WO1991004222A1 - Method for obtaining hydrogen-containing gas - Google Patents
Method for obtaining hydrogen-containing gas Download PDFInfo
- Publication number
- WO1991004222A1 WO1991004222A1 PCT/SU1989/000305 SU8900305W WO9104222A1 WO 1991004222 A1 WO1991004222 A1 WO 1991004222A1 SU 8900305 W SU8900305 W SU 8900305W WO 9104222 A1 WO9104222 A1 WO 9104222A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- steam
- mixture
- temperature
- conversion
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 239000007789 gas Substances 0.000 title abstract description 74
- 239000001257 hydrogen Substances 0.000 title abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 claims abstract description 46
- 230000003197 catalytic effect Effects 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract 2
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 238000004891 communication Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims 1
- 230000002040 relaxant effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 25
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 21
- 239000002253 acid Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 208000037516 chromosome inversion disease Diseases 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000009545 invasion Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000021074 carbohydrate intake Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
Definitions
- the method of producing synthesis gas for ammonia from hydrocarbons ( ⁇ , ⁇ , 4376758) is known, including: heating of raw hydrocarbons; Separation of the original steam and carbon mixture into two feeds, one of the feeds
- the present invention compares with that of ⁇ , ⁇ , 3441393 is a saving of 30% of the cost of carbohydrate consumption.
- 35 ⁇ dna ⁇ for u ⁇ azann ⁇ g ⁇ s ⁇ s ⁇ ba ⁇ a ⁇ a ⁇ e ⁇ n ⁇ nee ⁇ e ⁇ - ⁇ ivn ⁇ e is ⁇ lz ⁇ vanie ⁇ a ⁇ aliza ⁇ a in ⁇ tsesse ⁇ a ⁇ v ⁇ y ⁇ n- ve ⁇ sii ⁇ b ⁇ i ⁇ ⁇ v ⁇ a ⁇ uglev ⁇ d ⁇ dn ⁇ y mixture znachi ⁇ el- - 3-rd consumption of carbohydrate for consumption, a large content of in- tegrated metal in the industrial mixture due to the consumption of waste water.
- ba is an increase in the efficiency of the use of the catalytic converter, which reduces the volume of the system (reduction of the volume). This, however, is only available at the stage of the initial adiabatic coupled with an inoperative temperature.
- the indicated method is used to describe - - the second one is the conversion of hydrocarbon raw materials in the range of pressures from 25 to 50 bar and the temperature at the beginning of the process at 450 ° to 700 ° C when the pressure is turned on:
- the 5th part of the Republican Conversion is from 680 ° C to 790 ° C). There is a commercially available supply of 700 ° C to 900 ° C;
- the main object of the present invention has been set to by changing the conditions of the sale of an open communication service.
- the 35th gas supplied to the primary part is mixed before heating with the heater in the volumetric part of the medium: acid, equal to 0.5: 30.0.
- - 5 - ⁇ lag ⁇ da ⁇ ya zayavlyaem ⁇ mu iz ⁇ b ⁇ e ⁇ eniyu s ⁇ al ⁇ v ⁇ zm ⁇ zhn ⁇ decrease zi ⁇ ⁇ as ⁇ d ⁇ isl ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas and, sled ⁇ va ⁇ eln ⁇ and ⁇ as ⁇ d ele ⁇ ene ⁇ gii on eg ⁇ ⁇ yuluchenie and ⁇ a ⁇ zhe umenshi ⁇ ⁇ as ⁇ d uglev ⁇ d ⁇ d ⁇ v, ⁇ eagi ⁇ uyuschi ⁇ ⁇ isl ⁇ ds ⁇ de ⁇ zhaschim with gas-5 z ⁇ m on s ⁇ adii v ⁇ ichn ⁇ y ⁇ a ⁇ - ⁇ isl ⁇ dn ⁇ y ⁇ nve ⁇ sii.
- the total reduction in energy consumption in comparison with the obsolete method is 0.6 ⁇ _ ⁇ _ ⁇ .
