US9198804B2 - Method of manufacturing sheet, method of manufacturing material of absorbent article, and apparatus to manufacture sheet - Google Patents

Method of manufacturing sheet, method of manufacturing material of absorbent article, and apparatus to manufacture sheet Download PDF

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Publication number
US9198804B2
US9198804B2 US13/262,718 US201013262718A US9198804B2 US 9198804 B2 US9198804 B2 US 9198804B2 US 201013262718 A US201013262718 A US 201013262718A US 9198804 B2 US9198804 B2 US 9198804B2
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Prior art keywords
protruding portion
sheet
roll
circumferential direction
protruding
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US13/262,718
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US20120086145A1 (en
Inventor
Taishi Nakamura
Shinichi Ishikawa
Yukihisa AKANO
Satoshi Mitsuno
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Unicharm Corp
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Unicharm Corp
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Assigned to UNI-CHARM CORPORATION reassignment UNI-CHARM CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NAKAMURA, TAISHI, AKANO, YUKIHISA, ISHIKAWA, SHINICHI, MITSUNO, SATOSHI
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15577—Apparatus or processes for manufacturing
    • A61F13/15585—Apparatus or processes for manufacturing of babies' napkins, e.g. diapers
    • A61F13/15593—Apparatus or processes for manufacturing of babies' napkins, e.g. diapers having elastic ribbons fixed thereto; Devices for applying the ribbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15577—Apparatus or processes for manufacturing
    • A61F13/15699—Forming webs by bringing together several webs, e.g. by laminating or folding several webs, with or without additional treatment of the webs
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15577—Apparatus or processes for manufacturing
    • A61F13/15707—Mechanical treatment, e.g. notching, twisting, compressing, shaping
    • A61F13/15731—Treating webs, e.g. for giving them a fibrelike appearance, e.g. by embossing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15577—Apparatus or processes for manufacturing
    • A61F13/15707—Mechanical treatment, e.g. notching, twisting, compressing, shaping
    • A61F13/15739—Sealing, e.g. involving cutting
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15577—Apparatus or processes for manufacturing
    • A61F13/15756—Applying tabs, strips, tapes, loops; Knotting the ends of pads
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49—Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • A61F13/49007—Form-fitting, self-adjusting disposable diapers
    • A61F13/49009—Form-fitting, self-adjusting disposable diapers with elastic means
    • A61F13/49011—Form-fitting, self-adjusting disposable diapers with elastic means the elastic means is located at the waist region
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/515—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers characterised by the interconnection of the topsheet and the backsheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/44—Compression means for making articles of indefinite length
    • B29C43/46—Rollers
    • B29C2043/461—Rollers the rollers having specific surface features
    • B29C2043/463—Rollers the rollers having specific surface features corrugated, patterned or embossed surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/44—Compression means for making articles of indefinite length
    • B29C43/46—Rollers
    • B29C2043/461—Rollers the rollers having specific surface features
    • B29C2043/464—Rollers the rollers having specific surface features having projections or knives, e.g. for cutting-out or for forming local depressions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/224—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length having a profiled section, e.g. tubes, rods
    • B29C43/226—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length having a profiled section, e.g. tubes, rods having a corrugated section
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34—Auxiliary operations
    • B29C44/56—After-treatment of articles, e.g. for altering the shape
    • B29C44/5627—After-treatment of articles, e.g. for altering the shape by mechanical deformation, e.g. crushing, embossing, stretching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/22—Corrugating
    • B29C53/24—Corrugating of plates or sheets
    • B29C53/26—Corrugating of plates or sheets parallel with direction of feed
    • B29C53/265—Corrugating of plates or sheets parallel with direction of feed using rolls or endless bands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/22—Corrugating
    • B29C53/24—Corrugating of plates or sheets
    • B29C53/28—Corrugating of plates or sheets transverse to direction of feed
    • B29C53/285—Corrugating of plates or sheets transverse to direction of feed using rolls or endless bands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts

Definitions

  • the present invention relates to methods of manufacturing a sheet configuring an absorbent article, methods of manufacturing a material of the absorbent article, and apparatuses to manufacture a sheet.
  • a disposable diaper As an example of an absorbent article that absorbs a bodily waste fluid, a disposable diaper is used.
