US9226341B2 - Forming insulated conductors using a final reduction step after heat treating - Google Patents

Forming insulated conductors using a final reduction step after heat treating Download PDF

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US9226341B2
US9226341B2 US13/644,402 US201213644402A US9226341B2 US 9226341 B2 US9226341 B2 US 9226341B2 US 201213644402 A US201213644402 A US 201213644402A US 9226341 B2 US9226341 B2 US 9226341B2
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insulated conductor
formation
heat
cross
sectional area
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US20130086800A1 (en
Inventor
Justin Michael Noel
Robert Anthony Shaffer
Edward Everett de St. Remey
Gilbert Luis HERRERA
Trevor Alexander CRANEY
Robert Guy Harley
Dhruv Arora
David Booth Burns
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DMCX7318 LTD
Salamander International Holdings LLC
Salamander International LLC
Salamander Ip Holdings LLC
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Shell Oil Co
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Priority to US14/244,644 priority patent/US9661690B2/en
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Assigned to SALAMANDER INTERNATIONAL LLC reassignment SALAMANDER INTERNATIONAL LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SALAMANDER SOLUTIONS INC., SALAMANDER SOLUTIONS LIMITED
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Assigned to DMCX7318 LTD reassignment DMCX7318 LTD ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SALAMANDER INTERNATIONAL HOLDINGS LLC
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B36/00Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
    • E21B36/04Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones using electrical heaters
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/525Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/042Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material including a refractory ceramic layer, e.g. refractory metal oxides, ZrO2, rare earth oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/2401Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection by means of electricity
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/40Heating elements having the shape of rods or tubes
    • H05B3/42Heating elements having the shape of rods or tubes non-flexible
    • H05B3/48Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/40Heating elements having the shape of rods or tubes
    • H05B3/54Heating elements having the shape of rods or tubes flexible
    • H05B3/56Heating cables
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/017Manufacturing methods or apparatus for heaters
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/021Heaters specially adapted for heating liquids
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/022Heaters specially adapted for heating gaseous material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/037Heaters with zones of different power density
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2206/00Aspects relating to heating by electric, magnetic, or electromagnetic fields covered by group H05B6/00
    • H05B2206/02Induction heating
    • H05B2206/023Induction heating using the curie point of the material in which heating current is being generated to control the heating temperature
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2214/00Aspects relating to resistive heating, induction heating and heating using microwaves, covered by groups H05B3/00, H05B6/00
    • H05B2214/03Heating of hydrocarbons
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49082Resistor making
    • Y10T29/49083Heater type

