WO1986000223A1 - Colorant capillaire oxydant a base d'un excipient de basse viscosite - Google Patents

Colorant capillaire oxydant a base d'un excipient de basse viscosite Download PDF

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Publication number
WO1986000223A1
WO1986000223A1 PCT/EP1985/000165 EP8500165W WO8600223A1 WO 1986000223 A1 WO1986000223 A1 WO 1986000223A1 EP 8500165 W EP8500165 W EP 8500165W WO 8600223 A1 WO8600223 A1 WO 8600223A1
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WO
WIPO (PCT)
Prior art keywords
weight
hair
alcohol
amino
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1985/000165
Other languages
German (de)
English (en)
French (fr)
Inventor
Dietrich Hoch
Eugen Konrad
Gilbert Pasquier
Herbert Mager
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Priority to BR8506791A priority Critical patent/BR8506791A/pt
Priority to IN380/CAL/85A priority patent/IN164721B/en
Publication of WO1986000223A1 publication Critical patent/WO1986000223A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20—Halogens; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/51—Chelating agents

Definitions

  • Oxidation hair colorants in cream form have currently become particularly important.
  • Such hair dyes generally contain p-substituted benzene derivatives, such as 1,4-diaminobenzene, 2,5-diaminotoluene, p-aminophenol and 2,5-diaminobenzyl alcohol, as the most important oxidation dyes.
  • benzene derivatives such as 1,4-diaminobenzene, 2,5-diaminotoluene, p-aminophenol and 2,5-diaminobenzyl alcohol, as the most important oxidation dyes.
  • developer substances These are referred to as developer substances.
  • the developer substances must be used in combination with suitable coupler substances.
  • suitable coupler substances include resorcinol, 4-chlororesorcinol, 4-hydroxy-1,2-methylenedioxybenzene, 4-amino-1,2,2-methylenedioxybenzene, 2-methylresorcinol, 2,4-dihydroxyphenol ether, 4-hydroxyindole, 1 -Naphthol, m-aminophenol, m-phenylenediamine and m-phenylene-diami ⁇ derivate.
  • Customary oxidation hair colorants are made alkaline, preferably by adding ammonia or monoethanolamine.
  • the developer substances and coupler substances are often in the form of their chlorides or sulfates, as a result of which the corresponding ammonium salts are formed after the addition of ammonia.
  • These salts act with conventional cream-like ones Oxidation hair dyeing agents, together with the developers, the couplers and any direct-coloring dyes which may still be present, counteract the formation of the emulsion and reduce its stability. Particularly in the case of dark dye-rich hair dye compositions, there is therefore always a risk of emulsion separation.
  • fatty alcohols and fatty amides in particular are used to increase the viscosity.
  • these thickeners In order to obtain good emulsion stability, these thickeners must be used in high concentrations of about 15 to 30 percent by weight.
  • the emulsifiers used in customary cream-shaped hair dyeing agents are ethoxylated fatty alcohols, fatty alcohol sulfates and ethoxylated fatty alcohol sulfates.
  • the viscosity of the hair colorants is high, these agents are difficult to distribute in the hair. You usually have to use one Brushes are applied. Application to the hair with the help of a shaking bottle and thus application by the dyeing customer is not possible. As a result of the high viscosity, which increases due to the partial evaporation of liquid during the dyeing treatment, it is difficult to rinse out completely after the hair dyeing treatment, so that subsequent hair washing is indispensable.
  • the cre-shaped oxidation hair dye is mixed with an aqueous hydrogen peroxide solution, for example a 6% H 2 O 2 solution, usually in a ratio of about 1: 1.
  • an aqueous hydrogen peroxide solution for example a 6% H 2 O 2 solution, usually in a ratio of about 1: 1.
  • the hydrogen peroxide solution can be clear or cloudy, a latex dispersion, for example, being used as the clouding agent.
  • a further disadvantage of conventional, highly viscous hair colorants is that their viscosity increases during storage, so that removal from the tube is very difficult and mixing with the hydrogen peroxide solution requires more time.
  • the object of the present application was therefore to provide an oxidation hair colorant which has a lower viscosity than the known agents described above, nevertheless does not run off the hair and furthermore does not have the described disadvantages of known cream-shaped hair colorants.
  • the present application therefore relates to agents for the oxidative dyeing of human hair on the basis of a carrier composition and a dye mixture dissolved therein, characterized in that the carrier composition is formed from
  • the amounts preferably used for the inorganic salt are 1.0 to 3.0% by weight, particularly preferably 2.5% by weight.