  • This disposable diaper includes an absorbent main body that is applied to a crotch part of a wearer and absorbs a bodily waste fluid, an abdominal side member joined to one end portion in a longitudinal direction of an absorbent main body to cover an abdominal side portion of the wearer, and a back side member joined to another end portion in the longitudinal direction of the absorbent main body to cover a back side portion of the wearer.
  • this sheet like member 81 is formed by such as laying on and fixing a plurality of elastic members 85 such as a rubber thread along a width direction of the diaper onto an appropriate sheet 83 such as a nonwoven fabric.
  • the elastic member 85 is divided in order to weaken elasticity of the sheet like member 81 . This is because, if elasticity of this region 81 a is strong, creases appear in the end portion of the absorbent main body by contraction of the region 81 a , and liquid absorbency of the absorbent main body deteriorates.
  • PTL1 discloses dividing the elastic member 85 with embossing rolls 91 , 93 that rotate in a circumferential direction Dc (refer to FIG. 1 ). Namely, in a predetermined area on an outer circumferential face of the top roll is provided an embossing protruding portion group 92 G corresponding to the region 81 a .
  • the top roll 91 rises upward for an instance due to this large counterforce, and the part of the embossing protruding portion 92 corresponding to the rising timing cannot effectively perform dividing.
  • the part of the embossing protruding portion 92 corresponding to the rising timing cannot effectively perform dividing.
  • elasticity of the region 81 a remains large in part.
  • such a rising phenomenon is particularly likely to occur when starting dividing, namely when dividing with the embossing protruding portion row 92 A configuring a downstream end edge in the circumferential direction Dc of the embossing protruding portion group 92 G.
  • top and bottom rolls 91 , 93 are generally stored inside a case like housing (not shown), and from the housing, a total load in a vertical direction that is necessary when sandwiching is added. Then, normally, the total load is a constant value.
  • the arrangement direction of the embossing protruding portions 92 , 92 . . . are in parallel with the rotational axis direction C 91 of the top roll 91 , a plurality of embossing protruding portions 92 , 92 . . .
  • the invention has been made in view of the above problems, and the object is to provide a method of manufacturing a sheet in which in a predetermined portion of the sheet a region having a different flexibility property can be certainly formed, a method of manufacturing a material of an absorbent article, and an apparatus to manufacture a sheet.
  • An aspect of the invention to achieve the above advantages is a method of manufacturing a sheet formed, in a predetermined portion of the sheet, with a region having a different flexibility property, the sheet configuring an absorbent article, the method including:
  • the protruding portion group has a plurality of rows of protruding portion rows with intervals therebetween in the circumferential direction, each of the protruding portion rows including a plurality of protruding portions aligned along a rotational axis direction of the first roll,
  • a position of a downstream end in the circumferential direction of at least one protruding portion of the protruding portions configuring the protruding portion row positioned most downstream of the protruding portion group in the circumferential direction is arranged shifted from a position of a downstream end of another protruding portion configuring the protruding portion row.
  • Another aspect is a manufacturing apparatus of a sheet formed in a predetermined portion of the sheet with a region having a different flexibility property, the sheet configuring an absorbent article, the apparatus including:
  • a first roll that rotates in a circumferential direction and that is formed with a protruding portion group in a predetermined area of an outer circumferential face
  • a second roll that rotates in the circumferential direction and that is arranged with an outer circumferential face opposing the first roll
  • the protruding portion group has a plurality of protruding portion rows with intervals therebetween in the circumferential direction, each of the protruding portion rows including a plurality of protruding portions aligned along a rotational axis direction of the first roll,
  • a position of a downstream end in the circumferential direction of at least one protruding portion of the protruding portions configuring the protruding portion row positioned most downstream of the protruding portion group in the circumferential direction is arranged shifted from a position of a downstream end of another protruding portion configuring the protruding portion row.
  • a region with a different flexibility property from the sheet can be certainly formed.
  • FIG. 1 is an explanatory diagram of a known method to selectively weaken elasticity added to a sheet 81 in a part of a region 81 a.
  • FIG. 2 is a plan view of an opened state of a disposable diaper 1 .
  • FIG. 3 is a perspective view of a worn state of the diaper.
  • FIG. 4 is an exploded perspective view of the diaper.
  • FIG. 5 is a perspective view of a step performed in a method of manufacturing of this embodiment.
