WO1990004448A1 - Method of and apparatus for treating waste gas by irradiation with electron beam - Google Patents

Method of and apparatus for treating waste gas by irradiation with electron beam Download PDF

Info

Publication number
WO1990004448A1
WO1990004448A1 PCT/JP1988/001101 JP8801101W WO9004448A1 WO 1990004448 A1 WO1990004448 A1 WO 1990004448A1 JP 8801101 W JP8801101 W JP 8801101W WO 9004448 A1 WO9004448 A1 WO 9004448A1
Authority
WO
WIPO (PCT)
Prior art keywords
waste gas
electron beam
active species
electron beams
dust
Prior art date
Application number
PCT/JP1988/001101
Other languages
French (fr)
Inventor
Kanichi Ito
Akihiko Meazawa
Original Assignee
Ebara Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Corporation filed Critical Ebara Corporation
Priority to PCT/JP1988/001101 priority Critical patent/WO1990004448A1/en
Publication of WO1990004448A1 publication Critical patent/WO1990004448A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/812Electrons

Definitions

  • the present invention relates to a method of and apparatus for treating waste gas wherein waste gas con ⁇ taining noxious (gas) ingredients such as S0 2 and NO is irradiated with electron beams to change the noxious (gas) ingredients into the form of mist (sulfuric acid and/or) nitric acid) or dust (ammonium sulfate and/or ammonium nitrate) and the resulting mist or dust is then captured with a dust collector or the like.
  • noxious (gas) ingredients such as S0 2 and NO
  • mist sulfuric acid and/or
  • dust ammonium sulfate and/or ammonium nitrate
  • FIG. 1 schematically shows the structure of an electron beam irradiation portion of a waste gas treatment apparatus for carrying out this waste gas treatment method.
  • a waste gas duct 1 is provided with irradia ⁇ tion windows 2, and waste gas passing through the waste gas duct 1 is directly irradiated with electron beams 4 emitted from electron beam accelerators 3 through the irradiation window 2.
  • Table 1 shows the relationship between the maximum range of the electron beams according to the acceleration voltage therefor, the size of an electron beam irradiation chamber, the flow rate of waste gas and the thickness of a lead wall providing shielding from high- energy X-rays.
  • Table 1 shows an example of the maximum range of electron beams and the size of the electron beam irradiation chamber which are necessary to allow the waste gas to absorb the electron beams, whereby the amount of waste gas capable of being treated and the thickness of the lead wall for shielding against X-rays, i.e. the size of the shielding structure, are determined. These are necessary conditions for the shielding against X-rays.
  • a suitable level of electron beam energy accelerating voltage x amperage
  • the amperage is not an important factor for determining the thickness of the lead wall for shielding against X-rays.
  • the present invention is directed to solution of the above-described problems of the prior art and it is an object of the present invention to provide a method of and apparatus for treating waste gas by irradiation with electron beams, wherein a part of the waste gas taken from the main stream of waste gas is irradiated with electron beams using a low-voltage type accelerator to form active species such as 0 and OH radicals in the irradiated waste gas and to thereby activate it, the activated waste gas then being uniformly fed into the main stream of waste gas and thereby effectively removing noxious gas ingredients such as S0 2 and NO from the waste gas. Disclosure of Invention:
  • the present invention provides a waste gas treatment method which comprises: irradiating a part of the waste gas which is the object of treatment with electron beams to form active species such as 0 and OH radicals in the irradiated waste gas; mixing the waste gas having the active species formed therein with the waste gas which is the object of treatment, thereby changing the noxious (gas) ingredients in the waste gas to be treated into the form of a mist or dust by the action of the active species; and capturing the mist or dust.
  • the present invention also provides a waste gas treatment apparatus which comprises: an electron beam irradiation chamber for irradiation with electron beams j.rom an electron beam accelerator; a feeding device which introduces a part of the waste gas to be treated into the electron beam irradiation chamber where the waste gas is irradiated with electron beams to thereby form active species such as 0 and OH radicals, and which feeds the waste gas having the active species formed therein to a waste gas main duct through which the waste gas to be treated is flowing; a dispersing device for uniformly dispersing in the waste gas main duct the waste gas fed thereinto from the feeding device; and a capturing device for capturing noxious (gas) ingredients in the waste gas within the main duct which have been changed into the form of a mist or dust by the action of the active species.
  • Fig. 1 schematically shows the structure of an electron beam irradiation portion of a conventional waste gas treatment apparatus
  • FIG. 2 schematically shows the structure of a waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention
  • Fig. 3 is a sectional view taken along the line X-X of Fig. 2;
  • FIG. 4 schematically shows the structure of another waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention
