 3.45, and in Example 2 is 3.68.
- the vegetable blend When reheated, the vegetable blend has organoleptic properties similar to a vegetable blend cooked in a conventional manner by boiling in water.
- a 1100 gram sample of the following chopped vegetable blend is used in this sample: zucchini 550g
- the sample is blanched at 90°F for 5 minutes; drained for 1 minute; and held for 20 minutes in the blanching 10 solution at room temperature.
- the blanching solution contains (in grams) :
- the ph of the treated vegetable blend is 3.47.
- the vegetable blend When reheated, the vegetable blend has organoleptic properties similar to a vegetable blend cooked in a conventional manner by boiling in water.
- a chopped vegetable blend which includes 49.2% zucchini, 41.5% carrots and 9.3% red bell peppers is prepared and treated under the same condition as in Example 3 with the following blanching solution:
- the treated vegetable blend is combined with creamy Italian Dressing in a jar, and the jar is nitrogen flushed before sealing.
- the pH of the vegetables and dressing is less than 4.0.
- the mixed product has organoleptic properties similar to other non-treated products of the same type.
- a chicken gravy of the following formulation is prepared:
- a second formulation is prepared with the addition of 0.200% alginic acid.
- the first formulation is processed under full retort conditions at 115°C to achieve commercial sterility.
- the pH of the product is 6.20.
- the second formulation is processed under pasteurization conditions at 93°C for acidified products to achieve commercial sterility.
- the pH of the product is 4.11.
- the cheese is softened and blended thoroughly with the eggs.
- the acids and lemon juice are mixed and then thoroughly combined with the egg mixture.
- the sugar and salt are added and the mixture is blended.
- the mixture is poured into trays. Graham crumbs are sprinkled over the top. The product is packaged and pasteurized.
- the pH of the product after processing is 2.7 for Trial 1, 4.2 for Trial 2 and 2.66 for Trial 3.
- the resulting product has an excellent flavor and texture, and the organoleptic properties in general are similar to a conventional product.
- Sliced potatoes are blanched at 90° C in the following blanching solutions (weight in grams) :
- the resulting sliced potatoes had organoleptic properties similar to potatoes cooked in a conventional manner by boiling in water.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Dispersion Chemistry (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- General Preparation And Processing Of Foods (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US61231490A | 1990-11-13 | 1990-11-13 | |
US612,314 | 1990-11-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992008361A1 true WO1992008361A1 (fr) | 1992-05-29 |
Family
ID=24452647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1991/008359 WO1992008361A1 (fr) | 1990-11-13 | 1991-11-08 | Produits alimentaires stabilises a l'acide |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0563076A4 (fr) |
AU (1) | AU9025491A (fr) |
IE (1) | IE913931A1 (fr) |
IL (1) | IL100034A0 (fr) |
MX (1) | MX9102044A (fr) |
WO (1) | WO1992008361A1 (fr) |
ZA (1) | ZA919018B (fr) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995004468A1 (fr) * | 1993-08-09 | 1995-02-16 | The Pillsbury Company | Produits laitiers de longue conservation |
WO1996001566A1 (fr) * | 1994-07-12 | 1996-01-25 | Daratech Pty. Ltd. | Conservation de structures vegetales souterraines exposees |
WO1997016976A1 (fr) * | 1995-11-08 | 1997-05-15 | The University Of British Columbia | Preparation et conservation de pommes fraiches en morceaux coupes vitaminees, aromatisees ou non aromatisees |
