Classifications

• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
  • D21C7/00—Digesters
  • D21C7/14—Means for circulating the lye
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
  • D21C7/00—Digesters

Definitions

• the present invention relates to improvements in apparatus and methods for the fiber liberating digestion of continuously fed comminuted cellulosic fiber material by cooking liquor and subsequent washing of the liberated fiber material. More particularly, the invention relates to an improved apparatus and process utilizing spent black liquor for heating the chips to effect savings in thermal energy, and for accomplishing high sulfidity cooking without changes to the overall sulfide balance of the system to accomplish a pulp having improved mechanical characteristics, to improve pulp yield, and to achieve extended delignification.
• the so-called kraft or sulphate pulp is produced by cooking the raw chipped wood in a liquor wherein materials such as sodium hydroxide and sodium sulfide serve as the essential fiber liberating chemicals.
• the so-called soda pulp derives its name from the caustic soda-containing cooking liquor which is produced, namely a liquor containing principally caustic soda as the active pulping chemical. There are modifications of these processes based on the use of liquors containing caustic soda and sodium sulphite or containing caustic soda, and sodium sulphide.
• the spent liquor is allowed to flash and steam is generated.
• the steam is normally utilized to pre-steam the chips and to generate hot water.
• the heat and cooking chemicals could be utilized more efficiently if the spent liquors were used to preheat and precondition the chips and to preheat the cooking chemicals such as white liquor in kraft processes which enters the process.
• a further object of the invention is to provide a continuous digestion process wherein the used black cooking liquors and the white liquors are utilized in a unique manner in the process so as to obtain a saving in thermal energy, and to effect an improvement in the resultant qualities of the pulp which is produced.
• Yet another object of the present invention is to provide a process for achieving high sulfidity cooking without significant changes to the overall sulfide balance of the cooking system, and for achieving extended delignification in a continuous digesting system while improving pulp yield over existing continuous digesting systems.
• a feature of the invention is the provision of a continuous digestion process wherein a plurality of containers are used in sequence, with the first container receiving preconditioned chips and the chips being preimpregnated and heated in the first container with a low temperature black liquor. Further heating of the chips is accomplished with higher temperature liquors in the second and subsequent containers, and after the chips are brought up to the desired elevated temperature, a white liquor is circulated through the chips at the digestion temperature and pressure.
• the chips are continuously fed from the last of the preimpregnation containers to the digester for cooking.
• the cooked delignified chips are removed as pulp from the bottom of the digester and circulated to final washing.
• the wash liquor from the washer is utilized in two or more stages to displace from the digester the free liquor and liquor within the chips.
• the hot spent liquor is utilized to heat the incoming materials for the continuous digester.
• the spent liquor having been extracted from the digester, is accumulated in pressure vessels substantially at digester temperature. Lower temperature liquors from final displacement stages are also accumulated.
• the incoming chips are first exposed to the lower temperature liquors and then the higher temperature liquors.
• the white liquor is preheated in a heat exchanger, utilizing a portion of hot spent liquor.
• the white liquor can be stored in a hot white liquor accumulator whereas the hot spent liquor, after having given energy to the white liquor, goes to the low temperature accumulator.
• the process can be accomplished wherein a first initial chamber or vessel is utilized, being fed by a screw conveyor feeder to press the chips downwardly.
• the vessel may be employed with an extraction screen at the top and with a recirculation screen further down the vessel, with the recycled liquor flowing through a central pipe ending at the screen level.
• Low temperature liquor is fed from a low temperature tank to a circulation pump, and the liquor is evenly spread over the vessel area.
• the amount of liquor extracted from the top screen is an amount that generally corresponds to the white liquor charge, wood moisture and the dilution factor.
• the extracted liquor goes to the evaporators.
• the remaining part of the liquor goes with the chips downwardly in the chamber.
• the treatment with hot spent liquor takes place in a vessel at principally digester pressure.
• this high pressure vessel is located underneath the first vessel, and the transfer of material takes place in utilizing a high pressure feeder.
• the arrangement for heat exchange is, in principal, essentially the same as in the first lower temperature vessel.
• the hot spent liquor is introduced in a recirculation circuit, and a portion of the liquor flows countercurrent to the chips, being extracted from a top screen.
• the low temperature liquor is being displaced and substituted by a hot spent liquor.
• the low temperature liquor which leaves the top screen is conveyed back to the low temperature tank.
• a portion of the hot spent liquor is utilized to preheat the white liquor that is introduced in the bottom of the high pressure vessel.
• white liquor should be added after that mechanical device to avoid pulp deterioration. This can be done by utilizing a vessel which forms part of the continuous digester and is integrated into the digester apparatus itself.
• Figure 1 is a schematic drawing of a process for operating in accordance with the principles of the present invention.
• Figure 2 is a schematic drawing of a modification of the process shown in Figure 1, wherein the high pressure preimpregnation vessel forms a part of the continuous digester.
• wood chips are delivered to a first chamber or container 10 through a screw delivery mechanism 11.
• the chips may be preconditioned, such as by being heated by steam, in a supply container 12.
• the preheating occurs by a supply of low temperature black liquor supplied from a low temperature black liquor tank 13 through a supply line 14.
• the black liquor is circulated through the chips through a recirculating mechanism including a recirculating line 15 and a recirculating pump 16.
• preheated wood chips are forcibly conveyed downwardly to a second container 21, which is a hot liquor preimpregnator in which the wood chips are subjected to liquor for a predetermined time at a higher temperature and high pressure than in the first container.
• a mechanism such as a rotary delivery valve 20 is employed.
• Such valves are well-known to those skilled in the art and will not be described further herein.
• hot black liquor is delivered to the second container by line 23, which receives hot black liquor from a hot black liquor tank 22 delivered by a pressure pump 22a.
• the hot black liquor is recirculated through the moving chips by recirculation line 24, with the liquor being circulated by a pulp 24a.
• a portion of the liquor is removed through a line 24b, controlled by a valve 24c, to be delivered back to the low temperature black liquor tank 13, preferably upstream of a delivery pump 13a which pumps the low temperature black liquor to the first container 10.
• screens 21a, 21b, and 21c Arranged in the second container 21 are screens 21a, 21b, and 21c, which allow for the removal of the liquor, with the screen 21a facilitating the removal of the excess black liquor through the line 24b, and the screens 21b and 21c facilitating the recirculation of the high temperature black liquor in two recirculation paths.
• white liquor is delivered to the second container 21 through a line 25.
• the white liquor can be supplied through a line 25a, shown by dotted line in Figure 1, as the chips leave the second container.
• the white liquor is obtained from a high temperature white liquor tank 27, being delivered therefrom by a pump 27a.
• the white liquor is preheated before delivery to the second container 21 in a heat exchanger 28, with the white liquor being supplied to the heat exchanger from a supply source not shown and a supply line 29.
• the heat exchanger is heated by hot black liquor supplied through a line 30 leading from the high temperature black liquor tank 22, and, after passing through the heat exchanger, the black liquor flows through a line 31 to the low temperature black liquor tank 13.
• Cooking liquor is recirculated at the top of the digester through a circuit 34 having a recirculation pump 34a and extraction screen 34b therein. Temperature adjustment of the cooking liquor may be achieved with a trim heat exchanger 34c heated by steam from a steam source 34d.
• a portion of the cooking liquor is removed from the digester through a line 38 by a pump 38a, and is delivered through a line 39 to the location where the chips exit the second container. This recirculated cooking liquor further dilutes the chips and liquor exiting the second container to facilitate transport of the chips to the digester.
• the chips move continuously downward, and are cooked to the desired level of delignification.
• Recirculation takes place through an extraction line 35, an extraction screen 35a, a recirculation line 36, and a pump 36a.
• a portion of the recirculated liquor is directed to the hot liquor tank 22, controlled by a valve 36b.
• washer filtrate from a line 50 is recirculated through a circuit 52 by a pump 54, to eliminate temperature and spent liquor concentration gradients.
• the filtrate is added between an extraction screen 56 and the pump 54, so that the extracted liquor volume is less than the flow into the digester through circuit 52, causing an upward flow of filtrate in the bottom of the digester.
• a second recirculation circuit 60 including a pump 62, is provided to extract a portion of the upward flowing filtrate at an extraction screen 64, together with remaining hot spent black liquor.
• a portion of the extracted filtrate and liquor is directed to the low temperature tank 13, through line 66 controlled by a valve 68.
• a blow line 80 is provided for removing pulp from the digester to a washer.
• the manner in which the pulp is moved from the digester, including any secondary dilution, is well-known in the art of continuous digesters and will not be described further herein.
• preconditioned pulp is delivered via a screw conveyor 11 into a first chip preheating container 10 where it is heated by low temperature black liquor obtained from a low temperature black liquor tank 13.
• the preheated chips pass downwardly through a rotary delivery valve 20 to a second chamber 21, where the chips are further preheated by high temperature black liquor received from a high temperature black liquor tank 22.
• the high temperature and low temperature black liquors are obtained from the pulp washer with the high temperature liquor also being utilized for heating the white liquor through the heat exchanger 28.
• White liquor delivered through the screen 21c from a white liquor supply line 25, is added to the chips before the chips enter digester 33.
• the region of the countercurrent flow between screen 64 and screen 35a should be sufficiently long that the filtrate is heated by the chips substantially to cooking temperature, and the liquor and filtrate removed through line 35a are at or near cooking temperature.
• Figure 2 illustrates, in schematic format, a process in which the second chamber 21 is continguous with the digester. Corresponding parts of the process depicted in Figure 2 have been numbered similarly to Figure 1.
• the various extraction screens, recirculation circuits, pumps, and the like for both the high pressure preimpregnation process and the final digestion process are contained in the combined preimpregnation and digester vessel.