  • Fig. 5 is a sectional view taken along the line Y-Y of Fig. 4. Best Mode for Carrying Out the Invention:
  • D size of electron beam irradiation chamber (diameter, m) , which is set so as to be slightly greater than the maximum range of the electron beams which is mainly de ⁇ termined by the acceleration voltage. It further varies with the density and temperature of the waste gas. It is preferable for this to be about 2.0 m or less, corresponding to an accelerating voltage of about 500 KV or less, because it is then possible to markedly lower the installation cost of the electron beam accelerator and peripheral devices; V: flow rate of waste gas in the electron irradiation chamber (m/s) . This is preferably about 30 m/s or less which is generally adopted for waste gas ducts. If it is greater than about 30 m/s, the degree of pressure drop unfavorably increases;
  • Table 2 shows the relationship between accelerating voltage, size of the electron beam irradiation chamber and flow rate of waste gas.
  • FIG. 2 schematically shows the structure of a waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention
  • Fig. 3 is a sectional view taken along the line X-X of Fig. 2.
  • -A electron beam irradiation chamber 8 for irradia ⁇ tion with electron beams 7 from an electron beam accelerator 6 is disposed in the vicinity of a waste gas main duct 12 through which waste gas 17 flows.
  • the distance from the electron beam irradiation opening of the electron beam accelerator 6 to the wall surface of the electron beam irradiation chamber 8 is set so as to be slightly greater than the maximum range of the electron beams 7.
  • One end of the electron beam irradiation chamber 8 is communicated with a waste gas main duct 12, while the other end thereof is communicated with a dispersing device 13 set within the main duct 12 through a suction transfer blower 9 and a pipe line 10.
  • the dispersing device 13 comprises a plurality of radial tubes 14 disposed so as to extend radially from the central portion of the main duct 12 and concentric tubes 15 disposed concentrically, the radial tubes 14 and the concentric tubes 15 communicating with each other and also communicating with the pipe line 10.
  • Each of the radial and concentric tubes 14 and 15 has a multiplicity of small bores 16 so formed as to face downstream of the flow of waste gas 17.
  • the suction transfer blower 9 and the pipe line 10 constitute in combination a feeding device for feeding the air from the electron beam irradiation chamber 8 to the dispersing device 13.
  • the waste gas 18 sucked into the electron beam irradiation chamber 8 from the waste gas main duct is irradiated with the electron beams 7 from the electron beam accelerator 6, so that oxygen and water in the waste gas are formed into active species such as 0 and OH radicals.
  • the waste gas having the active species formed therein is supplied to the dispersing device 13 through the pipe line 10 by means of the suction transfer blower 9, and in the dispersing device 13 the waste gas is uniformly dispersed into and mixed with the waste gas 17 within the main duct 12.
  • the active species such as 0 and OH radicals act on noxious (gas) ingredients such as S0 2 and NO in the waste gas 17 to change such noxious (gas) ingredients into the form of mist (sulfuric acid, nitric acid, etc.).
  • mist sulfuric acid, nitric acid, etc.
  • ammonia gas is injected from a part (not shown) of the pipe line 10 to form dust (ammonium sulfate, ammonium nitrate, etc.).
  • a dust collector such as an electrostatic precipitator, a bag filter, an active carbon separator, etc;, all of which are conven ⁇ tional, it is possible to remove noxious (gas) ingredients such as S0 2 and NO from the waste gas 17.
  • FIG. 4 schematically shows the structure of another waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention
  • Fig. 5 is a sectional view taken along the line Y-Y of Fig. 4.
  • An electron beam irradiation chamber 21 is disposed in the vicinity of a waste gas main duct 23.
  • One end of the electron beam irradiation chamber 21 is communicated with the waste gas main duct 23 through a pipe line 22, while the other end thereof is communicated with a dispersing device 27 through a suction transfer blower 24, as pipe line 25 and an annular passage 26.
  • the electron beam irradiation chamber 21 is provided with an electron beam accelerator 19.
  • the distance from the electron beam irradiation opening of the electron beam accelerator 19 to the wall surface of the electron beam irradiation chamber 21 is set so as to be slightly greater than the maximum range of electron beams 20.
  • the dispersing device 27 comprises a plurality of fins 28 that communicate with the annular passage 26 and blades 29 which are so disposed as to face the fins 28 and which rotate in the direction of the arrow 30.
  • Each fin 28 has a multiplicity of small bores 31 formed in the reverse side thereof as viewed from the direction of the arrow 30, so that the vortex of waste gas 32 caused by the rotation of the blades 29 allows the waste gas irradiated with electron beams and delivered from the electron beam irradiation chamber 21 to be uniformly dispersed into and mixed with the waste gas 32,