- ⁇ s ⁇ ve ⁇ s ⁇ vii the claimed iz ⁇ b ⁇ e ⁇ eniem
- tseles ⁇ b ⁇ azn ⁇ is ⁇ lz ⁇ va ⁇ in ⁇ aches ⁇ ve ⁇ e ⁇ l ⁇ n ⁇ si ⁇ elya v ⁇ dyan ⁇ y ⁇ a ⁇ and / or U di ⁇ sid ugle ⁇ da
- the inventive ⁇ is intended for use in both commercial and commercial carcasses, such as - 6 - for example, methane, ethane, ⁇ an and ⁇ ⁇ me ⁇ i; vy ⁇ shie uglev ⁇ d ⁇ - ⁇ dy on ⁇ ⁇ dyaschie ⁇ ya ⁇ i n ⁇ malny ⁇ u ⁇ l ⁇ viya ⁇ in gaz ⁇ b ⁇ azn ⁇ m or zhid ⁇ m ⁇ yanii.
- the 10th paired gas mixture has a temperature of -39 ° C.
- ⁇ ⁇ ve ⁇ e ⁇ vii ⁇ claimed iz ⁇ b ⁇ e ⁇ eniem, ⁇ luchen- hydrochloric ⁇ a ⁇ -gaz ⁇ vuyu ⁇ me ⁇ nag ⁇ evayu ⁇ d ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y 480-570 ° C and ⁇ ed ⁇ ch ⁇ i ⁇ eln ⁇ d ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y 540-570 ° C and ⁇ dve ⁇ gayu ⁇ ⁇ edva ⁇ i ⁇ eln ⁇ y ⁇ a ⁇ v ⁇ y ⁇ a ⁇ ali ⁇ iche ⁇ y ⁇ nve ⁇ ii ⁇ i i ⁇ -
- a partial gas with a temperature of 440-5 ⁇ 0 ° C is used to increase the pressure of the gas inlet
- the paired investment in this case is carried out in accordance with the endothermic reaction of the Republic of Korea and the use of the traditional, for example, is not nickel.
- the process gas has a temperature of 650-850 ° C, which is a direct coupled to a catalytic converter, which is mainly driven by gas emissions.
- the indirect gas supplied to the secondary circuit has a temperature not exceeding 900 ° C.
- the acid-supporting gas is heated by mixing the heater with a voltage of 0.5 mm before the specified temperature is mixed.
- the lower part (0.5) of the indicated volumetric load is determined by the condition of safe operation of the process, if it is inadvertent
- an oxygen-containing gas is inadequate and consumes gas, for example, water vapor, carbon dioxide, nitrogen, and argon. According to the claimed invention, it is preferable in terms of the quality of the boiler and the use of water vapor and / or carbon dioxide.
- the ZS is 20 ° 30 ° C longer than LYSY than after the last conversion.
- the pressure is relieved on the burner, and the temperature is better than ⁇ - ⁇ ⁇ ⁇ C, more than 500 ° C.
- the target process is under pressure on the stage of the furnace: the conversions, it is cooled down, the temperature is 620 ° C, which eliminates the need for energy - 0 -
- a special solution of the target preparation by introducing ⁇ at least a fraction of the acid-containing gas is 960 ° ⁇ , and after the introduction of 970 ° ⁇ .
- the collection of the residual methane in the target production makes up 0.5% of the volume.
