WO1982001980A1 - Agricultural and horticultural microbiocidal compositions - Google Patents
Agricultural and horticultural microbiocidal compositions Download PDFInfo
- Publication number
- WO1982001980A1 WO1982001980A1 PCT/US1981/001646 US8101646W WO8201980A1 WO 1982001980 A1 WO1982001980 A1 WO 1982001980A1 US 8101646 W US8101646 W US 8101646W WO 8201980 A1 WO8201980 A1 WO 8201980A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- parts
- benomyl
- oxide
- wettable powder
- mixed
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 230000003641 microbiacidal effect Effects 0.000 title claims description 16
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 claims abstract description 67
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 claims abstract description 67
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Chemical group 0.000 claims abstract description 6
- 229910016287 MxOy Inorganic materials 0.000 claims abstract description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- 229910052788 barium Inorganic materials 0.000 claims abstract description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052796 boron Inorganic materials 0.000 claims abstract description 3
- 239000011575 calcium Substances 0.000 claims abstract description 3
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 3
- 229910052725 zinc Chemical group 0.000 claims abstract description 3
- 239000011701 zinc Chemical group 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 23
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims description 16
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000004563 wettable powder Substances 0.000 description 32
- 239000004927 clay Substances 0.000 description 26
- 239000011369 resultant mixture Substances 0.000 description 20
- 239000000428 dust Substances 0.000 description 19
- -1 benzonite Substances 0.000 description 16
- 238000002360 preparation method Methods 0.000 description 12
- 239000008187 granular material Substances 0.000 description 10
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 8
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 7
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 6
- 239000005909 Kieselgur Substances 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 5
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 4
- QPPOABGLLLVLBF-UHFFFAOYSA-N 2-(dithiocarboxyamino)ethylcarbamodithioic acid;manganese Chemical compound [Mn].SC(=S)NCCNC(S)=S QPPOABGLLLVLBF-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- GTCAXTIRRLKXRU-UHFFFAOYSA-N carbamic acid methyl ester Natural products COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 235000017168 chlorine Nutrition 0.000 description 2
- 229940060038 chlorine Drugs 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 2
- 239000008262 pumice Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- RGALBBQJPFDFCB-UHFFFAOYSA-N 2-(dithiocarboxyamino)ethylcarbamodithioic acid;zinc Chemical compound [Zn].SC(=S)NCCNC([S-])=[SH+] RGALBBQJPFDFCB-UHFFFAOYSA-N 0.000 description 1
- NMWKWBPNKPGATC-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-benzofuran-1(3H)-one Chemical compound ClC1=C(Cl)C(Cl)=C2COC(=O)C2=C1Cl NMWKWBPNKPGATC-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000005667 attractant Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-NJFSPNSNSA-N calcium-42 Chemical group [42Ca] OYPRJOBELJOOCE-NJFSPNSNSA-N 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- AVXHCUKQISJQBN-UHFFFAOYSA-N chloromethanesulfonamide Chemical compound NS(=O)(=O)CCl AVXHCUKQISJQBN-UHFFFAOYSA-N 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- MMUFAGXJPKNAHT-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1 MMUFAGXJPKNAHT-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- WZPMZMCZAGFKOC-UHFFFAOYSA-N diisopropyl hydrogen phosphate Chemical compound CC(C)OP(O)(=O)OC(C)C WZPMZMCZAGFKOC-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- IPENDKRRWFURRE-UHFFFAOYSA-N fluoroimide Chemical compound C1=CC(F)=CC=C1N1C(=O)C(Cl)=C(Cl)C1=O IPENDKRRWFURRE-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 229920000940 maneb Polymers 0.000 description 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000005461 organic phosphorous group Chemical group 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Definitions
- This invention relates to agricultural and horticultural microbiocidal compositions having good stability which comprises methyl 1-(n-butylcarbamoyl)- benzimidazole-2-ylcarbamate (hereinafter sometimes referred to as "benomyl”) as a microbiocidally active ingredient.
- Benomyl is known to have excellent microbiocidal power (Japanese Patent Publn. 25720/70), and is used as a microbiocide in the agricultural and horticultural field.
- One drawback to the use of benomyl is that it decomposes with time and thus has poor storage stability. There is therefore a need for benomyl compositions which enhance the stability of benomyl.