US6322829B1 (en) * | 1996-09-05 | 2001-11-27 | The Pillsbury Company | Savory fillings and food products including these fillings |
US6379730B1 (en) * | 1999-03-25 | 2002-04-30 | Cargill Incorporated | Method for the prevention of struvite in fish |
US6635290B1 (en) * | 1999-03-17 | 2003-10-21 | Furman Foods, Inc. | Shelf stable kit for making chili |
US6893675B1 (en) | 2000-06-23 | 2005-05-17 | Afp Advanced Food Products Llc | Acidified imitation cheese sauce and pudding compositions and methods for producing such compositions |
US6905721B2 (en) | 2001-06-25 | 2005-06-14 | Afp Advanced Food Products, Llc | Imitation cheese compositions for use in the manufacture of cheese loaves, slices and the like, and method of producing such compositions |
WO2012046086A1 (fr) * | 2010-10-08 | 2012-04-12 | Ntnu Technology Transfer As | Procédé de prolongement de la durée de conservation d'un produit alimentaire |
IT201700121460A1 (it) * | 2017-10-25 | 2019-04-25 | Food Solution S R L | Procedimento perfezionato per la produzione di un alimento confezionato |
WO2019165002A3 (fr) * | 2018-02-20 | 2019-12-26 | Kerry Luxembourg S.à.r.l. | Compositions pour retarder la rancidité dans des sauces et sauces d'assaisonnement alimentaires à base d'huile |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1071920A (fr) * | 1976-11-15 | 1980-02-19 | Carnation Company | Procede de mise en conserve |
JPS5881735A (ja) * | 1981-11-09 | 1983-05-17 | Toyo Seikan Kaisha Ltd | 剥皮果菜類缶びん詰の製造法 |
JPS5942838A (ja) * | 1982-08-31 | 1984-03-09 | Nippon Suisan Kaisha Ltd | 白身魚のレトルトパウチ食品の製造方法 |
JPS59216542A (ja) * | 1983-05-24 | 1984-12-06 | Kiyoshi Kumabe | 保存性生鮮食品及びその加工法 |
US4504504A (en) * | 1983-03-14 | 1985-03-12 | Campbell Soup Company | Texture preservation for diced fresh food products using gelled polyuronic acids |
JPS637770A (ja) * | 1986-06-27 | 1988-01-13 | Nippon Kayaku Co Ltd | 加工食品の製造方法 |
US4959230A (en) * | 1988-09-27 | 1990-09-25 | Kraft General Foods, Inc. | Composition for extending shelf life of fruits and vegetables |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS575680A (en) * | 1980-06-11 | 1982-01-12 | Kibun Kk | Food preservative and its method of use |
JPH01215239A (ja) * | 1988-02-20 | 1989-08-29 | Takenori Kato | 乳飲料 |
JPH02167037A (ja) * | 1988-10-03 | 1990-06-27 | Takenori Kato | ゲル物の品質劣化防止方法 |
EP0441937B1 (fr) * | 1989-09-01 | 1993-10-20 | Mars Incorporated | Produits de riz de longue conservation et procedes de fabrication |
-
1991
- 1991-11-08 EP EP19920900082 patent/EP0563076A4/en not_active Withdrawn
- 1991-11-08 WO PCT/US1991/008359 patent/WO1992008361A1/fr not_active Application Discontinuation
- 1991-11-08 AU AU90254/91A patent/AU9025491A/en not_active Abandoned
- 1991-11-11 IL IL100034A patent/IL100034A0/xx unknown
- 1991-11-12 IE IE393191A patent/IE913931A1/en unknown
- 1991-11-13 MX MX9102044A patent/MX9102044A/es unknown
- 1991-11-13 ZA ZA919018A patent/ZA919018B/xx unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1071920A (fr) * | 1976-11-15 | 1980-02-19 | Carnation Company | Procede de mise en conserve |
JPS5881735A (ja) * | 1981-11-09 | 1983-05-17 | Toyo Seikan Kaisha Ltd | 剥皮果菜類缶びん詰の製造法 |
JPS5942838A (ja) * | 1982-08-31 | 1984-03-09 | Nippon Suisan Kaisha Ltd | 白身魚のレトルトパウチ食品の製造方法 |
US4504504A (en) * | 1983-03-14 | 1985-03-12 | Campbell Soup Company | Texture preservation for diced fresh food products using gelled polyuronic acids |
JPS59216542A (ja) * | 1983-05-24 | 1984-12-06 | Kiyoshi Kumabe | 保存性生鮮食品及びその加工法 |
JPS637770A (ja) * | 1986-06-27 | 1988-01-13 | Nippon Kayaku Co Ltd | 加工食品の製造方法 |
US4959230A (en) * | 1988-09-27 | 1990-09-25 | Kraft General Foods, Inc. | Composition for extending shelf life of fruits and vegetables |
Non-Patent Citations (2)
Title |
---|