  • the reference numeral 33 denotes a motor for rotating the blades 29, while the numeral 34 denotes a support member for supporting the motor 33 within the waste gas main duct 23.
  • the arrangement may, of course, be such that the driving section, for example, a motor, for rotating the blades 29 is provided outside the waste gas main duct 23 and the rotational force from the driving section is transmitted by appropriate rotational force transmission means, for example, gears, chain or belt.
  • the driving section for example, a motor
  • the rotational force from the driving section is transmitted by appropriate rotational force transmission means, for example, gears, chain or belt.
  • the waste gas having the active species formed therein is dispersed into and mixed with the waste gas 32 in the waste gas main duct 23 through the dispersing device 27.
  • the active species act on noxious (gas) ingredients in the waste gas 32 to form mist or dust.
  • a dust collector such as an electrostatic precipitator, a bag filter, an active carbon separator, etc., all of which are conventional.
  • each section of the waste gas treatment apparatus may have any specific disposition and structure, provided that the apparatus is arranged such that an electron beam irradiation chamber for irradiation with electron beams from an electron beam accelerator is provided in the vicinity of a main duct for waste gas: a part of the waste gas to be treated is introduced into the electron beam irradiation chamber where waste gas is irradiated with electron beams to thereby form active species such as 0 and OH radicals; the waste gas having the active species formed therein is fed into the waste gas main duct by means of a feeding device; the waste gas fed into the waste gas main duct is dispersed into and mixed with the waste gas flowing through the main duct by means of a dispersing device, thereby changing noxious (gas) ingredients in the waste gas into the form of a mist or dust by the action of the active species
  • a part of a waste gas is taken and irradiated with electron beams to form active species in the waste gas to thereby activate it, and the activated waste gas is then mixed with the gas which is object of treatment, thereby changing noxious (gas) ingredients in the waste gas into the form of a mist or dust. Therefore, it is unnecessary to directly irradiate all of the waste gas as in the prior art, and even if the amount of waste gas increases to the extent that would be expected if the treatment is applied on a practical scale and the size of the waste gas duct increases correspondingly, it is unnecessary to dispose a multiplicity of electron beam accelerators and raise the acceleration voltage.
  • an electron beam accelerator and peripheral devices it is possible to markedly lower the installation cost of an electron beam accelerator and peripheral devices.
  • the acceleration voltage of the electron beam accelerators it has heretofore been necessary to set the acceleration voltage of the electron beam accelerators at a high level, i.e., 800 kV or 1,000 kV, in order to obtain satisfactory electron beam energy in relation to the waste gas duct size or the like for the purpose of uniformly forming active species in the waste gas, whereas, in the case of the present invention, an electron beam accelerator with an acceleration voltage of about 500 kV or less suffices and it is therefore possible to markedly lower the installation cost of the electron beam accelerator and peripheral devices.
  • a method of and apparatus for treating waste gas by irradiation with electron beams is one wherein the noxious ingredients in the waste gas are changed into the form of a mist or dust by the action of the active species (0 and OH radicals, etc.) and the mist or dust is captured by means of a conventional capturing device.
  • this invention differs from the case of using a wet absorption tower as described which requires treatment of the waste water emanating from the absorbing solution used in the wet absoprtion tower, allowing the costs of installation and maintenance to thus be lowered in this invention.
  • Example 1 the present invention will be described more specifically by way of Example. However, the present invention is in no way restricted by the Example.
  • Waste gas (20,000 Nm 3 /h) containing S0 2 (200 ppm) and NO .A. (180 ppm) was cooled down to 70°C and then a part of the waste gas was introduced into an irradiation chamber where it was irradiated with electron beams to form active species.
  • the waste gas containing these active species was returned to the main waste gas duct, and the mixed waste gas was passed through said main duct and introduced into an electrostatic precipitator where the resulting dust was separated and the treated gas released into the atmosphere.
  • An experimental operation was carried out for about 150 hours.
  • the operating conditions, the part (proportion %) of the waste gas to be treated with electron beams and the rates of desulfurization and denitration are shown in Table 3.
  • the method and apparatus of the invention are suitable for utilization as a method and apparatus for treating waste gas such as boiler combustion waste gas in thermoelectric powder plants that use fossil fuels, for example, heavy oil or coal, as a fuel or sintering waste gas in iron works.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