- a heated mixture of 500 ° C is also sold here with a steam mixture with a ratio of 2 _ _ 0 5
- the original carbon mixture is at a temperature of 4 ° C and is heated at 540 ° 0 and is priced at a state of aciabatic
- the target product is directly affected by the condition of the original convention, Hz and cooler
- the intentional use of the invention does not include the use of ammonia, methane, EXTREME, and also the invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Cosmetics (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK095391A DK95391A (da) | 1989-09-20 | 1991-05-21 | Fremgangsmaade til fremstilling af hydrogenholdig gas |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU894736269A RU1770265C (ru) | 1989-09-20 | 1989-09-20 | Способ получени водородсодержащего газа |
| SU4736269/23 | 1989-09-20 | ||
| SU894745475A RU1770266C (ru) | 1989-10-13 | 1989-10-13 | Способ получени водородсодержащего газа |
| SU4745475/23 | 1989-10-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1991004222A1 true WO1991004222A1 (en) | 1991-04-04 |
Family
ID=26666215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/SU1989/000305 WO1991004222A1 (en) | 1989-09-20 | 1989-12-08 | Method for obtaining hydrogen-containing gas |
Country Status (10)
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1069070B1 (en) * | 1999-07-15 | 2011-11-30 | Haldor Topsoe A/S | Process for the catalytic steam reforming of a hydrocarbon feedstock |
| CN110055109B (zh) * | 2018-04-08 | 2024-05-03 | 新能能源有限公司 | 流化床气化炉气化剂输送控制方法及系统 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0124226A2 (en) * | 1983-03-25 | 1984-11-07 | Imperial Chemical Industries Plc | Steam reforming |
| EP0168892A2 (en) * | 1984-07-18 | 1986-01-22 | Shell Internationale Researchmaatschappij B.V. | Production of gas mixtures containing hydrogen and carbon monoxide |
| WO1987006221A1 (en) * | 1986-04-15 | 1987-10-22 | The British Petroleum Company P.L.C. | Process and apparatus for the production of synthesis gas |
| EP0298525A1 (en) * | 1983-03-25 | 1989-01-11 | Imperial Chemical Industries Plc | Steam reforming |
| EP0303438A2 (en) * | 1987-08-14 | 1989-02-15 | DAVY McKEE CORPORATION | Production of synthesis gas from hydrocarbonaceous feedstock |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2940840A (en) * | 1956-12-31 | 1960-06-14 | Hercules Powder Co Ltd | Hydrocarbon conversion process |
| US3031286A (en) * | 1958-09-03 | 1962-04-24 | Basf Ag | Flameless reaction of sulfur-containing gaseous hydrocarbons to form carbon monoxide and hydrogen |
| ES279922A1 (es) * | 1961-09-14 | 1963-01-16 | The M W Kellog Company | Un procedimiento para la producción de una mezcla gaseosa rica en hidrógeno |
-
1989
- 1989-12-08 DE DE19893991744 patent/DE3991744T/de not_active Withdrawn
- 1989-12-08 WO PCT/SU1989/000305 patent/WO1991004222A1/ru active Application Filing
-
1990
- 1990-09-06 PT PT95234A patent/PT95234A/pt not_active Application Discontinuation
- 1990-09-11 FR FR9011222A patent/FR2652073A1/fr active Pending
- 1990-09-13 ES ES9002370A patent/ES2022042A6/es not_active Expired - Fee Related
- 1990-09-13 IT IT04827190A patent/IT1242707B/it active IP Right Grant
- 1990-09-19 CA CA002025740A patent/CA2025740A1/en not_active Abandoned
- 1990-09-20 CN CN90107959.6A patent/CN1050363A/zh active Pending
-
1991
- 1991-05-20 GB GB9110895A patent/GB2244494A/en not_active Withdrawn
- 1991-05-21 DK DK095391A patent/DK95391A/da unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0124226A2 (en) * | 1983-03-25 | 1984-11-07 | Imperial Chemical Industries Plc | Steam reforming |
| EP0298525A1 (en) * | 1983-03-25 | 1989-01-11 | Imperial Chemical Industries Plc | Steam reforming |
| EP0168892A2 (en) * | 1984-07-18 | 1986-01-22 | Shell Internationale Researchmaatschappij B.V. | Production of gas mixtures containing hydrogen and carbon monoxide |
| WO1987006221A1 (en) * | 1986-04-15 | 1987-10-22 | The British Petroleum Company P.L.C. | Process and apparatus for the production of synthesis gas |
| EP0303438A2 (en) * | 1987-08-14 | 1989-02-15 | DAVY McKEE CORPORATION | Production of synthesis gas from hydrocarbonaceous feedstock |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2652073A1 (fr) | 1991-03-22 |
| DK95391D0 (da) | 1991-05-21 |
| ES2022042A6 (es) | 1991-11-16 |
| PT95234A (pt) | 1991-05-22 |
| CA2025740A1 (en) | 1991-03-21 |
| IT1242707B (it) | 1994-05-17 |
| IT9048271A0 (it) | 1990-09-13 |
| GB2244494A (en) | 1991-12-04 |
| DK95391A (da) | 1991-07-02 |
| CN1050363A (zh) | 1991-04-03 |
| DE3991744T (enrdf_load_stackoverflow) | 1991-10-10 |
| IT9048271A1 (it) | 1992-03-13 |
| GB9110895D0 (en) | 1991-07-24 |
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