- This invention is directed to an agricultural and horticultural microbiocidal composition consisting of a microbiocidally effective amount of benomyl and one or more compounds (hereinafter referred to as "metallic oxide”) of the general formula MxOy where M is an atom of calcium, barium, aluminum, silicon, boron or zinc, x is an integer of 1 or 2, and y is an integer of 1, 2 or 3.
- M is an atom of calcium, barium, aluminum, silicon, boron or zinc
- x is an integer of 1 or 2
- y is an integer of 1, 2 or 3.
- the metallic oxide of the claimed composition is a compound of the general formula MxOy.
- Examples include calcium oxide (CaO), barium oxide (BaO), aluminum oxide (A1 2 O 3 ), silicon dioxide (SiO 2 ), diboron trioxide (B 2 O 3 ), zinc oxide (ZnO), etc. Hydrates of metallic oxides may also be used. These metallic oxides may be blended singly with benomyl or two or more of them may be blended in admixture with benomyl.
- Benomyl and metallic oxide are preferably blended in such proportions that the latter is used in an amount of 0.01 to 10 parts by weight, preferably 0.1 to 5 parts by weight on the basis of 1 part by weight of the former.
- Preparations of the agricultural and horticultural microbiocidal composition of the present invention can be produced by mixing or grinding the above compounds by known methods. It is possible to prepare a dust, wettable powder, finely divided granule and granule by blending general adjuvants used in agricultural and horticultural chemicals as required, such as diluent, surfactant, fixing agent or the like.
- diluent one can employ finely divided mineral powders and finely divided mineral particles such as clay, talc, benzonite, diatomaceous earth or the like, a solid diluent such as white carbon or a diluent which is liquid at ordinary temperature such as ethylene glycol, polyethylene glycol, fluid paraffin, etc.
- Suitable surfactants include nonionic surfactants such as polyoxyethylene alkylaryl ether, polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty ester or polyoxyethylene fatty ester, and ionic surfactants such as alkylaryl sulfonate, alkylsulfate, fatty acid salt, ligninsulfonate, naphthalene sulfonate or alkylamine salt.
- the fixing agent one can use a solid paraffin, a vinyl acetate resin, natural fats and oils, etc.
- Other natural or synthetic products may also be included in the composition of this invention such as stabilizers, microbiocides, insecticides, herbicides, plant growth regulators, extenders, attractants, repellants, fertilizers, perfumes, colorants, and physical modifiers.
- microbiocides and insecticides which can be blended with the benomylmetallic oxide composition of this invention: copper type microbiocides such as cupric hydroxide and 8- quinolinol copper; organic sulfur type microbiocides such as zinc ethylene-bis(dithiocarbamic acid), manganese ethylene-bis(dithiocarbamic acid), zinc-maneb complex compound, zinc dimethyldithiocarbamate, dimethyl 4,4-o-phenylene-bis(3-thioallophanic acid) and bis(dimethylthiocarbamoyl)disulfide; or organic chlor ine type microbiocides such as tetrachloroisophthalonitrile, N-(parafluorophenyl)dichloromaleimide, 4,5,6,7-tetrachlorophthalide and pentachlorophenyl organic phosphorous type microbiocides such as S-benzyl-0,0-diisopropyl thi
- the storage and application methods of the agricultural and horticultural microbiocidal composition of this invention are the same as those for conventional preparations containing benomyl.
- compositions of this invention are advantageous in that they can be stored for long periods of time without losing their microbiocidal effectiveness.
- Example 7 wettable powder
- benomyl There are mixed 20 parts of benomyl, 40 parts of manganese ethylene-bis(dithiocarbamic acid), 2 parts of calcium oxide, 3 parts of sodium dodecylbenzenesulfonate, 5 parts of calcium ligninsulfonate and 30 parts of clay.
- the resultant mixture is then ground to afford a wettable powder.
- the resultant mixture is then ground to prepare a wettable powder.
- Referential Example 2 wettable powder
- benomyl 3 parts of sodium dodecylbenzenesulfonate, 5 parts of calcium ligninsulfonate and 72 parts of sucrose.
- sucrose 6 parts
- Test Example 1 The enhanced stability of the composition of this invention is illustrated in the following test examples.
- Test Example 1 The enhanced stability of the composition of this invention is illustrated in the following test examples.