A method of and apparatus for treating waste gas by irradiation with electron beams wherein an electron beam irradiation chamber for irradiation with electron beams from an electron beam accelerator is provided in the vicinity of a main duct for waste gas; a part of the waste gas to be treated is introduced into the electron beam irradiation chamber where the waste gas is irradiated with electron beams to thereby form active species such as O and OH radiacals; the waste gas having the active species formed therein is fed int the waste gas main duct by means of a feeding device; the waste gas fed into the waste gas main duct is dispersed into and mixed with the waste gas flowing through the main duct by means of a dispersing device, thereby changing noxious (gas) ingredients in the waste gas into the form of a mist or dust by the action of the active species; and the mist or dust is captured by means of a capturing device, for example, a dust collector.

Description

DESCRIPTION
METHOD OF AND APPARATUS FOR TREATING WASTE GAS BY IRRADIATION WITH ELECTRON BEAM Technical Field:
The present invention relates to a method of and apparatus for treating waste gas wherein waste gas con¬ taining noxious (gas) ingredients such as S02 and NO is irradiated with electron beams to change the noxious (gas) ingredients into the form of mist (sulfuric acid and/or) nitric acid) or dust (ammonium sulfate and/or ammonium nitrate) and the resulting mist or dust is then captured with a dust collector or the like. Background Art: One method of waste gas treatment whereby noxious
(gas) ingredients such as S02 and NO are removed from waste gases is a method wherein waste gas is irradiated with electron beams to form various active species such as 0 and OH radicals from oxygen, water, etc. in the waste gas so that the active species act on the noxious (gas) ingredients in the waste gas such as to form mist and this mist is further changed into dust in the presence of ammonia or the like, the mist and dust then being captured with a dust collector or the like. Fig. 1 schematically shows the structure of an electron beam irradiation portion of a waste gas treatment apparatus for carrying out this waste gas treatment method. As illustrated, a waste gas duct 1 is provided with irradia¬ tion windows 2, and waste gas passing through the waste gas duct 1 is directly irradiated with electron beams 4 emitted from electron beam accelerators 3 through the irradiation window 2. In the structure wherein the electron beams 4 are directly applied to the inside of the waste gas duct 1, when the amount of waste gas increased to that which would be treated in a practical application and the size of the waste gas duct 1 increased correspondingly, it has heretofore been necessary, in order to allow all of the waste gas to absorb the electron beams 4, to dispose a multiplicity of electron beam accelerators 3 (two in the illustrated example) at the outer periphery of the waste gas duct 1 and also to increase the maximum range of the electron beams 4, as shown by the chain lines 5. However, disposition of a multiplicity of electron beam accelerators 3 involves disadvantage in that the structure of the waste gas treating apparatus becomes complicated and costs are raised. Further, in order to increase the maximum range of the electron beams 4, it is necessary to raise the acceleration voltage for electron beams, which leads to a substantial rise in the cost of the electron beam accelerators 3. In addition, if electron beams are accelerated at high voltages, high-energy X-rays are generated and a thick lead or concrete wall or the like must be provided in order to provide shielding from such high-energy X-rays, which results in a rise in the overall cost of the waste gas treatment apparatus. Thus, the prior art suffers from various problems.
The following Table 1 shows the relationship between the maximum range of the electron beams according to the acceleration voltage therefor, the size of an electron beam irradiation chamber, the flow rate of waste gas and the thickness of a lead wall providing shielding from high- energy X-rays.
Table 1
Maximum range of electron Size of Flow rate Thickness
Accelerating beam in electron of of voltage waste beam chamber waste gas lead wall CKV) gas (m) (diameter, m) (m3/h) mm
Figure imgf000004_0001
The above-mentioned Table 1 shows an example of the maximum range of electron beams and the size of the electron beam irradiation chamber which are necessary to allow the waste gas to absorb the electron beams, whereby the amount of waste gas capable of being treated and the thickness of the lead wall for shielding against X-rays, i.e. the size of the shielding structure, are determined. These are necessary conditions for the shielding against X-rays. In order to treat noxious gas ingredients such as S02 and NO , a suitable level of electron beam energy (accelerating voltage x amperage) is necessary. However, the amperage is not an important factor for determining the thickness of the lead wall for shielding against X-rays.
It should be noted that there are techniques which aim to have all of the waste gas irradiated with electron beams at a uniform dose, including those disclosed in the specifications of Japanese Patent Public Disclosure Nos. 49-096975 and 55-097232 and United States Patent Nos. 4,507,265 and 4,596,642, but none of them completely solves the above-described problems.
Further, there is a technique disclosed in the specification of Japanese Patent Public Disclosure No. 61-68126 wherein atmospheric air is introduced into an electronT>eam irradiation reactor to allow said air to be irradiated with electron beams to thereby form ozone and oxygen atoms therein. Said air having ozone and oxygen atoms is mixed with a waste gas to oxidize NO in the waste gas to form N02 and then the waste gas is introduced to a wet absorption tower to effect desulfurization and denitration.
In the desulfurization and denitration of that technique, since a wet absorption tower is used the ab¬ sorbing solution used in the wet absorption tower contains a large amount of nitrogen and sulfur compounds which are difficult to treat and costly waste water disposal equipment is therefore needed to treat the absorbing solution. This - leads to the problem of high costs in the installation and maintenance thereof. The present invention is directed to solution of the above-described problems of the prior art and it is an object of the present invention to provide a method of and apparatus for treating waste gas by irradiation with electron beams, wherein a part of the waste gas taken from the main stream of waste gas is irradiated with electron beams using a low-voltage type accelerator to form active species such as 0 and OH radicals in the irradiated waste gas and to thereby activate it, the activated waste gas then being uniformly fed into the main stream of waste gas and thereby effectively removing noxious gas ingredients such as S02 and NO from the waste gas. Disclosure of Invention:
To attain the above-described object, the present invention provides a waste gas treatment method which comprises: irradiating a part of the waste gas which is the object of treatment with electron beams to form active species such as 0 and OH radicals in the irradiated waste gas; mixing the waste gas having the active species formed therein with the waste gas which is the object of treatment, thereby changing the noxious (gas) ingredients in the waste gas to be treated into the form of a mist or dust by the action of the active species; and capturing the mist or dust. The present invention also provides a waste gas treatment apparatus which comprises: an electron beam irradiation chamber for irradiation with electron beams j.rom an electron beam accelerator; a feeding device which introduces a part of the waste gas to be treated into the electron beam irradiation chamber where the waste gas is irradiated with electron beams to thereby form active species such as 0 and OH radicals, and which feeds the waste gas having the active species formed therein to a waste gas main duct through which the waste gas to be treated is flowing; a dispersing device for uniformly dispersing in the waste gas main duct the waste gas fed thereinto from the feeding device; and a capturing device for capturing noxious (gas) ingredients in the waste gas within the main duct which have been changed into the form of a mist or dust by the action of the active species. Brief Description of Drawings:
Fig. 1 schematically shows the structure of an electron beam irradiation portion of a conventional waste gas treatment apparatus;
Fig. 2 schematically shows the structure of a waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention; Fig. 3 is a sectional view taken along the line X-X of Fig. 2;
Fig. 4 schematically shows the structure of another waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention; and Fig. 5 is a sectional view taken along the line Y-Y of Fig. 4. Best Mode for Carrying Out the Invention:
Modes for carrying out the present invention will be described hereinunder with reference to the drawings. The following equation represents the part (propor¬ tion %) of the waste gas to be treated with electron beams to form active species in the irradiated waste gas
= ιτ/4 D2 x V x 3600 v lnn Q x ιυυ wherein D: size of electron beam irradiation chamber (diameter, m) , which is set so as to be slightly greater than the maximum range of the electron beams which is mainly de¬ termined by the acceleration voltage. It further varies with the density and temperature of the waste gas. It is preferable for this to be about 2.0 m or less, corresponding to an accelerating voltage of about 500 KV or less, because it is then possible to markedly lower the installation cost of the electron beam accelerator and peripheral devices; V: flow rate of waste gas in the electron irradiation chamber (m/s) . This is preferably about 30 m/s or less which is generally adopted for waste gas ducts. If it is greater than about 30 m/s, the degree of pressure drop unfavorably increases;
Q: the amount of waste gas to be treated (m3/h) .
The following Table 2 shows the relationship between accelerating voltage, size of the electron beam irradiation chamber and flow rate of waste gas.
Table 2
Figure imgf000008_0001
Fig. 2 schematically shows the structure of a waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention, while Fig. 3 is a sectional view taken along the line X-X of Fig. 2.
-A electron beam irradiation chamber 8 for irradia¬ tion with electron beams 7 from an electron beam accelerator 6 is disposed in the vicinity of a waste gas main duct 12 through which waste gas 17 flows. The distance from the electron beam irradiation opening of the electron beam accelerator 6 to the wall surface of the electron beam irradiation chamber 8 is set so as to be slightly greater than the maximum range of the electron beams 7. One end of the electron beam irradiation chamber 8 is communicated with a waste gas main duct 12, while the other end thereof is communicated with a dispersing device 13 set within the main duct 12 through a suction transfer blower 9 and a pipe line 10. The dispersing device 13 comprises a plurality of radial tubes 14 disposed so as to extend radially from the central portion of the main duct 12 and concentric tubes 15 disposed concentrically, the radial tubes 14 and the concentric tubes 15 communicating with each other and also communicating with the pipe line 10. Each of the radial and concentric tubes 14 and 15 has a multiplicity of small bores 16 so formed as to face downstream of the flow of waste gas 17. It should be noted that the suction transfer blower 9 and the pipe line 10 constitute in combination a feeding device for feeding the air from the electron beam irradiation chamber 8 to the dispersing device 13.
By virtue of the above-described arrangement of the waste gas treatment apparatus, the waste gas 18 sucked into the electron beam irradiation chamber 8 from the waste gas main duct is irradiated with the electron beams 7 from the electron beam accelerator 6, so that oxygen and water in the waste gas are formed into active species such as 0 and OH radicals. The waste gas having the active species formed therein is supplied to the dispersing device 13 through the pipe line 10 by means of the suction transfer blower 9, and in the dispersing device 13 the waste gas is uniformly dispersed into and mixed with the waste gas 17 within the main duct 12. As a result, the active species such as 0 and OH radicals act on noxious (gas) ingredients such as S02 and NO in the waste gas 17 to change such noxious (gas) ingredients into the form of mist (sulfuric acid, nitric acid, etc.). If an appropriate amount of ammonia gas is injected from a part (not shown) of the pipe line 10, the mist and the ammonia gas react with each other to form dust (ammonium sulfate, ammonium nitrate, etc.). By capturing the mist and dust by means of a dust collector (not shown) such as an electrostatic precipitator, a bag filter, an active carbon separator, etc;, all of which are conven¬ tional, it is possible to remove noxious (gas) ingredients such as S02 and NO from the waste gas 17.
Fig. 4 schematically shows the structure of another waste gas treatment apparatus for carrying out the waste gas treatment method according to the present invention, while Fig. 5 is a sectional view taken along the line Y-Y of Fig. 4.
An electron beam irradiation chamber 21 is disposed in the vicinity of a waste gas main duct 23. One end of the electron beam irradiation chamber 21 is communicated with the waste gas main duct 23 through a pipe line 22, while the other end thereof is communicated with a dispersing device 27 through a suction transfer blower 24, as pipe line 25 and an annular passage 26. The electron beam irradiation chamber 21 is provided with an electron beam accelerator 19. The distance from the electron beam irradiation opening of the electron beam accelerator 19 to the wall surface of the electron beam irradiation chamber 21 is set so as to be slightly greater than the maximum range of electron beams 20.
The dispersing device 27 comprises a plurality of fins 28 that communicate with the annular passage 26 and blades 29 which are so disposed as to face the fins 28 and which rotate in the direction of the arrow 30. Each fin 28 has a multiplicity of small bores 31 formed in the reverse side thereof as viewed from the direction of the arrow 30, so that the vortex of waste gas 32 caused by the rotation of the blades 29 allows the waste gas irradiated with electron beams and delivered from the electron beam irradiation chamber 21 to be uniformly dispersed into and mixed with the waste gas 32, It should be noted that, in the figures, the reference numeral 33 denotes a motor for rotating the blades 29, while the numeral 34 denotes a support member for supporting the motor 33 within the waste gas main duct 23.