  • diglycol ether sulfate is preferably present in an amount of 2.0 to 3.5% by weight and particularly preferably in an amount of 2.8% by weight.
  • the coconut fatty acid diethanolamide is preferably contained in an amount of 2.0 to 4.0% by weight, in particular 3.0% by weight.
  • Component d), which is referred to hereinafter as a wax mixture, is preferably contained in an amount of 10.0 to 14.0% by weight and particularly preferably in an amount of 12% by weight.
  • the water content of the carrier composition is 56 to 83% by weight and is preferably approximately 60 to 70% by weight.
  • the quaternized homopolymer of dimethylaminoethyl methacrylate which is preferably 75% quaternized, for example with diethyl sulfate, should in particular in an amount of 0.1 to 0.5% by weight and particularly preferably in an amount of 0.25%. % included.
  • the carrier mass of the agents according to the invention is adjusted to a pH of about 8.0 to 11.5 by a content of about 0.1 to 5.0% by weight of ammonia.
  • Particularly suitable physiologically acceptable water-soluble inorganic salts are ammonium, sodium or potassium sulfite, sulfate or chloride, the total amount of these salts contained in the composition preferably being 1.0 to 3.0% by weight.
  • the sodium lauryl alcohol diglycol ether sulfate can be present, for example, in the form of a commercially available 28% strength aqueous solution.
  • suitable ones Cetylstearyl alcohols are the commercial products Lanette W ⁇ and Lanette 0 from Henkel, Düsseldorf.
  • a suitable glycerol monodistearate for example, one with 30 to 35% by weight monoester content can be used (eg commercial product Tegin ⁇ from Goldschmidt, Essen Germany).
  • An example of a commercially available quaternized homopolymer of dimethylaminoethyl methacrylate is the commercial product PLEX 7525L from Röhm, Darmstadt.
  • the oxidation hair dye as an aliphatic alcohol e.g. Contain ethanol or isopropanol in an amount of up to 5% by weight and as a complexing agent for heavy metals, for example ethylenediaminetetraacetate and nitrilotriacetic acid in an amount of up to 0.5% by weight.
  • Perfume oils can be contained in the agents in an amount of up to about 1% by weight.
  • the dye mixture contained in the oxidation hair dye consists of at least one coupler substance and at least one developer substance as well as, if necessary, additionally with self-coupling dye precursors and dyes which are absorbed directly onto the hair.
  • the developer and coupler substances are in the hair dye either as such or in
  • the coupler substances are generally used in an approximately equimolar amount, based on the developer substances used. Even if the equimolar use proves to be expedient, it is not disadvantageous if the coupler substances are used in a certain excess or deficit. Furthermore, it is not necessary for the developer component and the coupler component to be uniform products; rather, both the developer component can be a mixture of known developer substances and the coupler component can be a mixture of known coupler substances.
  • the hair colorants contain in particular 1-naphthol, 4-methoxy-1-naphthol, resorcinol, 4-chlororesorcinol, 4,6-dichlororesorcinol, 2-methylresorcinol, m-aminophenol, 4-hydroxy-1,2 -methylene dioxybenzene, 4-amino-1, 2-methylenedioxybenzene, 4- (ß-hydroxyethylamino) -l, Z -methylene dioxybenzene and 5-amino-2-methylphenol.
  • suitable coupler substances are, for example, 2,4-dihydroxyphenol ethers such as 2,4-dihydroxyanisole and 2,4-dihydroxyphenoxyethanol.
  • 1, 4-diaminobenzene, 2,5-diaminotoluene, 2,5-diaminoanisole, 2,5-diaminobenzyl come 3-methyl-4-aminophenol, 2- (.beta. Hydroxyethyl) -l, 4-diaminobenzene, tetraaminopyrimidine and 4-amino- phenol into consideration.
  • the total amount of the developer substance-coupler substance combination contained in the hair colorants described here should be about 0.1 to 5.0% by weight, in particular 0.5 to 5.0% by weight.
  • conventional direct dyes for example triphenylmethane dyes such as Diamond Fuchsin (CI 42 510) and Leather Ruby HF (CI 42 520), aromatic nitro dyes such as 2-amino-4,6-dinitro-phenol, 2- Nitro-4- ( ⁇ -hydroxyethylamino) aniline, 2-N- ⁇ / y-dihydroxypropylamino- 5- (N-methyl, N-hydroxyethyl) amino-nitrobenzene and 2-amino-4-nitrophenol, azo dyes such as acid Brown 4 (CI 14 805) and Acid Blue 135 (CI 13 385), anthraquinone dyes such as Disperse Violet 4 (CI 61 105), Disperse Blue 1 (CI 64 500), Disperse Red 15 (CI 60 710), Disperse Violet 1 ( CI 61 100), and also 1, 4,5,8-tetraaminoanthraquinone and 1,4-diaminoanthraquinone.
  • the hair colorants can also with self-coupling color precursors, such as 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-ethoxyphenol or 2-propylamino-5 -aminopyridine.
  • self-coupling color precursors such as 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-ethoxyphenol or 2-propylamino-5 -aminopyridine.
