WO1987006494A1 - Procede et dispositif pour traiter les gaz de cheminee en les irradiant par des faisceaux d'electrons - Google Patents

Procede et dispositif pour traiter les gaz de cheminee en les irradiant par des faisceaux d'electrons Download PDF

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Publication number
WO1987006494A1
WO1987006494A1 PCT/JP1987/000259 JP8700259W WO8706494A1 WO 1987006494 A1 WO1987006494 A1 WO 1987006494A1 JP 8700259 W JP8700259 W JP 8700259W WO 8706494 A1 WO8706494 A1 WO 8706494A1
Authority
WO
WIPO (PCT)
Prior art keywords
exhaust gas
electron beam
gas
air
active species
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP1987/000259
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English (en)
French (fr)
Japanese (ja)
Inventor
Kanichi Ito
Akihiko Maezawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ebara Corp
Original Assignee
Ebara Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Corp filed Critical Ebara Corp
Priority to DE8787902748T priority Critical patent/DE3786169T2/de
Publication of WO1987006494A1 publication Critical patent/WO1987006494A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • B01J19/085Electron beams only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/812Electrons
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S422/00Chemical apparatus and process disinfecting, deodorizing, preserving, or sterilizing
    • Y10S422/904Nitrogen fixation means

Definitions

  • This ⁇ is Ri by the and this is irradiated with an electron beam flue gas containing harmful gas components such as S 0 2 and New Omicron chi, Mist ( ⁇ , nitric acid) and Dust (ammonium sulfate, An exhaust gas treatment method and apparatus for trapping the mist or dust with a dust collector or the like after changing to the form of (ammonium nitrate).
  • harmful gas components such as S 0 2 and New Omicron chi, Mist ( ⁇ , nitric acid) and Dust (ammonium sulfate,
  • FIG. 1 is a view showing a schematic structure of an electron beam irradiation portion of an exhaust gas treatment apparatus for performing the gas treatment method.
  • an irradiation window 2 is provided in the exhaust gas duct 1, and the electron beam 4 emitted from the electron beam accelerator 3 is irradiated through the irradiation window 2 directly to the exhaust gas passing through the exhaust gas duct 1. ing.
  • the amount of exhaust gas is increased to a practical scale, and when the size of the exhaust gas duct 1 is increased, ⁇ gas does not leak.
  • a large number of collector accelerators 3 (two in the example in the figure) are installed around the exhaust gas duct 1, and as shown by the dotted line 5, It was necessary to increase the maximum range of the wire 4.
  • arranging a large number of electron beam accelerators 3 has the disadvantage that the structure of the exhaust gas treatment device is complicated and the cost is high. Also, electron beam
  • a low voltage accelerator is used to irradiate a part of the exhaust gas extracted from the external air and the main exhaust gas stream with a neutron beam.
  • La radical or OH La active species such as radical in ⁇ gas activated form raw, the activated air Ya ⁇ gas uniformly fed into the main exhaust gas, S 0 2 and N 0 in the exhaust gas Exhaust gas treatment by electron beam irradiation to effectively remove harmful gas components such as ⁇ It is intended to provide a method and apparatus.
  • the method for treating exhaust gas according to the present invention is characterized in that a part of the gas extracted from the external air or the exhaust gas to be treated is irradiated with an electron beam and the air or the By generating active species such as 0 radicals and 0 H radicals in the air and mixing the air or exhaust gas in which the active species is generated with the exhaust gas to be treated, the harmfulness of the exhaust gas to be treated is reduced.
  • An exhaust gas treatment method characterized by changing a component into a form of dust or mist by the action of the active species, and capturing the dust or mist.
  • the exhaust gas treatment apparatus of the present invention includes an electron beam irradiation chamber for irradiating an electron beam from a collector accelerator, and guiding the external air or a part of the exhaust gas to be treated to the electron beam irradiation chamber to irradiate the electron beam.
  • a line feeder that supplies air or exhaust gas from which the active species are generated to generate an active species such as 0 radicals or OH radicals and supplies it to the main exhaust gas where the exhaust gas to be treated flows, and an exhaust gas from the supply device
  • a dispersing device for evenly dispersing the air or gas supplied in the main duct in the main duct, and a dispersing device in the main duct which is changed into exhaust or mist exhaustion by the action of the active species.
  • a dust collecting device for trapping harmful gas components and gases.
  • FIG. 1 is a diagram showing the general structure of the electron beam irradiation part of a conventional exhaust gas treatment device.
  • FIG. 3 is a diagram showing a schematic structure of an exhaust gas treatment apparatus for carrying out the present invention, FIG. 3 is a sectional view taken along the line X--X in FIG. 2, and FIG.
  • FIG. 5 is a diagram showing a schematic structure of the processing apparatus, and FIG. 5 is a cross-sectional view taken along the line YY in FIG.
  • FIG. 2 is a view showing a cutting structure of an exhaust gas treatment apparatus for carrying out the exhaust gas treatment method of the present invention
  • FIG. 3 is a sectional view taken on line XX of FIG.
  • an electron beam irradiation chamber 8 for irradiating the collector beam 7 from the electron beam accelerator 6 is arranged.
  • the distance from the electron beam irradiation port of the electron beam accelerator 6 to the wall surface of the electron beam irradiation chamber 8 is slightly larger than the maximum range of the Xiaozi line 7. Further, one part of the Xiaozi line irradiation chamber 8 is opened to the atmosphere, and the other part is connected to a dispersion device 13 set in the main duct 12 through a suction pressure blower 9 and a pipe 10. Communicating.
  • the dispersing device 13 is composed of a plurality of radial tubes 14 arranged radially from the center of the main duct 12 and a concentric tube 15 arranged concentrically.
  • the pipe 14 and the concentric pipe 15 communicate with each other and with the pipe 10.
  • a number of small holes 16 are formed in each of the radial pipes 14 and the concentric pipes 15 so as to face the downstream of the flow of the exhaust gas 17.