Definitions

  • the present invention relates to systems and methods used for heating subsurface formations. More particularly, the invention relates to systems and methods for heating subsurface hydrocarbon containing formations.
  • Hydrocarbons obtained from subterranean formations are often used as energy resources, as feedstocks, and as consumer products.
  • Concerns over depletion of available hydrocarbon resources and concerns over declining overall quality of produced hydrocarbons have led to development of processes for more efficient recovery, processing and/or use of available hydrocarbon resources.
  • In situ processes may be used to remove hydrocarbon materials from subterranean formations that were previously inaccessible and/or too expensive to extract using available methods.
  • Chemical and/or physical properties of hydrocarbon material in a subterranean formation may need to be changed to allow hydrocarbon material to be more easily removed from the subterranean formation and/or increase the value of the hydrocarbon material.
  • the chemical and physical changes may include in situ reactions that produce removable fluids, composition changes, solubility changes, density changes, phase changes, and/or viscosity changes of the hydrocarbon material in the formation.
  • Heaters may be placed in wellbores to heat a formation during an in situ process.
  • heaters There are many different types of heaters which may be used to heat the formation. Examples of in situ processes utilizing downhole heaters are illustrated in U.S. Pat. No. 2,634,961 to Ljungstrom; U.S. Pat. No. 2,732,195 to Ljungstrom; U.S. Pat. No. 2,780,450 to Ljungstrom; U.S. Pat. No. 2,789,805 to Ljungstrom; U.S. Pat. No. 2,923,535 to Ljungstrom; U.S. Pat. No. 4,886,118 to Van Meurs et al.; and U.S. Pat. No. 6,688,387 to Wellington et al.; each of which is incorporated by reference as if fully set forth herein.
  • MI cables for use in subsurface applications, such as heating hydrocarbon containing formations in some applications, are longer, may have larger outside diameters, and may operate at higher voltages and temperatures than what is typical in the MI cable industry. There are many potential problems during manufacture and/or assembly of long length insulated conductors.
  • Embodiments described herein generally relate to systems, methods, and heaters for treating a subsurface formation. Embodiments described herein also generally relate to heaters that have novel components therein. Such heaters can be obtained by using the systems and methods described herein.
  • the invention provides one or more systems, methods, and/or heaters.
  • the systems, methods, and/or heaters are used for treating a subsurface formation.
  • a method for forming an insulated conductor heater includes: placing an insulation layer over at least part of an elongated, cylindrical inner electrical conductor; placing an elongated, cylindrical outer electrical conductor over at least part of the insulation layer to form the insulated conductor heater; performing one or more cold working/heat treating steps on the insulated conductor heater, wherein the cold working/heat treating steps includes: cold working the insulated conductor heater to reduce a cross-sectional area of the insulated conductor heater by at least about 30%; and heat treating the insulated conductor heater at a temperature of at least about 870° C.; and reducing the cross-sectional area of the insulated conductor heater by an amount ranging between about 5% and about 15% to a final cross-sectional area.
  • a method for forming an insulated conductor heater includes: forming a first sheath material into a tubular around a core, wherein longitudinal edges of the first sheath material at least partially overlap along a length of the tubular of the first sheath material; providing an electrical insulator powder into at least part of the tubular of the first sheath material; forming a second sheath material into a tubular around the first sheath material; and reducing an outer diameter of the tubular of the second sheath material into a final diameter of the insulated conductor heater.
  • a method for forming an insulated conductor heater includes: forming a first sheath material into a tubular around a core, wherein there is a gap between longitudinal edges of the first sheath material along a length of the tubular of the first sheath material; providing an electrical insulator powder into at least part of the tubular of the first sheath material; forming a second sheath material into a tubular around the first sheath material; and reducing an outer diameter of the tubular of the second sheath material into a final diameter of the insulated conductor heater such that the longitudinal edges of the first sheath material are proximate or substantially abut each other along the length of the tubular of the first sheath material.
  • features from specific embodiments may be combined with features from other embodiments.
  • features from one embodiment may be combined with features from any of the other embodiments.
  • treating a subsurface formation is performed using any of the methods, systems, power supplies, or heaters described herein.
  • FIG. 1 shows a schematic view of an embodiment of a portion of an in situ heat treatment system for treating a hydrocarbon containing formation.
  • FIG. 2 depicts an embodiment of an insulated conductor heat source.
  • FIG. 3 depicts an embodiment of an insulated conductor heat source.
  • FIG. 4 depicts an embodiment of an insulated conductor heat source.
  • FIGS. 5A and 5B depict cross-sectional representations of an embodiment of a temperature limited heater component used in an insulated conductor heater.
  • FIG. 6 depicts a cross-sectional representation of an embodiment of a pre-cold worked, pre-heat treated insulated conductor.
  • FIG. 7 depicts a cross-sectional representation of an embodiment of the insulated conductor depicted in FIG. 6 after cold working and heat treating.
  • FIG. 8 depicts a cross-sectional representation of an embodiment of the insulated conductor depicted in FIG. 7 after coldworking.
  • FIG. 9 depicts an embodiment of a process for manufacturing an insulated conductor using a powder for the electrical insulator.
  • FIG. 10A depicts a cross-sectional representation of a first design embodiment of a first sheath material inside an insulated conductor.
  • FIG. 10B depicts a cross-sectional representation of the first design embodiment with a second sheath material formed into a tubular and welded around the first sheath material.
  • FIG. 10C depicts a cross-sectional representation of the first design embodiment with a second sheath material formed into a tubular around the first sheath material after some reduction.
  • FIG. 10D depicts a cross-sectional representation of the first design embodiment as the insulated conductor passes through the final reduction step at the reduction rolls.
  • FIG. 11A depicts a cross-sectional representation of a second design embodiment of a first sheath material inside an insulated conductor.
  • FIG. 11B depicts a cross-sectional representation of the second design embodiment with a second sheath material formed into a tubular and welded around the first sheath material.
  • FIG. 11C depicts a cross-sectional representation of the second design embodiment with a second sheath material formed into a tubular around the first sheath material after some reduction.
  • FIG. 11D depicts a cross-sectional representation of the second design embodiment as the insulated conductor passes through the final reduction step at the reduction rolls.
  • the following description generally relates to systems and methods for treating hydrocarbons in the formations. Such formations may be treated to yield hydrocarbon products, hydrogen, and other products.
  • Alternating current refers to a time-varying current that reverses direction substantially sinusoidally. AC produces skin effect electricity flow in a ferromagnetic conductor.
  • the term “automatically” means such systems, apparatus, and methods function in a certain way without the use of external control (for example, external controllers such as a controller with a temperature sensor and a feedback loop, PID controller, or predictive controller).
  • external controllers such as a controller with a temperature sensor and a feedback loop, PID controller, or predictive controller.
  • Coupled means either a direct connection or an indirect connection (for example, one or more intervening connections) between one or more objects or components.
  • directly connected means a direct connection between objects or components such that the objects or components are connected directly to each other so that the objects or components operate in a “point of use” manner.
  • “Curie temperature” is the temperature above which a ferromagnetic material loses all of its ferromagnetic properties. In addition to losing all of its ferromagnetic properties above the Curie temperature, the ferromagnetic material begins to lose its ferromagnetic properties when an increasing electrical current is passed through the ferromagnetic material.
  • a “formation” includes one or more hydrocarbon containing layers, one or more non-hydrocarbon layers, an overburden, and/or an underburden.
  • Hydrocarbon layers refer to layers in the formation that contain hydrocarbons.
  • the hydrocarbon layers may contain non-hydrocarbon material and hydrocarbon material.
  • the “overburden” and/or the “underburden” include one or more different types of impermeable materials.
  • the overburden and/or underburden may include rock, shale, mudstone, or wet/tight carbonate.
  • the overburden and/or the underburden may include a hydrocarbon containing layer or hydrocarbon containing layers that are relatively impermeable and are not subjected to temperatures during in situ heat treatment processing that result in significant characteristic changes of the hydrocarbon containing layers of the overburden and/or the underburden.
  • the underburden may contain shale or mudstone, but the underburden is not allowed to heat to pyrolysis temperatures during the in situ heat treatment process.
  • the overburden and/or the underburden may be somewhat permeable.
  • Formation fluids refer to fluids present in a formation and may include pyrolyzation fluid, synthesis gas, mobilized hydrocarbons, and water (steam). Formation fluids may include hydrocarbon fluids as well as non-hydrocarbon fluids.
  • the term “mobilized fluid” refers to fluids in a hydrocarbon containing formation that are able to flow as a result of thermal treatment of the formation.
  • Produced fluids refer to fluids removed from the formation.
  • Heat flux is a flow of energy per unit of area per unit of time (for example, Watts/meter 2 ).
  • a “heat source” is any system for providing heat to at least a portion of a formation substantially by conductive and/or radiative heat transfer.
  • a heat source may include electrically conducting materials and/or electric heaters such as an insulated conductor, an elongated member, and/or a conductor disposed in a conduit.
  • a heat source may also include systems that generate heat by burning a fuel external to or in a formation. The systems may be surface burners, downhole gas burners, flameless distributed combustors, and natural distributed combustors.
  • heat provided to or generated in one or more heat sources may be supplied by other sources of energy. The other sources of energy may directly heat a formation, or the energy may be applied to a transfer medium that directly or indirectly heats the formation.
  • one or more heat sources that are applying heat to a formation may use different sources of energy.
  • some heat sources may supply heat from electrically conducting materials, electric resistance heaters, some heat sources may provide heat from combustion, and some heat sources may provide heat from one or more other energy sources (for example, chemical reactions, solar energy, wind energy, biomass, or other sources of renewable energy).
  • a chemical reaction may include an exothermic reaction (for example, an oxidation reaction).
  • a heat source may also include an electrically conducting material and/or a heater that provides heat to a zone proximate and/or surrounding a heating location such as a heater well.
  • a “heater” is any system or heat source for generating heat in a well or a near wellbore region.
  • Heaters may be, but are not limited to, electric heaters, burners, combustors that react with material in or produced from a formation, and/or combinations thereof.
  • Hydrocarbons are generally defined as molecules formed primarily by carbon and hydrogen atoms. Hydrocarbons may also include other elements such as, but not limited to, halogens, metallic elements, nitrogen, oxygen, and/or sulfur. Hydrocarbons may be, but are not limited to, kerogen, bitumen, pyrobitumen, oils, natural mineral waxes, and asphaltites. Hydrocarbons may be located in or adjacent to mineral matrices in the earth. Matrices may include, but are not limited to, sedimentary rock, sands, silicilytes, carbonates, diatomites, and other porous media. “Hydrocarbon fluids” are fluids that include hydrocarbons. Hydrocarbon fluids may include, entrain, or be entrained in non-hydrocarbon fluids such as hydrogen, nitrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, water, and ammonia.
  • An “in situ conversion process” refers to a process of heating a hydrocarbon containing formation from heat sources to raise the temperature of at least a portion of the formation above a pyrolysis temperature so that pyrolyzation fluid is produced in the formation.
  • An “in situ heat treatment process” refers to a process of heating a hydrocarbon containing formation with heat sources to raise the temperature of at least a portion of the formation above a temperature that results in mobilized fluid, visbreaking, and/or pyrolysis of hydrocarbon containing material so that mobilized fluids, visbroken fluids, and/or pyrolyzation fluids are produced in the formation.
  • Insulated conductor refers to any elongated material that is able to conduct electricity and that is covered, in whole or in part, by an electrically insulating material.
  • Modulated direct current refers to any substantially non-sinusoidal time-varying current that produces skin effect electricity flow in a ferromagnetic conductor.
  • Nitride refers to a compound of nitrogen and one or more other elements of the Periodic Table. Nitrides include, but are not limited to, silicon nitride, boron nitride, or alumina nitride.
  • Perforations include openings, slits, apertures, or holes in a wall of a conduit, tubular, pipe or other flow pathway that allow flow into or out of the conduit, tubular, pipe or other flow pathway.
  • Phase transformation temperature of a ferromagnetic material refers to a temperature or a temperature range during which the material undergoes a phase change (for example, from ferrite to austenite) that decreases the magnetic permeability of the ferromagnetic material.
  • the reduction in magnetic permeability is similar to reduction in magnetic permeability due to the magnetic transition of the ferromagnetic material at the Curie temperature.
  • Pyrolysis is the breaking of chemical bonds due to the application of heat.
  • pyrolysis may include transforming a compound into one or more other substances by heat alone. Heat may be transferred to a section of the formation to cause pyrolysis.
  • “Pyrolyzation fluids” or “pyrolysis products” refers to fluid produced substantially during pyrolysis of hydrocarbons. Fluid produced by pyrolysis reactions may mix with other fluids in a formation. The mixture would be considered pyrolyzation fluid or pyrolyzation product.
  • “pyrolysis zone” refers to a volume of a formation (for example, a relatively permeable formation such as a tar sands formation) that is reacted or reacting to form a pyrolyzation fluid.
  • Superposition of heat refers to providing heat from two or more heat sources to a selected section of a formation such that the temperature of the formation at least at one location between the heat sources is influenced by the heat sources.
  • Temperature limited heater generally refers to a heater that regulates heat output (for example, reduces heat output) above a specified temperature without the use of external controls such as temperature controllers, power regulators, rectifiers, or other devices. Temperature limited heaters may be AC (alternating current) or modulated (for example, “chopped”) DC (direct current) powered electrical resistance heaters.
  • Thickness of a layer refers to the thickness of a cross section of the layer, wherein the cross section is normal to a face of the layer.
  • Time-varying current refers to electrical current that produces skin effect electricity flow in a ferromagnetic conductor and has a magnitude that varies with time. Time-varying current includes both alternating current (AC) and modulated direct current (DC).
  • AC alternating current
  • DC modulated direct current
  • “Turndown ratio” for the temperature limited heater in which current is applied directly to the heater is the ratio of the highest AC or modulated DC resistance below the Curie temperature to the lowest resistance above the Curie temperature for a given current.
  • Turndown ratio for an inductive heater is the ratio of the highest heat output below the Curie temperature to the lowest heat output above the Curie temperature for a given current applied to the heater.
  • a “u-shaped wellbore” refers to a wellbore that extends from a first opening in the formation, through at least a portion of the formation, and out through a second opening in the formation.
  • the wellbore may be only roughly in the shape of a “v” or “u”, with the understanding that the “legs” of the “u” do not need to be parallel to each other, or perpendicular to the “bottom” of the “u” for the wellbore to be considered “u-shaped”.
  • wellbore refers to a hole in a formation made by drilling or insertion of a conduit into the formation.
  • a wellbore may have a substantially circular cross section, or another cross-sectional shape.
  • wellbore and opening when referring to an opening in the formation may be used interchangeably with the term “wellbore.”
  • a formation may be treated in various ways to produce many different products. Different stages or processes may be used to treat the formation during an in situ heat treatment process.
  • one or more sections of the formation are solution mined to remove soluble minerals from the sections. Solution mining minerals may be performed before, during, and/or after the in situ heat treatment process.
  • the average temperature of one or more sections being solution mined may be maintained below about 120° C.
  • one or more sections of the formation are heated to remove water from the sections and/or to remove methane and other volatile hydrocarbons from the sections.
  • the average temperature may be raised from ambient temperature to temperatures below about 220° C. during removal of water and volatile hydrocarbons.
  • one or more sections of the formation are heated to temperatures that allow for movement and/or visbreaking of hydrocarbons in the formation.
  • the average temperature of one or more sections of the formation are raised to mobilization temperatures of hydrocarbons in the sections (for example, to temperatures ranging from 100° C. to 250° C., from 120° C. to 240° C., or from 150° C. to 230° C.).
  • one or more sections are heated to temperatures that allow for pyrolysis reactions in the formation.
  • the average temperature of one or more sections of the formation may be raised to pyrolysis temperatures of hydrocarbons in the sections (for example, temperatures ranging from 230° C. to 900° C., from 240° C. to 400° C. or from 250° C. to 350° C.).
  • Heating the hydrocarbon containing formation with a plurality of heat sources may establish thermal gradients around the heat sources that raise the temperature of hydrocarbons in the formation to desired temperatures at desired heating rates.
  • the rate of temperature increase through the mobilization temperature range and/or the pyrolysis temperature range for desired products may affect the quality and quantity of the formation fluids produced from the hydrocarbon containing formation.
  • Slowly raising the temperature of the formation through the mobilization temperature range and/or pyrolysis temperature range may allow for the production of high quality, high API gravity hydrocarbons from the formation.
  • Slowly raising the temperature of the formation through the mobilization temperature range and/or pyrolysis temperature range may allow for the removal of a large amount of the hydrocarbons present in the formation as hydrocarbon product.
  • a portion of the formation is heated to a desired temperature instead of slowly raising the temperature through a temperature range.
  • the desired temperature is 300° C., 325° C., or 350° C. Other temperatures may be selected as the desired temperature.
  • Superposition of heat from heat sources allows the desired temperature to be relatively quickly and efficiently established in the formation.
  • Energy input into the formation from the heat sources may be adjusted to maintain the temperature in the formation substantially at a desired temperature.
  • Mobilization and/or pyrolysis products may be produced from the formation through production wells.
  • the average temperature of one or more sections is raised to mobilization temperatures and hydrocarbons are produced from the production wells.
  • the average temperature of one or more of the sections may be raised to pyrolysis temperatures after production due to mobilization decreases below a selected value.
  • the average temperature of one or more sections may be raised to pyrolysis temperatures without significant production before reaching pyrolysis temperatures.
  • Formation fluids including pyrolysis products may be produced through the production wells.
  • the average temperature of one or more sections may be raised to temperatures sufficient to allow synthesis gas production after mobilization and/or pyrolysis.
  • hydrocarbons may be raised to temperatures sufficient to allow synthesis gas production without significant production before reaching the temperatures sufficient to allow synthesis gas production.
  • synthesis gas may be produced in a temperature range from about 400° C. to about 1200° C., about 500° C. to about 1100° C., or about 550° C. to about 1000° C.
  • a synthesis gas generating fluid for example, steam and/or water
  • Synthesis gas may be produced from production wells.
  • Solution mining removal of volatile hydrocarbons and water, mobilizing hydrocarbons, pyrolyzing hydrocarbons, generating synthesis gas, and/or other processes may be performed during the in situ heat treatment process.
  • some processes may be performed after the in situ heat treatment process.
  • Such processes may include, but are not limited to, recovering heat from treated sections, storing fluids (for example, water and/or hydrocarbons) in previously treated sections, and/or sequestering carbon dioxide in previously treated sections.
  • FIG. 1 depicts a schematic view of an embodiment of a portion of the in situ heat treatment system for treating the hydrocarbon containing formation.
  • the in situ heat treatment system may include barrier wells 200 .
  • Barrier wells are used to form a barrier around a treatment area. The barrier inhibits fluid flow into and/or out of the treatment area.
  • Barrier wells include, but are not limited to, dewatering wells, vacuum wells, capture wells, injection wells, grout wells, freeze wells, or combinations thereof.
  • barrier wells 200 are dewatering wells. Dewatering wells may remove liquid water and/or inhibit liquid water from entering a portion of the formation to be heated, or to the formation being heated.
  • the barrier wells 200 are shown extending only along one side of heat sources 202 , but the barrier wells typically encircle all heat sources 202 used, or to be used, to heat a treatment area of the formation.
  • Heat sources 202 are placed in at least a portion of the formation.
  • Heat sources 202 may include heaters such as insulated conductors, conductor-in-conduit heaters, surface burners, flameless distributed combustors, and/or natural distributed combustors. Heat sources 202 may also include other types of heaters. Heat sources 202 provide heat to at least a portion of the formation to heat hydrocarbons in the formation. Energy may be supplied to heat sources 202 through supply lines 204 .
  • Supply lines 204 may be structurally different depending on the type of heat source or heat sources used to heat the formation.
  • Supply lines 204 for heat sources may transmit electricity for electric heaters, may transport fuel for combustors, or may transport heat exchange fluid that is circulated in the formation.
  • electricity for an in situ heat treatment process may be provided by a nuclear power plant or nuclear power plants. The use of nuclear power may allow for reduction or elimination of carbon dioxide emissions from the in situ heat treatment process.
  • the heat input into the formation may cause expansion of the formation and geomechanical motion.
  • the heat sources may be turned on before, at the same time, or during a dewatering process.
  • Computer simulations may model formation response to heating. The computer simulations may be used to develop a pattern and time sequence for activating heat sources in the formation so that geomechanical motion of the formation does not adversely affect the functionality of heat sources, production wells, and other equipment in the formation.
  • Heating the formation may cause an increase in permeability and/or porosity of the formation. Increases in permeability and/or porosity may result from a reduction of mass in the formation due to vaporization and removal of water, removal of hydrocarbons, and/or creation of fractures. Fluid may flow more easily in the heated portion of the formation because of the increased permeability and/or porosity of the formation. Fluid in the heated portion of the formation may move a considerable distance through the formation because of the increased permeability and/or porosity. The considerable distance may be over 1000 m depending on various factors, such as permeability of the formation, properties of the fluid, temperature of the formation, and pressure gradient allowing movement of the fluid. The ability of fluid to travel considerable distance in the formation allows production wells 206 to be spaced relatively far apart in the formation.
  • Production wells 206 are used to remove formation fluid from the formation.
  • production well 206 includes a heat source.
  • the heat source in the production well may heat one or more portions of the formation at or near the production well.
  • the amount of heat supplied to the formation from the production well per meter of the production well is less than the amount of heat applied to the formation from a heat source that heats the formation per meter of the heat source.
  • Heat applied to the formation from the production well may increase formation permeability adjacent to the production well by vaporizing and removing liquid phase fluid adjacent to the production well and/or by increasing the permeability of the formation adjacent to the production well by formation of macro and/or micro fractures.
  • More than one heat source may be positioned in the production well.
  • a heat source in a lower portion of the production well may be turned off when superposition of heat from adjacent heat sources heats the formation sufficiently to counteract benefits provided by heating the formation with the production well.
  • the heat source in an upper portion of the production well may remain on after the heat source in the lower portion of the production well is deactivated. The heat source in the upper portion of the well may inhibit condensation and reflux of formation fluid.
  • the heat source in production well 206 allows for vapor phase removal of formation fluids from the formation.
  • Providing heating at or through the production well may: (1) inhibit condensation and/or refluxing of production fluid when such production fluid is moving in the production well proximate the overburden, (2) increase heat input into the formation, (3) increase production rate from the production well as compared to a production well without a heat source, (4) inhibit condensation of high carbon number compounds (C6 hydrocarbons and above) in the production well, and/or (5) increase formation permeability at or proximate the production well.
  • C6 hydrocarbons and above high carbon number compounds
  • Subsurface pressure in the formation may correspond to the fluid pressure generated in the formation. As temperatures in the heated portion of the formation increase, the pressure in the heated portion may increase as a result of thermal expansion of in situ fluids, increased fluid generation and vaporization of water. Controlling rate of fluid removal from the formation may allow for control of pressure in the formation. Pressure in the formation may be determined at a number of different locations, such as near or at production wells, near or at heat sources, or at monitor wells.
  • Formation fluid may be produced from the formation when the formation fluid is of a selected quality.
  • the selected quality includes an API gravity of at least about 20°, 30°, or 40°.
  • Inhibiting production until at least some hydrocarbons are mobilized and/or pyrolyzed may increase conversion of heavy hydrocarbons to light hydrocarbons. Inhibiting initial production may minimize the production of heavy hydrocarbons from the formation. Production of substantial amounts of heavy hydrocarbons may require expensive equipment and/or reduce the life of production equipment.
  • hydrocarbons in the formation may be heated to mobilization and/or pyrolysis temperatures before substantial permeability has been generated in the heated portion of the formation.
  • An initial lack of permeability may inhibit the transport of generated fluids to production wells 206 .
  • fluid pressure in the formation may increase proximate heat sources 202 .
  • the increased fluid pressure may be released, monitored, altered, and/or controlled through one or more heat sources 202 .
  • selected heat sources 202 or separate pressure relief wells may include pressure relief valves that allow for removal of some fluid from the formation.
  • pressure generated by expansion of mobilized fluids, pyrolysis fluids or other fluids generated in the formation may be allowed to increase although an open path to production wells 206 or any other pressure sink may not yet exist in the formation.
  • the fluid pressure may be allowed to increase towards a lithostatic pressure.
  • Fractures in the hydrocarbon containing formation may form when the fluid approaches the lithostatic pressure.
  • fractures may form from heat sources 202 to production wells 206 in the heated portion of the formation.
  • the generation of fractures in the heated portion may relieve some of the pressure in the portion.
  • Pressure in the formation may have to be maintained below a selected pressure to inhibit unwanted production, fracturing of the overburden or underburden, and/or coking of hydrocarbons in the formation.
  • pressure in the formation may be varied to alter and/or control a composition of formation fluid produced, to control a percentage of condensable fluid as compared to non-condensable fluid in the formation fluid, and/or to control an API gravity of formation fluid being produced. For example, decreasing pressure may result in production of a larger condensable fluid component.
  • the condensable fluid component may contain a larger percentage of olefins.
  • pressure in the formation may be maintained high enough to promote production of formation fluid with an API gravity of greater than 20°. Maintaining increased pressure in the formation may inhibit formation subsidence during in situ heat treatment. Maintaining increased pressure may reduce or eliminate the need to compress formation fluids at the surface to transport the fluids in collection conduits to treatment facilities.
  • Maintaining increased pressure in a heated portion of the formation may surprisingly allow for production of large quantities of hydrocarbons of increased quality and of relatively low molecular weight. Pressure may be maintained so that formation fluid produced has a minimal amount of compounds above a selected carbon number.
  • the selected carbon number may be at most 25, at most 20, at most 12, or at most 8.
  • Some high carbon number compounds may be entrained in vapor in the formation and may be removed from the formation with the vapor. Maintaining increased pressure in the formation may inhibit entrainment of high carbon number compounds and/or multi-ring hydrocarbon compounds in the vapor.
  • High carbon number compounds and/or multi-ring hydrocarbon compounds may remain in a liquid phase in the formation for significant time periods. The significant time periods may provide sufficient time for the compounds to pyrolyze to form lower carbon number compounds.
  • Generation of relatively low molecular weight hydrocarbons is believed to be due, in part, to autogenous generation and reaction of hydrogen in a portion of the hydrocarbon containing formation.
  • maintaining an increased pressure may force hydrogen generated during pyrolysis into the liquid phase within the formation.
  • Heating the portion to a temperature in a pyrolysis temperature range may pyrolyze hydrocarbons in the formation to generate liquid phase pyrolyzation fluids.
  • the generated liquid phase pyrolyzation fluids components may include double bonds and/or radicals.
  • Hydrogen (H 2 ) in the liquid phase may reduce double bonds of the generated pyrolyzation fluids, thereby reducing a potential for polymerization or formation of long chain compounds from the generated pyrolyzation fluids.
  • H 2 may also neutralize radicals in the generated pyrolyzation fluids.
  • H 2 in the liquid phase may inhibit the generated pyrolyzation fluids from reacting with each other and/or with other compounds in the formation.
  • Formation fluid produced from production wells 206 may be transported through collection piping 208 to treatment facilities 210 .
  • Formation fluids may also be produced from heat sources 202 .
  • fluid may be produced from heat sources 202 to control pressure in the formation adjacent to the heat sources.
  • Fluid produced from heat sources 202 may be transported through tubing or piping to collection piping 208 or the produced fluid may be transported through tubing or piping directly to treatment facilities 210 .
  • Treatment facilities 210 may include separation units, reaction units, upgrading units, fuel cells, turbines, storage vessels, and/or other systems and units for processing produced formation fluids.
  • the treatment facilities may form transportation fuel from at least a portion of the hydrocarbons produced from the formation.
  • the transportation fuel may be jet fuel, such as JP-8.
  • An insulated conductor may be used as an electric heater element of a heater or a heat source.
  • the insulated conductor may include an inner electrical conductor (core) surrounded by an electrical insulator and an outer electrical conductor (jacket).
  • the electrical insulator may include mineral insulation (for example, magnesium oxide) or other electrical insulation.
  • the insulated conductor is placed in an opening in a hydrocarbon containing formation. In some embodiments, the insulated conductor is placed in an uncased opening in the hydrocarbon containing formation. Placing the insulated conductor in an uncased opening in the hydrocarbon containing formation may allow heat transfer from the insulated conductor to the formation by radiation as well as conduction. Using an uncased opening may facilitate retrieval of the insulated conductor from the well, if necessary.
  • an insulated conductor is placed within a casing in the formation; may be cemented within the formation; or may be packed in an opening with sand, gravel, or other fill material.
  • the insulated conductor may be supported on a support member positioned within the opening.
  • the support member may be a cable, rod, or a conduit (for example, a pipe).
  • the support member may be made of a metal, ceramic, inorganic material, or combinations thereof. Because portions of a support member may be exposed to formation fluids and heat during use, the support member may be chemically resistant and/or thermally resistant.
  • Ties, spot welds, and/or other types of connectors may be used to couple the insulated conductor to the support member at various locations along a length of the insulated conductor.
  • the support member may be attached to a wellhead at an upper surface of the formation.
  • the insulated conductor has sufficient structural strength such that a support member is not needed.
  • the insulated conductor may, in many instances, have at least some flexibility to inhibit thermal expansion damage when undergoing temperature changes.
  • insulated conductors are placed in wellbores without support members and/or centralizers.
  • An insulated conductor without support members and/or centralizers may have a suitable combination of temperature and corrosion resistance, creep strength, length, thickness (diameter), and metallurgy that will inhibit failure of the insulated conductor during use.
  • FIG. 2 depicts a perspective view of an end portion of an embodiment of insulated conductor 252 .
  • Insulated conductor 252 may have any desired cross-sectional shape such as, but not limited to, round (depicted in FIG. 2 ), triangular, ellipsoidal, rectangular, hexagonal, or irregular.
  • insulated conductor 252 includes core 218 , electrical insulator 214 , and jacket 216 .
  • Core 218 may resistively heat when an electrical current passes through the core. Alternating or time-varying current and/or direct current may be used to provide power to core 218 such that the core resistively heats.
  • electrical insulator 214 inhibits current leakage and arcing to jacket 216 .
  • Electrical insulator 214 may thermally conduct heat generated in core 218 to jacket 216 .
  • Jacket 216 may radiate or conduct heat to the formation.
  • insulated conductor 252 is 1000 m or more in length. Longer or shorter insulated conductors may also be used to meet specific application needs. The dimensions of core 218 , electrical insulator 214 , and jacket 216 of insulated conductor 252 may be selected such that the insulated conductor has enough strength to be self supporting even at upper working temperature limits.
  • Such insulated conductors may be suspended from wellheads or supports positioned near an interface between an overburden and a hydrocarbon containing formation without the need for support members extending into the hydrocarbon containing formation along with the insulated conductors.
  • Insulated conductor 252 may be designed to operate at power levels of up to about 1650 watts/meter or higher. In certain embodiments, insulated conductor 252 operates at a power level between about 500 watts/meter and about 1150 watts/meter when heating a formation. Insulated conductor 252 may be designed so that a maximum voltage level at a typical operating temperature does not cause substantial thermal and/or electrical breakdown of electrical insulator 214 . Insulated conductor 252 may be designed such that jacket 216 does not exceed a temperature that will result in a significant reduction in corrosion resistance properties of the jacket material. In certain embodiments, insulated conductor 252 may be designed to reach temperatures within a range between about 650° C. and about 900° C. Insulated conductors having other operating ranges may be formed to meet specific operational requirements.
  • FIG. 2 depicts insulated conductor 252 having a single core 218 .
  • insulated conductor 252 has two or more cores 218 .
  • a single insulated conductor may have three cores.
  • Core 218 may be made of metal or another electrically conductive material. The material used to form core 218 may include, but not be limited to, nichrome, copper, nickel, carbon steel, stainless steel, and combinations thereof.
  • core 218 is chosen to have a diameter and a resistivity at operating temperatures such that its resistance, as derived from Ohm's law, makes it electrically and structurally stable for the chosen power dissipation per meter, the length of the heater, and/or the maximum voltage allowed for the core material.
  • core 218 is made of different materials along a length of insulated conductor 252 .
  • a first section of core 218 may be made of a material that has a significantly lower resistance than a second section of the core.
  • the first section may be placed adjacent to a formation layer that does not need to be heated to as high a temperature as a second formation layer that is adjacent to the second section.
  • the resistivity of various sections of core 218 may be adjusted by having a variable diameter and/or by having core sections made of different materials.
  • Electrical insulator 214 may be made of a variety of materials. Commonly used powders may include, but are not limited to, MgO, Al 2 O 3 , BN, Si 3 N 4 , Zirconia, BeO, different chemical variations of Spinels, and combinations thereof. MgO may provide good thermal conductivity and electrical insulation properties. The desired electrical insulation properties include low leakage current and high dielectric strength. A low leakage current decreases the possibility of thermal breakdown and the high dielectric strength decreases the possibility of arcing across the insulator. Thermal breakdown can occur if the leakage current causes a progressive rise in the temperature of the insulator leading also to arcing across the insulator.
  • Jacket 216 may be an outer metallic layer or electrically conductive layer. Jacket 216 may be in contact with hot formation fluids. Jacket 216 may be made of material having a high resistance to corrosion at elevated temperatures. Alloys that may be used in a desired operating temperature range of jacket 216 include, but are not limited to, 304 stainless steel, 310 stainless steel, Incoloy® 800, and Inconel® 600 (Inco Alloys International, Huntington, W. Va., U.S.A.). The thickness of jacket 216 may have to be sufficient to last for three to ten years in a hot and corrosive environment. A thickness of jacket 216 may generally vary between about 1 mm and about 2.5 mm.
  • jacket 216 For example, a 1.3 mm thick, 310 stainless steel outer layer may be used as jacket 216 to provide good chemical resistance to sulfidation corrosion in a heated zone of a formation for a period of over 3 years. Larger or smaller jacket thicknesses may be used to meet specific application requirements.
  • One or more insulated conductors may be placed within an opening in a formation to form a heat source or heat sources. Electrical current may be passed through each insulated conductor in the opening to heat the formation. Alternatively, electrical current may be passed through selected insulated conductors in an opening. The unused conductors may be used as backup heaters. Insulated conductors may be electrically coupled to a power source in any convenient manner. Each end of an insulated conductor may be coupled to lead-in cables that pass through a wellhead. Such a configuration typically has a 180° bend (a “hairpin” bend) or turn located near a bottom of the heat source.
  • An insulated conductor that includes a 180° bend or turn may not require a bottom termination, but the 180° bend or turn may be an electrical and/or structural weakness in the heater.
  • Insulated conductors may be electrically coupled together in series, in parallel, or in series and parallel combinations.
  • electrical current may pass into the conductor of an insulated conductor and may be returned through the jacket of the insulated conductor by connecting core 218 to jacket 216 (shown in FIG. 2 ) at the bottom of the heat source.
  • three insulated conductors 252 are electrically coupled in a 3-phase wye configuration to a power supply.
  • FIG. 3 depicts an embodiment of three insulated conductors in an opening in a subsurface formation coupled in a wye configuration.
  • FIG. 4 depicts an embodiment of three insulated conductors 252 that are removable from opening 238 in the formation.
  • No bottom connection may be required for three insulated conductors in a wye configuration.
  • all three insulated conductors of the wye configuration may be connected together near the bottom of the opening.
  • the connection may be made directly at ends of heating sections of the insulated conductors or at ends of cold pins (less resistive sections) coupled to the heating sections at the bottom of the insulated conductors.
  • the bottom connections may be made with insulator filled and sealed canisters or with epoxy filled canisters.
  • the insulator may be the same composition as the insulator used as the electrical insulation.
  • Three insulated conductors 252 depicted in FIGS. 3 and 4 may be coupled to support member 220 using centralizers 222 .
  • insulated conductors 252 may be strapped directly to support member 220 using metal straps.
  • Centralizers 222 may maintain a location and/or inhibit movement of insulated conductors 252 on support member 220 .
  • Centralizers 222 may be made of metal, ceramic, or combinations thereof. The metal may be stainless steel or any other type of metal able to withstand a corrosive and high temperature environment.
  • centralizers 222 are bowed metal strips welded to the support member at distances less than about 6 m.
  • a ceramic used in centralizer 222 may be, but is not limited to, Al 2 O 3 , MgO, or another electrical insulator.
  • Centralizers 222 may maintain a location of insulated conductors 252 on support member 220 such that movement of insulated conductors is inhibited at operating temperatures of the insulated conductors.
  • Insulated conductors 252 may also be somewhat flexible to withstand expansion of support member 220 during heating.
  • Support member 220 , insulated conductor 252 , and centralizers 222 may be placed in opening 238 in hydrocarbon layer 240 .
  • Insulated conductors 252 may be coupled to bottom conductor junction 224 using cold pin 226 .
  • Bottom conductor junction 224 may electrically couple each insulated conductor 252 to each other.
  • Bottom conductor junction 224 may include materials that are electrically conducting and do not melt at temperatures found in opening 238 .
  • Cold pin 226 may be an insulated conductor having lower electrical resistance than insulated conductor 252 .
  • Lead-in conductor 228 may be coupled to wellhead 242 to provide electrical power to insulated conductor 252 .
  • Lead-in conductor 228 may be made of a relatively low electrical resistance conductor such that relatively little heat is generated from electrical current passing through the lead-in conductor.
  • the lead-in conductor is a rubber or polymer insulated stranded copper wire.
  • the lead-in conductor is a mineral insulated conductor with a copper core.
  • Lead-in conductor 228 may couple to wellhead 242 at surface 250 through a sealing flange located between overburden 246 and surface 250 . The sealing flange may inhibit fluid from escaping from opening 238 to surface 250 .
  • transition conductor 230 is coupled to insulated conductor 252 using transition conductor 230 .
  • Transition conductor 230 may be a less resistive portion of insulated conductor 252 .
  • Transition conductor 230 may be referred to as “cold pin” of insulated conductor 252 .
  • Transition conductor 230 may be designed to dissipate about one-tenth to about one-fifth of the power per unit length as is dissipated in a unit length of the primary heating section of insulated conductor 252 .
  • Transition conductor 230 may typically be between about 1.5 m and about 15 m, although shorter or longer lengths may be used to accommodate specific application needs.
  • the conductor of transition conductor 230 is copper.
  • the electrical insulator of transition conductor 230 may be the same type of electrical insulator used in the primary heating section.
  • a jacket of transition conductor 230 may be made of corrosion resistant material.
  • transition conductor 230 is coupled to lead-in conductor 228 by a splice or other coupling joint.
  • Splices may also be used to couple transition conductor 230 to insulated conductor 252 .
  • Splices may have to withstand a temperature equal to half of a target zone operating temperature. Density of electrical insulation in the splice should in many instances be high enough to withstand the required temperature and the operating voltage.
  • packing material 248 is placed between overburden casing 244 and opening 238 .
  • reinforcing material 232 may secure overburden casing 244 to overburden 246 .
  • Packing material 248 may inhibit fluid from flowing from opening 238 to surface 250 .
  • Reinforcing material 232 may include, for example, Class G or Class H Portland cement mixed with silica flour for improved high temperature performance, slag or silica flour, and/or a mixture thereof.
  • reinforcing material 232 extends radially a width of from about 5 cm to about 25 cm.
  • support member 220 and lead-in conductor 228 may be coupled to wellhead 242 at surface 250 of the formation.
  • Surface conductor 234 may enclose reinforcing material 232 and couple to wellhead 242 .
  • Embodiments of surface conductors may extend to depths of approximately 3 m to approximately 515 m into an opening in the formation. Alternatively, the surface conductor may extend to a depth of approximately 9 m into the formation.
  • Electrical current may be supplied from a power source to insulated conductor 252 to generate heat due to the electrical resistance of the insulated conductor. Heat generated from three insulated conductors 252 may transfer within opening 238 to heat at least a portion of hydrocarbon layer 240 .
  • Heat generated by insulated conductors 252 may heat at least a portion of a hydrocarbon containing formation.
  • heat is transferred to the formation substantially by radiation of the generated heat to the formation. Some heat may be transferred by conduction or convection of heat due to gases present in the opening.
  • the opening may be an uncased opening, as shown in FIGS. 3 and 4 .
  • An uncased opening eliminates cost associated with thermally cementing the heater to the formation, costs associated with a casing, and/or costs of packing a heater within an opening.
  • heat transfer by radiation is typically more efficient than by conduction, so the heaters may be operated at lower temperatures in an open wellbore. Conductive heat transfer during initial operation of a heat source may be enhanced by the addition of a gas in the opening.
  • the gas may be maintained at a pressure up to about 27 bars absolute.
  • the gas may include, but is not limited to, carbon dioxide and/or helium.
  • An insulated conductor heater in an open wellbore may advantageously be free to expand or contract to accommodate thermal expansion and contraction.
  • An insulated conductor heater may advantageously be removable or redeployable from an open wellbore.
  • an insulated conductor heater assembly is installed or removed using a spooling assembly. More than one spooling assembly may be used to install both the insulated conductor and a support member simultaneously. Alternatively, the support member may be installed using a coiled tubing unit. The heaters may be un-spooled and connected to the support as the support is inserted into the well. The electric heater and the support member may be un-spooled from the spooling assemblies. Spacers may be coupled to the support member and the heater along a length of the support member. Additional spooling assemblies may be used for additional electric heater elements.
  • Temperature limited heaters may be in configurations and/or may include materials that provide automatic temperature limiting properties for the heater at certain temperatures.
  • ferromagnetic materials are used in temperature limited heaters. Ferromagnetic material may self-limit temperature at or near the Curie temperature of the material and/or the phase transformation temperature range to provide a reduced amount of heat when a time-varying current is applied to the material.
  • the ferromagnetic material self-limits temperature of the temperature limited heater at a selected temperature that is approximately the Curie temperature and/or in the phase transformation temperature range. In certain embodiments, the selected temperature is within about 35° C., within about 25° C., within about 20° C., or within about 10° C.
  • ferromagnetic materials are coupled with other materials (for example, highly conductive materials, high strength materials, corrosion resistant materials, or combinations thereof) to provide various electrical and/or mechanical properties.
  • Some parts of the temperature limited heater may have a lower resistance (caused by different geometries and/or by using different ferromagnetic and/or non-ferromagnetic materials) than other parts of the temperature limited heater. Having parts of the temperature limited heater with various materials and/or dimensions allows for tailoring the desired heat output from each part of the heater.
  • Temperature limited heaters may be more reliable than other heaters. Temperature limited heaters may be less apt to break down or fail due to hot spots in the formation. In some embodiments, temperature limited heaters allow for substantially uniform heating of the formation. In some embodiments, temperature limited heaters are able to heat the formation more efficiently by operating at a higher average heat output along the entire length of the heater. The temperature limited heater operates at the higher average heat output along the entire length of the heater because power to the heater does not have to be reduced to the entire heater, as is the case with typical constant wattage heaters, if a temperature along any point of the heater exceeds, or is about to exceed, a maximum operating temperature of the heater.
  • Heat output from portions of a temperature limited heater approaching a Curie temperature and/or the phase transformation temperature range of the heater automatically reduces without controlled adjustment of the time-varying current applied to the heater.
  • the heat output automatically reduces due to changes in electrical properties (for example, electrical resistance) of portions of the temperature limited heater. Thus, more power is supplied by the temperature limited heater during a greater portion of a heating process.
  • the system including temperature limited heaters initially provides a first heat output and then provides a reduced (second) heat output, near, at, or above the Curie temperature and/or the phase transformation temperature range of an electrically resistive portion of the heater when the temperature limited heater is energized by a time-varying current.
  • the first heat output is the heat output at temperatures below which the temperature limited heater begins to self-limit. In some embodiments, the first heat output is the heat output at a temperature about 50° C., about 75° C., about 100° C., or about 125° C. below the Curie temperature and/or the phase transformation temperature range of the ferromagnetic material in the temperature limited heater.
  • the temperature limited heater may be energized by time-varying current (alternating current or modulated direct current) supplied at the wellhead.
  • the wellhead may include a power source and other components (for example, modulation components, transformers, and/or capacitors) used in supplying power to the temperature limited heater.
  • the temperature limited heater may be one of many heaters used to heat a portion of the formation.
  • a relatively thin conductive layer is used to provide the majority of the electrically resistive heat output of the temperature limited heater at temperatures up to a temperature at or near the Curie temperature and/or the phase transformation temperature range of the ferromagnetic conductor.
  • a temperature limited heater may be used as the heating member in an insulated conductor heater.
  • the heating member of the insulated conductor heater may be located inside a sheath with an insulation layer between the sheath and the heating member.
  • FIGS. 5A and 5B depict cross-sectional representations of an embodiment of the insulated conductor heater with the temperature limited heater as the heating member.
  • Insulated conductor 252 includes core 218 , ferromagnetic conductor 236 , inner conductor 212 , electrical insulator 214 , and jacket 216 .
  • Core 218 is a copper core.
  • Ferromagnetic conductor 236 is, for example, iron or an iron alloy.
  • Inner conductor 212 is a relatively thin conductive layer of non-ferromagnetic material with a higher electrical conductivity than ferromagnetic conductor 236 .
  • inner conductor 212 is copper.
  • Inner conductor 212 may be a copper alloy. Copper alloys typically have a flatter resistance versus temperature profile than pure copper. A flatter resistance versus temperature profile may provide less variation in the heat output as a function of temperature up to the Curie temperature and/or the phase transformation temperature range.
  • inner conductor 212 is copper with 6% by weight nickel (for example, CuNi6 or LOHMTM).
  • inner conductor 212 is CuNi10Fe1Mn alloy.
  • inner conductor 212 provides the majority of the resistive heat output of insulated conductor 252 below the Curie temperature and/or the phase transformation temperature range.
  • inner conductor 212 is dimensioned, along with core 218 and ferromagnetic conductor 236 , so that the inner conductor provides a desired amount of heat output and a desired turndown ratio.
  • inner conductor 212 may have a cross-sectional area that is around 2 or 3 times less than the cross-sectional area of core 218 .
  • inner conductor 212 has to have a relatively small cross-sectional area to provide a desired heat output if the inner conductor is copper or copper alloy.
  • core 218 has a diameter of 0.66 cm
  • ferromagnetic conductor 236 has an outside diameter of 0.91 cm
  • inner conductor 212 has an outside diameter of 1.03 cm
  • electrical insulator 214 has an outside diameter of 1.53 cm
  • jacket 216 has an outside diameter of 1.79 cm.
  • core 218 has a diameter of 0.66 cm
  • ferromagnetic conductor 236 has an outside diameter of 0.91 cm
  • inner conductor 212 has an outside diameter of 1.12 cm
  • electrical insulator 214 has an outside diameter of 1.63 cm
  • jacket 216 has an outside diameter of 1.88 cm.
  • Such insulated conductors are typically smaller and cheaper to manufacture than insulated conductors that do not use the thin inner conductor to provide the majority of heat output below the Curie temperature and/or the phase transformation temperature range.
  • Electrical insulator 214 may be magnesium oxide, aluminum oxide, silicon dioxide, beryllium oxide, boron nitride, silicon nitride, or combinations thereof. In certain embodiments, electrical insulator 214 is a compacted powder of magnesium oxide. In some embodiments, electrical insulator 214 includes beads of silicon nitride.
  • a small layer of material is placed between electrical insulator 214 and inner conductor 212 to inhibit copper from migrating into the electrical insulator at higher temperatures.
  • a small layer of nickel for example, about 0.5 mm of nickel may be placed between electrical insulator 214 and inner conductor 212 .
  • Jacket 216 is made of a corrosion resistant material such as, but not limited to, 347 stainless steel, 347H stainless steel, 446 stainless steel, or 825 stainless steel. In some embodiments, jacket 216 provides some mechanical strength for insulated conductor 252 at or above the Curie temperature and/or the phase transformation temperature range of ferromagnetic conductor 236 . In certain embodiments, jacket 216 is not used to conduct electrical current.
  • Insulated conductors include insulated conductor used as heaters and/or insulated conductors used in the overburden section of the formation (insulated conductors that provide little or no heat output). Insulated conductors may be, for example, mineral insulated conductors such as mineral insulated cables.
  • the jacket of the insulated conductor starts as a strip of electrically conducting material (for example, stainless steel).
  • the jacket strip is formed (longitudinally rolled) into a partial cylindrical shape and electrical insulator blocks (for example, magnesium oxide blocks) are inserted into the partially cylindrical jacket.
  • the inserted blocks may be partial cylinder blocks such as half-cylinder blocks.
  • the longitudinal core which is typically a solid cylinder, is placed in the partial cylinder and inside the half-cylinder blocks.
  • the core is made of electrically conducting material such as copper, nickel, and/or steel.
  • the portion of the jacket containing the blocks and the core may be formed into a complete cylinder around the blocks and the core.
  • the longitudinal edges of the jacket that close the cylinder may be welded to form an insulated conductor assembly with the core and electrical insulator blocks inside the jacket.
  • the process of inserting the blocks and closing the jacket cylinder may be repeated along a length of jacket to form the insulated conductor assembly in a desired length.
  • the insulated conductor assembly may be moved through a progressive reduction system (cold working system) to reduce gaps in the assembly.
  • a progressive reduction system is a roller system.
  • the insulated conductor assembly may progress through multiple horizontal and vertical rollers with the assembly alternating between horizontal and vertical rollers.
  • the rollers may progressively reduce the size of the insulated conductor assembly into the final, desired outside diameter or cross-sectional area (for example, the outside diameter or cross-sectional area of the outer electrical conductor (such as a sheath or jacket)).
  • the insulated conductor assembly is heat-treated and/or annealed between reduction steps. Heat treatment of the insulated conductor assembly may be needed to regain mechanical properties of the metal(s) used in the insulated conductor assembly to allow for further reduction (cold working) of the insulated conductor assembly.
  • the insulated conductor assembly may be heat treated and/or annealed to reduce stresses in metal in the assembly and improve the cold working (progressive reduction) properties of the metal.
  • Heat treatment of the insulated conductor assembly typically reduces the dielectric breakdown voltage (dielectric strength) of the insulated conductor assembly.
  • heat treatment may reduce the breakdown voltage by about 50% or more for typical heat treatments of metals used in the insulated conductor assembly.
  • Such reductions in the breakdown voltage may produce shorts or other electrical breakdowns when the insulated conductor assembly is used at the medium to high voltages needed for long length heaters (for example, voltages of about 5 kV or higher).
  • a final reduction (cold working) of the insulated conductor assembly after heat treatment may restore breakdown voltages to acceptable values for long length heaters.
  • the final reduction may not be as large a reduction as previous reductions of the insulated conductor assembly to avoid straining or over-straining the metal in the assembly beyond acceptable limits. Too much reduction in the final reduction may result in an additional heat treatment being needed to restore mechanical properties to the metals in the insulated conductor assembly.
  • FIG. 6 depicts an embodiment of pre-cold worked, pre-heat treated insulated conductor 252 .
  • insulated conductor includes core 218 , electrical insulator 214 , and jacket 216 (for example, sheath or outer electrical conductor).
  • electrical insulator 214 is made from a plurality of blocks of insulating material.
  • insulated conductor 252 is treated in a cold working/heat treating process prior to a final reduction of the insulated conductor to its final dimensions.
  • the insulated conductor assembly may be cold worked to reduce the cross-sectional area of the assembly by at least about 30% followed by a heat treatment step at a temperature of at least about 870° C.
  • FIG. 7 depicts an embodiment of insulated conductor 252 depicted in FIG. 6 after cold working and heat treating.
  • Cold working and heat treating insulated conductor 252 may reduce the cross-sectional area of jacket 216 by about 30% as compared to jacket 216 of the pre-cold worked, pre-heat treated insulated conductor.
  • the cross-sectional area of electrical insulator 214 and/or core 218 is reduced by about 30% during the cold working and heat treating process.
  • the insulated conductor assembly is cold worked to reduce the cross-sectional area of the assembly up to about 35% or close to a mechanical failure point of the insulated conductor assembly.
  • the insulated conductor assembly is heat treated and/or annealed at temperatures between about 760° C. and about 925° C. (for example, temperatures that restore as much mechanical integrity as possible to metals in the insulated conductor assembly without melting the electrical insulation in the assembly).
  • the heat treating step includes rapidly heating the insulated conductor assembly to the desired temperature and then quenching the assembly back to ambient temperature.
  • the cold working/heat treating steps are repeated two or more times until the cross-sectional area of the insulated conductor assembly is close to (for example, within about 5% to about 15%) of the desired, final cross-sectional area of the assembly.
  • the assembly is cold worked, in a final step, to reduce the cross-sectional area of the insulated conductor assembly to the final cross-sectional area.
  • FIG. 8 depicts an embodiment of insulated conductor 252 depicted in FIG. 7 after cold working.
  • the cross-sectional area of the embodiment of jacket 216 in FIG. 8 may be reduced by about 15% as compared to the embodiment of jacket 216 in FIG.
  • the final cold working step reduces the cross-sectional area of the insulated conductor assembly by an amount ranging between about 5% and about 20%. In some embodiments, the final cold working step reduces the cross-sectional area of the insulated conductor assembly by an amount ranging between about 10% and about 20%. In some embodiments, the cross-sectional area of electrical insulator 214 and/or core 218 , is reduced during the cold working and heat treating process.
  • Limiting the reduction in the cross-sectional area of the insulated conductor assembly to at most about 20% during the final cold working step reduces the cross-sectional area of the insulated conductor assembly to the desired value while maintaining sufficient mechanical integrity in the jacket (outer conductor) of the insulated conductor assembly for use in heating a subsurface formation.
  • the need for further heat treatment to restore mechanical integrity of the insulated conductor assembly is eliminated or substantially reduced.
  • Reducing the cross-sectional area of the insulated conductor assembly by more than about 20% during the final cold working step may require further heat treatment to return mechanical integrity to the insulated conductor assembly sufficient for use as a long heater in a subsurface formation.
  • having cold working being the final step in the process of making the insulated conductor assembly instead of heat treatment and/or heat treating improves the dielectric breakdown voltage of the insulated conductor assembly.
  • Cold working (reducing the cross-sectional area) of the insulated conductor assembly reduces pore volumes and/or porosity in the electrical insulation of the assembly. Reducing the pore volumes and/or porosity in the electrical insulation increases the breakdown voltage by eliminating pathways for electrical shorts and/or failures in the electrical insulation.
  • having the cold working being the final step instead of heat treatment which typically reduces the breakdown voltage
  • higher breakdown voltage insulated conductor assemblies can be produced using a final cold working step that reduces the cross-sectional area up to at most about 20%.
  • the breakdown voltage after the final cold working step approaches the breakdown voltage (dielectric strength) of the pre-heat treated insulated conductor assembly.
  • the dielectric strength of electrical insulation in the insulated conductor assembly after the final cold working step is within about 10%, within about 5%, or within about 2% of the dielectric strength of the electrical insulation in the pre-heat treated insulated conductor.
  • the breakdown voltage of the insulated conductor assembly is between about 12 kV and about 20 kV.
  • Insulated conductor assemblies with such good breakdown voltage properties may be smaller in diameter (cross-sectional area) and provide the same output as insulated conductor assemblies with lower breakdown voltages for heating similar lengths in a subsurface formation. Because the higher breakdown voltage allows the diameter of the insulated conductor assembly to be smaller, less insulating blocks may be used to make a heater of the same length as the insulating blocks are elongated further (take up more length) when compressed to the smaller diameter. Thus, the number of blocks used to make up the insulated conductor assembly may be reduced, thereby saving material costs for electrical insulation.
  • insulated conductors in relatively long lengths (for example, lengths of 10 m or longer) is to manufacture the electrical insulator from a powder based material.
  • mineral insulated conductors such as magnesium oxide (MgO) insulated conductors
  • MgO magnesium oxide
  • Previous attempts to form insulated conductors using electrical insulator powder were largely unsuccessful due to problems associated with powder flow, conductor (core) centralization, and interaction with the powder (for example, MgO powder) during the weld process for the outer sheath or jacket.
  • New developments in powder handling technology may allow for improvements in making insulated conductors with the powder. Producing insulated conductors from powder insulation may reduce material costs and provide increased manufacturing reliability compared to other methods for making insulated conductors.
  • FIG. 9 depicts an embodiment of a process for manufacturing an insulated conductor using a powder for the electrical insulator.
  • process 268 is performed in a tube mill or other tube (pipe) assembly facility.
  • process 268 begins with spool 270 and spool 272 feeding first sheath material 274 and conductor (core) material 276 , respectively, into the process flow line.
  • first sheath material 274 is thin sheath material such as stainless steel and core material 276 is copper rod or another conductive material used for the core.
  • First sheath material 274 and core material 276 may pass through centralizing rolls 278 . Centralizing rolls 278 may center core material 276 over first sheath material 274 , as shown in FIG. 9 .
  • Centralized core material 276 and first sheath material 274 may later pass into compression and centralization rolls 280 .
  • Compression and centralization rolls 280 may form first sheath material 274 into a tubular around core material 276 .
  • first sheath material 274 may begin to form into the tubular before reaching compression and centralization rolls 280 because of the pressure from sheath forming rolls 281 on the upstream portion of the first sheath material.
  • electrical insulator powder 282 may be added inside the first sheath material from powder dispenser 284 .
  • powder 282 is heated before entering first sheath material 274 by heater 286 .
  • Heater 286 may be, for example, an induction heater that heats powder 282 to release moisture from the powder and/or provide better flow properties in the powder and dielectric properties of the final assembled conductor.
  • the assembly may pass through vibrator 288 before entering compression and centralization rolls 280 .
  • Vibrator 288 may vibrate the assembly to increase compaction of powder 282 inside first sheath material 274 .
  • the filling of powder 282 into first sheath material 274 and other process steps upstream of vibrator 288 occur in a vertical formation. Performing such process steps in the vertical formation provides better compaction of powder 282 inside first sheath material 274 .
  • the vertical formation of process 268 may transition to a horizontal formation while the assembly passes through compression and centralization rolls 280 .
  • second sheath material 290 may be provided around the assembly.
  • Second sheath material 290 may be provided from spool 292 .
  • Second sheath material 290 may be thicker sheath material than first sheath material 274 .
  • first sheath material 274 has a thickness as thin as is permitted without the first sheath material breaking or causing defects later in the process (for example, during reduction of the outer diameter of the insulated conductor).
  • Second sheath material 290 may have a thickness as thick as possible that still allows for the final reduction of the outside diameter of the insulated conductor to the desired dimension.
  • the combined thickness of first sheath material 274 and second sheath material 290 may be, for example, between about 1 ⁇ 3 and about 1 ⁇ 8 (for example, about 1 ⁇ 6) of the final outside diameter of the insulated conductor.
  • first sheath material 274 has a thickness between about 0.020′′ and about 0.075′′ (for example, about 0.035′′) and second sheath material 290 has a thickness between about 0.100′′ and about 0.150′′ (for example, about 0.125′′) for an insulated conductor that has a final outside diameter of about 1′′ after the final reduction step.
  • second sheath material 290 is the same material as first sheath material 274 .
  • second sheath material 290 is a different material (for example, a different stainless steel or nickel based alloy) than first sheath material 274 .
  • Second sheath material 290 may be formed into a tubular around the assembly of first sheath material 274 , core material 276 , and powder 282 by forming rolls 294 . After forming second sheath material 290 into the tubular, the longitudinal edges of the second sheath material may be welded together using welder 296 .
  • Welder 296 may be, for example, a laser welder for welding stainless steel. Welding of second sheath material 290 forms the assembly into insulated conductor 252 with first sheath material 274 and the second sheath material forming the sheath (jacket) of the insulated conductor.
  • the insulated conductor is passed through one or more reduction rolls 298 .
  • Reduction rolls 298 may reduce the outside diameter of insulated conductor 252 by up to about 35% by cold working on the sheath (first sheath material 274 and second sheath material 290 ) and the core (core material 276 ).
  • the insulated conductor may be heat treated by heater 300 and quenched in quencher 302 .
  • Heater 300 may be, for example, an induction heater.
  • Quencher 302 may use, for example, water quenching to quickly cool insulated conductor 252 .
  • reduction of the outside diameter of insulated conductor 252 followed by heat treating and quenching can be repeated one or more times before the insulated conductor is provided to reduction rolls 304 for a final reduction step.
  • the insulated conductor is passed through reduction rolls 304 for the final reduction step (the final cold working step).
  • the final reduction step may reduce the outside diameter (cross-sectional area) of insulated conductor 252 to between about 5% and about 20% of the cross section prior to the final reduction step.
  • the final reduced insulated conductor 252 may then be provided to spool 306 .
  • Spool 306 may be, for example, a coiled tubing rig or other spool used for transporting insulated conductors (heaters) to a heater assembly location.
  • first sheath material 274 may protect powder 282 from interacting with the weld on second sheath material 290 .
  • the design of first sheath material 274 inhibits interaction between powder 282 and the weld on second sheath material 290 .
  • FIGS. 10 and 11 depict cross-sectional representations of two possible embodiments for designs of first sheath material 274 used in insulated conductor 252 .
  • FIG. 10A depicts a cross-sectional representation of a first design embodiment of first sheath material 274 inside insulated conductor 252 .
  • FIG. 10A depicts insulated conductor 252 as the insulated conductor passes through compression and centralization rolls 280 , shown in FIG. 9 .
  • first sheath material 274 overlaps itself (shown as overlap 308 ) as the first sheath material is formed into the tubular around powder 282 and core material 276 .
  • Overlap 308 is an overlap between longitudinal edges of first sheath material 274 .
  • FIG. 10B depicts a cross-sectional representation of the first design embodiment with second sheath material 290 formed into the tubular and welded around first sheath material 274 .
  • FIG. 10B depicts insulated conductor 252 immediately after the insulated conductor passes through welder 296 , shown in FIG. 9 .
  • first sheath material 274 rests inside the tubular formed by second sheath material 290 (for example, there is a gap between the upper portions of the sheath materials).
  • Weld 310 joins second sheath material 290 to form the tubular around first sheath material 274 .
  • weld 310 is placed at or near overlap 308 .
  • weld 310 is at a different location than overlap 308 .
  • the location of weld 310 may not be important as first sheath material 274 inhibits interaction between the weld and powder 282 inside the first sheath material.
  • Overlap 308 in first sheath material 274 may seal off powder 282 and inhibit any powder from being in contact with second sheath material 290 and/or weld 310 .
  • FIG. 10C depicts a cross-sectional representation of the first design embodiment with second sheath material 290 formed into the tubular around first sheath material 274 after some reduction.
  • FIG. 10C depicts insulated conductor 252 as the insulated conductor passes through reduction rolls 298 , shown in FIG. 9 .
  • second sheath material 290 is reduced by reduction rolls 298 such that the second sheath material contacts first sheath material 274 .
  • second sheath material 290 is in tight contact with first sheath material 274 after passing through reduction rolls 298 .
  • FIG. 10D depicts a cross-sectional representation of the first design embodiment as insulated conductor 252 passes through the final reduction step at reduction rolls 304 , shown in FIG. 9 .
  • first sheath material 274 and/or second sheath material 290 may provide a sealed corrosion barrier for insulated conductor 252 .
  • FIG. 11A depicts a cross-sectional representation of a second design embodiment of first sheath material 274 inside insulated conductor 252 .
  • FIG. 11A depicts insulated conductor 252 as the insulated conductor passes through compression and centralization rolls 280 , shown in FIG. 9 .
  • first sheath material 274 has gap 312 between the longitudinal edges of the tubular as the first sheath material is formed into the tubular around powder 282 and core material 276 .
  • FIG. 11B depicts a cross-sectional representation of the second design embodiment with second sheath material 290 formed into the tubular and welded around first sheath material 274 .
  • FIG. 11B depicts insulated conductor 252 immediately after the insulated conductor passes through welder 296 , shown in FIG. 9 .
  • first sheath material 274 rests inside the tubular formed by second sheath material 290 (for example, there is a gap between the upper portions of the sheath materials).
  • Weld 310 joins second sheath material 290 to form the tubular around first sheath material 274 .
  • weld 310 is at a different location than gap 312 to avoid interaction between the weld and powder 282 inside first sheath material 274 .
  • FIG. 11C depicts a cross-sectional representation of the second design embodiment with second sheath material 290 formed into the tubular around first sheath material 274 after some reduction.
  • FIG. 11C depicts insulated conductor 252 as the insulated conductor passes through reduction rolls 298 , shown in FIG. 9 .
  • second sheath material 290 is reduced by reduction rolls 298 such that the second sheath material contacts first sheath material 274 .
  • second sheath material 290 is in tight contact with first sheath material 274 after passing through reduction rolls 298 .
  • Gap 312 is reduced during reduction of insulated conductor 252 as the insulated conductor passes through reduction rolls 298 .
  • gap 312 is reduced such that the ends of first sheath material 274 on each side of gap abut each other after the reduction.
  • FIG. 11D depicts a cross-sectional representation of the second design embodiment as insulated conductor 252 passes through the final reduction step at reduction rolls 304 , shown in FIG. 9 .
  • insulated conductor 252 following the final reduction step, may have adequate breakdown voltages for use in heating subsurface formations.