  • the total amount of the dye mixture in the agents described here is about 0.1 to ' ?
  • the oxidation hair dye according to the invention is a mixture of the carrier mass and the dye mixture.
  • the hair colorants are mixed with an oxidizing agent immediately before use in a weight ratio of approximately 5: 1 to 1: 4 and an amount sufficient for hair coloration is generally used, depending on the hair volume, of approximately 60 to 200 g , this mixture on the hair.
  • the main oxidizing agents used to develop hair color are hydrogen peroxide, for example as a 6% strength aqueous solution or its addition compounds with urea, melamine or sodium borate.
  • the mixture is left at 15 to 50 ° C. for about 10 to 45 minutes, act on the hair, preferably for 30 minutes, then rinse the hair with water and dry. If necessary, this rinse is rinsed with a weak physiologically acceptable organic acid, such as citric acid or tartaric acid.
  • the hair dye composition comprising about 400 to 4000 ⁇ vorzugt be 1000 mPa. s at 30 ° C (measured with the Viskowaage from Haake with rod II and a support weight of 20 grams), the hair dye also not needing to be homogenized, and the high wetting agent content (sodium lauryl alcohol diglycol ether sulfate) is the hair dye according to the invention ⁇ medium in contrast to conventional cream-shaped Hair dyes can be mixed very easily and quickly with the hydrogen peroxide solution. After mixing, it is applied to the hair to be dyed using a brush or, preferably, an application bottle.
  • the hairline is treated with the mixture of hair dye and hydrogen peroxide solution. After a contact time of about 5 to 40 minutes at 15 to 50 ° C., the coloring mixture is then applied to the hair lengths and hair tips by combing.
  • the dye mixture is easy to distribute in the hair.
  • the correspondingly low mechanical stress on the hair when combing is particularly advantageous for porous hair.
  • the hair dye described here also has a detangling and smoothing effect on the hair, which also facilitates distribution of the agent in the hair.
  • the hair dye After the hair dye has acted on, it can easily be rinsed out of the hair again, so that washing the hair is no longer necessary.
  • the generally porous hair is detangled at the same time and is given a pleasantly smooth handle, so that it can be combed through very well even without the additional use of a cure or a hair conditioner.
  • the hair dyes according to the invention there is no thickening even after prolonged storage.
  • the agents also have the surprising property that they give the same final viscosity, largely independently of the type and amount of the dye or electrolyte additive contained. This makes it possible to use the same carrier material for all shades of a hair color series. This considerably facilitates the production of a hair color series. For creamy oxidation hair dye after
  • the prior art must have different properties for the carrier material for the respective color tones. For example, in dark shades of commercially available cream hair colors, the content of thickeners is higher than in light shades.
  • Example 1 Example 2 (black shades) (carrier mass)
  • the mixture is applied to the gray hair of gray human hair dyed black six weeks earlier. After an exposure time of 20 minutes at 45 ° C., the hair dye mixture is also distributed into the hair lengths and hair tips by combing. Because the agent according to the invention is easy to distribute, this is possible very quickly and with the greatest possible protection of the hair. The mixture is left to act for a few more minutes at room temperature. Finally, the hair dye mixture is rinsed out of the hair with warm water, the hair not being re-shampooed.
  • the hair treated in this way is colored evenly black from the roots to the ends of the hair.
  • the hair is very easy to comb and style both when wet and dry. In addition, it has a comfortable grip. There are no residues of the dye mixture in the hair.
  • Example 3 Example 4 (light blonde shades) (carrier mass)
  • cream-shaped hair colorants according to Examples 3 and 4 are used as described for Examples 1 and 2, but on the gray hair of a gray human hair colored blonde 6 weeks ago,
  • the hair is dyed evenly blonde and has all the advantageous properties as described above in Examples 1 and 2.
  • Examples 3 and 4 do not change their viscosity during prolonged storage and also have no phase separation.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Zoology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)
PCT/EP1985/000165 1984-06-27 1985-04-15 Colorant capillaire oxydant a base d'un excipient de basse viscosite Ceased WO1986000223A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
BR8506791A BR8506791A (pt) 1984-06-27 1985-04-15 Composicao para o tingimento oxidativo de cabelos a base de uma massa-suporte de baixa viscosidade
IN380/CAL/85A IN164721B (https=) 1984-06-27 1985-05-18