  • the suction and pressure blower 9 and the conduit 10 constitute a supply device for supplying air from the electron beam irradiation chamber 8 to the dispersion device 13.
  • the air 18 sucked into the electron beam irradiation chamber 8 from the atmosphere side is irradiated with the electron beam 7 from the electron beam accelerator 6, Oxygen and water in the air become active species such as 0 radical and OH radical.
  • the air in which the active species has been generated is sent to the dispersing device 13 through the pipe 10 by the suction pressure sending blower 9 to the dispersing device 13, and the dispersing device 13 uniformly disperses and mixes the exhaust gas 17 in the main duct 12.
  • these active species such as 0 radicals and 0 H radicals act on harmful gas components such as SO and NOz in the gas 17 to form mist (sulfuric acid, nitric acid, etc.).
  • FIG. 4 is a diagram showing a schematic structure of another gas treatment apparatus for carrying out the exhaust gas treatment method of the present invention
  • FIG. 5 is a cross-sectional view taken along the line YY of FIG.
  • An electron beam irradiation chamber 21 is provided near the gas main duct 23, and one of the electron beam irradiation chambers 21 communicates with the exhaust gas main duct 23 through a pipe 22. The other is in communication with a dispersion device 27 via a suction pressure blower 24, a pipe 25 and an annular passage 26.
  • the irradiation room 21 Is equipped with an electron beam accelerator 19, and the distance from the collector beam irradiation port of the electron beam accelerator 19 to the wall surface of the radiator beam irradiation chamber 21 is the maximum range of the electron beam 20. The size is slightly larger than that.
  • the dispersing device 27 is composed of a plurality of fins 28 communicating with the annular passage 26, and blades 29 arranged facing the fins 28 and rotating in the direction of the arrow 30. You. A large number of small holes 31 are formed in the fin 28 in an inverted manner as viewed from the arrow 30, and the vortex of the exhaust gas 32 generated by the rotation of the blade 29 causes the electron beam irradiation chamber 2 1 The exhaust gas irradiated with the electron beam sent from the main exhaust gas is uniformly dispersed and mixed into the main exhaust gas.
  • reference numeral 33 denotes a motor for rotating the blade 29
  • reference numeral 34 denotes a motor for rotating the motor 33.
  • 3 is a supporting member that is supported inside.
  • the drive unit such as the motor for rotating the blade 29 is an exhaust gas. It is a matter of course that the drive unit may be provided outside the main duct 23 and the torque of the drive unit may be transmitted by a suitable torque transmission means such as a gear wheel, a chain or a pelt.
  • the exhaust gas treatment device By configuring the exhaust gas treatment device as described above, a part of the exhaust gas sucked from the exhaust gas main duct 23 by the pipe 22 is supplied to the electron beam 2 from the electron beam accelerator 19.
  • oxygen and moisture in the gas are mixed with active species such as 0 radical and OH radical.
  • the exhaust gas having the active species formed therein is dispersed and mixed with the gas 32 of the exhaust gas main duct 23 through the dispersing device 27, and the active species is mixed with the harmful gas component of the gas 32. Acting as a mist or dust, it can be captured by the dust collector S or the like.
  • the structure of the exhaust gas treatment apparatus shown in FIGS. 2 to 5 is an embodiment of the present invention, and the present invention is not limited to this.
  • an electron beam from an electron beam accelerator is used.
  • An electron beam irradiation chamber for irradiating the gas is provided near the main exhaust gas duct, and the outside air or a part of the target gas to be treated is guided to the electron beam irradiation chamber, and is irradiated with an electron beam to obtain 0 radicals or less.
  • active species such as H radicals
  • the air or exhaust gas in which the active species is generated is supplied to the main exhaust gas duct by the supply unit g, and the air supplied in the main exhaust gas duct is supplied.
  • the exhaust gas is dispersed and mixed in the exhaust gas by a dispersing device, and the harmful gas components in the exhaust gas are changed into a form of mist and dust by the action of the active species.
  • a dispersing device such as a dust collector, what is the specific arrangement and structure of each part? It may be the one by a cormorant.
  • a part of air or exhaust gas is taken out and irradiated with electron beams to generate active species in the air or exhaust gas.
  • the activated air or active gas is mixed with the gas to be treated, thereby converting harmful components in the gas into a mist or dust form.
  • Direct electron beam as before It is not necessary to irradiate the entire amount of exhaust gas. Even if the amount of exhaust gas increases to a practical scale and the size of the exhaust gas duct becomes large, many electron beam accelerators can be installed and the acceleration voltage can be increased. There is no need to reduce the pressure, and the cost of the electron beam accelerator and its surrounding equipment can be significantly reduced.
  • the acceleration voltage of the accelerator had to be as high as 800 KV and 100 KV, in the case of the present invention, an electron beam accelerator with an acceleration voltage of about 300 KV was sufficient.
  • the cost of the wire accelerator and the surrounding equipment can be significantly reduced.
  • the exhaust gas processing direction and apparatus according to the electron beam irradiation according to the present invention S 0 2 and N 0 noxious gas component Mist of ⁇ such (sulfuric acid, nitric acid) in the exhaust gas and Dust (ammonium sulfate Mist and dust are trapped and removed by a dust collector, etc., so that thermal power plants that use fossil fuels such as heavy oil or coal as fuel It is used as a method and an apparatus for treating exhaust gas such as boiler combustion gas or sintering exhaust gas from steel mills.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Fertilizers (AREA)
PCT/JP1987/000259 1986-04-24 1987-04-23 Procede et dispositif pour traiter les gaz de cheminee en les irradiant par des faisceaux d'electrons Ceased WO1987006494A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE8787902748T DE3786169T2 (de) 1986-04-24 1987-04-23 Verfahren und einrichtung fuer die behandlung von abgasen durch bestrahlen mit elektronenstrahlen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP61095666A JPS62250933A (ja) 1986-04-24 1986-04-24 電子線照射による排ガス処理方法および装置
JP61/95666 1986-04-24