  • FIG. 6A is explanatory diagram of an arrangement pattern of a slit blade 41 in slit blade groups 41 G, 41 G and is a front view showing an appearance of a top roll 31
  • FIG. 6B is a B-B cross section view in FIG. 6A .
  • FIG. 7 is a diagram showing the right side slit blade group 41 G of FIG. 6A opened on a plane.
  • FIG. 8 is a side view of the top and bottom rolls 31 , 35 .
  • FIG. 9 is an enlarged diagram of an arrangement pattern of the right side slit blade group 41 G.
  • FIG. 10 is an explanatory diagram of a modified example of the arrangement pattern.
  • FIG. 11 is an explanatory diagram of another modified example of the arrangement pattern.
  • FIG. 12 is an explanatory diagram of yet another modified example of the arrangement pattern.
  • FIG. 13 is another embodiment of a planar view shape of a blade edge of the slit blade 41 .
  • the protruding portion group has a plurality of rows of protruding portion rows with intervals therebetween in the circumferential direction, each of the protruding portion rows including a plurality of protruding portions aligned along a rotational axis direction of the first roll,
  • a position of a downstream end in the circumferential direction of at least one protruding portion of the protruding portions configuring the protruding portion row positioned most downstream of the protruding portion group in the circumferential direction is arranged shifted from a position of a downstream end of another protruding portion configuring the protruding portion row.
  • a position of a downstream end of at least one protruding portion belonging to the protruding portion row positioned most downstream is arranged shifted in the circumferential direction than other protruding portion in the protruding portion row.
  • the sandwiching timing of the sheet by the protruding portions belonging to the most downstream protruding portion row can be certainly made different from each other and dispersed, and thus the counterforce that acts on the first roll and the second roll when the protruding portions sandwich the sheet is further alleviated. As a result, the rising of the roll is further suppressed.
  • the position of the downstream end in the circumferential direction of the protruding portion belonging to each protruding portion row is subsequently shifted to the upstream side in the circumferential direction, as the position advances in one direction of the rotational axis direction.
  • the sandwiching timing of the sheet with the protruding portions can certainly be made different from each other and dispersed, and thus the counterforce that acts on the first roll and the second roll when the protruding portions sandwich the sheet is furthermore alleviated. Therefore, the rising of the roll can be furthermore certainly suppressed.
  • a longitudinal direction of the protruding portion is arranged inclined by only a predetermined angle (excluding 90°) from the rotational axis direction.
  • the longitudinal direction of the protruding portion is inclined for only a predetermined angle from the rotational axis direction, thus the sandwiching timing of each section in the longitudinal direction between the protruding portions can be dispersed, and thus the counterforce that acts on the first roll and the second roll when the protruding portion sandwiches the sheet is alleviated.
  • the rising of the roll is furthermore certainly suppressed.
  • the protruding portions belonging to the same protruding portion row are not overlapped with each other in respect to the circumferential direction.
  • the protruding portions belonging to the same protruding portion row are not overlapped with each other in respect to the circumferential direction, thus the sandwiching timing of the sheet with the protruding portions belonging to the same protruding portion row can be made different from each other and dispersed, and thus the counterforce that acts on the first roll and the second roll when forming the region can be alleviated. Therefore, the rising of the roll can be furthermore certainly suppressed.
  • the protruding portion rows adjacent to each other in the circumferential direction are not overlapped with each other in the circumferential direction, thus between the adjacent protruding portion rows, the sandwiching timing of the sheet can be made different from each other and dispersed, and thus the counterforce that acts on the first roll and the second roll when forming the region is alleviated. Therefore, the rising of the roll can be furthermore certainly suppressed.
  • protruding portion is a blade member
  • the region with a different flexibility property is to be formed with slits that cut through the sheet in the thickness direction, for the number of the protruding portions of the protruding portion group. Then, with theses slits both surfaces of the sheet become an air permeable state. Therefore, the sheet with increased air permeability in the region with a different flexibility property can be manufactured.
  • a protruding portion of one protruding portion group of the pair of protruding portion groups is arranged based on a predetermined arrangement pattern
  • a protruding portion of another protruding portion group of the pair of protruding portion groups is arranged based on an arrangement pattern in a mirror image relationship of the arrangement pattern in respect to a center of the rotational axis direction.