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Abstract

A method for forming an insulated conductor heater includes placing an insulation layer over at least part of an elongated, cylindrical inner electrical conductor. An elongated, cylindrical outer electrical conductor is placed over at least part of the insulation layer to form the insulated conductor heater. One or more cold working/heat treating steps are performed on the insulated conductor heater. The cold working/heat treating steps include: cold working the insulated conductor heater to reduce a cross-sectional area of the insulated conductor heater by at least about 30% and heat treating the insulated conductor heater at a temperature of at least about 870° C. The cross-sectional area of the insulated conductor heater is then reduced by an amount ranging between about 5% and about 20% to a final cross-sectional area.

Description

PRIORITY CLAIM
This patent claims priority to U.S. Provisional Patent Application No. 61/544,797 to Noel et al., entitled “FORMING INSULATED CONDUCTORS USING A FINAL REDUCTION STEP AFTER HEAT TREATING”, filed Oct. 7, 2011, which is incorporated by reference in its entirety.
RELATED PATENTS
This patent application incorporates by reference in its entirety each of U.S. Pat. No. 6,688,387 to Wellington et al.; U.S. Pat. No. 6,991,036 to Sumnu-Dindoruk et al.; U.S. Pat. No. 6,698,515 to Karanikas et al.; U.S. Pat. No. 6,880,633 to Wellington et al.; U.S. Pat. No. 6,782,947 to de Rouffignac et al.; U.S. Pat. No. 6,991,045 to Vinegar et al.; U.S. Pat. No. 7,073,578 to Vinegar et al.; U.S. Pat. No. 7,121,342 to Vinegar et al.; U.S. Pat. No. 7,320,364 to Fairbanks; U.S. Pat. No. 7,527,094 to McKinzie et al.; U.S. Pat. No. 7,584,789 to Mo et al.; U.S. Pat. No. 7,533,719 to Hinson et al.; U.S. Pat. No. 7,562,707 to Miller; and U.S. Pat. No. 7,798,220 to Vinegar et al.; U.S. Patent Application Publication Nos. 2009-0189617 to Burns et al.; 2010-0071903 to Prince-Wright et al.; 2010-0096137 to Nguyen et al.; 2010-0258265 to Karanikas et al.; and 2011-0248018 to Bass et al.
BACKGROUND
1. Field of the Invention
The present invention relates to systems and methods used for heating subsurface formations. More particularly, the invention relates to systems and methods for heating subsurface hydrocarbon containing formations.
2. Description of Related Art
Hydrocarbons obtained from subterranean formations are often used as energy resources, as feedstocks, and as consumer products. Concerns over depletion of available hydrocarbon resources and concerns over declining overall quality of produced hydrocarbons have led to development of processes for more efficient recovery, processing and/or use of available hydrocarbon resources. In situ processes may be used to remove hydrocarbon materials from subterranean formations that were previously inaccessible and/or too expensive to extract using available methods. Chemical and/or physical properties of hydrocarbon material in a subterranean formation may need to be changed to allow hydrocarbon material to be more easily removed from the subterranean formation and/or increase the value of the hydrocarbon material. The chemical and physical changes may include in situ reactions that produce removable fluids, composition changes, solubility changes, density changes, phase changes, and/or viscosity changes of the hydrocarbon material in the formation.
Heaters may be placed in wellbores to heat a formation during an in situ process. There are many different types of heaters which may be used to heat the formation. Examples of in situ processes utilizing downhole heaters are illustrated in U.S. Pat. No. 2,634,961 to Ljungstrom; U.S. Pat. No. 2,732,195 to Ljungstrom; U.S. Pat. No. 2,780,450 to Ljungstrom; U.S. Pat. No. 2,789,805 to Ljungstrom; U.S. Pat. No. 2,923,535 to Ljungstrom; U.S. Pat. No. 4,886,118 to Van Meurs et al.; and U.S. Pat. No. 6,688,387 to Wellington et al.; each of which is incorporated by reference as if fully set forth herein.
Mineral insulated (MI) cables (insulated conductors) for use in subsurface applications, such as heating hydrocarbon containing formations in some applications, are longer, may have larger outside diameters, and may operate at higher voltages and temperatures than what is typical in the MI cable industry. There are many potential problems during manufacture and/or assembly of long length insulated conductors.
For example, there are potential electrical and/or mechanical problems due to degradation over time of the electrical insulator used in the insulated conductor. There are also potential problems with electrical insulators to overcome during assembly of the insulated conductor heater. Problems such as core bulge or other mechanical defects may occur during assembly of the insulated conductor heater. Such occurrences may lead to electrical problems during use of the heater and may potentially render the heater inoperable for its intended purpose.
In addition, there may be problems with increased stress on the insulated conductors during assembly and/or installation into the subsurface of the insulated conductors. For example, winding and unwinding of the insulated conductors on spools used for transport and installation of the insulated conductors may lead to mechanical stress on the electrical insulators and/or other components in the insulated conductors. Thus, more reliable systems and methods are needed to reduce or eliminate potential problems during manufacture, assembly, and/or installation of insulated conductors.
SUMMARY
Embodiments described herein generally relate to systems, methods, and heaters for treating a subsurface formation. Embodiments described herein also generally relate to heaters that have novel components therein. Such heaters can be obtained by using the systems and methods described herein.
In certain embodiments, the invention provides one or more systems, methods, and/or heaters. In some embodiments, the systems, methods, and/or heaters are used for treating a subsurface formation.
In certain embodiments, a method for forming an insulated conductor heater, includes: placing an insulation layer over at least part of an elongated, cylindrical inner electrical conductor; placing an elongated, cylindrical outer electrical conductor over at least part of the insulation layer to form the insulated conductor heater; performing one or more cold working/heat treating steps on the insulated conductor heater, wherein the cold working/heat treating steps includes: cold working the insulated conductor heater to reduce a cross-sectional area of the insulated conductor heater by at least about 30%; and heat treating the insulated conductor heater at a temperature of at least about 870° C.; and reducing the cross-sectional area of the insulated conductor heater by an amount ranging between about 5% and about 15% to a final cross-sectional area.
In certain embodiments, a method for forming an insulated conductor heater, includes: forming a first sheath material into a tubular around a core, wherein longitudinal edges of the first sheath material at least partially overlap along a length of the tubular of the first sheath material; providing an electrical insulator powder into at least part of the tubular of the first sheath material; forming a second sheath material into a tubular around the first sheath material; and reducing an outer diameter of the tubular of the second sheath material into a final diameter of the insulated conductor heater.
In certain embodiments, a method for forming an insulated conductor heater, includes: forming a first sheath material into a tubular around a core, wherein there is a gap between longitudinal edges of the first sheath material along a length of the tubular of the first sheath material; providing an electrical insulator powder into at least part of the tubular of the first sheath material; forming a second sheath material into a tubular around the first sheath material; and reducing an outer diameter of the tubular of the second sheath material into a final diameter of the insulated conductor heater such that the longitudinal edges of the first sheath material are proximate or substantially abut each other along the length of the tubular of the first sheath material.
In further embodiments, features from specific embodiments may be combined with features from other embodiments. For example, features from one embodiment may be combined with features from any of the other embodiments.
In further embodiments, treating a subsurface formation is performed using any of the methods, systems, power supplies, or heaters described herein.
In further embodiments, additional features may be added to the specific embodiments described herein.
BRIEF DESCRIPTION OF THE DRAWINGS
Features and advantages of the methods and apparatus of the present invention will be more fully appreciated by reference to the following detailed description of presently preferred but nonetheless illustrative embodiments in accordance with the present invention when taken in conjunction with the accompanying drawings.
FIG. 1 shows a schematic view of an embodiment of a portion of an in situ heat treatment system for treating a hydrocarbon containing formation.
FIG. 2 depicts an embodiment of an insulated conductor heat source.
FIG. 3 depicts an embodiment of an insulated conductor heat source.
FIG. 4 depicts an embodiment of an insulated conductor heat source.
FIGS. 5A and 5B depict cross-sectional representations of an embodiment of a temperature limited heater component used in an insulated conductor heater.
FIG. 6 depicts a cross-sectional representation of an embodiment of a pre-cold worked, pre-heat treated insulated conductor.
FIG. 7 depicts a cross-sectional representation of an embodiment of the insulated conductor depicted in FIG. 6 after cold working and heat treating.
FIG. 8 depicts a cross-sectional representation of an embodiment of the insulated conductor depicted in FIG. 7 after coldworking.
FIG. 9 depicts an embodiment of a process for manufacturing an insulated conductor using a powder for the electrical insulator.
FIG. 10A depicts a cross-sectional representation of a first design embodiment of a first sheath material inside an insulated conductor.
FIG. 10B depicts a cross-sectional representation of the first design embodiment with a second sheath material formed into a tubular and welded around the first sheath material.
FIG. 10C depicts a cross-sectional representation of the first design embodiment with a second sheath material formed into a tubular around the first sheath material after some reduction.
FIG. 10D depicts a cross-sectional representation of the first design embodiment as the insulated conductor passes through the final reduction step at the reduction rolls.
FIG. 11A depicts a cross-sectional representation of a second design embodiment of a first sheath material inside an insulated conductor.
FIG. 11B depicts a cross-sectional representation of the second design embodiment with a second sheath material formed into a tubular and welded around the first sheath material.
FIG. 11C depicts a cross-sectional representation of the second design embodiment with a second sheath material formed into a tubular around the first sheath material after some reduction.
FIG. 11D depicts a cross-sectional representation of the second design embodiment as the insulated conductor passes through the final reduction step at the reduction rolls.
While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are shown by way of example in the drawings and will herein be described in detail. The drawings may not be to scale. It should be understood that the drawings and detailed description thereto are not intended to limit the invention to the particular form disclosed, but to the contrary, the intention is to cover all modifications, equivalents and alternatives falling within the spirit and scope of the present invention as defined by the appended claims.
DETAILED DESCRIPTION
The following description generally relates to systems and methods for treating hydrocarbons in the formations. Such formations may be treated to yield hydrocarbon products, hydrogen, and other products.
“Alternating current (AC)” refers to a time-varying current that reverses direction substantially sinusoidally. AC produces skin effect electricity flow in a ferromagnetic conductor.
In the context of reduced heat output heating systems, apparatus, and methods, the term “automatically” means such systems, apparatus, and methods function in a certain way without the use of external control (for example, external controllers such as a controller with a temperature sensor and a feedback loop, PID controller, or predictive controller).
“Coupled” means either a direct connection or an indirect connection (for example, one or more intervening connections) between one or more objects or components. The phrase “directly connected” means a direct connection between objects or components such that the objects or components are connected directly to each other so that the objects or components operate in a “point of use” manner.
“Curie temperature” is the temperature above which a ferromagnetic material loses all of its ferromagnetic properties. In addition to losing all of its ferromagnetic properties above the Curie temperature, the ferromagnetic material begins to lose its ferromagnetic properties when an increasing electrical current is passed through the ferromagnetic material.
A “formation” includes one or more hydrocarbon containing layers, one or more non-hydrocarbon layers, an overburden, and/or an underburden. “Hydrocarbon layers” refer to layers in the formation that contain hydrocarbons. The hydrocarbon layers may contain non-hydrocarbon material and hydrocarbon material. The “overburden” and/or the “underburden” include one or more different types of impermeable materials. For example, the overburden and/or underburden may include rock, shale, mudstone, or wet/tight carbonate. In some embodiments of in situ heat treatment processes, the overburden and/or the underburden may include a hydrocarbon containing layer or hydrocarbon containing layers that are relatively impermeable and are not subjected to temperatures during in situ heat treatment processing that result in significant characteristic changes of the hydrocarbon containing layers of the overburden and/or the underburden. For example, the underburden may contain shale or mudstone, but the underburden is not allowed to heat to pyrolysis temperatures during the in situ heat treatment process. In some cases, the overburden and/or the underburden may be somewhat permeable.
“Formation fluids” refer to fluids present in a formation and may include pyrolyzation fluid, synthesis gas, mobilized hydrocarbons, and water (steam). Formation fluids may include hydrocarbon fluids as well as non-hydrocarbon fluids. The term “mobilized fluid” refers to fluids in a hydrocarbon containing formation that are able to flow as a result of thermal treatment of the formation. “Produced fluids” refer to fluids removed from the formation.
“Heat flux” is a flow of energy per unit of area per unit of time (for example, Watts/meter2).
A “heat source” is any system for providing heat to at least a portion of a formation substantially by conductive and/or radiative heat transfer. For example, a heat source may include electrically conducting materials and/or electric heaters such as an insulated conductor, an elongated member, and/or a conductor disposed in a conduit. A heat source may also include systems that generate heat by burning a fuel external to or in a formation. The systems may be surface burners, downhole gas burners, flameless distributed combustors, and natural distributed combustors. In some embodiments, heat provided to or generated in one or more heat sources may be supplied by other sources of energy. The other sources of energy may directly heat a formation, or the energy may be applied to a transfer medium that directly or indirectly heats the formation. It is to be understood that one or more heat sources that are applying heat to a formation may use different sources of energy. Thus, for example, for a given formation some heat sources may supply heat from electrically conducting materials, electric resistance heaters, some heat sources may provide heat from combustion, and some heat sources may provide heat from one or more other energy sources (for example, chemical reactions, solar energy, wind energy, biomass, or other sources of renewable energy). A chemical reaction may include an exothermic reaction (for example, an oxidation reaction). A heat source may also include an electrically conducting material and/or a heater that provides heat to a zone proximate and/or surrounding a heating location such as a heater well.
A “heater” is any system or heat source for generating heat in a well or a near wellbore region. Heaters may be, but are not limited to, electric heaters, burners, combustors that react with material in or produced from a formation, and/or combinations thereof.
“Hydrocarbons” are generally defined as molecules formed primarily by carbon and hydrogen atoms. Hydrocarbons may also include other elements such as, but not limited to, halogens, metallic elements, nitrogen, oxygen, and/or sulfur. Hydrocarbons may be, but are not limited to, kerogen, bitumen, pyrobitumen, oils, natural mineral waxes, and asphaltites. Hydrocarbons may be located in or adjacent to mineral matrices in the earth. Matrices may include, but are not limited to, sedimentary rock, sands, silicilytes, carbonates, diatomites, and other porous media. “Hydrocarbon fluids” are fluids that include hydrocarbons. Hydrocarbon fluids may include, entrain, or be entrained in non-hydrocarbon fluids such as hydrogen, nitrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, water, and ammonia.
An “in situ conversion process” refers to a process of heating a hydrocarbon containing formation from heat sources to raise the temperature of at least a portion of the formation above a pyrolysis temperature so that pyrolyzation fluid is produced in the formation.
An “in situ heat treatment process” refers to a process of heating a hydrocarbon containing formation with heat sources to raise the temperature of at least a portion of the formation above a temperature that results in mobilized fluid, visbreaking, and/or pyrolysis of hydrocarbon containing material so that mobilized fluids, visbroken fluids, and/or pyrolyzation fluids are produced in the formation.
“Insulated conductor” refers to any elongated material that is able to conduct electricity and that is covered, in whole or in part, by an electrically insulating material.
“Modulated direct current (DC)” refers to any substantially non-sinusoidal time-varying current that produces skin effect electricity flow in a ferromagnetic conductor.
“Nitride” refers to a compound of nitrogen and one or more other elements of the Periodic Table. Nitrides include, but are not limited to, silicon nitride, boron nitride, or alumina nitride.
“Perforations” include openings, slits, apertures, or holes in a wall of a conduit, tubular, pipe or other flow pathway that allow flow into or out of the conduit, tubular, pipe or other flow pathway.
“Phase transformation temperature” of a ferromagnetic material refers to a temperature or a temperature range during which the material undergoes a phase change (for example, from ferrite to austenite) that decreases the magnetic permeability of the ferromagnetic material. The reduction in magnetic permeability is similar to reduction in magnetic permeability due to the magnetic transition of the ferromagnetic material at the Curie temperature.
“Pyrolysis” is the breaking of chemical bonds due to the application of heat. For example, pyrolysis may include transforming a compound into one or more other substances by heat alone. Heat may be transferred to a section of the formation to cause pyrolysis.
“Pyrolyzation fluids” or “pyrolysis products” refers to fluid produced substantially during pyrolysis of hydrocarbons. Fluid produced by pyrolysis reactions may mix with other fluids in a formation. The mixture would be considered pyrolyzation fluid or pyrolyzation product. As used herein, “pyrolysis zone” refers to a volume of a formation (for example, a relatively permeable formation such as a tar sands formation) that is reacted or reacting to form a pyrolyzation fluid.
“Superposition of heat” refers to providing heat from two or more heat sources to a selected section of a formation such that the temperature of the formation at least at one location between the heat sources is influenced by the heat sources.
“Temperature limited heater” generally refers to a heater that regulates heat output (for example, reduces heat output) above a specified temperature without the use of external controls such as temperature controllers, power regulators, rectifiers, or other devices. Temperature limited heaters may be AC (alternating current) or modulated (for example, “chopped”) DC (direct current) powered electrical resistance heaters.
“Thickness” of a layer refers to the thickness of a cross section of the layer, wherein the cross section is normal to a face of the layer.
“Time-varying current” refers to electrical current that produces skin effect electricity flow in a ferromagnetic conductor and has a magnitude that varies with time. Time-varying current includes both alternating current (AC) and modulated direct current (DC).
“Turndown ratio” for the temperature limited heater in which current is applied directly to the heater is the ratio of the highest AC or modulated DC resistance below the Curie temperature to the lowest resistance above the Curie temperature for a given current. Turndown ratio for an inductive heater is the ratio of the highest heat output below the Curie temperature to the lowest heat output above the Curie temperature for a given current applied to the heater.
A “u-shaped wellbore” refers to a wellbore that extends from a first opening in the formation, through at least a portion of the formation, and out through a second opening in the formation. In this context, the wellbore may be only roughly in the shape of a “v” or “u”, with the understanding that the “legs” of the “u” do not need to be parallel to each other, or perpendicular to the “bottom” of the “u” for the wellbore to be considered “u-shaped”.
The term “wellbore” refers to a hole in a formation made by drilling or insertion of a conduit into the formation. A wellbore may have a substantially circular cross section, or another cross-sectional shape. As used herein, the terms “well” and “opening,” when referring to an opening in the formation may be used interchangeably with the term “wellbore.”
A formation may be treated in various ways to produce many different products. Different stages or processes may be used to treat the formation during an in situ heat treatment process. In some embodiments, one or more sections of the formation are solution mined to remove soluble minerals from the sections. Solution mining minerals may be performed before, during, and/or after the in situ heat treatment process. In some embodiments, the average temperature of one or more sections being solution mined may be maintained below about 120° C.
In some embodiments, one or more sections of the formation are heated to remove water from the sections and/or to remove methane and other volatile hydrocarbons from the sections. In some embodiments, the average temperature may be raised from ambient temperature to temperatures below about 220° C. during removal of water and volatile hydrocarbons.
In some embodiments, one or more sections of the formation are heated to temperatures that allow for movement and/or visbreaking of hydrocarbons in the formation. In some embodiments, the average temperature of one or more sections of the formation are raised to mobilization temperatures of hydrocarbons in the sections (for example, to temperatures ranging from 100° C. to 250° C., from 120° C. to 240° C., or from 150° C. to 230° C.).
In some embodiments, one or more sections are heated to temperatures that allow for pyrolysis reactions in the formation. In some embodiments, the average temperature of one or more sections of the formation may be raised to pyrolysis temperatures of hydrocarbons in the sections (for example, temperatures ranging from 230° C. to 900° C., from 240° C. to 400° C. or from 250° C. to 350° C.).
Heating the hydrocarbon containing formation with a plurality of heat sources may establish thermal gradients around the heat sources that raise the temperature of hydrocarbons in the formation to desired temperatures at desired heating rates. The rate of temperature increase through the mobilization temperature range and/or the pyrolysis temperature range for desired products may affect the quality and quantity of the formation fluids produced from the hydrocarbon containing formation. Slowly raising the temperature of the formation through the mobilization temperature range and/or pyrolysis temperature range may allow for the production of high quality, high API gravity hydrocarbons from the formation. Slowly raising the temperature of the formation through the mobilization temperature range and/or pyrolysis temperature range may allow for the removal of a large amount of the hydrocarbons present in the formation as hydrocarbon product.
In some in situ heat treatment embodiments, a portion of the formation is heated to a desired temperature instead of slowly raising the temperature through a temperature range. In some embodiments, the desired temperature is 300° C., 325° C., or 350° C. Other temperatures may be selected as the desired temperature.
Superposition of heat from heat sources allows the desired temperature to be relatively quickly and efficiently established in the formation. Energy input into the formation from the heat sources may be adjusted to maintain the temperature in the formation substantially at a desired temperature.
Mobilization and/or pyrolysis products may be produced from the formation through production wells. In some embodiments, the average temperature of one or more sections is raised to mobilization temperatures and hydrocarbons are produced from the production wells. The average temperature of one or more of the sections may be raised to pyrolysis temperatures after production due to mobilization decreases below a selected value. In some embodiments, the average temperature of one or more sections may be raised to pyrolysis temperatures without significant production before reaching pyrolysis temperatures. Formation fluids including pyrolysis products may be produced through the production wells.
In some embodiments, the average temperature of one or more sections may be raised to temperatures sufficient to allow synthesis gas production after mobilization and/or pyrolysis. In some embodiments, hydrocarbons may be raised to temperatures sufficient to allow synthesis gas production without significant production before reaching the temperatures sufficient to allow synthesis gas production. For example, synthesis gas may be produced in a temperature range from about 400° C. to about 1200° C., about 500° C. to about 1100° C., or about 550° C. to about 1000° C. A synthesis gas generating fluid (for example, steam and/or water) may be introduced into the sections to generate synthesis gas. Synthesis gas may be produced from production wells.
Solution mining, removal of volatile hydrocarbons and water, mobilizing hydrocarbons, pyrolyzing hydrocarbons, generating synthesis gas, and/or other processes may be performed during the in situ heat treatment process. In some embodiments, some processes may be performed after the in situ heat treatment process. Such processes may include, but are not limited to, recovering heat from treated sections, storing fluids (for example, water and/or hydrocarbons) in previously treated sections, and/or sequestering carbon dioxide in previously treated sections.
FIG. 1 depicts a schematic view of an embodiment of a portion of the in situ heat treatment system for treating the hydrocarbon containing formation. The in situ heat treatment system may include barrier wells 200. Barrier wells are used to form a barrier around a treatment area. The barrier inhibits fluid flow into and/or out of the treatment area. Barrier wells include, but are not limited to, dewatering wells, vacuum wells, capture wells, injection wells, grout wells, freeze wells, or combinations thereof. In some embodiments, barrier wells 200 are dewatering wells. Dewatering wells may remove liquid water and/or inhibit liquid water from entering a portion of the formation to be heated, or to the formation being heated. In the embodiment depicted in FIG. 1, the barrier wells 200 are shown extending only along one side of heat sources 202, but the barrier wells typically encircle all heat sources 202 used, or to be used, to heat a treatment area of the formation.
Heat sources 202 are placed in at least a portion of the formation. Heat sources 202 may include heaters such as insulated conductors, conductor-in-conduit heaters, surface burners, flameless distributed combustors, and/or natural distributed combustors. Heat sources 202 may also include other types of heaters. Heat sources 202 provide heat to at least a portion of the formation to heat hydrocarbons in the formation. Energy may be supplied to heat sources 202 through supply lines 204. Supply lines 204 may be structurally different depending on the type of heat source or heat sources used to heat the formation. Supply lines 204 for heat sources may transmit electricity for electric heaters, may transport fuel for combustors, or may transport heat exchange fluid that is circulated in the formation. In some embodiments, electricity for an in situ heat treatment process may be provided by a nuclear power plant or nuclear power plants. The use of nuclear power may allow for reduction or elimination of carbon dioxide emissions from the in situ heat treatment process.
When the formation is heated, the heat input into the formation may cause expansion of the formation and geomechanical motion. The heat sources may be turned on before, at the same time, or during a dewatering process. Computer simulations may model formation response to heating. The computer simulations may be used to develop a pattern and time sequence for activating heat sources in the formation so that geomechanical motion of the formation does not adversely affect the functionality of heat sources, production wells, and other equipment in the formation.
Heating the formation may cause an increase in permeability and/or porosity of the formation. Increases in permeability and/or porosity may result from a reduction of mass in the formation due to vaporization and removal of water, removal of hydrocarbons, and/or creation of fractures. Fluid may flow more easily in the heated portion of the formation because of the increased permeability and/or porosity of the formation. Fluid in the heated portion of the formation may move a considerable distance through the formation because of the increased permeability and/or porosity. The considerable distance may be over 1000 m depending on various factors, such as permeability of the formation, properties of the fluid, temperature of the formation, and pressure gradient allowing movement of the fluid. The ability of fluid to travel considerable distance in the formation allows production wells 206 to be spaced relatively far apart in the formation.
Production wells 206 are used to remove formation fluid from the formation. In some embodiments, production well 206 includes a heat source. The heat source in the production well may heat one or more portions of the formation at or near the production well. In some in situ heat treatment process embodiments, the amount of heat supplied to the formation from the production well per meter of the production well is less than the amount of heat applied to the formation from a heat source that heats the formation per meter of the heat source. Heat applied to the formation from the production well may increase formation permeability adjacent to the production well by vaporizing and removing liquid phase fluid adjacent to the production well and/or by increasing the permeability of the formation adjacent to the production well by formation of macro and/or micro fractures.
More than one heat source may be positioned in the production well. A heat source in a lower portion of the production well may be turned off when superposition of heat from adjacent heat sources heats the formation sufficiently to counteract benefits provided by heating the formation with the production well. In some embodiments, the heat source in an upper portion of the production well may remain on after the heat source in the lower portion of the production well is deactivated. The heat source in the upper portion of the well may inhibit condensation and reflux of formation fluid.
In some embodiments, the heat source in production well 206 allows for vapor phase removal of formation fluids from the formation. Providing heating at or through the production well may: (1) inhibit condensation and/or refluxing of production fluid when such production fluid is moving in the production well proximate the overburden, (2) increase heat input into the formation, (3) increase production rate from the production well as compared to a production well without a heat source, (4) inhibit condensation of high carbon number compounds (C6 hydrocarbons and above) in the production well, and/or (5) increase formation permeability at or proximate the production well.
Subsurface pressure in the formation may correspond to the fluid pressure generated in the formation. As temperatures in the heated portion of the formation increase, the pressure in the heated portion may increase as a result of thermal expansion of in situ fluids, increased fluid generation and vaporization of water. Controlling rate of fluid removal from the formation may allow for control of pressure in the formation. Pressure in the formation may be determined at a number of different locations, such as near or at production wells, near or at heat sources, or at monitor wells.
In some hydrocarbon containing formations, production of hydrocarbons from the formation is inhibited until at least some hydrocarbons in the formation have been mobilized and/or pyrolyzed. Formation fluid may be produced from the formation when the formation fluid is of a selected quality. In some embodiments, the selected quality includes an API gravity of at least about 20°, 30°, or 40°. Inhibiting production until at least some hydrocarbons are mobilized and/or pyrolyzed may increase conversion of heavy hydrocarbons to light hydrocarbons. Inhibiting initial production may minimize the production of heavy hydrocarbons from the formation. Production of substantial amounts of heavy hydrocarbons may require expensive equipment and/or reduce the life of production equipment.
In some hydrocarbon containing formations, hydrocarbons in the formation may be heated to mobilization and/or pyrolysis temperatures before substantial permeability has been generated in the heated portion of the formation. An initial lack of permeability may inhibit the transport of generated fluids to production wells 206. During initial heating, fluid pressure in the formation may increase proximate heat sources 202. The increased fluid pressure may be released, monitored, altered, and/or controlled through one or more heat sources 202. For example, selected heat sources 202 or separate pressure relief wells may include pressure relief valves that allow for removal of some fluid from the formation.
In some embodiments, pressure generated by expansion of mobilized fluids, pyrolysis fluids or other fluids generated in the formation may be allowed to increase although an open path to production wells 206 or any other pressure sink may not yet exist in the formation. The fluid pressure may be allowed to increase towards a lithostatic pressure. Fractures in the hydrocarbon containing formation may form when the fluid approaches the lithostatic pressure. For example, fractures may form from heat sources 202 to production wells 206 in the heated portion of the formation. The generation of fractures in the heated portion may relieve some of the pressure in the portion. Pressure in the formation may have to be maintained below a selected pressure to inhibit unwanted production, fracturing of the overburden or underburden, and/or coking of hydrocarbons in the formation.
After mobilization and/or pyrolysis temperatures are reached and production from the formation is allowed, pressure in the formation may be varied to alter and/or control a composition of formation fluid produced, to control a percentage of condensable fluid as compared to non-condensable fluid in the formation fluid, and/or to control an API gravity of formation fluid being produced. For example, decreasing pressure may result in production of a larger condensable fluid component. The condensable fluid component may contain a larger percentage of olefins.
In some in situ heat treatment process embodiments, pressure in the formation may be maintained high enough to promote production of formation fluid with an API gravity of greater than 20°. Maintaining increased pressure in the formation may inhibit formation subsidence during in situ heat treatment. Maintaining increased pressure may reduce or eliminate the need to compress formation fluids at the surface to transport the fluids in collection conduits to treatment facilities.
Maintaining increased pressure in a heated portion of the formation may surprisingly allow for production of large quantities of hydrocarbons of increased quality and of relatively low molecular weight. Pressure may be maintained so that formation fluid produced has a minimal amount of compounds above a selected carbon number. The selected carbon number may be at most 25, at most 20, at most 12, or at most 8. Some high carbon number compounds may be entrained in vapor in the formation and may be removed from the formation with the vapor. Maintaining increased pressure in the formation may inhibit entrainment of high carbon number compounds and/or multi-ring hydrocarbon compounds in the vapor. High carbon number compounds and/or multi-ring hydrocarbon compounds may remain in a liquid phase in the formation for significant time periods. The significant time periods may provide sufficient time for the compounds to pyrolyze to form lower carbon number compounds.
Generation of relatively low molecular weight hydrocarbons is believed to be due, in part, to autogenous generation and reaction of hydrogen in a portion of the hydrocarbon containing formation. For example, maintaining an increased pressure may force hydrogen generated during pyrolysis into the liquid phase within the formation. Heating the portion to a temperature in a pyrolysis temperature range may pyrolyze hydrocarbons in the formation to generate liquid phase pyrolyzation fluids. The generated liquid phase pyrolyzation fluids components may include double bonds and/or radicals. Hydrogen (H2) in the liquid phase may reduce double bonds of the generated pyrolyzation fluids, thereby reducing a potential for polymerization or formation of long chain compounds from the generated pyrolyzation fluids. In addition, H2 may also neutralize radicals in the generated pyrolyzation fluids. H2 in the liquid phase may inhibit the generated pyrolyzation fluids from reacting with each other and/or with other compounds in the formation.
Formation fluid produced from production wells 206 may be transported through collection piping 208 to treatment facilities 210. Formation fluids may also be produced from heat sources 202. For example, fluid may be produced from heat sources 202 to control pressure in the formation adjacent to the heat sources. Fluid produced from heat sources 202 may be transported through tubing or piping to collection piping 208 or the produced fluid may be transported through tubing or piping directly to treatment facilities 210. Treatment facilities 210 may include separation units, reaction units, upgrading units, fuel cells, turbines, storage vessels, and/or other systems and units for processing produced formation fluids. The treatment facilities may form transportation fuel from at least a portion of the hydrocarbons produced from the formation. In some embodiments, the transportation fuel may be jet fuel, such as JP-8.
An insulated conductor may be used as an electric heater element of a heater or a heat source. The insulated conductor may include an inner electrical conductor (core) surrounded by an electrical insulator and an outer electrical conductor (jacket). The electrical insulator may include mineral insulation (for example, magnesium oxide) or other electrical insulation.
In certain embodiments, the insulated conductor is placed in an opening in a hydrocarbon containing formation. In some embodiments, the insulated conductor is placed in an uncased opening in the hydrocarbon containing formation. Placing the insulated conductor in an uncased opening in the hydrocarbon containing formation may allow heat transfer from the insulated conductor to the formation by radiation as well as conduction. Using an uncased opening may facilitate retrieval of the insulated conductor from the well, if necessary.
In some embodiments, an insulated conductor is placed within a casing in the formation; may be cemented within the formation; or may be packed in an opening with sand, gravel, or other fill material. The insulated conductor may be supported on a support member positioned within the opening. The support member may be a cable, rod, or a conduit (for example, a pipe). The support member may be made of a metal, ceramic, inorganic material, or combinations thereof. Because portions of a support member may be exposed to formation fluids and heat during use, the support member may be chemically resistant and/or thermally resistant.
Ties, spot welds, and/or other types of connectors may be used to couple the insulated conductor to the support member at various locations along a length of the insulated conductor. The support member may be attached to a wellhead at an upper surface of the formation. In some embodiments, the insulated conductor has sufficient structural strength such that a support member is not needed. The insulated conductor may, in many instances, have at least some flexibility to inhibit thermal expansion damage when undergoing temperature changes.
In certain embodiments, insulated conductors are placed in wellbores without support members and/or centralizers. An insulated conductor without support members and/or centralizers may have a suitable combination of temperature and corrosion resistance, creep strength, length, thickness (diameter), and metallurgy that will inhibit failure of the insulated conductor during use.
FIG. 2 depicts a perspective view of an end portion of an embodiment of insulated conductor 252. Insulated conductor 252 may have any desired cross-sectional shape such as, but not limited to, round (depicted in FIG. 2), triangular, ellipsoidal, rectangular, hexagonal, or irregular. In certain embodiments, insulated conductor 252 includes core 218, electrical insulator 214, and jacket 216. Core 218 may resistively heat when an electrical current passes through the core. Alternating or time-varying current and/or direct current may be used to provide power to core 218 such that the core resistively heats.
In some embodiments, electrical insulator 214 inhibits current leakage and arcing to jacket 216. Electrical insulator 214 may thermally conduct heat generated in core 218 to jacket 216. Jacket 216 may radiate or conduct heat to the formation. In certain embodiments, insulated conductor 252 is 1000 m or more in length. Longer or shorter insulated conductors may also be used to meet specific application needs. The dimensions of core 218, electrical insulator 214, and jacket 216 of insulated conductor 252 may be selected such that the insulated conductor has enough strength to be self supporting even at upper working temperature limits. Such insulated conductors may be suspended from wellheads or supports positioned near an interface between an overburden and a hydrocarbon containing formation without the need for support members extending into the hydrocarbon containing formation along with the insulated conductors.
Insulated conductor 252 may be designed to operate at power levels of up to about 1650 watts/meter or higher. In certain embodiments, insulated conductor 252 operates at a power level between about 500 watts/meter and about 1150 watts/meter when heating a formation. Insulated conductor 252 may be designed so that a maximum voltage level at a typical operating temperature does not cause substantial thermal and/or electrical breakdown of electrical insulator 214. Insulated conductor 252 may be designed such that jacket 216 does not exceed a temperature that will result in a significant reduction in corrosion resistance properties of the jacket material. In certain embodiments, insulated conductor 252 may be designed to reach temperatures within a range between about 650° C. and about 900° C. Insulated conductors having other operating ranges may be formed to meet specific operational requirements.
FIG. 2 depicts insulated conductor 252 having a single core 218. In some embodiments, insulated conductor 252 has two or more cores 218. For example, a single insulated conductor may have three cores. Core 218 may be made of metal or another electrically conductive material. The material used to form core 218 may include, but not be limited to, nichrome, copper, nickel, carbon steel, stainless steel, and combinations thereof. In certain embodiments, core 218 is chosen to have a diameter and a resistivity at operating temperatures such that its resistance, as derived from Ohm's law, makes it electrically and structurally stable for the chosen power dissipation per meter, the length of the heater, and/or the maximum voltage allowed for the core material.