PATENT ABSTRACTS OF JAPAN, Vol. 12, No. 209 issued 15 June 1988 & JP,A,63 007770 (NIPPON KAYAKU CO., LTD) 27 June 1986, see the entire Abstract. * |
See also references of EP0563076A4 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995004468A1 (fr) * | 1993-08-09 | 1995-02-16 | The Pillsbury Company | Produits laitiers de longue conservation |
WO1996001566A1 (fr) * | 1994-07-12 | 1996-01-25 | Daratech Pty. Ltd. | Conservation de structures vegetales souterraines exposees |
WO1997016976A1 (fr) * | 1995-11-08 | 1997-05-15 | The University Of British Columbia | Preparation et conservation de pommes fraiches en morceaux coupes vitaminees, aromatisees ou non aromatisees |
US5922382A (en) * | 1995-11-08 | 1999-07-13 | The University Of British Columbia | Preparation and preservation of fresh, vitaminized, flavored and unflavored cut apple pieces |
US6322829B1 (en) * | 1996-09-05 | 2001-11-27 | The Pillsbury Company | Savory fillings and food products including these fillings |
US6635290B1 (en) * | 1999-03-17 | 2003-10-21 | Furman Foods, Inc. | Shelf stable kit for making chili |
US6379730B1 (en) * | 1999-03-25 | 2002-04-30 | Cargill Incorporated | Method for the prevention of struvite in fish |
US6893675B1 (en) | 2000-06-23 | 2005-05-17 | Afp Advanced Food Products Llc | Acidified imitation cheese sauce and pudding compositions and methods for producing such compositions |
US6905721B2 (en) | 2001-06-25 | 2005-06-14 | Afp Advanced Food Products, Llc | Imitation cheese compositions for use in the manufacture of cheese loaves, slices and the like, and method of producing such compositions |
WO2012046086A1 (fr) * | 2010-10-08 | 2012-04-12 | Ntnu Technology Transfer As | Procédé de prolongement de la durée de conservation d'un produit alimentaire |
IT201700121460A1 (it) * | 2017-10-25 | 2019-04-25 | Food Solution S R L | Procedimento perfezionato per la produzione di un alimento confezionato |
WO2019082092A1 (fr) * | 2017-10-25 | 2019-05-02 | Food Solution S.R.L. | Procédé pour obtenir un produit alimentaire emballé |
WO2019165002A3 (fr) * | 2018-02-20 | 2019-12-26 | Kerry Luxembourg S.à.r.l. | Compositions pour retarder la rancidité dans des sauces et sauces d'assaisonnement alimentaires à base d'huile |
Also Published As
Publication number | Publication date |
---|---|
IL100034A0 (en) | 1992-08-18 |
AU9025491A (en) | 1992-06-11 |
MX9102044A (es) | 1992-07-08 |
EP0563076A1 (fr) | 1993-10-06 |
ZA919018B (en) | 1992-07-29 |
IE913931A1 (en) | 1992-05-20 |
EP0563076A4 (en) | 1993-11-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5332587A (en) | Acid stabilized pasta | |
JP4679023B2 (ja) | 保存性に優れた食品の製造法および食品保存剤 | |
CA1319854C (fr) | Pates cuites "al dente" de longue conservation | |
US4741911A (en) | Method of thermally processing low-acid foodstuffs in hermetically sealed containers and the containers having the foodstuffs therein | |
Singh et al. | The major types of food spoilage: an overview | |
US11154080B2 (en) | High pressure frozen sterilization process | |
JPS5811831B2 (ja) | 密封包装食品 | |
WO1992008361A1 (fr) | Produits alimentaires stabilises a l'acide | |
EP0550466B1 (fr) | Produits alimentaires stabilises par acide et leur procede de preparation | |
JP4255099B2 (ja) | 青野菜ピューレ及びその製造法並びに該野菜ピューレを含有する食品 | |
KR0125010B1 (ko) | 산 안정화된 페이스타 | |
US20050019468A1 (en) | Pasteurization of deli-salads |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AU BR CA FI JP KR NO SU |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IT LU NL SE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1992900082 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1992900082 Country of ref document: EP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 1992900082 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: CA |