It should be noted that although in the above- described example the blades 29 are rotated by the motor 33, the arrangement may, of course, be such that the driving section, for example, a motor, for rotating the blades 29 is provided outside the waste gas main duct 23 and the rotational force from the driving section is transmitted by appropriate rotational force transmission means, for example, gears, chain or belt. By virtue of the above-described arrangement of the waste gas treatment apparatus, a part of the waste gas sucked in from the waste gas main duct 23 through the pipe line 22 is irradiated with the electron beams 20 from the electron beam accelerator 19, so that oxygen and water in the waste gas are formed into active species such as 0 and OH radicals in completely the same way as in the above- described example (the example shown in Fig. 2) . The waste gas having the active species formed therein is dispersed into and mixed with the waste gas 32 in the waste gas main duct 23 through the dispersing device 27. As a result, the active species act on noxious (gas) ingredients in the waste gas 32 to form mist or dust. Thus it is possible to capture the mist or dust by means of a dust collector such as an electrostatic precipitator, a bag filter, an active carbon separator, etc., all of which are conventional.
It should be noted that the structures of the waste gas treatment apparatus shown in Figs. 2 to 5 are one embodiment of the present invention and that the present invention is not necessarily limited thereto. In short, each section of the waste gas treatment apparatus may have any specific disposition and structure, provided that the apparatus is arranged such that an electron beam irradiation chamber for irradiation with electron beams from an electron beam accelerator is provided in the vicinity of a main duct for waste gas: a part of the waste gas to be treated is introduced into the electron beam irradiation chamber where waste gas is irradiated with electron beams to thereby form active species such as 0 and OH radicals; the waste gas having the active species formed therein is fed into the waste gas main duct by means of a feeding device; the waste gas fed into the waste gas main duct is dispersed into and mixed with the waste gas flowing through the main duct by means of a dispersing device, thereby changing noxious (gas) ingredients in the waste gas into the form of a mist or dust by the action of the active species; and the mist or dust is captured by means of a capturing device a duct collector such as an electrostatic precipitator, a bag filter, an active carbon separator, etc., all of which are conventional. As has been described above, according to the present invention, a part of a waste gas is taken and irradiated with electron beams to form active species in the waste gas to thereby activate it, and the activated waste gas is then mixed with the gas which is object of treatment, thereby changing noxious (gas) ingredients in the waste gas into the form of a mist or dust. Therefore, it is unnecessary to directly irradiate all of the waste gas as in the prior art, and even if the amount of waste gas increases to the extent that would be expected if the treatment is applied on a practical scale and the size of the waste gas duct increases correspondingly, it is unnecessary to dispose a multiplicity of electron beam accelerators and raise the acceleration voltage. Accordingly, it is possible to markedly lower the installation cost of an electron beam accelerator and peripheral devices. For example, in the conventional arrangement wherein electron beams are directly applied to waste gas, it has heretofore been necessary to set the acceleration voltage of the electron beam accelerators at a high level, i.e., 800 kV or 1,000 kV, in order to obtain satisfactory electron beam energy in relation to the waste gas duct size or the like for the purpose of uniformly forming active species in the waste gas, whereas, in the case of the present invention, an electron beam accelerator with an acceleration voltage of about 500 kV or less suffices and it is therefore possible to markedly lower the installation cost of the electron beam accelerator and peripheral devices.
Further, a method of and apparatus for treating waste gas by irradiation with electron beams according to the subject invention is one wherein the noxious ingredients in the waste gas are changed into the form of a mist or dust by the action of the active species (0 and OH radicals, etc.) and the mist or dust is captured by means of a conventional capturing device. Accordingly, this invention differs from the case of using a wet absorption tower as described which requires treatment of the waste water emanating from the absorbing solution used in the wet absoprtion tower, allowing the costs of installation and maintenance to thus be lowered in this invention.
Furthermore, in the present invention, since a part of the waste gas is taken and irradiated with electron beams, there is no increase in the volume of waste gas even when the waste gas irradiated with electron beams is mixed with the waste gas flowing through the main duct, compared with the case wherein air which is externally taken in is irradiated with electron beams. Thus this invention has no necessity for a large-capacity blower. However, if the increase in the volume of total gas and some decrease in the efficiency of desulfurization and denitration is not a significant problem and can be permitted and if air is favorably taken in and irradiated with electron beams, air instead of a part of waste gas may be taken in.
Hereinunder, the present invention will be described more specifically by way of Example. However, the present invention is in no way restricted by the Example. Example
Waste gas (20,000 Nm3/h) containing S02 (200 ppm) and NO .A. (180 ppm) was cooled down to 70°C and then a part of the waste gas was introduced into an irradiation chamber where it was irradiated with electron beams to form active species. The waste gas containing these active species was returned to the main waste gas duct, and the mixed waste gas was passed through said main duct and introduced into an electrostatic precipitator where the resulting dust was separated and the treated gas released into the atmosphere. An experimental operation was carried out for about 150 hours. The operating conditions, the part (proportion %) of the waste gas to be treated with electron beams and the rates of desulfurization and denitration are shown in Table 3. Table 3
Figure imgf000014_0001
Industrial Applicability:
Thus, in the method of and apparatus for treating waste gas by irradiation with electron beams according to the present invention, noxious (gas) ingredients such as S02 and NO -A. in waste gas are changed into the form of a mist (sulfuric acid and/or nitric acid) or dust (ammonium sulfate and/or ammonium nitrate) and the resulting mist or dust is then captured with a dust collector or the like. Accordingly, the method and apparatus of the invention are suitable for utilization as a method and apparatus for treating waste gas such as boiler combustion waste gas in thermoelectric powder plants that use fossil fuels, for example, heavy oil or coal, as a fuel or sintering waste gas in iron works.