In some embodiments, core 218 is made of different materials along a length of insulated conductor 252. For example, a first section of core 218 may be made of a material that has a significantly lower resistance than a second section of the core. The first section may be placed adjacent to a formation layer that does not need to be heated to as high a temperature as a second formation layer that is adjacent to the second section. The resistivity of various sections of core 218 may be adjusted by having a variable diameter and/or by having core sections made of different materials.
Electrical insulator 214 may be made of a variety of materials. Commonly used powders may include, but are not limited to, MgO, Al2O3, BN, Si3N4, Zirconia, BeO, different chemical variations of Spinels, and combinations thereof. MgO may provide good thermal conductivity and electrical insulation properties. The desired electrical insulation properties include low leakage current and high dielectric strength. A low leakage current decreases the possibility of thermal breakdown and the high dielectric strength decreases the possibility of arcing across the insulator. Thermal breakdown can occur if the leakage current causes a progressive rise in the temperature of the insulator leading also to arcing across the insulator.
Jacket 216 may be an outer metallic layer or electrically conductive layer. Jacket 216 may be in contact with hot formation fluids. Jacket 216 may be made of material having a high resistance to corrosion at elevated temperatures. Alloys that may be used in a desired operating temperature range of jacket 216 include, but are not limited to, 304 stainless steel, 310 stainless steel, Incoloy® 800, and Inconel® 600 (Inco Alloys International, Huntington, W. Va., U.S.A.). The thickness of jacket 216 may have to be sufficient to last for three to ten years in a hot and corrosive environment. A thickness of jacket 216 may generally vary between about 1 mm and about 2.5 mm. For example, a 1.3 mm thick, 310 stainless steel outer layer may be used as jacket 216 to provide good chemical resistance to sulfidation corrosion in a heated zone of a formation for a period of over 3 years. Larger or smaller jacket thicknesses may be used to meet specific application requirements.
One or more insulated conductors may be placed within an opening in a formation to form a heat source or heat sources. Electrical current may be passed through each insulated conductor in the opening to heat the formation. Alternatively, electrical current may be passed through selected insulated conductors in an opening. The unused conductors may be used as backup heaters. Insulated conductors may be electrically coupled to a power source in any convenient manner. Each end of an insulated conductor may be coupled to lead-in cables that pass through a wellhead. Such a configuration typically has a 180° bend (a “hairpin” bend) or turn located near a bottom of the heat source. An insulated conductor that includes a 180° bend or turn may not require a bottom termination, but the 180° bend or turn may be an electrical and/or structural weakness in the heater. Insulated conductors may be electrically coupled together in series, in parallel, or in series and parallel combinations. In some embodiments of heat sources, electrical current may pass into the conductor of an insulated conductor and may be returned through the jacket of the insulated conductor by connecting core 218 to jacket 216 (shown in FIG. 2) at the bottom of the heat source.
In some embodiments, three insulated conductors 252 are electrically coupled in a 3-phase wye configuration to a power supply. FIG. 3 depicts an embodiment of three insulated conductors in an opening in a subsurface formation coupled in a wye configuration. FIG. 4 depicts an embodiment of three insulated conductors 252 that are removable from opening 238 in the formation. No bottom connection may be required for three insulated conductors in a wye configuration. Alternately, all three insulated conductors of the wye configuration may be connected together near the bottom of the opening. The connection may be made directly at ends of heating sections of the insulated conductors or at ends of cold pins (less resistive sections) coupled to the heating sections at the bottom of the insulated conductors. The bottom connections may be made with insulator filled and sealed canisters or with epoxy filled canisters. The insulator may be the same composition as the insulator used as the electrical insulation.
Three insulated conductors 252 depicted in FIGS. 3 and 4 may be coupled to support member 220 using centralizers 222. Alternatively, insulated conductors 252 may be strapped directly to support member 220 using metal straps. Centralizers 222 may maintain a location and/or inhibit movement of insulated conductors 252 on support member 220. Centralizers 222 may be made of metal, ceramic, or combinations thereof. The metal may be stainless steel or any other type of metal able to withstand a corrosive and high temperature environment. In some embodiments, centralizers 222 are bowed metal strips welded to the support member at distances less than about 6 m. A ceramic used in centralizer 222 may be, but is not limited to, Al2O3, MgO, or another electrical insulator. Centralizers 222 may maintain a location of insulated conductors 252 on support member 220 such that movement of insulated conductors is inhibited at operating temperatures of the insulated conductors. Insulated conductors 252 may also be somewhat flexible to withstand expansion of support member 220 during heating.
Support member 220, insulated conductor 252, and centralizers 222 may be placed in opening 238 in hydrocarbon layer 240. Insulated conductors 252 may be coupled to bottom conductor junction 224 using cold pin 226. Bottom conductor junction 224 may electrically couple each insulated conductor 252 to each other. Bottom conductor junction 224 may include materials that are electrically conducting and do not melt at temperatures found in opening 238. Cold pin 226 may be an insulated conductor having lower electrical resistance than insulated conductor 252.
Lead-in conductor 228 may be coupled to wellhead 242 to provide electrical power to insulated conductor 252. Lead-in conductor 228 may be made of a relatively low electrical resistance conductor such that relatively little heat is generated from electrical current passing through the lead-in conductor. In some embodiments, the lead-in conductor is a rubber or polymer insulated stranded copper wire. In some embodiments, the lead-in conductor is a mineral insulated conductor with a copper core. Lead-in conductor 228 may couple to wellhead 242 at surface 250 through a sealing flange located between overburden 246 and surface 250. The sealing flange may inhibit fluid from escaping from opening 238 to surface 250.
In certain embodiments, lead-in conductor 228 is coupled to insulated conductor 252 using transition conductor 230. Transition conductor 230 may be a less resistive portion of insulated conductor 252. Transition conductor 230 may be referred to as “cold pin” of insulated conductor 252. Transition conductor 230 may be designed to dissipate about one-tenth to about one-fifth of the power per unit length as is dissipated in a unit length of the primary heating section of insulated conductor 252. Transition conductor 230 may typically be between about 1.5 m and about 15 m, although shorter or longer lengths may be used to accommodate specific application needs. In an embodiment, the conductor of transition conductor 230 is copper. The electrical insulator of transition conductor 230 may be the same type of electrical insulator used in the primary heating section. A jacket of transition conductor 230 may be made of corrosion resistant material.
In certain embodiments, transition conductor 230 is coupled to lead-in conductor 228 by a splice or other coupling joint. Splices may also be used to couple transition conductor 230 to insulated conductor 252. Splices may have to withstand a temperature equal to half of a target zone operating temperature. Density of electrical insulation in the splice should in many instances be high enough to withstand the required temperature and the operating voltage.
In some embodiments, as shown in FIG. 3, packing material 248 is placed between overburden casing 244 and opening 238. In some embodiments, reinforcing material 232 may secure overburden casing 244 to overburden 246. Packing material 248 may inhibit fluid from flowing from opening 238 to surface 250. Reinforcing material 232 may include, for example, Class G or Class H Portland cement mixed with silica flour for improved high temperature performance, slag or silica flour, and/or a mixture thereof. In some embodiments, reinforcing material 232 extends radially a width of from about 5 cm to about 25 cm.
As shown in FIGS. 3 and 4, support member 220 and lead-in conductor 228 may be coupled to wellhead 242 at surface 250 of the formation. Surface conductor 234 may enclose reinforcing material 232 and couple to wellhead 242. Embodiments of surface conductors may extend to depths of approximately 3 m to approximately 515 m into an opening in the formation. Alternatively, the surface conductor may extend to a depth of approximately 9 m into the formation. Electrical current may be supplied from a power source to insulated conductor 252 to generate heat due to the electrical resistance of the insulated conductor. Heat generated from three insulated conductors 252 may transfer within opening 238 to heat at least a portion of hydrocarbon layer 240.
Heat generated by insulated conductors 252 may heat at least a portion of a hydrocarbon containing formation. In some embodiments, heat is transferred to the formation substantially by radiation of the generated heat to the formation. Some heat may be transferred by conduction or convection of heat due to gases present in the opening. The opening may be an uncased opening, as shown in FIGS. 3 and 4. An uncased opening eliminates cost associated with thermally cementing the heater to the formation, costs associated with a casing, and/or costs of packing a heater within an opening. In addition, heat transfer by radiation is typically more efficient than by conduction, so the heaters may be operated at lower temperatures in an open wellbore. Conductive heat transfer during initial operation of a heat source may be enhanced by the addition of a gas in the opening. The gas may be maintained at a pressure up to about 27 bars absolute. The gas may include, but is not limited to, carbon dioxide and/or helium. An insulated conductor heater in an open wellbore may advantageously be free to expand or contract to accommodate thermal expansion and contraction. An insulated conductor heater may advantageously be removable or redeployable from an open wellbore.
In certain embodiments, an insulated conductor heater assembly is installed or removed using a spooling assembly. More than one spooling assembly may be used to install both the insulated conductor and a support member simultaneously. Alternatively, the support member may be installed using a coiled tubing unit. The heaters may be un-spooled and connected to the support as the support is inserted into the well. The electric heater and the support member may be un-spooled from the spooling assemblies. Spacers may be coupled to the support member and the heater along a length of the support member. Additional spooling assemblies may be used for additional electric heater elements.
Temperature limited heaters may be in configurations and/or may include materials that provide automatic temperature limiting properties for the heater at certain temperatures. In certain embodiments, ferromagnetic materials are used in temperature limited heaters. Ferromagnetic material may self-limit temperature at or near the Curie temperature of the material and/or the phase transformation temperature range to provide a reduced amount of heat when a time-varying current is applied to the material. In certain embodiments, the ferromagnetic material self-limits temperature of the temperature limited heater at a selected temperature that is approximately the Curie temperature and/or in the phase transformation temperature range. In certain embodiments, the selected temperature is within about 35° C., within about 25° C., within about 20° C., or within about 10° C. of the Curie temperature and/or the phase transformation temperature range. In certain embodiments, ferromagnetic materials are coupled with other materials (for example, highly conductive materials, high strength materials, corrosion resistant materials, or combinations thereof) to provide various electrical and/or mechanical properties. Some parts of the temperature limited heater may have a lower resistance (caused by different geometries and/or by using different ferromagnetic and/or non-ferromagnetic materials) than other parts of the temperature limited heater. Having parts of the temperature limited heater with various materials and/or dimensions allows for tailoring the desired heat output from each part of the heater.
Temperature limited heaters may be more reliable than other heaters. Temperature limited heaters may be less apt to break down or fail due to hot spots in the formation. In some embodiments, temperature limited heaters allow for substantially uniform heating of the formation. In some embodiments, temperature limited heaters are able to heat the formation more efficiently by operating at a higher average heat output along the entire length of the heater. The temperature limited heater operates at the higher average heat output along the entire length of the heater because power to the heater does not have to be reduced to the entire heater, as is the case with typical constant wattage heaters, if a temperature along any point of the heater exceeds, or is about to exceed, a maximum operating temperature of the heater. Heat output from portions of a temperature limited heater approaching a Curie temperature and/or the phase transformation temperature range of the heater automatically reduces without controlled adjustment of the time-varying current applied to the heater. The heat output automatically reduces due to changes in electrical properties (for example, electrical resistance) of portions of the temperature limited heater. Thus, more power is supplied by the temperature limited heater during a greater portion of a heating process.
In certain embodiments, the system including temperature limited heaters initially provides a first heat output and then provides a reduced (second) heat output, near, at, or above the Curie temperature and/or the phase transformation temperature range of an electrically resistive portion of the heater when the temperature limited heater is energized by a time-varying current. The first heat output is the heat output at temperatures below which the temperature limited heater begins to self-limit. In some embodiments, the first heat output is the heat output at a temperature about 50° C., about 75° C., about 100° C., or about 125° C. below the Curie temperature and/or the phase transformation temperature range of the ferromagnetic material in the temperature limited heater.
The temperature limited heater may be energized by time-varying current (alternating current or modulated direct current) supplied at the wellhead. The wellhead may include a power source and other components (for example, modulation components, transformers, and/or capacitors) used in supplying power to the temperature limited heater. The temperature limited heater may be one of many heaters used to heat a portion of the formation.
In some embodiments, a relatively thin conductive layer is used to provide the majority of the electrically resistive heat output of the temperature limited heater at temperatures up to a temperature at or near the Curie temperature and/or the phase transformation temperature range of the ferromagnetic conductor. Such a temperature limited heater may be used as the heating member in an insulated conductor heater. The heating member of the insulated conductor heater may be located inside a sheath with an insulation layer between the sheath and the heating member.
FIGS. 5A and 5B depict cross-sectional representations of an embodiment of the insulated conductor heater with the temperature limited heater as the heating member. Insulated conductor 252 includes core 218, ferromagnetic conductor 236, inner conductor 212, electrical insulator 214, and jacket 216. Core 218 is a copper core. Ferromagnetic conductor 236 is, for example, iron or an iron alloy.
Inner conductor 212 is a relatively thin conductive layer of non-ferromagnetic material with a higher electrical conductivity than ferromagnetic conductor 236. In certain embodiments, inner conductor 212 is copper. Inner conductor 212 may be a copper alloy. Copper alloys typically have a flatter resistance versus temperature profile than pure copper. A flatter resistance versus temperature profile may provide less variation in the heat output as a function of temperature up to the Curie temperature and/or the phase transformation temperature range. In some embodiments, inner conductor 212 is copper with 6% by weight nickel (for example, CuNi6 or LOHM™). In some embodiments, inner conductor 212 is CuNi10Fe1Mn alloy. Below the Curie temperature and/or the phase transformation temperature range of ferromagnetic conductor 236, the magnetic properties of the ferromagnetic conductor confine the majority of the flow of electrical current to inner conductor 212. Thus, inner conductor 212 provides the majority of the resistive heat output of insulated conductor 252 below the Curie temperature and/or the phase transformation temperature range.
In certain embodiments, inner conductor 212 is dimensioned, along with core 218 and ferromagnetic conductor 236, so that the inner conductor provides a desired amount of heat output and a desired turndown ratio. For example, inner conductor 212 may have a cross-sectional area that is around 2 or 3 times less than the cross-sectional area of core 218. Typically, inner conductor 212 has to have a relatively small cross-sectional area to provide a desired heat output if the inner conductor is copper or copper alloy. In an embodiment with copper inner conductor 212, core 218 has a diameter of 0.66 cm, ferromagnetic conductor 236 has an outside diameter of 0.91 cm, inner conductor 212 has an outside diameter of 1.03 cm, electrical insulator 214 has an outside diameter of 1.53 cm, and jacket 216 has an outside diameter of 1.79 cm. In an embodiment with a CuNi6 inner conductor 212, core 218 has a diameter of 0.66 cm, ferromagnetic conductor 236 has an outside diameter of 0.91 cm, inner conductor 212 has an outside diameter of 1.12 cm, electrical insulator 214 has an outside diameter of 1.63 cm, and jacket 216 has an outside diameter of 1.88 cm. Such insulated conductors are typically smaller and cheaper to manufacture than insulated conductors that do not use the thin inner conductor to provide the majority of heat output below the Curie temperature and/or the phase transformation temperature range.
Electrical insulator 214 may be magnesium oxide, aluminum oxide, silicon dioxide, beryllium oxide, boron nitride, silicon nitride, or combinations thereof. In certain embodiments, electrical insulator 214 is a compacted powder of magnesium oxide. In some embodiments, electrical insulator 214 includes beads of silicon nitride.
In certain embodiments, a small layer of material is placed between electrical insulator 214 and inner conductor 212 to inhibit copper from migrating into the electrical insulator at higher temperatures. For example, a small layer of nickel (for example, about 0.5 mm of nickel) may be placed between electrical insulator 214 and inner conductor 212.
Jacket 216 is made of a corrosion resistant material such as, but not limited to, 347 stainless steel, 347H stainless steel, 446 stainless steel, or 825 stainless steel. In some embodiments, jacket 216 provides some mechanical strength for insulated conductor 252 at or above the Curie temperature and/or the phase transformation temperature range of ferromagnetic conductor 236. In certain embodiments, jacket 216 is not used to conduct electrical current.
There are many potential problems in making insulated conductors in relatively long lengths (for example, lengths of 10 m or longer). For example, gaps may exist between blocks of material used to form the electrical insulator in the insulated conductor and/or breakdown voltages across the insulation may not be high enough to withstand the operating voltages needed to provide heat along such heater lengths. Insulated conductors include insulated conductor used as heaters and/or insulated conductors used in the overburden section of the formation (insulated conductors that provide little or no heat output). Insulated conductors may be, for example, mineral insulated conductors such as mineral insulated cables.
In a typical process used to make (form) an insulated conductor, the jacket of the insulated conductor starts as a strip of electrically conducting material (for example, stainless steel). The jacket strip is formed (longitudinally rolled) into a partial cylindrical shape and electrical insulator blocks (for example, magnesium oxide blocks) are inserted into the partially cylindrical jacket. The inserted blocks may be partial cylinder blocks such as half-cylinder blocks. Following insertion of the blocks, the longitudinal core, which is typically a solid cylinder, is placed in the partial cylinder and inside the half-cylinder blocks. The core is made of electrically conducting material such as copper, nickel, and/or steel.
Once the electrical insulator blocks and the core are in place, the portion of the jacket containing the blocks and the core may be formed into a complete cylinder around the blocks and the core. The longitudinal edges of the jacket that close the cylinder may be welded to form an insulated conductor assembly with the core and electrical insulator blocks inside the jacket. The process of inserting the blocks and closing the jacket cylinder may be repeated along a length of jacket to form the insulated conductor assembly in a desired length.
As the insulated conductor assembly is formed, further steps may be taken to reduce gaps and/or porosity in the assembly. For example, the insulated conductor assembly may be moved through a progressive reduction system (cold working system) to reduce gaps in the assembly. One example of a progressive reduction system is a roller system. In the roller system, the insulated conductor assembly may progress through multiple horizontal and vertical rollers with the assembly alternating between horizontal and vertical rollers. The rollers may progressively reduce the size of the insulated conductor assembly into the final, desired outside diameter or cross-sectional area (for example, the outside diameter or cross-sectional area of the outer electrical conductor (such as a sheath or jacket)).
In certain embodiments, the insulated conductor assembly is heat-treated and/or annealed between reduction steps. Heat treatment of the insulated conductor assembly may be needed to regain mechanical properties of the metal(s) used in the insulated conductor assembly to allow for further reduction (cold working) of the insulated conductor assembly. For example, the insulated conductor assembly may be heat treated and/or annealed to reduce stresses in metal in the assembly and improve the cold working (progressive reduction) properties of the metal.
Heat treatment of the insulated conductor assembly, however, typically reduces the dielectric breakdown voltage (dielectric strength) of the insulated conductor assembly. For example, heat treatment may reduce the breakdown voltage by about 50% or more for typical heat treatments of metals used in the insulated conductor assembly. Such reductions in the breakdown voltage may produce shorts or other electrical breakdowns when the insulated conductor assembly is used at the medium to high voltages needed for long length heaters (for example, voltages of about 5 kV or higher).
In certain embodiments, a final reduction (cold working) of the insulated conductor assembly after heat treatment may restore breakdown voltages to acceptable values for long length heaters. The final reduction, however, may not be as large a reduction as previous reductions of the insulated conductor assembly to avoid straining or over-straining the metal in the assembly beyond acceptable limits. Too much reduction in the final reduction may result in an additional heat treatment being needed to restore mechanical properties to the metals in the insulated conductor assembly.
FIG. 6 depicts an embodiment of pre-cold worked, pre-heat treated insulated conductor 252. In certain embodiments, insulated conductor includes core 218, electrical insulator 214, and jacket 216 (for example, sheath or outer electrical conductor). In some embodiments, electrical insulator 214 is made from a plurality of blocks of insulating material. In certain embodiments, insulated conductor 252 is treated in a cold working/heat treating process prior to a final reduction of the insulated conductor to its final dimensions. For example, the insulated conductor assembly may be cold worked to reduce the cross-sectional area of the assembly by at least about 30% followed by a heat treatment step at a temperature of at least about 870° C. as measured by an optical pyrometer at the exit of an induction coil. FIG. 7 depicts an embodiment of insulated conductor 252 depicted in FIG. 6 after cold working and heat treating. Cold working and heat treating insulated conductor 252 may reduce the cross-sectional area of jacket 216 by about 30% as compared to jacket 216 of the pre-cold worked, pre-heat treated insulated conductor. In some embodiments, the cross-sectional area of electrical insulator 214 and/or core 218, is reduced by about 30% during the cold working and heat treating process.
In some embodiments, the insulated conductor assembly is cold worked to reduce the cross-sectional area of the assembly up to about 35% or close to a mechanical failure point of the insulated conductor assembly. In some embodiments, the insulated conductor assembly is heat treated and/or annealed at temperatures between about 760° C. and about 925° C. (for example, temperatures that restore as much mechanical integrity as possible to metals in the insulated conductor assembly without melting the electrical insulation in the assembly). In some embodiments, the heat treating step includes rapidly heating the insulated conductor assembly to the desired temperature and then quenching the assembly back to ambient temperature.
In certain embodiments, the cold working/heat treating steps are repeated two or more times until the cross-sectional area of the insulated conductor assembly is close to (for example, within about 5% to about 15%) of the desired, final cross-sectional area of the assembly. After the heat treating step that gets the cross-sectional area of the insulated conductor assembly close to the final cross-sectional area of the assembly, the assembly is cold worked, in a final step, to reduce the cross-sectional area of the insulated conductor assembly to the final cross-sectional area. FIG. 8 depicts an embodiment of insulated conductor 252 depicted in FIG. 7 after cold working. The cross-sectional area of the embodiment of jacket 216 in FIG. 8 may be reduced by about 15% as compared to the embodiment of jacket 216 in FIG. 7. In certain embodiments, the final cold working step reduces the cross-sectional area of the insulated conductor assembly by an amount ranging between about 5% and about 20%. In some embodiments, the final cold working step reduces the cross-sectional area of the insulated conductor assembly by an amount ranging between about 10% and about 20%. In some embodiments, the cross-sectional area of electrical insulator 214 and/or core 218, is reduced during the cold working and heat treating process.
Limiting the reduction in the cross-sectional area of the insulated conductor assembly to at most about 20% during the final cold working step reduces the cross-sectional area of the insulated conductor assembly to the desired value while maintaining sufficient mechanical integrity in the jacket (outer conductor) of the insulated conductor assembly for use in heating a subsurface formation. Thus, the need for further heat treatment to restore mechanical integrity of the insulated conductor assembly is eliminated or substantially reduced. Reducing the cross-sectional area of the insulated conductor assembly by more than about 20% during the final cold working step may require further heat treatment to return mechanical integrity to the insulated conductor assembly sufficient for use as a long heater in a subsurface formation.
Additionally, having cold working being the final step in the process of making the insulated conductor assembly instead of heat treatment and/or heat treating improves the dielectric breakdown voltage of the insulated conductor assembly. Cold working (reducing the cross-sectional area) of the insulated conductor assembly reduces pore volumes and/or porosity in the electrical insulation of the assembly. Reducing the pore volumes and/or porosity in the electrical insulation increases the breakdown voltage by eliminating pathways for electrical shorts and/or failures in the electrical insulation. Thus, having the cold working being the final step instead of heat treatment (which typically reduces the breakdown voltage), higher breakdown voltage insulated conductor assemblies can be produced using a final cold working step that reduces the cross-sectional area up to at most about 20%.
In some embodiments, the breakdown voltage after the final cold working step approaches the breakdown voltage (dielectric strength) of the pre-heat treated insulated conductor assembly. In certain embodiments, the dielectric strength of electrical insulation in the insulated conductor assembly after the final cold working step is within about 10%, within about 5%, or within about 2% of the dielectric strength of the electrical insulation in the pre-heat treated insulated conductor. In certain embodiments, the breakdown voltage of the insulated conductor assembly is between about 12 kV and about 20 kV.
Insulated conductor assemblies with such good breakdown voltage properties (breakdown voltages above about 12 kV) may be smaller in diameter (cross-sectional area) and provide the same output as insulated conductor assemblies with lower breakdown voltages for heating similar lengths in a subsurface formation. Because the higher breakdown voltage allows the diameter of the insulated conductor assembly to be smaller, less insulating blocks may be used to make a heater of the same length as the insulating blocks are elongated further (take up more length) when compressed to the smaller diameter. Thus, the number of blocks used to make up the insulated conductor assembly may be reduced, thereby saving material costs for electrical insulation.
Another possible solution for making insulated conductors in relatively long lengths (for example, lengths of 10 m or longer) is to manufacture the electrical insulator from a powder based material. For example, mineral insulated conductors, such as magnesium oxide (MgO) insulated conductors, can be manufactured using a mineral powder insulation that is compacted to form the electrical insulator over the core of the insulated conductor and inside the sheath. Previous attempts to form insulated conductors using electrical insulator powder were largely unsuccessful due to problems associated with powder flow, conductor (core) centralization, and interaction with the powder (for example, MgO powder) during the weld process for the outer sheath or jacket. New developments in powder handling technology may allow for improvements in making insulated conductors with the powder. Producing insulated conductors from powder insulation may reduce material costs and provide increased manufacturing reliability compared to other methods for making insulated conductors.
FIG. 9 depicts an embodiment of a process for manufacturing an insulated conductor using a powder for the electrical insulator. In certain embodiments, process 268 is performed in a tube mill or other tube (pipe) assembly facility. In certain embodiments, process 268 begins with spool 270 and spool 272 feeding first sheath material 274 and conductor (core) material 276, respectively, into the process flow line. In certain embodiments, first sheath material 274 is thin sheath material such as stainless steel and core material 276 is copper rod or another conductive material used for the core. First sheath material 274 and core material 276 may pass through centralizing rolls 278. Centralizing rolls 278 may center core material 276 over first sheath material 274, as shown in FIG. 9.
Centralized core material 276 and first sheath material 274 may later pass into compression and centralization rolls 280. Compression and centralization rolls 280 may form first sheath material 274 into a tubular around core material 276. As shown in FIG. 9, first sheath material 274 may begin to form into the tubular before reaching compression and centralization rolls 280 because of the pressure from sheath forming rolls 281 on the upstream portion of the first sheath material. As first sheath material 274 begins to form into the tubular, electrical insulator powder 282 may be added inside the first sheath material from powder dispenser 284. In some embodiments, powder 282 is heated before entering first sheath material 274 by heater 286. Heater 286 may be, for example, an induction heater that heats powder 282 to release moisture from the powder and/or provide better flow properties in the powder and dielectric properties of the final assembled conductor.
As powder 282 enters first sheath material 274, the assembly may pass through vibrator 288 before entering compression and centralization rolls 280. Vibrator 288 may vibrate the assembly to increase compaction of powder 282 inside first sheath material 274. In certain embodiments, the filling of powder 282 into first sheath material 274 and other process steps upstream of vibrator 288 occur in a vertical formation. Performing such process steps in the vertical formation provides better compaction of powder 282 inside first sheath material 274. As shown in FIG. 9, the vertical formation of process 268 may transition to a horizontal formation while the assembly passes through compression and centralization rolls 280.
As the assembly of first sheath material 274, core material 276, and powder 282 exits compression and centralization rolls 280, second sheath material 290 may be provided around the assembly. Second sheath material 290 may be provided from spool 292. Second sheath material 290 may be thicker sheath material than first sheath material 274. In certain embodiments, first sheath material 274 has a thickness as thin as is permitted without the first sheath material breaking or causing defects later in the process (for example, during reduction of the outer diameter of the insulated conductor). Second sheath material 290 may have a thickness as thick as possible that still allows for the final reduction of the outside diameter of the insulated conductor to the desired dimension. The combined thickness of first sheath material 274 and second sheath material 290 may be, for example, between about ⅓ and about ⅛ (for example, about ⅙) of the final outside diameter of the insulated conductor.
In some embodiments, first sheath material 274 has a thickness between about 0.020″ and about 0.075″ (for example, about 0.035″) and second sheath material 290 has a thickness between about 0.100″ and about 0.150″ (for example, about 0.125″) for an insulated conductor that has a final outside diameter of about 1″ after the final reduction step. In some embodiments, second sheath material 290 is the same material as first sheath material 274. In some embodiments, second sheath material 290 is a different material (for example, a different stainless steel or nickel based alloy) than first sheath material 274.
Second sheath material 290 may be formed into a tubular around the assembly of first sheath material 274, core material 276, and powder 282 by forming rolls 294. After forming second sheath material 290 into the tubular, the longitudinal edges of the second sheath material may be welded together using welder 296. Welder 296 may be, for example, a laser welder for welding stainless steel. Welding of second sheath material 290 forms the assembly into insulated conductor 252 with first sheath material 274 and the second sheath material forming the sheath (jacket) of the insulated conductor.
After insulated conductor 252 is formed, the insulated conductor is passed through one or more reduction rolls 298. Reduction rolls 298 may reduce the outside diameter of insulated conductor 252 by up to about 35% by cold working on the sheath (first sheath material 274 and second sheath material 290) and the core (core material 276). Following reduction of the cross-section of insulated conductor 252, the insulated conductor may be heat treated by heater 300 and quenched in quencher 302. Heater 300 may be, for example, an induction heater. Quencher 302 may use, for example, water quenching to quickly cool insulated conductor 252. In some embodiments, reduction of the outside diameter of insulated conductor 252 followed by heat treating and quenching can be repeated one or more times before the insulated conductor is provided to reduction rolls 304 for a final reduction step.
After heat treating and quenching of insulated conductor 252 at heater 300 and quencher 302, the insulated conductor is passed through reduction rolls 304 for the final reduction step (the final cold working step). The final reduction step may reduce the outside diameter (cross-sectional area) of insulated conductor 252 to between about 5% and about 20% of the cross section prior to the final reduction step. The final reduced insulated conductor 252 may then be provided to spool 306. Spool 306 may be, for example, a coiled tubing rig or other spool used for transporting insulated conductors (heaters) to a heater assembly location.
In certain embodiments, the combination of using first sheath material 274 and second sheath material 290 allows the use of powder 282 in process 268 to form insulated conductor 252. For example, first sheath material 274 may protect powder 282 from interacting with the weld on second sheath material 290. In certain embodiments, the design of first sheath material 274 inhibits interaction between powder 282 and the weld on second sheath material 290. FIGS. 10 and 11 depict cross-sectional representations of two possible embodiments for designs of first sheath material 274 used in insulated conductor 252.
FIG. 10A depicts a cross-sectional representation of a first design embodiment of first sheath material 274 inside insulated conductor 252. FIG. 10A depicts insulated conductor 252 as the insulated conductor passes through compression and centralization rolls 280, shown in FIG. 9. As shown in FIG. 10A, first sheath material 274 overlaps itself (shown as overlap 308) as the first sheath material is formed into the tubular around powder 282 and core material 276. Overlap 308 is an overlap between longitudinal edges of first sheath material 274.
FIG. 10B depicts a cross-sectional representation of the first design embodiment with second sheath material 290 formed into the tubular and welded around first sheath material 274. FIG. 10B depicts insulated conductor 252 immediately after the insulated conductor passes through welder 296, shown in FIG. 9. As shown in FIG. 10B, first sheath material 274 rests inside the tubular formed by second sheath material 290 (for example, there is a gap between the upper portions of the sheath materials). Weld 310 joins second sheath material 290 to form the tubular around first sheath material 274. In some embodiments, weld 310 is placed at or near overlap 308. In other embodiments, weld 310 is at a different location than overlap 308. The location of weld 310 may not be important as first sheath material 274 inhibits interaction between the weld and powder 282 inside the first sheath material. Overlap 308 in first sheath material 274 may seal off powder 282 and inhibit any powder from being in contact with second sheath material 290 and/or weld 310.
FIG. 10C depicts a cross-sectional representation of the first design embodiment with second sheath material 290 formed into the tubular around first sheath material 274 after some reduction. FIG. 10C depicts insulated conductor 252 as the insulated conductor passes through reduction rolls 298, shown in FIG. 9. As shown in FIG. 10C, second sheath material 290 is reduced by reduction rolls 298 such that the second sheath material contacts first sheath material 274. In certain embodiments, second sheath material 290 is in tight contact with first sheath material 274 after passing through reduction rolls 298.
FIG. 10D depicts a cross-sectional representation of the first design embodiment as insulated conductor 252 passes through the final reduction step at reduction rolls 304, shown in FIG. 9. As shown in FIG. 10D, there may be some bulging or non-uniformity along the outer and inner surfaces of first sheath material 274 and/or second sheath material 290 due to overlap 308 when the cross-sectional area of insulated conductor 252 is reduced during the final reduction step. Overlap 308 may cause some discontinuity along the inner surface of first sheath material 274. This discontinuity, however, may minimally affect any electric field produced in insulated conductor 252. Thus, insulated conductor 252, following the final reduction step, may have adequate breakdown voltages for use in heating subsurface formations. Second sheath material 290 may provide a sealed corrosion barrier for insulated conductor 252.
FIG. 11A depicts a cross-sectional representation of a second design embodiment of first sheath material 274 inside insulated conductor 252. FIG. 11A depicts insulated conductor 252 as the insulated conductor passes through compression and centralization rolls 280, shown in FIG. 9. As shown in FIG. 11A, first sheath material 274 has gap 312 between the longitudinal edges of the tubular as the first sheath material is formed into the tubular around powder 282 and core material 276.
FIG. 11B depicts a cross-sectional representation of the second design embodiment with second sheath material 290 formed into the tubular and welded around first sheath material 274. FIG. 11B depicts insulated conductor 252 immediately after the insulated conductor passes through welder 296, shown in FIG. 9. As shown in FIG. 11B, first sheath material 274 rests inside the tubular formed by second sheath material 290 (for example, there is a gap between the upper portions of the sheath materials). Weld 310 joins second sheath material 290 to form the tubular around first sheath material 274. In certain embodiments, weld 310 is at a different location than gap 312 to avoid interaction between the weld and powder 282 inside first sheath material 274.
FIG. 11C depicts a cross-sectional representation of the second design embodiment with second sheath material 290 formed into the tubular around first sheath material 274 after some reduction. FIG. 11C depicts insulated conductor 252 as the insulated conductor passes through reduction rolls 298, shown in FIG. 9. As shown in FIG. 11C, second sheath material 290 is reduced by reduction rolls 298 such that the second sheath material contacts first sheath material 274. In certain embodiments, second sheath material 290 is in tight contact with first sheath material 274 after passing through reduction rolls 298. Gap 312 is reduced during reduction of insulated conductor 252 as the insulated conductor passes through reduction rolls 298. In certain embodiments, gap 312 is reduced such that the ends of first sheath material 274 on each side of gap abut each other after the reduction.
FIG. 11D depicts a cross-sectional representation of the second design embodiment as insulated conductor 252 passes through the final reduction step at reduction rolls 304, shown in FIG. 9. As shown in FIG. 11D, there may be some discontinuity along the inner surface of first sheath material 274 at gap 312. This discontinuity, however, may minimally affect any electric field produced in insulated conductor 252. Thus, insulated conductor 252, following the final reduction step, may have adequate breakdown voltages for use in heating subsurface formations.
It is to be understood the invention is not limited to particular systems described which may, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting. As used in this specification, the singular forms “a”, “an” and “the” include plural referents unless the content clearly indicates otherwise. Thus, for example, reference to “a core” includes a combination of two or more cores and reference to “a material” includes mixtures of materials.
In this patent, certain U.S. patents and U.S. patent applications have been incorporated by reference. The text of such U.S. patents and U.S. patent applications is, however, only incorporated by reference to the extent that no conflict exists between such text and the other statements and drawings set forth herein. In the event of such conflict, then any such conflicting text in such incorporated by reference U.S. patents and U.S. patent applications is specifically not incorporated by reference in this patent.
Further modifications and alternative embodiments of various aspects of the invention will be apparent to those skilled in the art in view of this description. Accordingly, this description is to be construed as illustrative only and is for the purpose of teaching those skilled in the art the general manner of carrying out the invention. It is to be understood that the forms of the invention shown and described herein are to be taken as the presently preferred embodiments. Elements and materials may be substituted for those illustrated and described herein, parts and processes may be reversed, and certain features of the invention may be utilized independently, all as would be apparent to one skilled in the art after having the benefit of this description of the invention. Changes may be made in the elements described herein without departing from the spirit and scope of the invention as described in the following claims.

