WO1990009346A1 - Production d'un element moule carbone presentant un excellent module de compression - Google Patents

Production d'un element moule carbone presentant un excellent module de compression Download PDF

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Publication number
WO1990009346A1
WO1990009346A1 PCT/JP1990/000143 JP9000143W WO9009346A1 WO 1990009346 A1 WO1990009346 A1 WO 1990009346A1 JP 9000143 W JP9000143 W JP 9000143W WO 9009346 A1 WO9009346 A1 WO 9009346A1
Authority
WO
WIPO (PCT)
Prior art keywords
binder
carbonaceous
elastic
elastic graphite
resin
Prior art date
Application number
PCT/JP1990/000143
Other languages
English (en)
Japanese (ja)
Inventor
Masaki Fujii
Masanori Minohata
Original Assignee
Koa Oil Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP1027874A external-priority patent/JPH02208213A/ja
Priority claimed from JP1027875A external-priority patent/JPH02208214A/ja
Application filed by Koa Oil Company, Limited filed Critical Koa Oil Company, Limited
Priority to DE69018923T priority Critical patent/DE69018923T2/de
Priority to EP90902688A priority patent/EP0424537B1/fr
Publication of WO1990009346A1 publication Critical patent/WO1990009346A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/522Graphite
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/20Graphite
    • C01B32/205Preparation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/536Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite based on expanded graphite or complexed graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values

Definitions

  • These carbonaceous compacts have the properties of carbon, that is, various properties such as light weight, high strength, high elastic modulus, conductivity, corrosion resistance, heat resistance, and sliding properties.
  • properties of carbon that is, various properties such as light weight, high strength, high elastic modulus, conductivity, corrosion resistance, heat resistance, and sliding properties.
  • high modulus conventional materials are relatively advantageous when rigidity is required, while on the other hand, There is also a drawback of lacking, and from the standpoint of safety, higher strength is currently required.
  • the above-mentioned elastic graphite particles are used as an aggregate, and the above-mentioned binder is mixed with the aggregate.
  • the amount of the resin is blended so as to be 0.1 to 5 parts by weight, particularly preferably 5 to 5 parts by weight with respect to 1 part by weight of the elastic graphite particles. If the amount of the resin exceeds 5 parts by weight with respect to 1 part by weight of the body particles, it is not preferable because the bulk density of the obtained molded article tends to increase.
  • the compact obtained in this way has properties that are lightweight and excellent in elasticity, which are not present in conventional carbonaceous compacts.
  • the heat resistance, the heat resistance, and the like may be inferior to those of the carbon material because they are affected by the properties of the binder resin.
  • the conductivity, slidability, etc. are sufficiently maintained because a mixture of the elastic graphite particles and the binder resin can be obtained uniformly. Can be held.
  • the yield of aqua meth- es was 133.5% by weight based on the raw coke.
  • the aqua mesoface was placed in a 500 ml cylindrical glass container, and then placed in a salt bath previously heated to 30 ° C. and held for 30 minutes. Then, 40 hours in a stream of argon. The mixture was heated to 280 ° C. at a rate of temperature increase of C / hr, held for 30 minutes, and graphitized.
  • the yields based on the raw coke were 85 and 52% by weight, respectively.
  • the compression elasticity (compression rate, recovery rate) of the graphitized sample was measured as follows.
  • the yield of aqua mesophase was 133% by weight based on the raw coke.
  • Transfer this Aqua Method into a 500 ml cylindrical glass container.
  • the mixture was put into a salt bath heated to 300 ° C. in advance, and kept for 3 minutes. Then, in an argon stream, 400.
  • the mixture was heated to 2800 ° C. at a heating rate of Cr and held for 30 minutes to be graphitized.
  • the yields based on the raw coke were 85 and 52% by weight, respectively.
  • Compression rate (%) ((h 0 -h ⁇ ) / h 0 ) x 1 0 0

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Ceramic Products (AREA)

Abstract

Procédé de production d'un élément moulé carboné, consistant à mouler un mélange de particules de graphite élastiques avec un liant, afin d'obtenir un élément moulé carboné élastique léger présentant une densité apparente inférieure ou égale à 1,0 g/cm3 et une récupération d'au moins 50 % avec une compressibilité comprise entre 5 et 50 %.
PCT/JP1990/000143 1989-02-07 1990-02-06 Production d'un element moule carbone presentant un excellent module de compression WO1990009346A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE69018923T DE69018923T2 (de) 1989-02-07 1990-02-06 VERFAHREN ZUR HERSTELLUNG EINES KOHLENSTOFFORMKöRPERS MIT EXZELLENTER KOMPRESSIONS ELASTIZITÄT.
EP90902688A EP0424537B1 (fr) 1989-02-07 1990-02-06 Procede de production d'un element moule carbone presentant un excellente elasticite de compression

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP1027874A JPH02208213A (ja) 1989-02-07 1989-02-07 圧縮弾性にすぐれた炭素質成形体の製造方法
JP1/27875 1989-02-07
JP1027875A JPH02208214A (ja) 1989-02-07 1989-02-07 圧縮弾性にすぐれた炭素成形体およびその製造方法
JP1/27874 1989-02-07