  • the pair of protruding portion groups are each provided in positions that sandwich the center in the rotational axis direction, and these pair of protruding portion groups are formed so that the protruding portions are arranged based on an arrangement pattern in which the protruding portion groups are in a mirror image relationship with each other. Therefore, the counterforce that acts on the first roll and the second roll when forming the region with the different flexibility property can be made as a substantially symmetric pressure distribution in regard to the center, and as a result an asymmetric load in regard to the center is not placed on the sheet or the roll, and thus the method is superior in view of stability when processing the region.
  • protruding portion belonging to one protruding portion group and the protruding portion belonging to the other protruding portion group are not overlapped with each other in respect to the circumferential direction.
  • a method of manufacturing a material using a sheet manufactured by a method of manufacturing a sheet
  • the absorbent article includes an absorbent main body that is applied to a crotch portion of a wearer and that absorbs a bodily waste fluid, an abdominal side member joined to one end portion in a longitudinal direction of the absorbent main body to cover an abdominal side portion of the wearer, and a back side member joined to another end portion in the longitudinal direction of the absorbent main body to cover a back side portion of the wearer,
  • the sheet configures at least one of the abdominal side member and the back side member
  • region, in the sheet, with the different flexibility property is joined with end portions of the absorbent main body and forms the material.
  • protruding portion is a blade member
  • the sheet is to be joined to a surface to the wearer's side of the absorbent main body.
  • the region of the sheet to be joined to the end portions in the longitudinal direction of the absorbent main body is formed with the slits cut through in the thickness direction of the sheet for the number of the protruding portions of the protruding portion group, and air permeability of the region is increased by the openings of these slits. Therefore, the absorbent article that can decrease the wearer's skin opposing the end portions in the longitudinal direction of the absorbent main body becoming hot and stuffy and the like can be manufactured.
  • the apparatus including:
  • a first roll that rotates in a circumferential direction and that is formed with a protruding portion group in a predetermined area of an outer circumferential face
  • a second roll that rotates in the circumferential direction and that is arranged with an outer circumferential face opposing the first roll
  • the protruding portion group has a plurality of protruding portion rows with intervals therebetween in the circumferential direction, each of the protruding portion rows including a plurality of protruding portions aligned along a rotational axis direction of the first roll,
  • a position of a downstream end in the circumferential direction of at least one protruding portion of the protruding portions configuring the protruding portion row positioned most downstream of the protruding portion group in the circumferential direction is arranged shifted from a position of a downstream end of another protruding portion configuring the protruding portion row.
  • the position in the downstream end of at least one protruding portion belonging to the protruding portion row positioned most downstream is arranged shifted in the circumferential direction from the other protruding portion of the protruding portion row. Therefore, the sandwiching timing of the protruding portion in which the position of the downstream end is shifted is shifted from that of the other protruding portion, thus the counterforce that acts on the first roll and the second roll when the protruding portion row positioned most downstream sandwiches the sheet is alleviated for the above-described timing shift amount. As a result, the rising of the roll is alleviated. Then, by suppressing this rising, the sheet can be certainly sandwiched with a larger number of protruding portions, and as a result the region with the different flexibility property can be formed in the sheet.
  • the load to be assigned for one protruding portion can be enlarged.
  • a sandwiching force in the protruding portion can be made large, and the region with the different flexibility property can be certainly formed.
  • a method of manufacturing a sheet and an apparatus to manufacture a sheet of this embodiment are applied to a manufacturing line of, for example, a disposable diaper 1 (corresponds to absorbent article).
  • FIG. 2 to FIG. 4 are explanatory diagrams of the disposable diaper 1 .
  • FIG. 2 is a plan view of an opened state
  • FIG. 3 is a perspective view of a worn state
  • FIG. 4 is an exploded perspective view.
  • the diaper 1 includes an absorbent main body 3 that is applied to a wearer's crotch portion and absorbs a bodily waste fluid, an abdominal side strip member 5 (corresponds to abdominal side member) that has been joined to a front end portion 3 a in a longitudinal direction of the absorbent main body 3 so as to cover the wearer's abdominal side portion, and a back side strip member 7 (corresponds to back side member) that has been joined to a back end portion 3 b in the longitudinal direction of the absorbent main body 3 so as to cover the wearer's back side portion, and the appearance of the diaper 1 in the open state is a planar substantially H shape. Note that, in this open state, the longitudinal direction of the diaper 1 matches the longitudinal direction of the absorbent main body 3 , and further a width direction of the diaper 1 intersects with the longitudinal direction.