Claims (8)

What is clamed is:
1. A method for forming an insulated conductor heater with a final cross-sectional area, comprising:
placing an insulation layer over at least part of an elongated, cylindrical inner electrical conductor;
placing an elongated, cylindrical outer electrical conductor over at least part of the insulation layer to form an insulated conductor assembly;
performing at least one combination of a cold working step and a heat treating step on the insulated conductor assembly, wherein the at least one combination of the cold working step and the heat treating step comprises:
cold working the insulated conductor assembly to reduce a cross-sectional area of the insulated conductor assembly by at least about 30%; and
heat treating the insulated conductor assembly at a temperature of at least about 870° C.; and
forming the insulated conductor heater with a final cross-sectional area from the insulated conductor assembly by further reducing the cross-sectional area of the insulated conductor assembly after the at least one combination of the cold working step and the heat treating step is completed, wherein further reducing the cross-sectional area of the insulated conductor assembly comprises cold working the insulated conductor assembly to further reduce the cross-sectional area of the insulated conductor assembly by an additional amount ranging between about 5% and about 20% of the cross-sectional area of the insulated conductor assembly after the at least one combination of the cold working step and the heat treating step is completed.
2. The method of claim 1, wherein the amount of reduction of the cross-sectional area of the insulated conductor assembly ranges between about 10% and about 20% of the cross-sectional area of the insulated conductor assembly after the at least one combination of the cold working step and the heat treating step is completed.
3. The method of claim 1, wherein reducing the cross-sectional area of the insulated conductor assembly comprises reducing the cross-sectional area of the outer electrical conductor.
4. The method of claim 1, wherein the insulation layer comprises one or more blocks of insulation.
5. The method of claim 1, wherein the insulated conductor heater with the final cross-sectional area is not heat treated after the at least one combination of the cold working step and the heat treating step is completed.
6. The method of claim 1, wherein reducing the cross-sectional area of the insulated conductor assembly by the amount ranging between about 5% and about 20% increases a dielectric strength of the insulation layer to within 5% of the dielectric strength of the pre-heat treated insulation layer.
7. The method of claim 1, wherein reducing the cross-sectional area of the insulated conductor assembly by the amount ranging between about 5% and about 20% provides a breakdown voltage of between about 12 kV and about 20 kV for the insulated conductor heater with the final cross-sectional area.
8. The method of claim 1, wherein the at least one combination of the cold working step and the heat treating step are repeated more than once prior to forming the insulated conductor heater with the final cross-sectional area.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170171918A1 (en) * 2011-10-07 2017-06-15 Shell Oil Company Forming insulated conductors using a final reduction step after heat treating

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8502120B2 (en) 2010-04-09 2013-08-06 Shell Oil Company Insulating blocks and methods for installation in insulated conductor heaters
US8732946B2 (en) 2010-10-08 2014-05-27 Shell Oil Company Mechanical compaction of insulator for insulated conductor splices
US8943686B2 (en) 2010-10-08 2015-02-03 Shell Oil Company Compaction of electrical insulation for joining insulated conductors
US8857051B2 (en) 2010-10-08 2014-10-14 Shell Oil Company System and method for coupling lead-in conductor to insulated conductor
RU2587459C2 (en) 2011-04-08 2016-06-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Systems for joining insulated conductors
CA3176275A1 (en) 2014-02-18 2015-08-18 Athabasca Oil Corporation Cable-based well heater
JP2017512930A (en) * 2014-04-04 2017-05-25 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Insulated conductors formed using a final rolling step after heat treatment
IT201600081518A1 (en) * 2016-08-03 2018-02-03 C S M Spa IN-LINE AND CONTINUOUS PLANT FOR LOADING AND ANNEALING WITH INDUCTION OF ELECTRIC HEATING ELEMENTS

