WO1991018584A1 - Compositions de peroxyde d'hydrogene - Google Patents

Compositions de peroxyde d'hydrogene Download PDF

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Publication number
WO1991018584A1
WO1991018584A1 PCT/EP1991/000999 EP9100999W WO9118584A1 WO 1991018584 A1 WO1991018584 A1 WO 1991018584A1 EP 9100999 W EP9100999 W EP 9100999W WO 9118584 A1 WO9118584 A1 WO 9118584A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
hair
group
hydrogen peroxide
bleaching
Prior art date
Application number
PCT/EP1991/000999
Other languages
German (de)
English (en)
Inventor
Horst Höffkes
Karin Nelles
Winifried Neuhaus
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to JP91509536A priority Critical patent/JPH05507476A/ja
Publication of WO1991018584A1 publication Critical patent/WO1991018584A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the invention relates to aqueous preparations of hydrogen peroxide, which are particularly suitable as oxidizing agent preparations for bleaching and for oxidative coloring of the hair with oxidizing coloring agents.
  • the bleaching and dyeing of the hair with oxidation hair dyeing agents is generally carried out with the aid of two separately packaged preparations - the bleaching cream or oxidation hair dyeing cream (A) and the oxidizing agent preparation (B) - which are combined only shortly before use and in one Application bottle is mixed by simple shaking and then applied to the hair as a ready-to-use blending or dyeing preparation.
  • Two-chamber mixing and dispensing containers have also been developed for home use, in which components A and B are packed separately from one another in a suitable quantity ratio and have a partition which can be mechanically destroyed from the outside between the two chambers and a dispensing opening on one of the two chambers . Shortly before use, the partition is destroyed, whereupon components A and B are combined and mixed by shaking or other mechanical measures. Then the ready-to-use hair dyeing or bleaching preparation can be removed through the dispensing opening or applied directly to the hair to be colored.
  • a rapid and homogeneous mixing of the bleaching or coloring cream (A) and the oxidizing agent preparation (B) is very important for the success of the dyeing process.
  • Foaming is caused primarily by the fact that the oxidizing agent preparations, generally aqueous preparations of hydrogen peroxide, contain strongly foaming anionic surfactants for stabilization. These are necessary in order to stabilize the dispersions of alkali-soluble, thickening, carboxyl-containing polymers contained in such preparations for increasing viscosity after mixing. Bleaching and oxidation dye creams also often contain highly foaming anionic surfactants in order to keep the fatty alcohols dispersed in these products for viscosity build-up in the dispersed state. Since the use of these high-foaming anionic surfactants cannot be avoided for the reasons mentioned, the problem arises of controlling the development of foam by means of a suitable additive.
  • the invention relates to aqueous preparations of hydrogen peroxide for the oxidative dyeing and bleaching of the hair with a content of anionic surfactants and a thickening, carboxyl group-containing polymer or copolymer with addition of a nonionic surfactant of the formula I which is soluble in aqueous alkali
  • R * is an alkyl or alkenyl group with 10 - 22 C atoms or an alkylphenyl group with 6 - 15 C atoms in the alkyl group
  • the preparations of hydrogen peroxide according to the invention are preferably in the form of an aqueous dispersion of the carboxyl group-containing polymer merisats- or copolymer, but they can also contain an emulsified or dispersed fat phase.
  • the hydrogen peroxide content is preferably 1-15% by weight of the preparations.
  • a polymer or copolymer of acrylic acid or methacrylic acid is preferably used as the polymer or copolymer containing carboxyl groups.
  • Such polymers and copolymers are known per se and have long been used as thickeners for aqueous solutions.
  • GB-A 870 994 e.g. Dispersions of copolymers of at least 10% by weight of lower alkyl acrylate, 25 to 70% by weight of methacrylic acid and optionally 0 to 40% by weight of another comonomer with a solids content of 25 to 50% by weight are described.
  • Copolymers of 50-75% by weight of ethyl acrylate, 25-35% by weight of acrylic acid and 0 to 25% by weight of other comonomers are known from DE-A 11 64 095.
  • copolymers can be modified by adding crosslinking, polyunsaturated copolymerizable comonomers in molecular weight and thus in the thickening effect.
  • Particularly effective acrylate dispersions for this purpose are e.g. known from DE-A 3445549.
  • the suitable polymers are usually aqueous dispersions, usually with a solids content of 20 to 30% by weight, which are stable and have a low viscosity in a pH range of about 2 to 5.
  • aqueous bases for example by alkali hydroxide solutions (for example sodium hydroxide solution or potassium hydroxide solution), ammonia solution, alkanolamines (for example; mono-, di- or triethanolamine) and the carboxyl groups are converted into the salt form,
  • alkali hydroxide solutions for example sodium hydroxide solution or potassium hydroxide solution