Claims

1. A method of treating waste gas by irradiation with electron beams, comprising: irradiating a part of the waste gas to be treated with electron beams to form active species in the irradiated waste gas, said part (proportion %) of waste gas being defined by the following equation:
= /4 D2 x V x 3600 ιnn Q X XUU
wherein D is the diameter of an electron beam irradiation chamber, that is, about 2.0 m or less corresponding to an accelerating voltage of about 500 KV or less, V is the flow rate of waste gas in the electron beam irradiation chamber of about 30 m/s or less, Q (m3/h) is the amount of waste gas to be treated; mixing the waste gas having said active species formed therein with said waste gas to be treated, thereby changing noxious (gas) ingredients in said waste gas to be treated into the form of mist or dust by the action of said active species; and capturing said mist or dust by means of a dust collector.
2. An apparatus for treating waste gas by irradiation with electron beams, comprising: an electron beam irradiation chamber for irradiation with electron beams from electron beam accelerators; a feeding device which introduces a part of waste gas to be treated into said electron beam irradiation chamber where waste gas is irradiated with electron beam to thereby form active species and which feeds the waste gas having said active species formed therein to a waste gas main duct through which said waste gas to be treated is flowing, said part (proportion %) of waste gas being defined by the following equation:
= π/ D2 x V x 3600 1Q0
wherein D is the diameter of an electron beam irradiation chamber, that is, about 2.0 m or less corresponding to an accelerating voltage of about 500 KV or less, V is the flow rate of waste gas in the electron beam irradiation chamber of about 30 m/s or less, Q (m3/h) is the amount of waste gas to be treated; a dispersing device for uniformly dispersing in the main duct waste gas fed from said feeding device; and a dust collector for capturing the mist or dust into which noxious (gas) ingredients in the waste gas within the main duct have been changed by the action of said active species.
PCT/JP1988/001101 1988-10-28 1988-10-28 Method of and apparatus for treating waste gas by irradiation with electron beam WO1990004448A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/JP1988/001101 WO1990004448A1 (en) 1988-10-28 1988-10-28 Method of and apparatus for treating waste gas by irradiation with electron beam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1988/001101 WO1990004448A1 (en) 1988-10-28 1988-10-28 Method of and apparatus for treating waste gas by irradiation with electron beam