Citations (260)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1457690A (en) 1923-06-05 Percival iv brine
US1477802A (en) 1921-02-28 1923-12-18 Cutler Hammer Mfg Co Oil-well heater
US2011710A (en) 1928-08-18 1935-08-20 Nat Aniline & Chem Co Inc Apparatus for measuring temperature
US2078051A (en) 1935-04-11 1937-04-20 Electroline Corp Connecter for stranded cable
US2208087A (en) 1939-11-06 1940-07-16 Carlton J Somers Electric heater
US2244255A (en) 1939-01-18 1941-06-03 Electrical Treating Company Well clearing system
US2595728A (en) 1945-03-09 1952-05-06 Westinghouse Electric Corp Polysiloxanes containing allyl radicals
GB676543A (en) 1949-11-14 1952-07-30 Telegraph Constr & Maintenance Improvements in the moulding and jointing of thermoplastic materials for example in the jointing of electric cables
US2634961A (en) 1946-01-07 1953-04-14 Svensk Skifferolje Aktiebolage Method of electrothermal production of shale oil
US2680086A (en) 1950-11-14 1954-06-01 W T Glover & Co Ltd Manufacture of insulated electric conductors
US2732195A (en) 1956-01-24 Ljungstrom
US2757739A (en) 1952-01-07 1956-08-07 Parelex Corp Heating apparatus
US2780450A (en) 1952-03-07 1957-02-05 Svenska Skifferolje Ab Method of recovering oil and gases from non-consolidated bituminous geological formations by a heating treatment in situ
US2789805A (en) 1952-05-27 1957-04-23 Svenska Skifferolje Ab Device for recovering fuel from subterraneous fuel-carrying deposits by heating in their natural location using a chain heat transfer member
US2794504A (en) 1954-05-10 1957-06-04 Union Oil Co Well heater
US2905919A (en) * 1956-01-17 1959-09-22 British Insulated Callenders Electric heating cables
US2923535A (en) 1955-02-11 1960-02-02 Svenska Skifferolje Ab Situ recovery from carbonaceous deposits
US2937228A (en) 1958-12-29 1960-05-17 Robinson Machine Works Inc Coaxial cable splice
US2942223A (en) 1957-08-09 1960-06-21 Gen Electric Electrical resistance heater
US3026940A (en) 1958-05-19 1962-03-27 Electronic Oil Well Heater Inc Oil well temperature indicator and control
US3114417A (en) 1961-08-14 1963-12-17 Ernest T Saftig Electric oil well heater apparatus
US3131763A (en) 1959-12-30 1964-05-05 Texaco Inc Electrical borehole heater
US3141924A (en) 1962-03-16 1964-07-21 Amp Inc Coaxial cable shield braid terminators
US3149672A (en) 1962-05-04 1964-09-22 Jersey Prod Res Co Method and apparatus for electrical heating of oil-bearing formations
US3207220A (en) 1961-06-26 1965-09-21 Chester I Williams Electric well heater
GB1010023A (en) 1963-03-11 1965-11-17 Shell Int Research Heating of underground formations
US3220479A (en) 1960-02-08 1965-11-30 Exxon Production Research Co Formation stabilization system
US3278673A (en) 1963-09-06 1966-10-11 Gore & Ass Conductor insulated with polytetra-fluoroethylene containing a dielectric-dispersionand method of making same
US3299202A (en) 1965-04-02 1967-01-17 Okonite Co Oil well cable
US3316344A (en) 1965-04-26 1967-04-25 Central Electr Generat Board Prevention of icing of electrical conductors
US3342267A (en) 1965-04-29 1967-09-19 Gerald S Cotter Turbo-generator heater for oil and gas wells and pipe lines
US3384704A (en) 1965-07-26 1968-05-21 Amp Inc Connector for composite cables
US3410977A (en) 1966-03-28 1968-11-12 Ando Masao Method of and apparatus for heating the surface part of various construction materials
US3477058A (en) 1968-02-01 1969-11-04 Gen Electric Magnesia insulated heating elements and methods of production
US3492463A (en) 1966-10-20 1970-01-27 Reactor Centrum Nederland Electrical resistance heater
US3515837A (en) 1966-04-01 1970-06-02 Chisso Corp Heat generating pipe
US3515213A (en) 1967-04-19 1970-06-02 Shell Oil Co Shale oil recovery process using heated oil-miscible fluids
GB1204405A (en) 1967-03-22 1970-09-09 Chisso Corp Method for supplying electricity to a heat-generating pipe utilizing skin effect of a.c.
US3547192A (en) 1969-04-04 1970-12-15 Shell Oil Co Method of metal coating and electrically heating a subterranean earth formation
US3562401A (en) 1969-03-03 1971-02-09 Union Carbide Corp Low temperature electric transmission systems
US3580987A (en) 1968-03-26 1971-05-25 Pirelli Electric cable
US3614387A (en) 1969-09-22 1971-10-19 Watlow Electric Mfg Co Electrical heater with an internal thermocouple
US3629551A (en) 1968-10-29 1971-12-21 Chisso Corp Controlling heat generation locally in a heat-generating pipe utilizing skin-effect current
US3657520A (en) 1970-08-20 1972-04-18 Michel A Ragault Heating cable with cold outlets
CA899987A (en) 1972-05-09 Chisso Corporation Method for controlling heat generation locally in a heat-generating pipe utilizing skin effect current
US3672196A (en) 1969-08-02 1972-06-27 Felten & Guilleaume Kabelwerk Method and apparatus for making corrugations in tubes consisting of ductile material
US3679812A (en) 1970-11-13 1972-07-25 Schlumberger Technology Corp Electrical suspension cable for well tools
US3685148A (en) 1970-03-20 1972-08-22 Jack Garfinkel Method for making a wire splice
US3757860A (en) 1972-08-07 1973-09-11 Atlantic Richfield Co Well heating
US3761599A (en) 1972-09-05 1973-09-25 Gen Electric Means for reducing eddy current heating of a tank in electric apparatus
US3790697A (en) 1972-10-30 1974-02-05 Okonite Co Power cable shielding
US3798349A (en) 1970-02-19 1974-03-19 G Gillemot Molded plastic splice casing with combination cable anchorage and cable shielding grounding facility
US3844352A (en) 1971-12-17 1974-10-29 Brown Oil Tools Method for modifying a well to provide gas lift production
US3859503A (en) 1973-06-12 1975-01-07 Richard D Palone Electric heated sucker rod
US3893961A (en) 1974-01-07 1975-07-08 Basil Vivian Edwin Walton Telephone cable splice closure filling composition
US3895180A (en) 1973-04-03 1975-07-15 Walter A Plummer Grease filled cable splice assembly
US3896260A (en) 1973-04-03 1975-07-22 Walter A Plummer Powder filled cable splice assembly
US3955043A (en) 1974-04-11 1976-05-04 General Electric Company High voltage cable splice using foam insulation with thick integral skin in highly stressed regions
US4001760A (en) 1974-06-21 1977-01-04 Pyrotenax Of Canada Limited Heating cables and manufacture thereof
US4110550A (en) 1976-11-01 1978-08-29 Amerace Corporation Electrical connector with adaptor for paper-insulated, lead-jacketed electrical cables and method
US4234755A (en) 1978-06-29 1980-11-18 Amerace Corporation Adaptor for paper-insulated, lead-jacketed electrical cables
US4256945A (en) 1979-08-31 1981-03-17 Iris Associates Alternating current electrically resistive heating element having intrinsic temperature control
US4266992A (en) 1977-09-30 1981-05-12 Les Cables De Lyon Method for end to end connection of mineral-insulated electric cable and assembly for same
US4280046A (en) 1978-12-01 1981-07-21 Tokyo Shibaura Denki Kabushiki Kaisha Sheath heater
US4317003A (en) 1980-01-17 1982-02-23 Gray Stanley J High tensile multiple sheath cable
US4344483A (en) 1981-09-08 1982-08-17 Fisher Charles B Multiple-site underground magnetic heating of hydrocarbons
US4354053A (en) 1978-02-01 1982-10-12 Gold Marvin H Spliced high voltage cable
US4365947A (en) 1978-07-14 1982-12-28 Gk Technologies, Incorporated, General Cable Company Division Apparatus for molding stress control cones insitu on the terminations of insulated high voltage power cables
US4368452A (en) 1981-06-22 1983-01-11 Kerr Jr Robert L Thermal protection of aluminum conductor junctions
US4370518A (en) 1979-12-03 1983-01-25 Hughes Tool Company Splice for lead-coated and insulated conductors
US4403110A (en) 1981-05-15 1983-09-06 Walter Kidde And Company, Inc. Electrical cable splice
US4470459A (en) 1983-05-09 1984-09-11 Halliburton Company Apparatus and method for controlled temperature heating of volumes of hydrocarbonaceous materials in earth formations
US4477376A (en) 1980-03-10 1984-10-16 Gold Marvin H Castable mixture for insulating spliced high voltage cable
US4484022A (en) 1980-11-05 1984-11-20 Hew-Kabel, Heinz Eilentropp Kg Method of making tensile-, pressure-, and moisture-proof connections
EP0130671A2 (en) 1983-05-26 1985-01-09 Metcal Inc. Multiple temperature autoregulating heater
US4496795A (en) 1984-05-16 1985-01-29 Harvey Hubbell Incorporated Electrical cable splicing system
US4520229A (en) 1983-01-03 1985-05-28 Amerace Corporation Splice connector housing and assembly of cables employing same
US4524827A (en) 1983-04-29 1985-06-25 Iit Research Institute Single well stimulation for the recovery of liquid hydrocarbons from subsurface formations
US4532375A (en) 1981-10-22 1985-07-30 Ricwil, Incorporated Heating device for utilizing the skin effect of alternating current
US4538682A (en) 1983-09-08 1985-09-03 Mcmanus James W Method and apparatus for removing oil well paraffin
US4549073A (en) 1981-11-06 1985-10-22 Oximetrix, Inc. Current controller for resistive heating element
US4570715A (en) 1984-04-06 1986-02-18 Shell Oil Company Formation-tailored method and apparatus for uniformly heating long subterranean intervals at high temperature
US4572299A (en) 1984-10-30 1986-02-25 Shell Oil Company Heater cable installation
US4585066A (en) 1984-11-30 1986-04-29 Shell Oil Company Well treating process for installing a cable bundle containing strands of changing diameter
US4614392A (en) 1985-01-15 1986-09-30 Moore Boyd B Well bore electric pump power cable connector for multiple individual, insulated conductors of a pump power cable
US4623401A (en) 1984-03-06 1986-11-18 Metcal, Inc. Heat treatment with an autoregulating heater
US4626665A (en) 1985-06-24 1986-12-02 Shell Oil Company Metal oversheathed electrical resistance heater
US4639712A (en) 1984-10-25 1987-01-27 Nippondenso Co., Ltd. Sheathed heater
US4645906A (en) 1985-03-04 1987-02-24 Thermon Manufacturing Company Reduced resistance skin effect heat generating system
US4662437A (en) 1985-11-14 1987-05-05 Atlantic Richfield Company Electrically stimulated well production system with flexible tubing conductor
CN85109010A (en) 1985-12-09 1987-06-17 国际壳牌研究有限公司 Installation contains the well treatment process that becomes diameter share of cable bundle
US4694907A (en) 1986-02-21 1987-09-22 Carbotek, Inc. Thermally-enhanced oil recovery method and apparatus
US4695713A (en) 1982-09-30 1987-09-22 Metcal, Inc. Autoregulating, electrically shielded heater
US4698583A (en) 1985-03-26 1987-10-06 Raychem Corporation Method of monitoring a heater for faults
US4701587A (en) 1979-08-31 1987-10-20 Metcal, Inc. Shielded heating element having intrinsic temperature control
US4704514A (en) 1985-01-11 1987-11-03 Egmond Cor F Van Heating rate variant elongated electrical resistance heater
US4716960A (en) 1986-07-14 1988-01-05 Production Technologies International, Inc. Method and system for introducing electric current into a well
US4717814A (en) 1983-06-27 1988-01-05 Metcal, Inc. Slotted autoregulating heater
US4733057A (en) 1985-04-19 1988-03-22 Raychem Corporation Sheet heater
US4752673A (en) 1982-12-01 1988-06-21 Metcal, Inc. Autoregulating heater
US4785163A (en) 1985-03-26 1988-11-15 Raychem Corporation Method for monitoring a heater
US4786760A (en) 1985-10-25 1988-11-22 Raychem Gmbh Cable connection
EP0107927B1 (en) 1982-09-30 1988-12-07 Metcal Inc. Autoregulating electrically shielded heater
US4794226A (en) 1983-05-26 1988-12-27 Metcal, Inc. Self-regulating porous heater device
US4814587A (en) 1986-06-10 1989-03-21 Metcal, Inc. High power self-regulating heater
US4821798A (en) 1987-06-09 1989-04-18 Ors Development Corporation Heating system for rathole oil well
CA1253555A (en) 1985-11-21 1989-05-02 Cornelis F.H. Van Egmond Heating rate variant elongated electrical resistance heater
US4834825A (en) 1987-09-21 1989-05-30 Robert Adams Assembly for connecting multi-duct conduits
US4837409A (en) 1984-03-02 1989-06-06 Homac Mfg. Company Submerisible insulated splice assemblies
US4849611A (en) 1985-12-16 1989-07-18 Raychem Corporation Self-regulating heater employing reactive components
US4859200A (en) 1988-12-05 1989-08-22 Baker Hughes Incorporated Downhole electrical connector for submersible pump
US4886118A (en) 1983-03-21 1989-12-12 Shell Oil Company Conductively heating a subterranean oil shale to create permeability and subsequently produce oil
US4947672A (en) 1989-04-03 1990-08-14 Burndy Corporation Hydraulic compression tool having an improved relief and release valve
US4979296A (en) 1986-07-25 1990-12-25 Shell Oil Company Method for fabricating helical flowline bundles
US4985313A (en) 1985-01-14 1991-01-15 Raychem Limited Wire and cable
US5040601A (en) 1990-06-21 1991-08-20 Baker Hughes Incorporated Horizontal well bore system
CA1288043C (en) 1986-12-15 1991-08-27 Peter Van Meurs Conductively heating a subterranean oil shale to create permeabilityand subsequently produce oil
US5060287A (en) 1990-12-04 1991-10-22 Shell Oil Company Heater utilizing copper-nickel alloy core
US5066852A (en) 1990-09-17 1991-11-19 Teledyne Ind. Inc. Thermoplastic end seal for electric heating elements
US5065501A (en) 1988-11-29 1991-11-19 Amp Incorporated Generating electromagnetic fields in a self regulating temperature heater by positioning of a current return bus
US5065818A (en) 1991-01-07 1991-11-19 Shell Oil Company Subterranean heaters
US5070533A (en) 1990-11-07 1991-12-03 Uentech Corporation Robust electrical heating systems for mineral wells
US5073625A (en) 1983-05-26 1991-12-17 Metcal, Inc. Self-regulating porous heating device
US5082494A (en) 1987-12-16 1992-01-21 Crompton Design Manufacturing Limited Materials for and manufacture of fire and heat resistant components
US5106701A (en) 1990-02-01 1992-04-21 Fujikura Ltd. Copper alloy wire, and insulated electric wires and multiple core parallel bonded wires made of the same
US5117912A (en) 1991-05-24 1992-06-02 Marathon Oil Company Method of positioning tubing within a horizontal well
US5152341A (en) 1990-03-09 1992-10-06 Raymond S. Kasevich Electromagnetic method and apparatus for the decontamination of hazardous material-containing volumes
US5182427A (en) 1990-09-20 1993-01-26 Metcal, Inc. Self-regulating heater utilizing ferrite-type body
US5189283A (en) 1991-08-28 1993-02-23 Shell Oil Company Current to power crossover heater control
US5207273A (en) 1990-09-17 1993-05-04 Production Technologies International Inc. Method and apparatus for pumping wells
US5209987A (en) 1983-07-08 1993-05-11 Raychem Limited Wire and cable
US5226961A (en) 1992-06-12 1993-07-13 Shell Oil Company High temperature wellbore cement slurry
US5231249A (en) 1990-02-23 1993-07-27 The Furukawa Electric Co., Ltd. Insulated power cable
US5245161A (en) 1990-08-31 1993-09-14 Tokyo Kogyo Boyeki Shokai, Ltd. Electric heater
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
US5278353A (en) 1992-06-05 1994-01-11 Powertech Labs Inc. Automatic splice
US5289882A (en) 1991-02-06 1994-03-01 Boyd B. Moore Sealed electrical conductor method and arrangement for use with a well bore in hazardous areas
US5315065A (en) 1992-08-21 1994-05-24 Donovan James P O Versatile electrically insulating waterproof connectors
US5316492A (en) 1989-05-03 1994-05-31 Nkf Kabel B.V. Plug-in connection for high-voltage plastic cable
US5336851A (en) 1989-12-27 1994-08-09 Sumitomo Electric Industries, Ltd. Insulated electrical conductor wire having a high operating temperature
US5403977A (en) 1990-12-20 1995-04-04 Raychem Limited Cable-sealing mastic material
US5406030A (en) 1990-08-24 1995-04-11 Electric Power Research Institute High voltage, high-current power cable termination with single condenser grading stack
US5408047A (en) 1990-10-25 1995-04-18 Minnesota Mining And Manufacturing Company Transition joint for oil-filled cables
US5443665A (en) 1991-04-05 1995-08-22 Sumitomo Electric Industries, Ltd. Method of manufacturing a copper electrical conductor, especially for transmitting audio and video signals and quality control method for such conductors
US5453599A (en) 1994-02-14 1995-09-26 Hoskins Manufacturing Company Tubular heating element with insulating core
US5463187A (en) 1992-09-30 1995-10-31 The George Ingraham Corp. Flexible multi-duct conduit assembly
US5483414A (en) 1992-04-01 1996-01-09 Vaisala Oy Electrical impedance detector for measurement of physical quantities, in particular of temperature
US5512732A (en) 1990-09-20 1996-04-30 Thermon Manufacturing Company Switch controlled, zone-type heating cable and method
US5528824A (en) 1993-05-18 1996-06-25 Baker Hughes Incorporated Method of forming a double armor cable with auxiliary line for an electrical submersible pump
US5553478A (en) 1994-04-08 1996-09-10 Burndy Corporation Hand-held compression tool
US5579575A (en) 1992-04-01 1996-12-03 Raychem S.A. Method and apparatus for forming an electrical connection
US5594211A (en) 1995-02-22 1997-01-14 Burndy Corporation Electrical solder splice connector
US5606148A (en) 1993-01-15 1997-02-25 Raychem Gmbh Cable joint
US5619611A (en) 1995-12-12 1997-04-08 Tub Tauch-Und Baggertechnik Gmbh Device for removing downhole deposits utilizing tubular housing and passing electric current through fluid heating medium contained therein
US5621844A (en) 1995-03-01 1997-04-15 Uentech Corporation Electrical heating of mineral well deposits using downhole impedance transformation networks
WO1997023924A1 (en) 1995-12-21 1997-07-03 Raychem S.A. Electrical connector
US5667009A (en) 1991-02-06 1997-09-16 Moore; Boyd B. Rubber boots for electrical connection for down hole well
US5669275A (en) 1995-08-18 1997-09-23 Mills; Edward Otis Conductor insulation remover
US5683273A (en) 1996-07-24 1997-11-04 The Whitaker Corporation Mechanical splice connector for cable
US5713415A (en) 1995-03-01 1998-02-03 Uentech Corporation Low flux leakage cables and cable terminations for A.C. electrical heating of oil deposits
US5782301A (en) 1996-10-09 1998-07-21 Baker Hughes Incorporated Oil well heater cable
US5784530A (en) 1996-02-13 1998-07-21 Eor International, Inc. Iterated electrodes for oil wells
US5788376A (en) 1996-07-01 1998-08-04 General Motors Corporation Temperature sensor
US5801332A (en) 1995-08-31 1998-09-01 Minnesota Mining And Manufacturing Company Elastically recoverable silicone splice cover
US5854472A (en) 1996-05-29 1998-12-29 Sperika Enterprises Ltd. Low-voltage and low flux density heating system
US5875283A (en) 1996-10-11 1999-02-23 Lufran Incorporated Purged grounded immersion heater
US5911898A (en) 1995-05-25 1999-06-15 Electric Power Research Institute Method and apparatus for providing multiple autoregulated temperatures
US5987745A (en) 1993-06-07 1999-11-23 Kabeldon Ab Method and devices for jointing cables
US6015015A (en) 1995-06-20 2000-01-18 Bj Services Company U.S.A. Insulated and/or concentric coiled tubing
US6023554A (en) 1997-05-20 2000-02-08 Shell Oil Company Electrical heater
US6056057A (en) 1996-10-15 2000-05-02 Shell Oil Company Heater well method and apparatus
US6079499A (en) 1996-10-15 2000-06-27 Shell Oil Company Heater well method and apparatus
US6102122A (en) 1997-06-11 2000-08-15 Shell Oil Company Control of heat injection based on temperature and in-situ stress measurement
JP2000340350A (en) 1999-05-28 2000-12-08 Kyocera Corp Silicon nitride ceramic heater and its manufacture
US6269876B1 (en) 1998-03-06 2001-08-07 Shell Oil Company Electrical heater
US6288372B1 (en) 1999-11-03 2001-09-11 Tyco Electronics Corporation Electric cable having braidless polymeric ground plane providing fault detection
US6313431B1 (en) 1998-07-09 2001-11-06 Illinois Tool Works Inc. Plasma cutter for auxiliary power output of a power source
US6326546B1 (en) 1996-10-03 2001-12-04 Per Karlsson Strain relief for a screen cable
US20020027001A1 (en) 2000-04-24 2002-03-07 Wellington Scott L. In situ thermal processing of a coal formation to produce a selected gas mixture
US20020028070A1 (en) 1998-09-14 2002-03-07 Petter Holen Heating system for crude oil transporting metallic tubes
US6355318B1 (en) 1996-11-14 2002-03-12 Shawcor Ltd. Heat shrinkable member
US6364721B2 (en) 1999-12-27 2002-04-02 Stewart, Iii Kenneth G. Wire connector
WO2000019061A9 (en) 1999-09-24 2002-04-25 System, apparatus, and method for installing control lines in a well
US6423952B1 (en) 1999-10-09 2002-07-23 Airbus Deutschland Gmbh Heater arrangement with connector or terminating element and fluoropolymer seal, and method of making the same
US6452105B2 (en) 2000-01-12 2002-09-17 Meggitt Safety Systems, Inc. Coaxial cable assembly with a discontinuous outer jacket
US6472600B1 (en) 1997-04-07 2002-10-29 Cables Pirelli Connecting cord junction
US20030066642A1 (en) 2000-04-24 2003-04-10 Wellington Scott Lee In situ thermal processing of a coal formation producing a mixture with oxygenated hydrocarbons
US20030079877A1 (en) 2001-04-24 2003-05-01 Wellington Scott Lee In situ thermal processing of a relatively impermeable formation in a reducing environment
US20030085034A1 (en) 2000-04-24 2003-05-08 Wellington Scott Lee In situ thermal processing of a coal formation to produce pyrolsis products
US6583351B1 (en) 2002-01-11 2003-06-24 Bwx Technologies, Inc. Superconducting cable-in-conduit low resistance splice
US6585046B2 (en) 2000-08-28 2003-07-01 Baker Hughes Incorporated Live well heater cable
US6588504B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
US20030146002A1 (en) 2001-04-24 2003-08-07 Vinegar Harold J. Removable heat sources for in situ thermal processing of an oil shale formation
US20030196789A1 (en) 2001-10-24 2003-10-23 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation and upgrading of produced fluids prior to further treatment
US6698515B2 (en) 2000-04-24 2004-03-02 Shell Oil Company In situ thermal processing of a coal formation using a relatively slow heating rate
US6715546B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ production of synthesis gas from a hydrocarbon containing formation through a heat source wellbore
US6715548B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce nitrogen containing formation fluids
US20040140096A1 (en) 2002-10-24 2004-07-22 Sandberg Chester Ledlie Insulated conductor temperature limited heaters
US6773311B2 (en) 2002-02-06 2004-08-10 Fci Americas Technology, Inc. Electrical splice connector
US20040163801A1 (en) 2001-08-27 2004-08-26 Dalrymple Larry V. Heater Cable and method for manufacturing
US20050006128A1 (en) 2003-07-10 2005-01-13 Yazaki Corporation Shielding structure of shielding electric wire
US6849800B2 (en) 2001-03-19 2005-02-01 Hewlett-Packard Development Company, L.P. Board-level conformal EMI shield having an electrically-conductive polymer coating over a thermally-conductive dielectric coating
US6886638B2 (en) 2001-10-03 2005-05-03 Schlumbergr Technology Corporation Field weldable connections
US6942032B2 (en) 2002-11-06 2005-09-13 Thomas A. La Rovere Resistive down hole heating tool
US6948562B2 (en) 2001-04-24 2005-09-27 Shell Oil Company Production of a blending agent using an in situ thermal process in a relatively permeable formation
US6958704B2 (en) 2000-01-24 2005-10-25 Shell Oil Company Permanent downhole, wireless, two-way telemetry backbone using redundant repeaters
US6963053B2 (en) 2001-07-03 2005-11-08 Cci Thermal Technologies, Inc. Corrugated metal ribbon heating element
US6969123B2 (en) 2001-10-24 2005-11-29 Shell Oil Company Upgrading and mining of coal
US20050269313A1 (en) 2004-04-23 2005-12-08 Vinegar Harold J Temperature limited heaters with high power factors
US7011154B2 (en) 2000-04-24 2006-03-14 Shell Oil Company In situ recovery from a kerogen and liquid hydrocarbon containing formation
US7066254B2 (en) 2001-04-24 2006-06-27 Shell Oil Company In situ thermal processing of a tar sands formation
US7077199B2 (en) 2001-10-24 2006-07-18 Shell Oil Company In situ thermal processing of an oil reservoir formation
US7090013B2 (en) 2001-10-24 2006-08-15 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce heated fluids
US7096953B2 (en) 2000-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a coal formation using a movable heating element
US7104319B2 (en) 2001-10-24 2006-09-12 Shell Oil Company In situ thermal processing of a heavy oil diatomite formation
US7121342B2 (en) 2003-04-24 2006-10-17 Shell Oil Company Thermal processes for subsurface formations
US20060231283A1 (en) 2005-04-19 2006-10-19 Stagi William R Cable connector having fluid reservoir
WO2006116078A1 (en) 2005-04-22 2006-11-02 Shell Internationale Research Maatschappij B.V. Insulated conductor temperature limited heater for subsurface heating coupled in a three-phase wye configuration
US7153373B2 (en) 2000-12-14 2006-12-26 Caterpillar Inc Heat and corrosion resistant cast CF8C stainless steel with improved high temperature strength and ductility
US7165615B2 (en) 2001-10-24 2007-01-23 Shell Oil Company In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden
US7172038B2 (en) 1997-10-27 2007-02-06 Halliburton Energy Services, Inc. Well system
US20070127897A1 (en) 2005-10-24 2007-06-07 John Randy C Subsurface heaters with low sulfidation rates
US20070173122A1 (en) 2006-01-26 2007-07-26 Yazaki Corporation Method of processing end portion of shielded wire and end portion processing apparatus
US7258752B2 (en) 2003-03-26 2007-08-21 Ut-Battelle Llc Wrought stainless steel compositions having engineered microstructures for improved heat resistance
US7337841B2 (en) 2004-03-24 2008-03-04 Halliburton Energy Services, Inc. Casing comprising stress-absorbing materials and associated methods of use
US20080073104A1 (en) 2006-09-26 2008-03-27 Barberree Daniel A Mineral insulated metal sheathed cable connector and method of forming the connector
US20080135244A1 (en) 2006-10-20 2008-06-12 David Scott Miller Heating hydrocarbon containing formations in a line drive staged process
US7398823B2 (en) 2005-01-10 2008-07-15 Conocophillips Company Selective electromagnetic production tool
US7405358B2 (en) 2006-10-17 2008-07-29 Quick Connectors, Inc Splice for down hole electrical submersible pump cable
US7435037B2 (en) 2005-04-22 2008-10-14 Shell Oil Company Low temperature barriers with heat interceptor wells for in situ processes
US7486498B2 (en) 2004-01-12 2009-02-03 Case Western Reserve University Strong substrate alloy and compressively stressed dielectric film for capacitor with high energy density
US20090070997A1 (en) 2007-05-15 2009-03-19 Sealco Commercial Vehicle Products, Inc. Methods for making electrical terminals and for fabricating electrical connectors
US20090095479A1 (en) 2007-04-20 2009-04-16 John Michael Karanikas Production from multiple zones of a tar sands formation
US7533719B2 (en) 2006-04-21 2009-05-19 Shell Oil Company Wellhead with non-ferromagnetic materials
US7563983B2 (en) 2002-04-23 2009-07-21 Ctc Cable Corporation Collet-type splice and dead end for use with an aluminum conductor composite core reinforced cable
US20090189617A1 (en) 2007-10-19 2009-07-30 David Burns Continuous subsurface heater temperature measurement
US20100038112A1 (en) 2008-08-15 2010-02-18 3M Innovative Properties Company Stranded composite cable and method of making and using
US20100044068A1 (en) 2006-09-14 2010-02-25 Biovidvienda S.I. Subsea umbilical
US20100044781A1 (en) 2007-03-28 2010-02-25 Akihito Tanabe Semiconductor device
US20100071903A1 (en) 2008-04-18 2010-03-25 Shell Oil Company Mines and tunnels for use in treating subsurface hydrocarbon containing formations
US20100089584A1 (en) 2008-10-13 2010-04-15 David Booth Burns Double insulated heaters for treating subsurface formations
US7730936B2 (en) 2007-02-07 2010-06-08 Schlumberger Technology Corporation Active cable for wellbore heating and distributed temperature sensing
US7764871B2 (en) 2006-08-29 2010-07-27 Star Progetti Tecnologie Applicate Infrared heat irradiating device
US20100190649A1 (en) 2009-01-29 2010-07-29 Doll David W Low loss joint for superconducting wire
US20100258265A1 (en) 2009-04-10 2010-10-14 John Michael Karanikas Recovering energy from a subsurface formation
US20110124228A1 (en) 2009-10-09 2011-05-26 John Matthew Coles Compacted coupling joint for coupling insulated conductors
US20110134958A1 (en) 2009-10-09 2011-06-09 Dhruv Arora Methods for assessing a temperature in a subsurface formation
US20110132661A1 (en) 2009-10-09 2011-06-09 Patrick Silas Harmason Parallelogram coupling joint for coupling insulated conductors
US20110247805A1 (en) 2010-04-09 2011-10-13 De St Remey Edward Everett Insulated conductor heaters with semiconductor layers
US20110247818A1 (en) 2010-04-09 2011-10-13 Ronald Marshall Bass Variable thickness insulated conductors
US8122957B2 (en) 2002-09-03 2012-02-28 Baker Hughes Incorporated Sand control method using porous particulate materials
US20120084978A1 (en) 2010-10-08 2012-04-12 Carrie Elizabeth Hartford Compaction of electrical insulation for joining insulated conductors
US20120085564A1 (en) 2010-10-08 2012-04-12 D Angelo Iii Charles Hydroformed splice for insulated conductors
US20120110845A1 (en) 2010-10-08 2012-05-10 David Booth Burns System and method for coupling lead-in conductor to insulated conductor
US20120255772A1 (en) 2011-04-08 2012-10-11 Shell Oil Company Systems for joining insulated conductors
US20130087327A1 (en) 2011-10-07 2013-04-11 Shell Oil Company Using dielectric properties of an insulated conductor in a subsurface formation to assess properties of the insulated conductor
US20130086803A1 (en) 2011-10-07 2013-04-11 Shell Oil Company Forming a tubular around insulated conductors and/or tubulars
US20130087383A1 (en) 2011-10-07 2013-04-11 Shell Oil Company Integral splice for insulated conductors
US8631866B2 (en) 2010-04-09 2014-01-21 Shell Oil Company Leak detection in circulated fluid systems for heating subsurface formations
US8701769B2 (en) 2010-04-09 2014-04-22 Shell Oil Company Methods for treating hydrocarbon formations based on geology

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5911196B2 (en) * 1978-02-22 1984-03-14 株式会社日立ホームテック Manufacturing method of sheathed heater
JPS574196U (en) * 1980-06-09 1982-01-09
US4491822A (en) 1981-11-02 1985-01-01 Xco International, Inc. Heat sensitive cable
DE3334853A1 (en) 1983-09-27 1985-04-11 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt Method for producing tubular shell heaters
EP0382359B1 (en) 1989-01-28 1993-03-24 City Electrical Factors Ltd. Method for making a mineral-insulated cable
EP0393264A1 (en) 1989-04-18 1990-10-24 Inco Alloys Limited Method for making mineral insulated metal sheathed cables
DE69307236T2 (en) * 1992-09-16 1997-07-17 Gen Director Of National Resea Process for the production of a conductive material based on copper alloy
US5769974A (en) * 1997-02-03 1998-06-23 Crs Holdings, Inc. Process for improving magnetic performance in a free-machining ferritic stainless steel
DE69930290T2 (en) 1998-09-25 2006-12-14 Tesco Corp., Calgary SYSTEM, APPARATUS AND METHOD FOR INSTALLING CONTROL LINES IN A FOOD PITCH
US6143241A (en) * 1999-02-09 2000-11-07 Chrysalis Technologies, Incorporated Method of manufacturing metallic products such as sheet by cold working and flash annealing
JP3891826B2 (en) * 2001-11-07 2007-03-14 助川電気工業株式会社 Heater adapter
JP4233998B2 (en) * 2003-02-13 2009-03-04 日本特殊陶業株式会社 Manufacturing method of sheathed heater and manufacturing method of glow plug
RU2248442C1 (en) * 2003-09-10 2005-03-20 Мельников Виктор Ильич Method and device for liquidation and prevention of forming of deposits and obstructions in oil and gas wells
CA2871784A1 (en) * 2005-10-24 2007-10-04 Shell Internationale Research Maatschappij B.V. Systems, methods and processes for use in treating subsurface formations
JO3139B1 (en) * 2011-10-07 2017-09-20 Shell Int Research Forming insulated conductors using a final reduction step after heat treating