  • ammonia solution for example sodium hydroxide solution or potassium hydroxide solution
  • alkanolamines for example; mono-, di- or triethanolamine
  • the polymers are preferably present in the preparations according to the invention in an amount of 0.1-10% by weight (calculated as solids) based on the preparation.
  • the preparations according to the invention contain anionic surfactants for stabilization.
  • anionic surfactants examples include alkyl sulfates, alkane sulfonates, ⁇ -olefin sulfonates, alkyl polyglycol ether sulfates and alkyl polyglycol ether sulfonates.
  • Other suitable anionic surfactants are sulfosuccinic acid monoester salts, alkyl polyglucol ether carboxylates, oleic acid sulfonates and other high-foaming, anionic sulfate or sulfonate surfactants.
  • the anionic surfactants are preferably in the form of their alkali metal, magnesium, ammonium or mono-, di- or trialkanolammonium salts with 2-4 C atoms in the alkanol group. They are preferably contained in an amount of 0.1-10% by weight of the preparation.
  • the nonionic surfactants of the formula I to be used according to the invention for foam control are substances which are known per se and are commercially available. They are produced by adding x moles of ethylene oxide to fatty alcohols, preferably to linear, saturated fatty alcohols, with 10-22 carbon atoms and then adding a less hydrophilic end group R 2 . This end group can be introduced, for example, by adding 3-5 moles of propylene oxide to the ethoxylate.
  • R 2 is either a group -0 (C3H5 ⁇ ) 4-H d 0 e -j he ne n-butyl group.
  • a polymer which contains carboxyl groups and is thickening in aqueous alkali 1-10% by weight of a polymer which contains carboxyl groups and is thickening in aqueous alkali, and 0.1-5% by weight of a nonionic surfactant of the formula I.
  • the hydrogen peroxide preparation according to the invention can also contain an emulsified or dispersed fat phase for clouding and for setting an increased viscosity and better miscibility.
  • fat components e.g. Paraffins, petroleum jelly, waxes, hard fats, fatty acid mono- and diglycerides and especially linear, saturated fatty alcohols, preferably cetyl and stearyl alcohol, are added to the preparation in an amount of 0.5-5% by weight.
  • These fat components can either already be added in dispersed form or can be dispersed in the preparation with the aid of the anionic and nonionic surfactant.
  • the hydrogen peroxide preparations according to the invention can also contain other auxiliaries in minor amounts.
  • auxiliaries e.g., phenol, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium sulfate, sodium bicarbonate, sodium bicarbonate, sodium sulfate, sodium sulfate, sodium
  • - Stabilizers for hydrogen peroxide such as dipicolinic acid, quinolinic acid, polyphosphates or those from DE-B 11 07 207 known acylation products of phosphorous acid, for example l-hydroxyethane-l, l-diphosphonic acid in an amount of about 0.05 to 1.5% by weight
  • the bleaching or dyeing preparations used for bleaching or dyeing the hair are preferably oil-in-water emulsions (creams).
  • fat components they preferably contain the fat components already mentioned above, preferably cetyl and stearyl alcohol.
  • the coloring creams serve as carriers for the oxidation dye or products dissolved in them.
  • these oil-in-water emulsions only occasionally contain smaller amounts of oxidation dye precursors which, when used, compensate for too strong, natural shades of yellow and red in the hair.
  • the bleaching and coloring creams are preferably at a pH of 8-11 and are mixed with the hydrogen peroxide preparation according to the invention before use.
  • the invention therefore furthermore relates to a process for dyeing or lightening the hair using an oxidation hair dyeing cream or bleaching cream (A) in the form of an oil-in-water emulsion with a pH of 8-11.
  • A oxidation hair dyeing cream or bleaching cream
  • B hydrogen peroxide preparation
  • the hydrogen peroxide preparations according to the invention can be mixed by shaking them gently in the application bottle without great energy expenditure or long shaking times. The homogeneity of the dyeing or blending preparations achieved is shown in an improved dyeing result.
  • each of the hydrogen peroxide preparations 1,1 or 1,2 according to the invention or of the comparison preparation 1,3 were filled into flexible 100 ml polyethylene application bags.
  • the Oxidations ⁇ hair dye cream was filled in 40 nl tubes.
  • the contents of one tube of oxidation hair dye cream were pressed into one of the application vials with the hydrogen peroxide preparation. After unscrewing the the contents were mixed by hand shaking. It was found that the preparation 1, 3 not according to the invention was only mixed with the cream so homogeneously after very long shaking that no inhomogeneities could be seen with the naked eye. The reason for the poorer mixing was obviously due to the strong foaming, which hindered the mechanical movement of the liquid when shaken.
  • the ready-to-use dyeing preparations obtained after mixing were applied to the hair in a customary manner and washed out with water after the exposure time. When washing out, a sufficient amount of foam still developed in the preparations according to the invention.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