- Example 3 98.1 99.9
- TPN tetrachloroisophthalonitrile
- Example 20 (wettable powder)
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB08222159A GB2106391B (en) | 1980-12-12 | 1981-12-11 | Agricultural and horticultural microbiocidal compositions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP80/174689801212 | 1980-12-12 | ||
| JP17468980A JPS5799505A (en) | 1980-12-12 | 1980-12-12 | Fungicidal composition for agricultural and horticultural use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1982001980A1 true WO1982001980A1 (en) | 1982-06-24 |
Family
ID=15982955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1981/001646 WO1982001980A1 (en) | 1980-12-12 | 1981-12-11 | Agricultural and horticultural microbiocidal compositions |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5799505A (enrdf_load_stackoverflow) |
| GB (1) | GB2106391B (enrdf_load_stackoverflow) |
| WO (1) | WO1982001980A1 (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0668015A3 (en) * | 1994-02-07 | 1995-11-22 | Isk Biotech Corp | Pesticide compositions containing zinc oxide. |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD513935S1 (en) * | 2004-05-06 | 2006-01-31 | Syracuse China Company | Plate |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3454700A (en) * | 1966-05-06 | 1969-07-08 | Du Pont | Methods for stabilizing pesticidal compositions of 2 - alkoxycarbonylaminobenzimidazolecarboxylic esters |
| JPS49133527A (enrdf_load_stackoverflow) * | 1973-04-27 | 1974-12-21 | ||
| DE2340741A1 (de) * | 1973-08-11 | 1975-02-20 | Basf Ag | Fungizid |
| JPS5040739A (enrdf_load_stackoverflow) * | 1973-08-14 | 1975-04-14 | ||
| GB1420605A (en) * | 1972-10-27 | 1976-01-07 | British Petroleum Co | Fungicidal composition |
| JPS517128A (en) * | 1975-04-08 | 1976-01-21 | Kumiai Chemical Industry Co | Anteiseiryokonaru noengeiyosakinsoseibutsu |
| US4000290A (en) * | 1970-06-23 | 1976-12-28 | C. F. Spiess & Sohn | Fungistatic composition for treating seeds using a mixture of a substituted benzimidazole and 2-(thiocyanomethylthio)-benzothiazole |
| JPS5417124A (en) * | 1977-07-08 | 1979-02-08 | Kumiai Chem Ind Co Ltd | Stabilization of fungicide |
-
1980
- 1980-12-12 JP JP17468980A patent/JPS5799505A/ja active Granted
-
1981
- 1981-12-11 GB GB08222159A patent/GB2106391B/en not_active Expired
- 1981-12-11 WO PCT/US1981/001646 patent/WO1982001980A1/en unknown
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3454700A (en) * | 1966-05-06 | 1969-07-08 | Du Pont | Methods for stabilizing pesticidal compositions of 2 - alkoxycarbonylaminobenzimidazolecarboxylic esters |
| US4000290A (en) * | 1970-06-23 | 1976-12-28 | C. F. Spiess & Sohn | Fungistatic composition for treating seeds using a mixture of a substituted benzimidazole and 2-(thiocyanomethylthio)-benzothiazole |
| GB1420605A (en) * | 1972-10-27 | 1976-01-07 | British Petroleum Co | Fungicidal composition |
| JPS49133527A (enrdf_load_stackoverflow) * | 1973-04-27 | 1974-12-21 | ||
| DE2340741A1 (de) * | 1973-08-11 | 1975-02-20 | Basf Ag | Fungizid |
| JPS5040739A (enrdf_load_stackoverflow) * | 1973-08-14 | 1975-04-14 | ||
| JPS517128A (en) * | 1975-04-08 | 1976-01-21 | Kumiai Chemical Industry Co | Anteiseiryokonaru noengeiyosakinsoseibutsu |
| JPS5417124A (en) * | 1977-07-08 | 1979-02-08 | Kumiai Chem Ind Co Ltd | Stabilization of fungicide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0668015A3 (en) * | 1994-02-07 | 1995-11-22 | Isk Biotech Corp | Pesticide compositions containing zinc oxide. |
| US5667795A (en) * | 1994-02-07 | 1997-09-16 | Isk Biosciences Corporation | Pesticidal micronutrient compositions containing zinc oxide |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5799505A (en) | 1982-06-21 |
| GB2106391A (en) | 1983-04-13 |
| JPS6152801B2 (enrdf_load_stackoverflow) | 1986-11-14 |
| GB2106391B (en) | 1984-05-31 |
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