Patent Citations (524)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA899987A (en) 1972-05-09 Chisso Corporation Method for controlling heat generation locally in a heat-generating pipe utilizing skin effect current
US1457690A (en) 1923-06-05 Percival iv brine
US2732195A (en) 1956-01-24 Ljungstrom
US1477802A (en) 1921-02-28 1923-12-18 Cutler Hammer Mfg Co Oil-well heater
US2011710A (en) 1928-08-18 1935-08-20 Nat Aniline & Chem Co Inc Apparatus for measuring temperature
US2078051A (en) 1935-04-11 1937-04-20 Electroline Corp Connecter for stranded cable
US2244255A (en) 1939-01-18 1941-06-03 Electrical Treating Company Well clearing system
US2208087A (en) 1939-11-06 1940-07-16 Carlton J Somers Electric heater
US2595728A (en) 1945-03-09 1952-05-06 Westinghouse Electric Corp Polysiloxanes containing allyl radicals
US2634961A (en) 1946-01-07 1953-04-14 Svensk Skifferolje Aktiebolage Method of electrothermal production of shale oil
GB676543A (en) 1949-11-14 1952-07-30 Telegraph Constr & Maintenance Improvements in the moulding and jointing of thermoplastic materials for example in the jointing of electric cables
US2680086A (en) 1950-11-14 1954-06-01 W T Glover & Co Ltd Manufacture of insulated electric conductors
US2757739A (en) 1952-01-07 1956-08-07 Parelex Corp Heating apparatus
US2780450A (en) 1952-03-07 1957-02-05 Svenska Skifferolje Ab Method of recovering oil and gases from non-consolidated bituminous geological formations by a heating treatment in situ
US2789805A (en) 1952-05-27 1957-04-23 Svenska Skifferolje Ab Device for recovering fuel from subterraneous fuel-carrying deposits by heating in their natural location using a chain heat transfer member
US2794504A (en) 1954-05-10 1957-06-04 Union Oil Co Well heater
US2923535A (en) 1955-02-11 1960-02-02 Svenska Skifferolje Ab Situ recovery from carbonaceous deposits
US2905919A (en) * 1956-01-17 1959-09-22 British Insulated Callenders Electric heating cables
US2942223A (en) 1957-08-09 1960-06-21 Gen Electric Electrical resistance heater
US3026940A (en) 1958-05-19 1962-03-27 Electronic Oil Well Heater Inc Oil well temperature indicator and control
US2937228A (en) 1958-12-29 1960-05-17 Robinson Machine Works Inc Coaxial cable splice
US3131763A (en) 1959-12-30 1964-05-05 Texaco Inc Electrical borehole heater
US3220479A (en) 1960-02-08 1965-11-30 Exxon Production Research Co Formation stabilization system
US3207220A (en) 1961-06-26 1965-09-21 Chester I Williams Electric well heater
US3114417A (en) 1961-08-14 1963-12-17 Ernest T Saftig Electric oil well heater apparatus
US3141924A (en) 1962-03-16 1964-07-21 Amp Inc Coaxial cable shield braid terminators
US3149672A (en) 1962-05-04 1964-09-22 Jersey Prod Res Co Method and apparatus for electrical heating of oil-bearing formations
GB1010023A (en) 1963-03-11 1965-11-17 Shell Int Research Heating of underground formations
US3278673A (en) 1963-09-06 1966-10-11 Gore & Ass Conductor insulated with polytetra-fluoroethylene containing a dielectric-dispersionand method of making same
US3299202A (en) 1965-04-02 1967-01-17 Okonite Co Oil well cable
US3316344A (en) 1965-04-26 1967-04-25 Central Electr Generat Board Prevention of icing of electrical conductors
US3342267A (en) 1965-04-29 1967-09-19 Gerald S Cotter Turbo-generator heater for oil and gas wells and pipe lines
US3384704A (en) 1965-07-26 1968-05-21 Amp Inc Connector for composite cables
US3410977A (en) 1966-03-28 1968-11-12 Ando Masao Method of and apparatus for heating the surface part of various construction materials
US3515837A (en) 1966-04-01 1970-06-02 Chisso Corp Heat generating pipe
US3492463A (en) 1966-10-20 1970-01-27 Reactor Centrum Nederland Electrical resistance heater
GB1204405A (en) 1967-03-22 1970-09-09 Chisso Corp Method for supplying electricity to a heat-generating pipe utilizing skin effect of a.c.
US3515213A (en) 1967-04-19 1970-06-02 Shell Oil Co Shale oil recovery process using heated oil-miscible fluids
US3477058A (en) 1968-02-01 1969-11-04 Gen Electric Magnesia insulated heating elements and methods of production
US3580987A (en) 1968-03-26 1971-05-25 Pirelli Electric cable
US3629551A (en) 1968-10-29 1971-12-21 Chisso Corp Controlling heat generation locally in a heat-generating pipe utilizing skin-effect current
US3562401A (en) 1969-03-03 1971-02-09 Union Carbide Corp Low temperature electric transmission systems
US3547192A (en) 1969-04-04 1970-12-15 Shell Oil Co Method of metal coating and electrically heating a subterranean earth formation
US3672196A (en) 1969-08-02 1972-06-27 Felten & Guilleaume Kabelwerk Method and apparatus for making corrugations in tubes consisting of ductile material
US3614387A (en) 1969-09-22 1971-10-19 Watlow Electric Mfg Co Electrical heater with an internal thermocouple
US3798349A (en) 1970-02-19 1974-03-19 G Gillemot Molded plastic splice casing with combination cable anchorage and cable shielding grounding facility
US3685148A (en) 1970-03-20 1972-08-22 Jack Garfinkel Method for making a wire splice
US3657520A (en) 1970-08-20 1972-04-18 Michel A Ragault Heating cable with cold outlets
US3679812A (en) 1970-11-13 1972-07-25 Schlumberger Technology Corp Electrical suspension cable for well tools
US3844352A (en) 1971-12-17 1974-10-29 Brown Oil Tools Method for modifying a well to provide gas lift production
US3757860A (en) 1972-08-07 1973-09-11 Atlantic Richfield Co Well heating
US3761599A (en) 1972-09-05 1973-09-25 Gen Electric Means for reducing eddy current heating of a tank in electric apparatus
US3790697A (en) 1972-10-30 1974-02-05 Okonite Co Power cable shielding
US3895180A (en) 1973-04-03 1975-07-15 Walter A Plummer Grease filled cable splice assembly
US3896260A (en) 1973-04-03 1975-07-22 Walter A Plummer Powder filled cable splice assembly
US3859503A (en) 1973-06-12 1975-01-07 Richard D Palone Electric heated sucker rod
US3893961A (en) 1974-01-07 1975-07-08 Basil Vivian Edwin Walton Telephone cable splice closure filling composition
US3955043A (en) 1974-04-11 1976-05-04 General Electric Company High voltage cable splice using foam insulation with thick integral skin in highly stressed regions
US4001760A (en) 1974-06-21 1977-01-04 Pyrotenax Of Canada Limited Heating cables and manufacture thereof
US4110550A (en) 1976-11-01 1978-08-29 Amerace Corporation Electrical connector with adaptor for paper-insulated, lead-jacketed electrical cables and method
US4266992A (en) 1977-09-30 1981-05-12 Les Cables De Lyon Method for end to end connection of mineral-insulated electric cable and assembly for same
US4354053A (en) 1978-02-01 1982-10-12 Gold Marvin H Spliced high voltage cable
US4234755A (en) 1978-06-29 1980-11-18 Amerace Corporation Adaptor for paper-insulated, lead-jacketed electrical cables
US4365947A (en) 1978-07-14 1982-12-28 Gk Technologies, Incorporated, General Cable Company Division Apparatus for molding stress control cones insitu on the terminations of insulated high voltage power cables
US4280046A (en) 1978-12-01 1981-07-21 Tokyo Shibaura Denki Kabushiki Kaisha Sheath heater
US4256945A (en) 1979-08-31 1981-03-17 Iris Associates Alternating current electrically resistive heating element having intrinsic temperature control
US4701587A (en) 1979-08-31 1987-10-20 Metcal, Inc. Shielded heating element having intrinsic temperature control
US4370518A (en) 1979-12-03 1983-01-25 Hughes Tool Company Splice for lead-coated and insulated conductors
US4317003A (en) 1980-01-17 1982-02-23 Gray Stanley J High tensile multiple sheath cable
US4477376A (en) 1980-03-10 1984-10-16 Gold Marvin H Castable mixture for insulating spliced high voltage cable
US4484022A (en) 1980-11-05 1984-11-20 Hew-Kabel, Heinz Eilentropp Kg Method of making tensile-, pressure-, and moisture-proof connections
US4403110A (en) 1981-05-15 1983-09-06 Walter Kidde And Company, Inc. Electrical cable splice
US4368452A (en) 1981-06-22 1983-01-11 Kerr Jr Robert L Thermal protection of aluminum conductor junctions
US4344483A (en) 1981-09-08 1982-08-17 Fisher Charles B Multiple-site underground magnetic heating of hydrocarbons
US4532375A (en) 1981-10-22 1985-07-30 Ricwil, Incorporated Heating device for utilizing the skin effect of alternating current
US4549073A (en) 1981-11-06 1985-10-22 Oximetrix, Inc. Current controller for resistive heating element
US4695713A (en) 1982-09-30 1987-09-22 Metcal, Inc. Autoregulating, electrically shielded heater
EP0107927B1 (en) 1982-09-30 1988-12-07 Metcal Inc. Autoregulating electrically shielded heater
US4752673A (en) 1982-12-01 1988-06-21 Metcal, Inc. Autoregulating heater
US4520229A (en) 1983-01-03 1985-05-28 Amerace Corporation Splice connector housing and assembly of cables employing same
US4886118A (en) 1983-03-21 1989-12-12 Shell Oil Company Conductively heating a subterranean oil shale to create permeability and subsequently produce oil
US4524827A (en) 1983-04-29 1985-06-25 Iit Research Institute Single well stimulation for the recovery of liquid hydrocarbons from subsurface formations
US4470459A (en) 1983-05-09 1984-09-11 Halliburton Company Apparatus and method for controlled temperature heating of volumes of hydrocarbonaceous materials in earth formations
US5073625A (en) 1983-05-26 1991-12-17 Metcal, Inc. Self-regulating porous heating device
US4794226A (en) 1983-05-26 1988-12-27 Metcal, Inc. Self-regulating porous heater device
EP0130671A2 (en) 1983-05-26 1985-01-09 Metcal Inc. Multiple temperature autoregulating heater
US4717814A (en) 1983-06-27 1988-01-05 Metcal, Inc. Slotted autoregulating heater
US5209987A (en) 1983-07-08 1993-05-11 Raychem Limited Wire and cable
US4538682A (en) 1983-09-08 1985-09-03 Mcmanus James W Method and apparatus for removing oil well paraffin
US4837409A (en) 1984-03-02 1989-06-06 Homac Mfg. Company Submerisible insulated splice assemblies
US4623401A (en) 1984-03-06 1986-11-18 Metcal, Inc. Heat treatment with an autoregulating heater
US4570715A (en) 1984-04-06 1986-02-18 Shell Oil Company Formation-tailored method and apparatus for uniformly heating long subterranean intervals at high temperature
US4496795A (en) 1984-05-16 1985-01-29 Harvey Hubbell Incorporated Electrical cable splicing system
US4639712A (en) 1984-10-25 1987-01-27 Nippondenso Co., Ltd. Sheathed heater
US4572299A (en) 1984-10-30 1986-02-25 Shell Oil Company Heater cable installation
US4585066A (en) 1984-11-30 1986-04-29 Shell Oil Company Well treating process for installing a cable bundle containing strands of changing diameter
US4704514A (en) 1985-01-11 1987-11-03 Egmond Cor F Van Heating rate variant elongated electrical resistance heater
US4985313A (en) 1985-01-14 1991-01-15 Raychem Limited Wire and cable
US4614392A (en) 1985-01-15 1986-09-30 Moore Boyd B Well bore electric pump power cable connector for multiple individual, insulated conductors of a pump power cable
US4645906A (en) 1985-03-04 1987-02-24 Thermon Manufacturing Company Reduced resistance skin effect heat generating system
US4698583A (en) 1985-03-26 1987-10-06 Raychem Corporation Method of monitoring a heater for faults
US4785163A (en) 1985-03-26 1988-11-15 Raychem Corporation Method for monitoring a heater
US4733057A (en) 1985-04-19 1988-03-22 Raychem Corporation Sheet heater
US4626665A (en) 1985-06-24 1986-12-02 Shell Oil Company Metal oversheathed electrical resistance heater
US4786760A (en) 1985-10-25 1988-11-22 Raychem Gmbh Cable connection
US4662437A (en) 1985-11-14 1987-05-05 Atlantic Richfield Company Electrically stimulated well production system with flexible tubing conductor
CA1253555A (en) 1985-11-21 1989-05-02 Cornelis F.H. Van Egmond Heating rate variant elongated electrical resistance heater
CN85109010A (en) 1985-12-09 1987-06-17 国际壳牌研究有限公司 Installation contains the well treatment process that becomes diameter share of cable bundle
US4849611A (en) 1985-12-16 1989-07-18 Raychem Corporation Self-regulating heater employing reactive components
US4694907A (en) 1986-02-21 1987-09-22 Carbotek, Inc. Thermally-enhanced oil recovery method and apparatus
US4814587A (en) 1986-06-10 1989-03-21 Metcal, Inc. High power self-regulating heater
US4716960A (en) 1986-07-14 1988-01-05 Production Technologies International, Inc. Method and system for introducing electric current into a well
US4979296A (en) 1986-07-25 1990-12-25 Shell Oil Company Method for fabricating helical flowline bundles
CA1288043C (en) 1986-12-15 1991-08-27 Peter Van Meurs Conductively heating a subterranean oil shale to create permeabilityand subsequently produce oil
US4821798A (en) 1987-06-09 1989-04-18 Ors Development Corporation Heating system for rathole oil well
US4834825A (en) 1987-09-21 1989-05-30 Robert Adams Assembly for connecting multi-duct conduits
US5082494A (en) 1987-12-16 1992-01-21 Crompton Design Manufacturing Limited Materials for and manufacture of fire and heat resistant components
US5065501A (en) 1988-11-29 1991-11-19 Amp Incorporated Generating electromagnetic fields in a self regulating temperature heater by positioning of a current return bus
US4859200A (en) 1988-12-05 1989-08-22 Baker Hughes Incorporated Downhole electrical connector for submersible pump
US4947672A (en) 1989-04-03 1990-08-14 Burndy Corporation Hydraulic compression tool having an improved relief and release valve
US5316492A (en) 1989-05-03 1994-05-31 Nkf Kabel B.V. Plug-in connection for high-voltage plastic cable
US5336851A (en) 1989-12-27 1994-08-09 Sumitomo Electric Industries, Ltd. Insulated electrical conductor wire having a high operating temperature
US5106701A (en) 1990-02-01 1992-04-21 Fujikura Ltd. Copper alloy wire, and insulated electric wires and multiple core parallel bonded wires made of the same
US5231249A (en) 1990-02-23 1993-07-27 The Furukawa Electric Co., Ltd. Insulated power cable
US5152341A (en) 1990-03-09 1992-10-06 Raymond S. Kasevich Electromagnetic method and apparatus for the decontamination of hazardous material-containing volumes
US5040601A (en) 1990-06-21 1991-08-20 Baker Hughes Incorporated Horizontal well bore system
US5406030A (en) 1990-08-24 1995-04-11 Electric Power Research Institute High voltage, high-current power cable termination with single condenser grading stack
US5245161A (en) 1990-08-31 1993-09-14 Tokyo Kogyo Boyeki Shokai, Ltd. Electric heater
US5066852A (en) 1990-09-17 1991-11-19 Teledyne Ind. Inc. Thermoplastic end seal for electric heating elements
US5207273A (en) 1990-09-17 1993-05-04 Production Technologies International Inc. Method and apparatus for pumping wells
US5512732A (en) 1990-09-20 1996-04-30 Thermon Manufacturing Company Switch controlled, zone-type heating cable and method
US5182427A (en) 1990-09-20 1993-01-26 Metcal, Inc. Self-regulating heater utilizing ferrite-type body
US5408047A (en) 1990-10-25 1995-04-18 Minnesota Mining And Manufacturing Company Transition joint for oil-filled cables
US5070533A (en) 1990-11-07 1991-12-03 Uentech Corporation Robust electrical heating systems for mineral wells
US5060287A (en) 1990-12-04 1991-10-22 Shell Oil Company Heater utilizing copper-nickel alloy core
US5403977A (en) 1990-12-20 1995-04-04 Raychem Limited Cable-sealing mastic material
US5065818A (en) 1991-01-07 1991-11-19 Shell Oil Company Subterranean heaters
US5667009A (en) 1991-02-06 1997-09-16 Moore; Boyd B. Rubber boots for electrical connection for down hole well
US5289882A (en) 1991-02-06 1994-03-01 Boyd B. Moore Sealed electrical conductor method and arrangement for use with a well bore in hazardous areas
US5443665A (en) 1991-04-05 1995-08-22 Sumitomo Electric Industries, Ltd. Method of manufacturing a copper electrical conductor, especially for transmitting audio and video signals and quality control method for such conductors
US5117912A (en) 1991-05-24 1992-06-02 Marathon Oil Company Method of positioning tubing within a horizontal well
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
US5189283A (en) 1991-08-28 1993-02-23 Shell Oil Company Current to power crossover heater control
US5483414A (en) 1992-04-01 1996-01-09 Vaisala Oy Electrical impedance detector for measurement of physical quantities, in particular of temperature
US5579575A (en) 1992-04-01 1996-12-03 Raychem S.A. Method and apparatus for forming an electrical connection
US5278353A (en) 1992-06-05 1994-01-11 Powertech Labs Inc. Automatic splice
US5226961A (en) 1992-06-12 1993-07-13 Shell Oil Company High temperature wellbore cement slurry
US5315065A (en) 1992-08-21 1994-05-24 Donovan James P O Versatile electrically insulating waterproof connectors
US5463187A (en) 1992-09-30 1995-10-31 The George Ingraham Corp. Flexible multi-duct conduit assembly
US5606148A (en) 1993-01-15 1997-02-25 Raychem Gmbh Cable joint
US5528824A (en) 1993-05-18 1996-06-25 Baker Hughes Incorporated Method of forming a double armor cable with auxiliary line for an electrical submersible pump
US5987745A (en) 1993-06-07 1999-11-23 Kabeldon Ab Method and devices for jointing cables
US5453599A (en) 1994-02-14 1995-09-26 Hoskins Manufacturing Company Tubular heating element with insulating core
US5553478A (en) 1994-04-08 1996-09-10 Burndy Corporation Hand-held compression tool
US5594211A (en) 1995-02-22 1997-01-14 Burndy Corporation Electrical solder splice connector
US5621844A (en) 1995-03-01 1997-04-15 Uentech Corporation Electrical heating of mineral well deposits using downhole impedance transformation networks
US5713415A (en) 1995-03-01 1998-02-03 Uentech Corporation Low flux leakage cables and cable terminations for A.C. electrical heating of oil deposits
US5911898A (en) 1995-05-25 1999-06-15 Electric Power Research Institute Method and apparatus for providing multiple autoregulated temperatures
US6015015A (en) 1995-06-20 2000-01-18 Bj Services Company U.S.A. Insulated and/or concentric coiled tubing
US5669275A (en) 1995-08-18 1997-09-23 Mills; Edward Otis Conductor insulation remover
US5801332A (en) 1995-08-31 1998-09-01 Minnesota Mining And Manufacturing Company Elastically recoverable silicone splice cover
US5619611A (en) 1995-12-12 1997-04-08 Tub Tauch-Und Baggertechnik Gmbh Device for removing downhole deposits utilizing tubular housing and passing electric current through fluid heating medium contained therein
WO1997023924A1 (en) 1995-12-21 1997-07-03 Raychem S.A. Electrical connector
US5784530A (en) 1996-02-13 1998-07-21 Eor International, Inc. Iterated electrodes for oil wells
US5854472A (en) 1996-05-29 1998-12-29 Sperika Enterprises Ltd. Low-voltage and low flux density heating system
US5788376A (en) 1996-07-01 1998-08-04 General Motors Corporation Temperature sensor
US5683273A (en) 1996-07-24 1997-11-04 The Whitaker Corporation Mechanical splice connector for cable
US6326546B1 (en) 1996-10-03 2001-12-04 Per Karlsson Strain relief for a screen cable
US5782301A (en) 1996-10-09 1998-07-21 Baker Hughes Incorporated Oil well heater cable
US5875283A (en) 1996-10-11 1999-02-23 Lufran Incorporated Purged grounded immersion heater
US6056057A (en) 1996-10-15 2000-05-02 Shell Oil Company Heater well method and apparatus
US6079499A (en) 1996-10-15 2000-06-27 Shell Oil Company Heater well method and apparatus
US6355318B1 (en) 1996-11-14 2002-03-12 Shawcor Ltd. Heat shrinkable member
US6472600B1 (en) 1997-04-07 2002-10-29 Cables Pirelli Connecting cord junction
US6023554A (en) 1997-05-20 2000-02-08 Shell Oil Company Electrical heater
US6102122A (en) 1997-06-11 2000-08-15 Shell Oil Company Control of heat injection based on temperature and in-situ stress measurement
US7172038B2 (en) 1997-10-27 2007-02-06 Halliburton Energy Services, Inc. Well system
US6269876B1 (en) 1998-03-06 2001-08-07 Shell Oil Company Electrical heater
US6313431B1 (en) 1998-07-09 2001-11-06 Illinois Tool Works Inc. Plasma cutter for auxiliary power output of a power source
US20020028070A1 (en) 1998-09-14 2002-03-07 Petter Holen Heating system for crude oil transporting metallic tubes
JP2000340350A (en) 1999-05-28 2000-12-08 Kyocera Corp Silicon nitride ceramic heater and its manufacture
WO2000019061A9 (en) 1999-09-24 2002-04-25 System, apparatus, and method for installing control lines in a well
US6423952B1 (en) 1999-10-09 2002-07-23 Airbus Deutschland Gmbh Heater arrangement with connector or terminating element and fluoropolymer seal, and method of making the same
US6288372B1 (en) 1999-11-03 2001-09-11 Tyco Electronics Corporation Electric cable having braidless polymeric ground plane providing fault detection
US6364721B2 (en) 1999-12-27 2002-04-02 Stewart, Iii Kenneth G. Wire connector
US6452105B2 (en) 2000-01-12 2002-09-17 Meggitt Safety Systems, Inc. Coaxial cable assembly with a discontinuous outer jacket
US6958704B2 (en) 2000-01-24 2005-10-25 Shell Oil Company Permanent downhole, wireless, two-way telemetry backbone using redundant repeaters
US6588504B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
US6739393B2 (en) 2000-04-24 2004-05-25 Shell Oil Company In situ thermal processing of a coal formation and tuning production
US20020076212A1 (en) 2000-04-24 2002-06-20 Etuan Zhang In situ thermal processing of a hydrocarbon containing formation producing a mixture with oxygenated hydrocarbons
US20020040780A1 (en) 2000-04-24 2002-04-11 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce a selected mixture
US20020040779A1 (en) 2000-04-24 2002-04-11 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce a mixture containing olefins, oxygenated hydrocarbons, and/or aromatic hydrocarbons
US20020038069A1 (en) 2000-04-24 2002-03-28 Wellington Scott Lee In situ thermal processing of a coal formation to produce a mixture of olefins, oxygenated hydrocarbons, and aromatic hydrocarbons
US20030066642A1 (en) 2000-04-24 2003-04-10 Wellington Scott Lee In situ thermal processing of a coal formation producing a mixture with oxygenated hydrocarbons
US8485252B2 (en) 2000-04-24 2013-07-16 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US20030085034A1 (en) 2000-04-24 2003-05-08 Wellington Scott Lee In situ thermal processing of a coal formation to produce pyrolsis products
US6581684B2 (en) 2000-04-24 2003-06-24 Shell Oil Company In Situ thermal processing of a hydrocarbon containing formation to produce sulfur containing formation fluids
US8225866B2 (en) 2000-04-24 2012-07-24 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US6953087B2 (en) 2000-04-24 2005-10-11 Shell Oil Company Thermal processing of a hydrocarbon containing formation to increase a permeability of the formation
US20020036089A1 (en) 2000-04-24 2002-03-28 Vinegar Harold J. In situ thermal processing of a hydrocarbon containing formation using distributed combustor heat sources
US6588503B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In Situ thermal processing of a coal formation to control product composition
US6591907B2 (en) 2000-04-24 2003-07-15 Shell Oil Company In situ thermal processing of a coal formation with a selected vitrinite reflectance
US6591906B2 (en) 2000-04-24 2003-07-15 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with a selected oxygen content
US7798221B2 (en) 2000-04-24 2010-09-21 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US6607033B2 (en) 2000-04-24 2003-08-19 Shell Oil Company In Situ thermal processing of a coal formation to produce a condensate
US6609570B2 (en) 2000-04-24 2003-08-26 Shell Oil Company In situ thermal processing of a coal formation and ammonia production
US20020033253A1 (en) 2000-04-24 2002-03-21 Rouffignac Eric Pierre De In situ thermal processing of a hydrocarbon containing formation using insulated conductor heat sources
US6948563B2 (en) 2000-04-24 2005-09-27 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with a selected hydrogen content
US6688387B1 (en) 2000-04-24 2004-02-10 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce a hydrocarbon condensate
US6698515B2 (en) 2000-04-24 2004-03-02 Shell Oil Company In situ thermal processing of a coal formation using a relatively slow heating rate
US6702016B2 (en) 2000-04-24 2004-03-09 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with heat sources located at an edge of a formation layer
US6712136B2 (en) 2000-04-24 2004-03-30 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using a selected production well spacing
US6712135B2 (en) 2000-04-24 2004-03-30 Shell Oil Company In situ thermal processing of a coal formation in reducing environment
US6712137B2 (en) 2000-04-24 2004-03-30 Shell Oil Company In situ thermal processing of a coal formation to pyrolyze a selected percentage of hydrocarbon material
US6715546B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ production of synthesis gas from a hydrocarbon containing formation through a heat source wellbore
US6715548B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce nitrogen containing formation fluids
US6715549B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with a selected atomic oxygen to carbon ratio
US6715547B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to form a substantially uniform, high permeability formation
US6719047B2 (en) 2000-04-24 2004-04-13 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation in a hydrogen-rich environment
US6722430B2 (en) 2000-04-24 2004-04-20 Shell Oil Company In situ thermal processing of a coal formation with a selected oxygen content and/or selected O/C ratio
US6722429B2 (en) 2000-04-24 2004-04-20 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation leaving one or more selected unprocessed areas
US6722431B2 (en) 2000-04-24 2004-04-20 Shell Oil Company In situ thermal processing of hydrocarbons within a relatively permeable formation
US6725920B2 (en) 2000-04-24 2004-04-27 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to convert a selected amount of total organic carbon into hydrocarbon products
US6725928B2 (en) 2000-04-24 2004-04-27 Shell Oil Company In situ thermal processing of a coal formation using a distributed combustor
US6729397B2 (en) 2000-04-24 2004-05-04 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with a selected vitrinite reflectance
US6729396B2 (en) 2000-04-24 2004-05-04 Shell Oil Company In situ thermal processing of a coal formation to produce hydrocarbons having a selected carbon number range
US6729401B2 (en) 2000-04-24 2004-05-04 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation and ammonia production
US6729395B2 (en) 2000-04-24 2004-05-04 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with a selected ratio of heat sources to production wells
US6732796B2 (en) 2000-04-24 2004-05-11 Shell Oil Company In situ production of synthesis gas from a hydrocarbon containing formation, the synthesis gas having a selected H2 to CO ratio
US6732794B2 (en) 2000-04-24 2004-05-11 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce a mixture with a selected hydrogen content
US6732795B2 (en) 2000-04-24 2004-05-11 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to pyrolyze a selected percentage of hydrocarbon material
US6736215B2 (en) 2000-04-24 2004-05-18 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation, in situ production of synthesis gas, and carbon dioxide sequestration
US20020053431A1 (en) 2000-04-24 2002-05-09 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce a selected ratio of components in a gas
US6739394B2 (en) 2000-04-24 2004-05-25 Shell Oil Company Production of synthesis gas from a hydrocarbon containing formation
US6742589B2 (en) 2000-04-24 2004-06-01 Shell Oil Company In situ thermal processing of a coal formation using repeating triangular patterns of heat sources
US6742587B2 (en) 2000-04-24 2004-06-01 Shell Oil Company In situ thermal processing of a coal formation to form a substantially uniform, relatively high permeable formation
US6742593B2 (en) 2000-04-24 2004-06-01 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using heat transfer from a heat transfer fluid to heat the formation
US6742588B2 (en) 2000-04-24 2004-06-01 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce formation fluids having a relatively low olefin content
US6745831B2 (en) 2000-04-24 2004-06-08 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation by controlling a pressure of the formation
US6745837B2 (en) 2000-04-24 2004-06-08 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using a controlled heating rate
US6745832B2 (en) 2000-04-24 2004-06-08 Shell Oil Company Situ thermal processing of a hydrocarbon containing formation to control product composition
US6749021B2 (en) 2000-04-24 2004-06-15 Shell Oil Company In situ thermal processing of a coal formation using a controlled heating rate
US6752210B2 (en) 2000-04-24 2004-06-22 Shell Oil Company In situ thermal processing of a coal formation using heat sources positioned within open wellbores
US6758268B2 (en) 2000-04-24 2004-07-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using a relatively slow heating rate
US6761216B2 (en) 2000-04-24 2004-07-13 Shell Oil Company In situ thermal processing of a coal formation to produce hydrocarbon fluids and synthesis gas
US7096953B2 (en) 2000-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a coal formation using a movable heating element
US6769483B2 (en) 2000-04-24 2004-08-03 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using conductor in conduit heat sources
US6769485B2 (en) 2000-04-24 2004-08-03 Shell Oil Company In situ production of synthesis gas from a coal formation through a heat source wellbore
US7096941B2 (en) 2000-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a coal formation with heat sources located at an edge of a coal layer
US7086468B2 (en) 2000-04-24 2006-08-08 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using heat sources positioned within open wellbores
US7036583B2 (en) 2000-04-24 2006-05-02 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to increase a porosity of the formation
US6789625B2 (en) 2000-04-24 2004-09-14 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using exposed metal heat sources
US6805195B2 (en) 2000-04-24 2004-10-19 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce hydrocarbon fluids and synthesis gas
US6820688B2 (en) 2000-04-24 2004-11-23 Shell Oil Company In situ thermal processing of coal formation with a selected hydrogen content and/or selected H/C ratio
US7011154B2 (en) 2000-04-24 2006-03-14 Shell Oil Company In situ recovery from a kerogen and liquid hydrocarbon containing formation
US6959761B2 (en) 2000-04-24 2005-11-01 Shell Oil Company In situ thermal processing of a coal formation with a selected ratio of heat sources to production wells
US6866097B2 (en) 2000-04-24 2005-03-15 Shell Oil Company In situ thermal processing of a coal formation to increase a permeability/porosity of the formation
US6871707B2 (en) 2000-04-24 2005-03-29 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with carbon dioxide sequestration
US6997255B2 (en) 2000-04-24 2006-02-14 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation in a reducing environment
US6877554B2 (en) 2000-04-24 2005-04-12 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using pressure and/or temperature control
US6880635B2 (en) 2000-04-24 2005-04-19 Shell Oil Company In situ production of synthesis gas from a coal formation, the synthesis gas having a selected H2 to CO ratio
US20020027001A1 (en) 2000-04-24 2002-03-07 Wellington Scott L. In situ thermal processing of a coal formation to produce a selected gas mixture
US6994160B2 (en) 2000-04-24 2006-02-07 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce hydrocarbons having a selected carbon number range
US6889769B2 (en) 2000-04-24 2005-05-10 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation with a selected moisture content
US6896053B2 (en) 2000-04-24 2005-05-24 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using repeating triangular patterns of heat sources
US6902003B2 (en) 2000-04-24 2005-06-07 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation having a selected total organic carbon content
US6902004B2 (en) 2000-04-24 2005-06-07 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using a movable heating element
US6910536B2 (en) 2000-04-24 2005-06-28 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using a natural distributed combustor
US6913078B2 (en) 2000-04-24 2005-07-05 Shell Oil Company In Situ thermal processing of hydrocarbons within a relatively impermeable formation
US6994161B2 (en) 2000-04-24 2006-02-07 Kevin Albert Maher In situ thermal processing of a coal formation with a selected moisture content
US6994168B2 (en) 2000-04-24 2006-02-07 Scott Lee Wellington In situ thermal processing of a hydrocarbon containing formation with a selected hydrogen to carbon ratio
US6973967B2 (en) 2000-04-24 2005-12-13 Shell Oil Company Situ thermal processing of a coal formation using pressure and/or temperature control
US6923258B2 (en) 2000-04-24 2005-08-02 Shell Oil Company In situ thermal processsing of a hydrocarbon containing formation to produce a mixture with a selected hydrogen content
US6966372B2 (en) 2000-04-24 2005-11-22 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce oxygen containing formation fluids
US6585046B2 (en) 2000-08-28 2003-07-01 Baker Hughes Incorporated Live well heater cable
US7153373B2 (en) 2000-12-14 2006-12-26 Caterpillar Inc Heat and corrosion resistant cast CF8C stainless steel with improved high temperature strength and ductility
US6849800B2 (en) 2001-03-19 2005-02-01 Hewlett-Packard Development Company, L.P. Board-level conformal EMI shield having an electrically-conductive polymer coating over a thermally-conductive dielectric coating
US6880633B2 (en) 2001-04-24 2005-04-19 Shell Oil Company In situ thermal processing of an oil shale formation to produce a desired product
US6918443B2 (en) 2001-04-24 2005-07-19 Shell Oil Company In situ thermal processing of an oil shale formation to produce hydrocarbons having a selected carbon number range
US6951247B2 (en) 2001-04-24 2005-10-04 Shell Oil Company In situ thermal processing of an oil shale formation using horizontal heat sources
US20030079877A1 (en) 2001-04-24 2003-05-01 Wellington Scott Lee In situ thermal processing of a relatively impermeable formation in a reducing environment
US6948562B2 (en) 2001-04-24 2005-09-27 Shell Oil Company Production of a blending agent using an in situ thermal process in a relatively permeable formation
US6929067B2 (en) 2001-04-24 2005-08-16 Shell Oil Company Heat sources with conductive material for in situ thermal processing of an oil shale formation
US7055600B2 (en) 2001-04-24 2006-06-06 Shell Oil Company In situ thermal recovery from a relatively permeable formation with controlled production rate
US6964300B2 (en) 2001-04-24 2005-11-15 Shell Oil Company In situ thermal recovery from a relatively permeable formation with backproduction through a heater wellbore
US6923257B2 (en) 2001-04-24 2005-08-02 Shell Oil Company In situ thermal processing of an oil shale formation to produce a condensate
US6966374B2 (en) 2001-04-24 2005-11-22 Shell Oil Company In situ thermal recovery from a relatively permeable formation using gas to increase mobility
US7225866B2 (en) 2001-04-24 2007-06-05 Shell Oil Company In situ thermal processing of an oil shale formation using a pattern of heat sources
US7735935B2 (en) 2001-04-24 2010-06-15 Shell Oil Company In situ thermal processing of an oil shale formation containing carbonate minerals
US6918442B2 (en) 2001-04-24 2005-07-19 Shell Oil Company In situ thermal processing of an oil shale formation in a reducing environment
US6981548B2 (en) 2001-04-24 2006-01-03 Shell Oil Company In situ thermal recovery from a relatively permeable formation
US20030146002A1 (en) 2001-04-24 2003-08-07 Vinegar Harold J. Removable heat sources for in situ thermal processing of an oil shale formation
US6991033B2 (en) 2001-04-24 2006-01-31 Shell Oil Company In situ thermal processing while controlling pressure in an oil shale formation
US6991036B2 (en) 2001-04-24 2006-01-31 Shell Oil Company Thermal processing of a relatively permeable formation
US6991032B2 (en) 2001-04-24 2006-01-31 Shell Oil Company In situ thermal processing of an oil shale formation using a pattern of heat sources
US6994169B2 (en) 2001-04-24 2006-02-07 Shell Oil Company In situ thermal processing of an oil shale formation with a selected property
US7066254B2 (en) 2001-04-24 2006-06-27 Shell Oil Company In situ thermal processing of a tar sands formation
US6915850B2 (en) 2001-04-24 2005-07-12 Shell Oil Company In situ thermal processing of an oil shale formation having permeable and impermeable sections
US7051811B2 (en) 2001-04-24 2006-05-30 Shell Oil Company In situ thermal processing through an open wellbore in an oil shale formation
US6997518B2 (en) 2001-04-24 2006-02-14 Shell Oil Company In situ thermal processing and solution mining of an oil shale formation
US6877555B2 (en) 2001-04-24 2005-04-12 Shell Oil Company In situ thermal processing of an oil shale formation while inhibiting coking
US7004251B2 (en) 2001-04-24 2006-02-28 Shell Oil Company In situ thermal processing and remediation of an oil shale formation
US7004247B2 (en) 2001-04-24 2006-02-28 Shell Oil Company Conductor-in-conduit heat sources for in situ thermal processing of an oil shale formation
US7096942B1 (en) 2001-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a relatively permeable formation while controlling pressure
US7013972B2 (en) 2001-04-24 2006-03-21 Shell Oil Company In situ thermal processing of an oil shale formation using a natural distributed combustor
US6782947B2 (en) 2001-04-24 2004-08-31 Shell Oil Company In situ thermal processing of a relatively impermeable formation to increase permeability of the formation
US7040400B2 (en) 2001-04-24 2006-05-09 Shell Oil Company In situ thermal processing of a relatively impermeable formation using an open wellbore
US7040398B2 (en) 2001-04-24 2006-05-09 Shell Oil Company In situ thermal processing of a relatively permeable formation in a reducing environment
US7040399B2 (en) 2001-04-24 2006-05-09 Shell Oil Company In situ thermal processing of an oil shale formation using a controlled heating rate
US7040397B2 (en) 2001-04-24 2006-05-09 Shell Oil Company Thermal processing of an oil shale formation to increase permeability of the formation
US7051807B2 (en) 2001-04-24 2006-05-30 Shell Oil Company In situ thermal recovery from a relatively permeable formation with quality control
US6963053B2 (en) 2001-07-03 2005-11-08 Cci Thermal Technologies, Inc. Corrugated metal ribbon heating element
US20040163801A1 (en) 2001-08-27 2004-08-26 Dalrymple Larry V. Heater Cable and method for manufacturing
US6886638B2 (en) 2001-10-03 2005-05-03 Schlumbergr Technology Corporation Field weldable connections
US7066257B2 (en) 2001-10-24 2006-06-27 Shell Oil Company In situ recovery from lean and rich zones in a hydrocarbon containing formation
US6932155B2 (en) 2001-10-24 2005-08-23 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation via backproducing through a heater well
US7063145B2 (en) 2001-10-24 2006-06-20 Shell Oil Company Methods and systems for heating a hydrocarbon containing formation in situ with an opening contacting the earth's surface at two locations
US7461691B2 (en) 2001-10-24 2008-12-09 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US7077199B2 (en) 2001-10-24 2006-07-18 Shell Oil Company In situ thermal processing of an oil reservoir formation
US7077198B2 (en) 2001-10-24 2006-07-18 Shell Oil Company In situ recovery from a hydrocarbon containing formation using barriers
US7086465B2 (en) 2001-10-24 2006-08-08 Shell Oil Company In situ production of a blending agent from a hydrocarbon containing formation
US7051808B1 (en) 2001-10-24 2006-05-30 Shell Oil Company Seismic monitoring of in situ conversion in a hydrocarbon containing formation
US7090013B2 (en) 2001-10-24 2006-08-15 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce heated fluids
US20030201098A1 (en) 2001-10-24 2003-10-30 Karanikas John Michael In situ recovery from a hydrocarbon containing formation using one or more simulations
US8627887B2 (en) 2001-10-24 2014-01-14 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US7156176B2 (en) 2001-10-24 2007-01-02 Shell Oil Company Installation and use of removable heaters in a hydrocarbon containing formation
US7100994B2 (en) 2001-10-24 2006-09-05 Shell Oil Company Producing hydrocarbons and non-hydrocarbon containing materials when treating a hydrocarbon containing formation
US7104319B2 (en) 2001-10-24 2006-09-12 Shell Oil Company In situ thermal processing of a heavy oil diatomite formation
US7114566B2 (en) 2001-10-24 2006-10-03 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using a natural distributed combustor
US6969123B2 (en) 2001-10-24 2005-11-29 Shell Oil Company Upgrading and mining of coal
US20030196789A1 (en) 2001-10-24 2003-10-23 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation and upgrading of produced fluids prior to further treatment
US6991045B2 (en) 2001-10-24 2006-01-31 Shell Oil Company Forming openings in a hydrocarbon containing formation using magnetic tracking
US7128153B2 (en) 2001-10-24 2006-10-31 Shell Oil Company Treatment of a hydrocarbon containing formation after heating
US7165615B2 (en) 2001-10-24 2007-01-23 Shell Oil Company In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden
US6583351B1 (en) 2002-01-11 2003-06-24 Bwx Technologies, Inc. Superconducting cable-in-conduit low resistance splice
US6773311B2 (en) 2002-02-06 2004-08-10 Fci Americas Technology, Inc. Electrical splice connector
US7563983B2 (en) 2002-04-23 2009-07-21 Ctc Cable Corporation Collet-type splice and dead end for use with an aluminum conductor composite core reinforced cable
US8122957B2 (en) 2002-09-03 2012-02-28 Baker Hughes Incorporated Sand control method using porous particulate materials
US8238730B2 (en) 2002-10-24 2012-08-07 Shell Oil Company High voltage temperature limited heaters
US7121341B2 (en) 2002-10-24 2006-10-17 Shell Oil Company Conductor-in-conduit temperature limited heaters
US7219734B2 (en) 2002-10-24 2007-05-22 Shell Oil Company Inhibiting wellbore deformation during in situ thermal processing of a hydrocarbon containing formation
US20040140096A1 (en) 2002-10-24 2004-07-22 Sandberg Chester Ledlie Insulated conductor temperature limited heaters
US7073578B2 (en) 2002-10-24 2006-07-11 Shell Oil Company Staged and/or patterned heating during in situ thermal processing of a hydrocarbon containing formation
US8200072B2 (en) 2002-10-24 2012-06-12 Shell Oil Company Temperature limited heaters for heating subsurface formations or wellbores
US8224164B2 (en) 2002-10-24 2012-07-17 Shell Oil Company Insulated conductor temperature limited heaters
US6942032B2 (en) 2002-11-06 2005-09-13 Thomas A. La Rovere Resistive down hole heating tool
US7258752B2 (en) 2003-03-26 2007-08-21 Ut-Battelle Llc Wrought stainless steel compositions having engineered microstructures for improved heat resistance
US7640980B2 (en) 2003-04-24 2010-01-05 Shell Oil Company Thermal processes for subsurface formations
US7360588B2 (en) 2003-04-24 2008-04-22 Shell Oil Company Thermal processes for subsurface formations
US7942203B2 (en) 2003-04-24 2011-05-17 Shell Oil Company Thermal processes for subsurface formations
US7121342B2 (en) 2003-04-24 2006-10-17 Shell Oil Company Thermal processes for subsurface formations
US20050006128A1 (en) 2003-07-10 2005-01-13 Yazaki Corporation Shielding structure of shielding electric wire
US7486498B2 (en) 2004-01-12 2009-02-03 Case Western Reserve University Strong substrate alloy and compressively stressed dielectric film for capacitor with high energy density
US7337841B2 (en) 2004-03-24 2008-03-04 Halliburton Energy Services, Inc. Casing comprising stress-absorbing materials and associated methods of use
US7353872B2 (en) 2004-04-23 2008-04-08 Shell Oil Company Start-up of temperature limited heaters using direct current (DC)
US7490665B2 (en) 2004-04-23 2009-02-17 Shell Oil Company Variable frequency temperature limited heaters
US7431076B2 (en) 2004-04-23 2008-10-07 Shell Oil Company Temperature limited heaters using modulated DC power
US7320364B2 (en) 2004-04-23 2008-01-22 Shell Oil Company Inhibiting reflux in a heated well of an in situ conversion system
US20050269313A1 (en) 2004-04-23 2005-12-08 Vinegar Harold J Temperature limited heaters with high power factors
US7481274B2 (en) 2004-04-23 2009-01-27 Shell Oil Company Temperature limited heaters with relatively constant current
US8355623B2 (en) 2004-04-23 2013-01-15 Shell Oil Company Temperature limited heaters with high power factors
US7424915B2 (en) 2004-04-23 2008-09-16 Shell Oil Company Vacuum pumping of conductor-in-conduit heaters
US7357180B2 (en) 2004-04-23 2008-04-15 Shell Oil Company Inhibiting effects of sloughing in wellbores
US7370704B2 (en) 2004-04-23 2008-05-13 Shell Oil Company Triaxial temperature limited heater
US7510000B2 (en) 2004-04-23 2009-03-31 Shell Oil Company Reducing viscosity of oil for production from a hydrocarbon containing formation
US7383877B2 (en) 2004-04-23 2008-06-10 Shell Oil Company Temperature limited heaters with thermally conductive fluid used to heat subsurface formations
US20060289536A1 (en) 2004-04-23 2006-12-28 Vinegar Harold J Subsurface electrical heaters using nitride insulation
US7398823B2 (en) 2005-01-10 2008-07-15 Conocophillips Company Selective electromagnetic production tool
US20060231283A1 (en) 2005-04-19 2006-10-19 Stagi William R Cable connector having fluid reservoir
US7860377B2 (en) 2005-04-22 2010-12-28 Shell Oil Company Subsurface connection methods for subsurface heaters
US7500528B2 (en) 2005-04-22 2009-03-10 Shell Oil Company Low temperature barrier wellbores formed using water flushing
US7527094B2 (en) 2005-04-22 2009-05-05 Shell Oil Company Double barrier system for an in situ conversion process
US7546873B2 (en) 2005-04-22 2009-06-16 Shell Oil Company Low temperature barriers for use with in situ processes
WO2006116078A1 (en) 2005-04-22 2006-11-02 Shell Internationale Research Maatschappij B.V. Insulated conductor temperature limited heater for subsurface heating coupled in a three-phase wye configuration
US7942197B2 (en) 2005-04-22 2011-05-17 Shell Oil Company Methods and systems for producing fluid from an in situ conversion process
US7986869B2 (en) 2005-04-22 2011-07-26 Shell Oil Company Varying properties along lengths of temperature limited heaters
US8027571B2 (en) 2005-04-22 2011-09-27 Shell Oil Company In situ conversion process systems utilizing wellbores in at least two regions of a formation
US7831134B2 (en) 2005-04-22 2010-11-09 Shell Oil Company Grouped exposed metal heaters
US7831133B2 (en) 2005-04-22 2010-11-09 Shell Oil Company Insulated conductor temperature limited heater for subsurface heating coupled in a three-phase WYE configuration
US20120193099A1 (en) 2005-04-22 2012-08-02 Shell Oil Company Temperature limited heater utilizing non-ferromagnetic conductor
US7435037B2 (en) 2005-04-22 2008-10-14 Shell Oil Company Low temperature barriers with heat interceptor wells for in situ processes
US8230927B2 (en) 2005-04-22 2012-07-31 Shell Oil Company Methods and systems for producing fluid from an in situ conversion process
US8233782B2 (en) 2005-04-22 2012-07-31 Shell Oil Company Grouped exposed metal heaters
US8224165B2 (en) 2005-04-22 2012-07-17 Shell Oil Company Temperature limited heater utilizing non-ferromagnetic conductor
US7575053B2 (en) 2005-04-22 2009-08-18 Shell Oil Company Low temperature monitoring system for subsurface barriers
US7575052B2 (en) 2005-04-22 2009-08-18 Shell Oil Company In situ conversion process utilizing a closed loop heating system
US7584789B2 (en) 2005-10-24 2009-09-08 Shell Oil Company Methods of cracking a crude product to produce additional crude products
US7556095B2 (en) 2005-10-24 2009-07-07 Shell Oil Company Solution mining dawsonite from hydrocarbon containing formations with a chelating agent
US7591310B2 (en) 2005-10-24 2009-09-22 Shell Oil Company Methods of hydrotreating a liquid stream to remove clogging compounds
US8606091B2 (en) 2005-10-24 2013-12-10 Shell Oil Company Subsurface heaters with low sulfidation rates
US7581589B2 (en) 2005-10-24 2009-09-01 Shell Oil Company Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid
US7549470B2 (en) 2005-10-24 2009-06-23 Shell Oil Company Solution mining and heating by oxidation for treating hydrocarbon containing formations
US7556096B2 (en) 2005-10-24 2009-07-07 Shell Oil Company Varying heating in dawsonite zones in hydrocarbon containing formations
US8151880B2 (en) 2005-10-24 2012-04-10 Shell Oil Company Methods of making transportation fuel
US7559367B2 (en) 2005-10-24 2009-07-14 Shell Oil Company Temperature limited heater with a conduit substantially electrically isolated from the formation
US7559368B2 (en) 2005-10-24 2009-07-14 Shell Oil Company Solution mining systems and methods for treating hydrocarbon containing formations
US7635025B2 (en) 2005-10-24 2009-12-22 Shell Oil Company Cogeneration systems and processes for treating hydrocarbon containing formations
US7562706B2 (en) 2005-10-24 2009-07-21 Shell Oil Company Systems and methods for producing hydrocarbons from tar sands formations
US20070127897A1 (en) 2005-10-24 2007-06-07 John Randy C Subsurface heaters with low sulfidation rates
US20070173122A1 (en) 2006-01-26 2007-07-26 Yazaki Corporation Method of processing end portion of shielded wire and end portion processing apparatus
US7912358B2 (en) 2006-04-21 2011-03-22 Shell Oil Company Alternate energy source usage for in situ heat treatment processes
US7631689B2 (en) 2006-04-21 2009-12-15 Shell Oil Company Sulfur barrier for use with in situ processes for treating formations
US8192682B2 (en) 2006-04-21 2012-06-05 Shell Oil Company High strength alloys
US7785427B2 (en) 2006-04-21 2010-08-31 Shell Oil Company High strength alloys
US7673786B2 (en) 2006-04-21 2010-03-09 Shell Oil Company Welding shield for coupling heaters
US8083813B2 (en) 2006-04-21 2011-12-27 Shell Oil Company Methods of producing transportation fuel
US7635023B2 (en) 2006-04-21 2009-12-22 Shell Oil Company Time sequenced heating of multiple layers in a hydrocarbon containing formation
US7793722B2 (en) 2006-04-21 2010-09-14 Shell Oil Company Non-ferromagnetic overburden casing
US7683296B2 (en) 2006-04-21 2010-03-23 Shell Oil Company Adjusting alloy compositions for selected properties in temperature limited heaters
US7597147B2 (en) 2006-04-21 2009-10-06 Shell Oil Company Temperature limited heaters using phase transformation of ferromagnetic material
US7610962B2 (en) 2006-04-21 2009-11-03 Shell Oil Company Sour gas injection for use with in situ heat treatment
US7604052B2 (en) 2006-04-21 2009-10-20 Shell Oil Company Compositions produced using an in situ heat treatment process
US7866385B2 (en) 2006-04-21 2011-01-11 Shell Oil Company Power systems utilizing the heat of produced formation fluid
US7533719B2 (en) 2006-04-21 2009-05-19 Shell Oil Company Wellhead with non-ferromagnetic materials
US8381806B2 (en) 2006-04-21 2013-02-26 Shell Oil Company Joint used for coupling long heaters
US8450540B2 (en) 2006-04-21 2013-05-28 Shell Oil Company Compositions produced using an in situ heat treatment process
US7764871B2 (en) 2006-08-29 2010-07-27 Star Progetti Tecnologie Applicate Infrared heat irradiating device
US20100044068A1 (en) 2006-09-14 2010-02-25 Biovidvienda S.I. Subsea umbilical
US20080073104A1 (en) 2006-09-26 2008-03-27 Barberree Daniel A Mineral insulated metal sheathed cable connector and method of forming the connector
US7405358B2 (en) 2006-10-17 2008-07-29 Quick Connectors, Inc Splice for down hole electrical submersible pump cable
US7644765B2 (en) 2006-10-20 2010-01-12 Shell Oil Company Heating tar sands formations while controlling pressure
US7677314B2 (en) 2006-10-20 2010-03-16 Shell Oil Company Method of condensing vaporized water in situ to treat tar sands formations
US7540324B2 (en) 2006-10-20 2009-06-02 Shell Oil Company Heating hydrocarbon containing formations in a checkerboard pattern staged process
US7562707B2 (en) 2006-10-20 2009-07-21 Shell Oil Company Heating hydrocarbon containing formations in a line drive staged process
US7631690B2 (en) 2006-10-20 2009-12-15 Shell Oil Company Heating hydrocarbon containing formations in a spiral startup staged sequence
US7730947B2 (en) 2006-10-20 2010-06-08 Shell Oil Company Creating fluid injectivity in tar sands formations
US7635024B2 (en) 2006-10-20 2009-12-22 Shell Oil Company Heating tar sands formations to visbreaking temperatures
US7730946B2 (en) 2006-10-20 2010-06-08 Shell Oil Company Treating tar sands formations with dolomite
US7730945B2 (en) 2006-10-20 2010-06-08 Shell Oil Company Using geothermal energy to heat a portion of a formation for an in situ heat treatment process
US8191630B2 (en) 2006-10-20 2012-06-05 Shell Oil Company Creating fluid injectivity in tar sands formations
US7673681B2 (en) 2006-10-20 2010-03-09 Shell Oil Company Treating tar sands formations with karsted zones
US7677310B2 (en) 2006-10-20 2010-03-16 Shell Oil Company Creating and maintaining a gas cap in tar sands formations
US20080135244A1 (en) 2006-10-20 2008-06-12 David Scott Miller Heating hydrocarbon containing formations in a line drive staged process
US7681647B2 (en) 2006-10-20 2010-03-23 Shell Oil Company Method of producing drive fluid in situ in tar sands formations
US7717171B2 (en) 2006-10-20 2010-05-18 Shell Oil Company Moving hydrocarbons through portions of tar sands formations with a fluid
US8555971B2 (en) 2006-10-20 2013-10-15 Shell Oil Company Treating tar sands formations with dolomite
US7703513B2 (en) 2006-10-20 2010-04-27 Shell Oil Company Wax barrier for use with in situ processes for treating formations
US7841401B2 (en) 2006-10-20 2010-11-30 Shell Oil Company Gas injection to inhibit migration during an in situ heat treatment process
US7845411B2 (en) 2006-10-20 2010-12-07 Shell Oil Company In situ heat treatment process utilizing a closed loop heating system
US7730936B2 (en) 2007-02-07 2010-06-08 Schlumberger Technology Corporation Active cable for wellbore heating and distributed temperature sensing
US20100044781A1 (en) 2007-03-28 2010-02-25 Akihito Tanabe Semiconductor device
US7931086B2 (en) 2007-04-20 2011-04-26 Shell Oil Company Heating systems for heating subsurface formations
US7832484B2 (en) 2007-04-20 2010-11-16 Shell Oil Company Molten salt as a heat transfer fluid for heating a subsurface formation
US7798220B2 (en) 2007-04-20 2010-09-21 Shell Oil Company In situ heat treatment of a tar sands formation after drive process treatment
US20090126929A1 (en) 2007-04-20 2009-05-21 Vinegar Harold J Treating nahcolite containing formations and saline zones
US8459359B2 (en) 2007-04-20 2013-06-11 Shell Oil Company Treating nahcolite containing formations and saline zones
US20090321417A1 (en) 2007-04-20 2009-12-31 David Burns Floating insulated conductors for heating subsurface formations
US20090095478A1 (en) 2007-04-20 2009-04-16 John Michael Karanikas Varying properties of in situ heat treatment of a tar sands formation based on assessed viscosities
US7841425B2 (en) 2007-04-20 2010-11-30 Shell Oil Company Drilling subsurface wellbores with cutting structures
US8791396B2 (en) * 2007-04-20 2014-07-29 Shell Oil Company Floating insulated conductors for heating subsurface formations
US7841408B2 (en) 2007-04-20 2010-11-30 Shell Oil Company In situ heat treatment from multiple layers of a tar sands formation
US7950453B2 (en) 2007-04-20 2011-05-31 Shell Oil Company Downhole burner systems and methods for heating subsurface formations
US8042610B2 (en) 2007-04-20 2011-10-25 Shell Oil Company Parallel heater system for subsurface formations
US20090095479A1 (en) 2007-04-20 2009-04-16 John Michael Karanikas Production from multiple zones of a tar sands formation
US7849922B2 (en) 2007-04-20 2010-12-14 Shell Oil Company In situ recovery from residually heated sections in a hydrocarbon containing formation
US20090120646A1 (en) 2007-04-20 2009-05-14 Dong Sub Kim Electrically isolating insulated conductor heater
US8381815B2 (en) 2007-04-20 2013-02-26 Shell Oil Company Production from multiple zones of a tar sands formation
US20090070997A1 (en) 2007-05-15 2009-03-19 Sealco Commercial Vehicle Products, Inc. Methods for making electrical terminals and for fabricating electrical connectors
US8146669B2 (en) 2007-10-19 2012-04-03 Shell Oil Company Multi-step heater deployment in a subsurface formation
US20090194524A1 (en) 2007-10-19 2009-08-06 Dong Sub Kim Methods for forming long subsurface heaters
US8011451B2 (en) 2007-10-19 2011-09-06 Shell Oil Company Ranging methods for developing wellbores in subsurface formations
US8536497B2 (en) 2007-10-19 2013-09-17 Shell Oil Company Methods for forming long subsurface heaters
US8276661B2 (en) 2007-10-19 2012-10-02 Shell Oil Company Heating subsurface formations by oxidizing fuel on a fuel carrier
US8113272B2 (en) 2007-10-19 2012-02-14 Shell Oil Company Three-phase heaters with common overburden sections for heating subsurface formations
US7866388B2 (en) 2007-10-19 2011-01-11 Shell Oil Company High temperature methods for forming oxidizer fuel
US20090189617A1 (en) 2007-10-19 2009-07-30 David Burns Continuous subsurface heater temperature measurement
US8146661B2 (en) 2007-10-19 2012-04-03 Shell Oil Company Cryogenic treatment of gas
US8162059B2 (en) 2007-10-19 2012-04-24 Shell Oil Company Induction heaters used to heat subsurface formations
US8196658B2 (en) 2007-10-19 2012-06-12 Shell Oil Company Irregular spacing of heat sources for treating hydrocarbon containing formations
US20090200290A1 (en) 2007-10-19 2009-08-13 Paul Gregory Cardinal Variable voltage load tap changing transformer
US7866386B2 (en) 2007-10-19 2011-01-11 Shell Oil Company In situ oxidation of subsurface formations
US8151907B2 (en) 2008-04-18 2012-04-10 Shell Oil Company Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations
US8162405B2 (en) 2008-04-18 2012-04-24 Shell Oil Company Using tunnels for treating subsurface hydrocarbon containing formations
US8172335B2 (en) 2008-04-18 2012-05-08 Shell Oil Company Electrical current flow between tunnels for use in heating subsurface hydrocarbon containing formations
US20100071903A1 (en) 2008-04-18 2010-03-25 Shell Oil Company Mines and tunnels for use in treating subsurface hydrocarbon containing formations
US8177305B2 (en) 2008-04-18 2012-05-15 Shell Oil Company Heater connections in mines and tunnels for use in treating subsurface hydrocarbon containing formations
US8636323B2 (en) 2008-04-18 2014-01-28 Shell Oil Company Mines and tunnels for use in treating subsurface hydrocarbon containing formations
US20100038112A1 (en) 2008-08-15 2010-02-18 3M Innovative Properties Company Stranded composite cable and method of making and using
US8281861B2 (en) 2008-10-13 2012-10-09 Shell Oil Company Circulated heated transfer fluid heating of subsurface hydrocarbon formations
US8353347B2 (en) 2008-10-13 2013-01-15 Shell Oil Company Deployment of insulated conductors for treating subsurface formations
US20100147522A1 (en) 2008-10-13 2010-06-17 Xueying Xie Systems and methods for treating a subsurface formation with electrical conductors
US20100108379A1 (en) 2008-10-13 2010-05-06 David Alston Edbury Systems and methods of forming subsurface wellbores
US8220539B2 (en) 2008-10-13 2012-07-17 Shell Oil Company Controlling hydrogen pressure in self-regulating nuclear reactors used to treat a subsurface formation
US20100224368A1 (en) 2008-10-13 2010-09-09 Stanley Leroy Mason Deployment of insulated conductors for treating subsurface formations
US8256512B2 (en) 2008-10-13 2012-09-04 Shell Oil Company Movable heaters for treating subsurface hydrocarbon containing formations
US8261832B2 (en) 2008-10-13 2012-09-11 Shell Oil Company Heating subsurface formations with fluids
US20100096137A1 (en) 2008-10-13 2010-04-22 Scott Vinh Nguyen Circulated heated transfer fluid heating of subsurface hydrocarbon formations
US20100089584A1 (en) 2008-10-13 2010-04-15 David Booth Burns Double insulated heaters for treating subsurface formations
US20100147521A1 (en) 2008-10-13 2010-06-17 Xueying Xie Perforated electrical conductors for treating subsurface formations
US20100155070A1 (en) 2008-10-13 2010-06-24 Augustinus Wilhelmus Maria Roes Organonitrogen compounds used in treating hydrocarbon containing formations
US8267170B2 (en) 2008-10-13 2012-09-18 Shell Oil Company Offset barrier wells in subsurface formations
US20100190649A1 (en) 2009-01-29 2010-07-29 Doll David W Low loss joint for superconducting wire
US8327932B2 (en) 2009-04-10 2012-12-11 Shell Oil Company Recovering energy from a subsurface formation
US8434555B2 (en) 2009-04-10 2013-05-07 Shell Oil Company Irregular pattern treatment of a subsurface formation
US20100258265A1 (en) 2009-04-10 2010-10-14 John Michael Karanikas Recovering energy from a subsurface formation
US20100258291A1 (en) 2009-04-10 2010-10-14 Everett De St Remey Edward Heated liners for treating subsurface hydrocarbon containing formations
US20100258290A1 (en) 2009-04-10 2010-10-14 Ronald Marshall Bass Non-conducting heater casings
US20110042084A1 (en) 2009-04-10 2011-02-24 Robert Bos Irregular pattern treatment of a subsurface formation
US20110124228A1 (en) 2009-10-09 2011-05-26 John Matthew Coles Compacted coupling joint for coupling insulated conductors
US20110132661A1 (en) 2009-10-09 2011-06-09 Patrick Silas Harmason Parallelogram coupling joint for coupling insulated conductors
US8356935B2 (en) 2009-10-09 2013-01-22 Shell Oil Company Methods for assessing a temperature in a subsurface formation
US8257112B2 (en) 2009-10-09 2012-09-04 Shell Oil Company Press-fit coupling joint for joining insulated conductors
US20110134958A1 (en) 2009-10-09 2011-06-09 Dhruv Arora Methods for assessing a temperature in a subsurface formation
US8485847B2 (en) 2009-10-09 2013-07-16 Shell Oil Company Press-fit coupling joint for joining insulated conductors
US8631866B2 (en) 2010-04-09 2014-01-21 Shell Oil Company Leak detection in circulated fluid systems for heating subsurface formations
US20110248018A1 (en) 2010-04-09 2011-10-13 Ronald Marshall Bass Insulating blocks and methods for installation in insulated conductor heaters
US8939207B2 (en) * 2010-04-09 2015-01-27 Shell Oil Company Insulated conductor heaters with semiconductor layers
US20110247818A1 (en) 2010-04-09 2011-10-13 Ronald Marshall Bass Variable thickness insulated conductors
US20110247805A1 (en) 2010-04-09 2011-10-13 De St Remey Edward Everett Insulated conductor heaters with semiconductor layers
US8701768B2 (en) 2010-04-09 2014-04-22 Shell Oil Company Methods for treating hydrocarbon formations
US8485256B2 (en) 2010-04-09 2013-07-16 Shell Oil Company Variable thickness insulated conductors
US8701769B2 (en) 2010-04-09 2014-04-22 Shell Oil Company Methods for treating hydrocarbon formations based on geology
US8502120B2 (en) 2010-04-09 2013-08-06 Shell Oil Company Insulating blocks and methods for installation in insulated conductor heaters
US20110247817A1 (en) 2010-04-09 2011-10-13 Ronald Marshall Bass Helical winding of insulated conductor heaters for installation
US20120084978A1 (en) 2010-10-08 2012-04-12 Carrie Elizabeth Hartford Compaction of electrical insulation for joining insulated conductors
US20120090174A1 (en) 2010-10-08 2012-04-19 Patrick Silas Harmason Mechanical compaction of insulator for insulated conductor splices
US20120110845A1 (en) 2010-10-08 2012-05-10 David Booth Burns System and method for coupling lead-in conductor to insulated conductor
US20120118634A1 (en) 2010-10-08 2012-05-17 Shell Oil Company End termination for three-phase insulated conductors
US20120085564A1 (en) 2010-10-08 2012-04-12 D Angelo Iii Charles Hydroformed splice for insulated conductors
US8943686B2 (en) * 2010-10-08 2015-02-03 Shell Oil Company Compaction of electrical insulation for joining insulated conductors
US20120255772A1 (en) 2011-04-08 2012-10-11 Shell Oil Company Systems for joining insulated conductors
US20130087383A1 (en) 2011-10-07 2013-04-11 Shell Oil Company Integral splice for insulated conductors
US20130087327A1 (en) 2011-10-07 2013-04-11 Shell Oil Company Using dielectric properties of an insulated conductor in a subsurface formation to assess properties of the insulated conductor
US20130086803A1 (en) 2011-10-07 2013-04-11 Shell Oil Company Forming a tubular around insulated conductors and/or tubulars