Des compositions aqueuses de péroxyde d'hydrogène, utiles pour teindre ou pour décolorer des cheveux par oxydation, contiennent des agents tensio-actifs anioniques très moussants et un polymère épaississant soluble dans l'alcali et contenant des groupes carboxyle. Afin de modérer et d'ajuster la quantité de mousse lors du mélange avec des crèmes de teinture par oxydation et des crèmes d'oxygénation en émulsion, ces compositions contiennent entre 0,1 et 5 % en poids d'un agent tensio-actif non ionique ayant la formule (I), R1-O-(C2H4O)x-R2, dans laquelle R1 est un groupe alkyle ou alcényle ayant de 10 à 22 atomes de C ou un groupe alkylphényle ayant de 6 à 15 atomes de C dans le groupe alkyle, R2 est un groupe -(C¿3?H6O)y-H, -CnH2n+1 ou -(C3H6O)y-CnH2n+1, où x est compris entre 1 et 10, y entre 3 et 5 et n entre 1 et 4.
PCT/EP1991/000999 1990-06-07 1991-05-29 Compositions de peroxyde d'hydrogene WO1991018584A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP91509536A JPH05507476A (ja) 1990-06-07 1991-05-29 過酸化水素製剤

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4018259.2 1990-06-07
DE19904018259 DE4018259A1 (de) 1990-06-07 1990-06-07 Wasserstoffperoxid-zubereitungen

Publications (1)

Publication Number Publication Date
WO1991018584A1 true WO1991018584A1 (fr) 1991-12-12

Family

ID=6407970

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1991/000999 WO1991018584A1 (fr) 1990-06-07 1991-05-29 Compositions de peroxyde d'hydrogene

Country Status (6)

Country Link
EP (1) EP0531391A1 (fr)
JP (1) JPH05507476A (fr)
CS (1) CS168391A3 (fr)
DE (1) DE4018259A1 (fr)
WO (1) WO1991018584A1 (fr)
YU (1) YU97991A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994002117A1 (fr) * 1992-07-17 1994-02-03 Eastman Chemical Company Emulsions melangees a froid utilisees comme revelateur dans des colorants pour cheveux par oxydation et dans des decolorants pour cheveux
WO1995008978A1 (fr) * 1993-09-30 1995-04-06 Henkel Kommanditgesellschaft Auf Aktien Preparations d'eau oxygenee
US8430935B2 (en) 2010-03-25 2013-04-30 Henkel Ag & Co. Kgaa Colorants for keratinic fibres having optimized viscosity adjustment