  • the diaper 1 is folded into two with a central portion C 3 in the longitudinal direction of the absorbent main body 3 as a folding position, and when the strip members 5 , 7 opposing each other in this two-folded state are fixed at the wearer's sides in sections to be contacted to each other 5 e , 7 e , the strip members 5 , 7 are connected to each other in a circular state, and thus the diaper 1 in a worn state formed with a waist opening la and a pair of around-leg openings 1 b , 1 b is formed as shown in FIG. 3 .
  • the absorbent main body 3 includes an absorbent body 3 c made of a liquid absorbent fiber such as a pulp fiber, a liquid permeable surface sheet 3 d that covers the absorbent body 3 c from the wearer's skin side, and a liquid nonpermeable back face sheet 3 e that covers the absorbent body 3 c from an opposite side of the surface sheet 3 d .
  • the absorbent body 3 c may include a superabsorbent polymer.
  • the absorbent main body 3 may include a pair of standing gathers 4 , 4 by arranging an elastic member (not shown) such as a rubber thread along both end edges in the width direction.
  • the abdominal side strip member 5 has a skin side sheet 5 a that comes into contact with the wearer's skin and an outer side sheet 5 b that is an outer. Then, these sheets 5 a , 5 b are adhered to each other with such as a hotmelt adhesive in a state the front end portion 3 a in the longitudinal direction of the absorbent main body 3 is sandwiched between the sheets 5 a , 5 b .
  • An elastic member 6 such as a rubber thread in an extended state is fixed along the width direction of the diaper 1 to the outer side sheet 5 b , thus flexibility is added in the width direction to the outer side sheet 5 b
  • the elastic member 6 is not arranged in the region 5 d where the front end portion 3 a is joined to the absorbent main body 3 of the outer side sheet 5 b This is because if elasticity in this region 5 d is strong, the region 5 d largely contracts in the width direction of the diaper 1 , and therefore creases appear in the front end portion 3 a of the absorbent main body 3 and its liquid absorbent property deteriorates.
  • a flexible sheet added with flexibility by such as a so-called gear drawing processing is used as the skin side sheet 5 a
  • elasticity of the region 5 c to be joined with the front end portion 3 a of the absorbent main body 3 is weakened in the width direction of the diaper 1 , by putting in multiple slits 10 in this region 5 c .
  • these slits 10 are cut through in the thickness direction of the skin side sheet 5 a , and the longitudinal direction of the slits 10 is facing a direction intersecting the width direction of the diaper 1 .
  • the slits 10 are made so as to be able to open promptly under the effect of a tensile force in the width direction of the diaper 1 , and thus elasticity of the region 5 c in the width direction is weakened. Note that, with such openings of the slits 10 , air permeability of the region 5 c is improved and also contributes to prevent stuffiness.
  • the back side strip member 7 is only different in shape with the abdominal side strip member 5 , and its configuration is substantially the same. Namely, the back side strip member 7 also includes a skin side sheet 7 a that comes into contact with a skin of the wearer, and an outer side sheet 7 b that becomes an outer, and these sheets 7 a , 7 b are adhered together by such as a hotmelt adhesive in a state sandwiching the back end portion 3 b of the absorbent main body 3 in the longitudinal direction between these sheets 7 a , 7 b
  • the structure of the skin side sheet 7 a and the outer side sheet 7 b is also the same as in the case of the above-described abdominal side strip member 5 .
  • a flexible sheet is used for the skin side sheet 7 a , and elasticity of the region 7 c that is to be joined with the back end portion 3 b of the absorbent main body 3 , is weakened in regards to the width direction of the diaper 1 by putting in multiple slits 10 in the region 7 c.
  • Such a diaper 1 is completed by having any component that continuously flows in the manufacturing line as a base material, and by such as joining various components to the base material.
  • a method of manufacturing a sheet and an apparatus 30 to manufacture a sheet of this embodiment handles one step.
  • FIG. 5 is a perspective view of a step handled in the method of manufacturing the sheet in this embodiment.