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19843423589 DE3423589A1 (de) 1984-06-27 1984-06-27 Oxidationshaarfaerbemittel auf basis einer niedrigviskosen traegermasse
DEP3423589.2 1984-06-27
CN85103112A CN85103112B (zh) 1984-06-27 1985-04-24 以低粘度载体物质为基础的氧化染发剂

Publications (1)

Publication Number Publication Date
WO1986000223A1 true WO1986000223A1 (fr) 1986-01-16

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ID=25741587

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1985/000165 Ceased WO1986000223A1 (fr) 1984-06-27 1985-04-15 Colorant capillaire oxydant a base d'un excipient de basse viscosite

Country Status (11)

Country Link
US (1) US4725282A (https=)
EP (1) EP0166100B1 (https=)
JP (1) JPS61502531A (https=)
CN (1) CN85103112B (https=)
AU (1) AU579633B2 (https=)
BR (1) BR8506791A (https=)
CA (1) CA1254833A (https=)
DE (2) DE3423589A1 (https=)
GR (1) GR851577B (https=)
MX (1) MX161858A (https=)
WO (1) WO1986000223A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005058261A1 (de) * 2003-12-17 2005-06-30 Henkel Kommanditgesellschaft Auf Aktien Oxidationsfärbemittel in tube
US7247173B2 (en) 2003-12-17 2007-07-24 Henkel Kommandit Gesellschaft Auf Aktien Tinting agent in tubes
US7294153B2 (en) 2003-12-17 2007-11-13 Henkel Kommanditgesellschaft Auf Aktien Caring oxidation coloring agent in a tube