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4332965A1 (de) * 1993-09-28 1995-03-30 Wella Ag Oxidationshaarfärbemittel aus einer cremeförmigen Farbstoffträgermasse und einer ein Polymer und ein Oxidationsmittel enthaltenden Zubereitung sowie Verfahren zum oxidativen Färben von Haaren
DE4431577A1 (de) * 1994-09-05 1996-03-07 Wella Ag Wasserstoffperoxidhaltiges Aerosolpräparat
DE19714370A1 (de) † 1997-04-08 1998-10-15 Henkel Kgaa Wäßrige pflegende Haut- und Haarbehandlungsmittel
DE10016497A1 (de) 2000-04-01 2001-10-18 Goldwell Gmbh Verfahren und Zusammensetzung zum oxidativen Färben von menschlichen Haaren
JP2011184428A (ja) * 2010-02-10 2011-09-22 Kao Corp 染色又は脱色キット
EP2425809A1 (fr) * 2010-09-03 2012-03-07 KPSS-Kao Professional Salon Services GmbH Composition de coloration aqueuse

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2182781A1 (en) * 1971-03-16 1973-12-14 Henkel & Cie Gmbh Aq oxidising baths - esp for cold-bleaching and washing of textiles, contg acylated 2,4,6,8-tetraaza-bicyclo-(3,3,1)-nonan-3,7-d
FR2303075A1 (fr) * 1975-03-06 1976-10-01 Solvay Compositions detergentes liquides
EP0039002A2 (fr) * 1980-04-25 1981-11-04 Hoechst Aktiengesellschaft Utilisation d'éthers alkylpolyglycol-tert.butyliques comme adjuvants de blanchiment et bains de blanchiment contenant ces adjuvants
EP0308825A1 (fr) * 1987-09-24 1989-03-29 Henkel Kommanditgesellschaft auf Aktien Composition sous forme d'émulsion contenant du peroxyde d'hydrogène, pour la décoloration et pour la teinture par oxydation des cheveux

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2182781A1 (en) * 1971-03-16 1973-12-14 Henkel & Cie Gmbh Aq oxidising baths - esp for cold-bleaching and washing of textiles, contg acylated 2,4,6,8-tetraaza-bicyclo-(3,3,1)-nonan-3,7-d
FR2303075A1 (fr) * 1975-03-06 1976-10-01 Solvay Compositions detergentes liquides
EP0039002A2 (fr) * 1980-04-25 1981-11-04 Hoechst Aktiengesellschaft Utilisation d'éthers alkylpolyglycol-tert.butyliques comme adjuvants de blanchiment et bains de blanchiment contenant ces adjuvants
EP0308825A1 (fr) * 1987-09-24 1989-03-29 Henkel Kommanditgesellschaft auf Aktien Composition sous forme d'émulsion contenant du peroxyde d'hydrogène, pour la décoloration et pour la teinture par oxydation des cheveux

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994002117A1 (fr) * 1992-07-17 1994-02-03 Eastman Chemical Company Emulsions melangees a froid utilisees comme revelateur dans des colorants pour cheveux par oxydation et dans des decolorants pour cheveux
WO1995008978A1 (fr) * 1993-09-30 1995-04-06 Henkel Kommanditgesellschaft Auf Aktien Preparations d'eau oxygenee
US5651793A (en) * 1993-09-30 1997-07-29 Henkel Kommanditgesellschaft Auf Aktien Hydrogen peroxide preparations containing foam regulators
US8430935B2 (en) 2010-03-25 2013-04-30 Henkel Ag & Co. Kgaa Colorants for keratinic fibres having optimized viscosity adjustment

Also Published As

Publication number Publication date
DE4018259A1 (de) 1991-12-12
CS168391A3 (en) 1992-02-19
YU97991A (sh) 1993-11-16
JPH05507476A (ja) 1993-10-28
EP0531391A1 (fr) 1993-03-17

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