Publications (1)

Publication Number Publication Date
WO1990004448A1 true WO1990004448A1 (en) 1990-05-03

Family

ID=13930867

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1988/001101 WO1990004448A1 (en) 1988-10-28 1988-10-28 Method of and apparatus for treating waste gas by irradiation with electron beam

Country Status (1)

Country Link
WO (1) WO1990004448A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000006289A1 (en) * 1998-07-27 2000-02-10 Enex Co., Ltd. Method and apparatus for cleaning harmful gas by irradiation with gas laser and electron beams

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3608291A1 (en) * 1985-10-23 1987-04-23 Licentia Gmbh Process for the selective or simultaneous separation of pollutants from flue gases by irradiating the flue gases with electron beams
WO1987006494A1 (en) * 1986-04-24 1987-11-05 Ebara Corporation Method and device for flue gas treatment by irradiation with electron beams

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3608291A1 (en) * 1985-10-23 1987-04-23 Licentia Gmbh Process for the selective or simultaneous separation of pollutants from flue gases by irradiating the flue gases with electron beams
WO1987006494A1 (en) * 1986-04-24 1987-11-05 Ebara Corporation Method and device for flue gas treatment by irradiation with electron beams

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000006289A1 (en) * 1998-07-27 2000-02-10 Enex Co., Ltd. Method and apparatus for cleaning harmful gas by irradiation with gas laser and electron beams
AU751955B2 (en) * 1998-07-27 2002-09-05 Enex Co., Ltd. Method and apparatus for cleaning harmful gas by irradiation with gas laser and electron beams

Similar Documents

Publication Publication Date Title
US5015443A (en) Method of and apparatus for treating waste gas by irradiation with electron beam
US4657738A (en) Stack gas emissions control system
US20100170779A1 (en) Gas conversion system
US4419331A (en) Sulphur dioxide converter and pollution arrester system
RU2038131C1 (en) Method for treatment of exhaust gas containing impurities of nitrogen and sulfur oxides
CN1011858B (en) Process for treating waste gas
US3997415A (en) Process for removing sulfur dioxide and nitrogen oxides from effluent gases
CN1090043C (en) Method and apparatus for treating gas by irradiation of electron beam
JPH08504123A (en) Toxic substance detoxification device and method
US4004995A (en) Process for removing nitrogen oxides and sulfur dioxide from effluent gases
JP3431731B2 (en) Electron beam irradiation exhaust gas treatment equipment
JPS60179123A (en) Method and apparatus for desulfurization and denitration of flue gas by electron irradiation
EP0313989A1 (en) Method of inhibiting adhesion of by-product inside duct in treatment of waste gas by electron beam irradiation
CN106000039A (en) Dry type ammonia desulphurization and denitration device
US3714764A (en) Boiler flue gas scrubber
KR920010275B1 (en) Stack gas emission control system
WO1990004448A1 (en) Method of and apparatus for treating waste gas by irradiation with electron beam
CN114849434B (en) Prilling tower system and tail gas treatment device
JPS61238325A (en) Desulfurization and densitration apparatus of exhaust gas byelectron irradiation
EP0293759A1 (en) An exhaust gas treatment process using irradiation and apparatus for same
KR0133367Y1 (en) Apparatus for treatment of exhaust gas using plasma
WO1997001386A1 (en) A method and apparatus for purifying a gaseous mixture including molecules and/or cells of toxic or polluting substances
CN212369887U (en) High-energy electron beam irradiation treatment reaction device
JPH0616815B2 (en) Method and apparatus for treating exhaust gas by electron beam irradiation
KR100229585B1 (en) Method and apparatus of simultaneous removal of so2 & nox using electron beam cyclone reactor

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): JP

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): DE GB IT