Publications (1)

Publication Number Publication Date
WO1987006494A1 true WO1987006494A1 (fr) 1987-11-05

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PCT/JP1987/000259 Ceased WO1987006494A1 (fr) 1986-04-24 1987-04-23 Procede et dispositif pour traiter les gaz de cheminee en les irradiant par des faisceaux d'electrons

Country Status (5)

Country Link
US (2) US5015443A (enExample)
EP (1) EP0308505B1 (enExample)
JP (1) JPS62250933A (enExample)
DE (1) DE3786169T2 (enExample)
WO (1) WO1987006494A1 (enExample)

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WO1990004448A1 (en) * 1988-10-28 1990-05-03 Ebara Corporation Method of and apparatus for treating waste gas by irradiation with electron beam
PL425063A1 (pl) * 2018-03-28 2019-10-07 Instytut Chemii i Techniki Jądrowej Urządzenie do jednoczesnego usuwania kwaśnych zanieczyszczeń nieorganicznych i lotnych zanieczyszczeń organicznych ze strumienia gazów odlotowych, zwłaszcza z silnika Diesla oraz sposób usuwania zanieczyszczeń

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Publication number Priority date Publication date Assignee Title
US4915916A (en) * 1986-04-24 1990-04-10 Ebara Corporation Method of and apparatus for treating waste gas by irradiation with electron beam
US5015443A (en) * 1986-04-24 1991-05-14 Ebara Corporation Method of and apparatus for treating waste gas by irradiation with electron beam
WO1990004448A1 (en) * 1988-10-28 1990-05-03 Ebara Corporation Method of and apparatus for treating waste gas by irradiation with electron beam
PL425063A1 (pl) * 2018-03-28 2019-10-07 Instytut Chemii i Techniki Jądrowej Urządzenie do jednoczesnego usuwania kwaśnych zanieczyszczeń nieorganicznych i lotnych zanieczyszczeń organicznych ze strumienia gazów odlotowych, zwłaszcza z silnika Diesla oraz sposób usuwania zanieczyszczeń

Also Published As

Publication number Publication date
DE3786169D1 (de) 1993-07-15
EP0308505A1 (en) 1989-03-29
EP0308505B1 (en) 1993-06-09
JPH0365210B2 (enExample) 1991-10-11
US4915916A (en) 1990-04-10
US5015443A (en) 1991-05-14
JPS62250933A (ja) 1987-10-31
EP0308505A4 (en) 1989-06-26
DE3786169T2 (de) 1993-09-23

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