Publications (1)

Publication Number Publication Date
WO1990009346A1 true WO1990009346A1 (fr) 1990-08-23

Family

ID=26365868

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1990/000143 WO1990009346A1 (fr) 1989-02-07 1990-02-06 Production d'un element moule carbone presentant un excellent module de compression

Country Status (6)

Country Link
US (1) US5190696A (fr)
EP (1) EP0424537B1 (fr)
AT (1) ATE121711T1 (fr)
CA (1) CA2026774A1 (fr)
DE (1) DE69018923T2 (fr)
WO (1) WO1990009346A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5451554A (en) * 1993-08-12 1995-09-19 Corning, Inc. Activated carbon bodies having epoxy resin and bentonite binders
US5776372A (en) * 1995-05-29 1998-07-07 Nisshinbo Industries, Inc. Carbon composite material
US5891822A (en) * 1996-09-17 1999-04-06 Honda Giken Kogyo Kabushiki Kaisha Production process of active carbon used for electrode for organic solvent type electric double layer capacitor
JP3716275B1 (ja) * 2005-01-14 2005-11-16 株式会社山本プラスチック工業所 成形用合成樹脂組成物およびその成形方法、成形体
JP2007326999A (ja) * 2006-06-09 2007-12-20 Akebono Brake Ind Co Ltd 摩擦材
US10155914B2 (en) * 2011-02-08 2018-12-18 Eugene Kverel Solid lubricant
JP5753518B2 (ja) * 2012-07-04 2015-07-22 日清紡ブレーキ株式会社 摩擦材
JP6290598B2 (ja) * 2013-11-12 2018-03-07 曙ブレーキ工業株式会社 摩擦材組成物および摩擦材
US9458703B2 (en) 2013-12-26 2016-10-04 Superior Graphite Co. Compressible carbonaceous particulate material and method of making same
US10689301B2 (en) 2018-05-03 2020-06-23 Doosan Fuel Cell America, Inc. Method of making a porous fuel cell component
CN110526727B (zh) * 2019-08-29 2022-01-04 航天材料及工艺研究所 一种陶瓷基复合材料结构及其制备方法
US20240173889A1 (en) * 2022-11-29 2024-05-30 Corning Incorporated Methods of fabrication of graphite powder molds

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS649808A (en) * 1987-07-01 1989-01-13 Koa Oil Co Ltd Production of elastic graphite material
JPH01145370A (ja) * 1987-11-30 1989-06-07 Hitachi Chem Co Ltd 炭素材の製造法

Family Cites Families (14)

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US3492197A (en) * 1965-03-22 1970-01-27 Dow Chemical Co Novel compressed cohered graphite structures and method of preparing same
US3969124A (en) * 1974-02-11 1976-07-13 Exxon Research And Engineering Company Carbon articles
US4199628A (en) * 1978-03-23 1980-04-22 The Dow Chemical Company Vermicular expanded graphite composite material
US4534951A (en) * 1981-11-17 1985-08-13 Union Carbide Corporation Manufacture of high quality graphite electrodes using calcined anthracite coal as raw material
US4582632A (en) * 1983-04-11 1986-04-15 Kabushiki Kaisha Kobe Seiko Sho Non-permeable carbonaceous formed bodies and method for producing same
US4816289A (en) * 1984-04-25 1989-03-28 Asahi Kasei Kogyo Kabushiki Kaisha Process for production of a carbon filament
US4897170A (en) * 1986-04-07 1990-01-30 Borden, Inc. Manufacture of a Soderberg electrode incorporating a high carbon-contributing phenolic sacrificial binder
JPH0621018B2 (ja) * 1986-11-29 1994-03-23 工業技術院長 微細黒鉛粉の製造方法
JPS63139080A (ja) * 1986-11-29 1988-06-10 工業技術院長 黒鉛体およびその製造方法
US4824739A (en) * 1986-12-29 1989-04-25 International Fuel Cells Method of operating an electrochemical cell stack
US4923637A (en) * 1987-06-24 1990-05-08 Yazaki Corporation High conductivity carbon fiber
US5057297A (en) * 1987-07-01 1991-10-15 Koa Oil Company, Limited Method for producing elastic graphite structures
JPH0662285B2 (ja) * 1988-09-22 1994-08-17 工業技術院長 弾性黒鉛体の製造方法
EP0462274A4 (en) * 1990-01-11 1993-01-27 Koa Oil Company, Limited Production of elastic graphite molding

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS649808A (en) * 1987-07-01 1989-01-13 Koa Oil Co Ltd Production of elastic graphite material
JPH01145370A (ja) * 1987-11-30 1989-06-07 Hitachi Chem Co Ltd 炭素材の製造法

Also Published As

Publication number Publication date
US5190696A (en) 1993-03-02
EP0424537B1 (fr) 1995-04-26
CA2026774A1 (fr) 1990-08-08
DE69018923D1 (de) 1995-06-01
DE69018923T2 (de) 1995-08-24
ATE121711T1 (de) 1995-05-15
EP0424537A4 (en) 1993-01-27
EP0424537A1 (fr) 1991-05-02

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