Non-Patent Citations (59)

* Cited by examiner, † Cited by third party
Title
"IEEE Recommended Practice for Electrical Impedance, Induction, and Skin Effect Heating of Pipelines and Vessels," IEEE Std. 844-200, 2000; 6 pages.
"Mineral insulated Cable-Aeropak MI Thermocouple Cable" www.ariindustries.com/cable/aeropak.php3. first visited Feb. 6, 2005.
Australian Communication for Australian Patent Application No. 2011237617, mailed Apr. 2, 2013, 4 pages.
Boggs, "The Case for Frequency Domain PD Testing in the Context of Distribution Cable", Electrical Insulation Magazine, IEEE, vol. 19, Issue 4, Jul.-Aug. 2003, pp. 13-19.
Bosch et al. "Evaluation of Downhole Electric Impedance Heating Systems for Paraffin Control in Oil Wells," IEEE Transactions on Industrial Applications, 1992, vol. 28; pp. 190-194.
Bosch et al., "Evaluation of Downhole Electric Impedance Heating Systems for Paraffin Control in Oil Wells," Industry Applications Society 37th Annual Petroleum and Chemical Industry Conference; The Institute of Electrical and Electronics Engineers Inc., Sep. 1990, pp. 223-227.
Canadian Communication for Canadian Application No. 2,606,210 mailed Feb. 25, 2013, 2 pages.
Canadian Communication for Canadian Application No. 2,626,969, mailed Dec. 19, 2012.
Canadian Communication for Canadian Patent Application No. 2650089, mailed Oct. 1, 2013, 3 pages.
Canadian Communication for Canadian Patent Applicatoin No. 2649394, mailed Oct. 3, 2013.
GCC Communication for GCC Patent Application No. GCC/P/2008/11972, mailed Jul. 22, 2013, 3 pages.
Korean Communication for Korean Application No. 2008-7011678, mailed Jun. 24, 2013, 2 pages.
Korean Communication for Korean Patent Application No. 2008-7011678, mailed Dec. 31, 2013, 10 pages.
Korean Communication for Korean Patent Application No. 2008-7028482, mailed Sep. 24, 2013, 11 pages.
Kovscek, Anthony R., "Reservoir Engineering analysis of Novel Thermal Oil Recovery Techniques applicable to Alaskan North Slope Heavy Oils", pp. 1-6.
McGee et al. "Electrical Heating with Horizontal Wells, The Heat Transfer Problem," International Conference on Horizontal Well Tehcnology, Calgary, Alberta Canada, 1996; 14 pages.
PCT International Search Report, Application No. PCT/US2012/058579 dated Dec. 26, 2012.
Rangel-German et al., "Electrical-Heating-Assisted Recovery for Heavy Oil", pp. 1-43. 2004.
Swedish shale oil-Production methods in Sweden, Organisation for European Economic Cooperation, 1952, (70 pages).
Translation of Russian Communication for Russian Application No. 2010119956, mailed Apr. 19, 2013, 2 pages.
U.S. Patent and Trademark "Office Communication" for U.S. Appl. No. 13/268,226, mailed Sep. 3, 2013.
U.S. Patent and Trademark "Office Communication" for U.S. Appl. No. 13/268,246, mailed Aug. 30, 2013.
U.S. Patent and Trademark Office, "Office Communication," for U.S. Appl. No. 11,584,801 mailed Aug. 11, 2008.
U.S. Patent and Trademark Office, "Office Communication," for U.S. Appl. No. 11/113,353 mailed Jul. 25, 2008
U.S. Patent and Trademark Office, "Office Communication," for U.S. Appl. No. 11/113,353 mailed Nov. 18, 2008
U.S. Patent and Trademark Office, "Office Communication," for U.S. Appl. No. 11/113,353 mailed Sep. 20, 2012.
U.S. Patent and Trademark Office, "Office Communication," for U.S. Appl. No. 11/584,801 mailed Jan. 11, 2008; 7 pages.
U.S. Patent and Trademark Office, "Office Communication," for U.S. Appl. No. 11/584,801 mailed Oct. 27, 2009
U.S. Patent and Trademark Office, Office Communication for co-pending U.S. Appl. No. 12/576,772; mailed Oct. 13, 2011.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 11/788,869; mailed May 4, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/106,065; mailed Jun. 27, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/106,065; mailed Nov. 28, 2011.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/106,139; mailed Apr. 10, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/106,139; mailed Jan. 19, 2011
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/106,139; mailed Jul. 21, 2010
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/106,139; mailed Oct. 6, 2011
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/250,346; mailed Sep. 5, 2012
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/576,772; mailed Dec. 12, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/576,772; mailed Jun. 25, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/576,772; mailed Mar. 10, 2014.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/576,772; mailed May 1, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/757,650; mailed Jul. 19, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/901,231; mailed Aug. 15, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/901,231; mailed Dec. 19, 2012
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/901,237; mailed Apr. 3, 2014.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/901,237; mailed Aug. 2, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/901,237; mailed Dec. 26, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 12/901,237; mailed Jun. 13, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/083,169; mailed Sep. 11, 2012.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/083,177; mailed Mar. 13, 2014.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/083,177; mailed Oct. 9, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/083,200; mailed Jul. 22, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/268,238; mailed May 16, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/268,258; mailed May 21, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/411,300; mailed May 14, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/411,300; mailed Oct. 16, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/567,799; mailed Oct. 16, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/738,345; mailed Oct. 16, 2013.
U.S. Patent and Trademark Office, Office Communication for U.S. Appl. No. 13/960,355; mailed Dec. 3, 2013.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170171918A1 (en) * 2011-10-07 2017-06-15 Shell Oil Company Forming insulated conductors using a final reduction step after heat treating

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