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• Paper (AREA)
• Chemical And Physical Treatments For Wood And The Like (AREA)

Priority Applications (5)

Applications Claiming Priority (2)

Publications (2)

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Country Status (10)

Cited By (12)

Families Citing this family (10)

Citations (4)

• 1990
  • 1990-09-25 ES ES90914988T patent/ES2045948T3/es not_active Expired - Lifetime
  • 1990-09-25 DE DE90914988T patent/DE69004438T2/de not_active Expired - Fee Related
  • 1990-09-25 KR KR1019920700696A patent/KR0171423B1/ko not_active IP Right Cessation
  • 1990-09-25 WO PCT/US1990/005443 patent/WO1991005103A2/en active IP Right Grant
  • 1990-09-25 JP JP2514062A patent/JPH0674557B2/ja not_active Expired - Lifetime
  • 1990-09-25 CA CA002066181A patent/CA2066181C/en not_active Expired - Fee Related
  • 1990-09-25 EP EP90914988A patent/EP0502852B1/en not_active Expired - Lifetime
  • 1990-09-28 CN CN90108125A patent/CN1021980C/zh not_active Expired - Fee Related
• 1992
  • 1992-02-18 NO NO920630A patent/NO179016C/no unknown
  • 1992-03-27 FI FI921373A patent/FI921373A/fi not_active Application Discontinuation

Patent Citations (4)

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