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3610396A1 (de) * 1986-03-27 1987-10-01 Wella Ag Mittel und verfahren zur oxidativen faerbung von haaren
DE3627746A1 (de) * 1986-08-16 1988-02-18 Henkel Kgaa Verfahren zur dauerhaften haarverformung
US5161553A (en) * 1986-09-19 1992-11-10 Clairol Incorporated Process for simultaneously waving and coloring hair
DE3825163A1 (de) * 1988-07-23 1990-02-01 Wella Ag Verwendung von 2,6-dinitro-phenol-derivaten in haarfaerbemitteln
DE4005008C2 (de) * 1990-02-19 1995-01-05 Wella Ag Oxidationshaarfärbemittel aus einer flüssigen Farbträgermasse und einer emulsionsförmigen, oxidationsmittelhaltigen Zusammensetzung und Verfahren zum oxidativen Färben von Haaren
US5560750A (en) * 1990-05-08 1996-10-01 Preemptive Advertising, Inc. Compositions and methods for altering the color of hair
DE4103292C2 (de) * 1991-02-04 1994-02-10 Goldwell Ag Haarfärbemittel
US5403357A (en) * 1991-04-17 1995-04-04 Yamahatsu Sangyo Kaisha, Ltd. Hair coloring composition containing stearate derivatives as drying inhibitors
DE4216381A1 (de) * 1992-05-18 1993-11-25 Wella Ag Oxidationshaarfärbemittel auf der Basis einer cremeförmigen Trägermasse und Verfahren zum Färben von Haaren
US5344463A (en) * 1993-05-17 1994-09-06 Clairol, Inc. Hair dye compositions and methods utilizing 2-substituted-1-naphthol couplers
DE4316602A1 (de) * 1993-05-18 1994-11-24 Henkel Kgaa Verwendung von Hydroxynaphthalinen in Färbemitteln
WO1995009600A1 (en) * 1993-10-01 1995-04-13 The Procter & Gamble Company Hair care compositions containing low melting point fatty alcohol and crosslinked polymeric thickener
FR2715297B1 (fr) * 1994-01-24 1996-02-23 Oreal Composition de teinture d'oxydation des fibres kératiniques comprenant un dérivé de paraphénylènediamine et un dérivé de métaaminophénol, et procédé de teinture utilisant une telle composition.
FR2729565A1 (fr) * 1995-01-20 1996-07-26 Oreal Composition de teinture d'oxydation des fibres keratiniques et procede de teinture mettant en oeuvre cette composition
FR2793408A1 (fr) * 1999-05-10 2000-11-17 Oreal Procede de teinture d'oxydation en un seul temps des fibres keratiniques avec un 1-naphtol 4-substitue
DE10007776A1 (de) * 2000-02-21 2001-09-06 Goldwell Gmbh Haarfärbemittel
FR2833837B1 (fr) * 2001-12-21 2005-08-05 Oreal Composition pour la teinture d'oxydation des fibres keratiniques comprenant un amide d'acide gras de colza oxyethylene
FR2925311B1 (fr) * 2007-12-21 2009-12-18 Oreal Procede d'eclaircissement de fibres keratiniques humaines mettant en oeuvre une composition anhydre et une amine organique particuliere et dispositif approprie
FR2925323B1 (fr) 2007-12-21 2009-12-18 Oreal Procede de coloration en presence d'un agent oxydant et d'une amine organique particuliere et dispositif
FR2925307B1 (fr) 2007-12-21 2009-12-18 Oreal Procede de coloration directe eclaircissante ou d'oxydation en presence d'une amine organique particuliere et dispositif
FR2939645B1 (fr) * 2008-12-12 2011-02-11 Oreal Procede de coloration capillaire a partir d'une composition comprenant au moins un orthodiphenol, un sel metallique, du peroxyde d'hydrogene et du (bi)carbonate
FR2940067B1 (fr) * 2008-12-19 2011-02-25 Oreal Composition oxydante pour le traitement des fibres keratiniques comprenant un polymere cationique, un amide gras et un agent-oxygene
FR2940107B1 (fr) 2008-12-19 2011-03-18 Oreal Procede d'eclaircissement de matieres keratiniques mettant en oeuvre une emulsion comprenant un agent alcalin et une composition oxydante
EP2198838B1 (fr) 2008-12-19 2018-09-05 L'Oréal Procédé et dispositif d'éclaircissement ou de coloration directe éclaircissante ou d'oxydation des fibres kératiniques en présence d'une composition aqueuse riche en corps gras
FR2940078B1 (fr) * 2008-12-19 2011-05-13 Oreal Composition comprenant un corps gras et un polymere cationique, procede de coloration la mettant en oeuvre et dispositifs
FR2940061B1 (fr) 2008-12-19 2011-03-04 Oreal Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras et un derive de diaminopyrazolone.
FR2940105B1 (fr) * 2008-12-19 2011-04-08 Oreal Composition comprenant un corps gras et un tensioactif oxyethylene particulier, procede de coloration la mettant en oeuvre et dispositifs
FR2940090B1 (fr) 2008-12-19 2011-02-25 Oreal Composition oxydante pour le traitement des fibres keratiniques comprenant une huile, un alcool gras et un alcool gras oxyalkylene
BRPI0911109B8 (pt) * 2008-12-19 2017-05-30 Oreal processo de coloração ou de clareamento das matérias queratínicas humanas e dispositivo com múltiplos compartimentos
FR2940100B1 (fr) * 2008-12-19 2011-02-18 Oreal Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras et la n,n bis (beta-hydroxyethyl)-paraphenylene diamine
FR2940055B1 (fr) * 2008-12-19 2015-03-27 Oreal Composition de teinture d'oxydation des fibres keratiniques comprenant le para-aminophenol, du dipropyleneglycol, et un precurseur de colorant additionnel.
BRPI0906138A2 (pt) * 2008-12-19 2013-04-09 Oreal processo de coloraÇço das fibras queratÍnicas humanas, processo de clareamento das fibras queratÍnicas humanas e dispositivo com vÁrios compartimentos
FR2940102B1 (fr) 2008-12-19 2016-03-11 Oreal Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras, un epaississant et un precurseur de colorant d'oxydation
FR2940079B1 (fr) 2008-12-19 2011-02-18 Oreal Composition comprenant au moins un alcool gras solide, procede de coloration la mettant en oeuvre et dispositifs
FR2940092B1 (fr) * 2008-12-19 2011-02-18 Oreal Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras amide ou ester
FR2940104B1 (fr) 2008-12-19 2011-08-19 Oreal Procede de traitement des cheveux mettant en oeuvre une emulsion directe comprenant un agent oxydant et une composition contenant un agent alcalin
FR2940077B1 (fr) * 2008-12-19 2012-07-20 Oreal Procede de coloration eclaircissante de matieres keratiniques mettant en oeuvre une composition anhydre colorante comprenant un agent alcalin et une composition oxydante.
FR2940103B1 (fr) 2008-12-19 2011-06-10 Oreal Procede de coloration eclaircissante de matieres keratiniques mettant en oeuvre une emulsion comprenant un colorant et un agent alcalin et une composition oxydante
JP5808521B2 (ja) 2008-12-19 2015-11-10 ロレアル アンモニウム塩の存在下で、淡色化し、あるいは淡色化直接染色し、あるいは酸化染色する方法、及びそのためのデバイス
US7935154B2 (en) 2008-12-19 2011-05-03 L'oreal S.A. Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine and at least one inorganic base, and device therefor
FR2940101B1 (fr) * 2008-12-19 2011-02-18 Oreal Composition de teinture d'oxydation de fibres keratiniques comprenant un corps gras et un derive 4,5-diaminopyrazole
FR2940106B1 (fr) * 2008-12-19 2013-04-12 Oreal Composition comprenant un corps gras et un silicate, procede de coloration la mettant en oeuvre et dispositifs
CN101843564A (zh) 2008-12-19 2010-09-29 莱雅公司 使蛋白纤维色泽变淡和染色的无水组合物、及其装置
FR2940108B1 (fr) 2008-12-19 2011-04-29 Oreal Procede d'eclaircissement de matieres keratiniques mettant en oeuvre une composition anhydre comprenant un agent alcalin et une composition oxydante
DE102009028584A1 (de) * 2009-08-17 2011-02-24 Henkel Ag & Co. Kgaa Zusammensetzungen zur Haarpflege enthaltend Lanolinalkohol mit einem hohen Gehalt langkettiger Fettalkohole
FR2954127B1 (fr) 2009-12-22 2015-10-30 Oreal Agent de coloration et/ou de decoloration des fibres keratiniques en deux parties, comprenant un corps gras et un agent sequestrant.
FR2954160B1 (fr) 2009-12-22 2012-03-30 Oreal Composition de coloration ou d'eclaircissement comprenant un corps gras et un polymere amphotere
FR2954121B1 (fr) 2009-12-22 2016-03-25 Oreal Agent de coloration et/ou de decoloration des fibres keratiniques en deux parties, comprenant un corps gras particulier et une reductone.
FR2954159B1 (fr) * 2009-12-22 2012-02-10 Oreal Agent de coloration et/ou de decoloration des fibres keratiniques comprenant une composition comprenant un agent alcalinisant et une composition anhydre comprenant un oxydant, l'une ou l'autre des compositions pouvant contenir un corps gras
FR2962032B1 (fr) * 2009-12-23 2019-11-15 L'oreal Composition pour colorer les fibres keratiniques comprenant au moins un derive d'orthodiphenol, un agent oxydant, une argile et un agent alcalinisant

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WO2005058261A1 (de) * 2003-12-17 2005-06-30 Henkel Kommanditgesellschaft Auf Aktien Oxidationsfärbemittel in tube
US7244277B2 (en) 2003-12-17 2007-07-17 Henkel Kommanditgesellschaft Auf Aktien Oxidation colorant in a tube
US7247173B2 (en) 2003-12-17 2007-07-24 Henkel Kommandit Gesellschaft Auf Aktien Tinting agent in tubes
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AU4239485A (en) 1986-01-24
GR851577B (https=) 1985-11-25
EP0166100B1 (de) 1989-01-11
CN85103112A (zh) 1986-10-22
CN85103112B (zh) 1988-09-28
JPS61502531A (ja) 1986-11-06
DE3423589A1 (de) 1986-01-09
BR8506791A (pt) 1986-11-25
JPH0212929B2 (https=) 1990-03-30
EP0166100A1 (de) 1986-01-02
CA1254833A (en) 1989-05-30
AU579633B2 (en) 1988-12-01
DE3567372D1 (en) 1989-02-16
US4725282A (en) 1988-02-16
MX161858A (es) 1991-01-29

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