  • the above-described slit processing is performed in product units of the diaper 1 in respect to both a continuous body of the skin side sheet 5 a of the abdominal side strip member 5 and a continuous body of the skin side sheet 7 a of the back side strip member 7 , and thus elasticity of the regions 5 c , 7 c (hereinbelow, also referred to as joining target regions 5 c , 7 c ) to which the front end portion 3 a and the back end portion 3 b of the above-described absorbent main body 3 are to be joined is weakened.
  • the pair of skin side sheets 5 a , 7 a at the time of being supplied in this step is continuously transported, in a form of a continuous body along the transporting direction, and in a state aligned in the CD direction (a direction that intersects the transporting direction and that is also referred to as a left to right direction) with an interval therebetween.
  • the transporting form in this step is a so-called horizontal flow, that is, the partially completed products of the diapers 1 are aligned with the width direction of the diaper 1 aligned in the transporting direction, and each partially completed product is transported in a state aligned with a predetermined pitch P 1 in the transporting direction.
  • generation of the above-described pair of skin side sheets 5 a , 7 a is performed by dividing in two one continuous sheet 8 to the left and right in the CD direction by the discal rotating blade 21 , while continuously transporting in the transporting direction the one continuous sheet 8 that is continuously let out from a reel device (not shown) in an upper step of this step.
  • a pair of the top and the bottom rolls 31 , 35 for slit processing are installed.
  • Each roll 31 , 35 is opposed with the outer circumferential face to each other while directing the rotational axis directions C 31 , C 35 in the CD direction.
  • the rolls are drivingly rotated in the circumferential direction Dc by an appropriate drive source such as a motor.
  • the outer circumferential face of the top roll 31 is provided with a pair of slit blade groups 41 G, 41 G (corresponds to protruding portion group) with multiple slit blades 41 (corresponds to protruding portions) arranged closely together, for example sandwiching the center of the top roll 31 in the CD direction.
  • One of the slit blade group 41 G is for performing a slit processing to the joining target region 5 c of the skin side sheet 5 a of the abdominal side strip member 5
  • the other slit blade group 41 G is for performing the slit processing to the joining target region 7 c of the skin side sheet 7 a of the back side strip member 7 .
  • the bottom roll 35 is an anvil roll to receive the slit blade 41 , that is, the outer circumferential face is formed as a smooth surface.
  • a manufacturing step of the absorbent main body 3 joins in as shown in FIG. 5 , and the absorbent main body 3 is put across between a pair of the skin side sheets to form a ladder like partially completed product (corresponds to a material).
  • both end portions 3 a , 3 b of the absorbent main body 3 in the longitudinal direction are each joined to each joining target region 5 c , 7 c of the pair of the skin side sheets 5 a , 7 a.
  • FIG. 6A to FIG. 7 are explanatory diagrams of an arrangement pattern of the slit blades 41 of the slit blade groups 41 G, 41 G.
  • FIG. 6A is a front view showing an appearance of the top roll 31
  • FIG. 6B is a B-B cross section view in FIG. 6A .
  • FIG. 7 is a diagram showing the right side slit blade group 41 G opened on a flat surface.
  • the pair of slit blade groups 41 G, 41 G are different from each other in the number of blades they each have. Namely, the number of blades of the right side slit blade group 41 G, is larger than that of the left side slit blade group 41 G.
  • the arrangement of the slit blades 41 in these pair of slit blade groups 41 G, 41 G is basically made based on the arrangement pattern that is in a mirror image relationship to each other in regards to the central line CL in the CD direction.
  • the right side slit blade group 41 G in FIG. 6A will be mainly described, and the description of the left side slit blade group 41 G will be omitted.
  • each slit blade 41 is a flat blade (linear blade) with the same shape and size as each other, in other words, the plane shape of the blade edge is linear.
  • the section shape of the blade is, as shown in FIG. 6B , a substantially triangular shape with the root side being wider than the blade edge side. Note that, the blade edge in this example is pointed in an acute angle with the blade edge angle a being 60°, but the blade edge may be beveled in a range in which the cutting property does not deteriorate.
  • the outline of the slit blade group 41 G is a substantially rectangular shape.
  • the arrangement pattern of the slit blade 41 is a so-called staggered arrangement. Namely, a plurality of the slit blade rows 41 A (corresponds to protruding portion row) in which a plurality of slit blades 41 , 41 . . .
  • each slit blade row 41 A belonging to the same slit blade row 41 A are arranged so that a center C 41 in each slit blade 41 is positioned on one line, and further the longitudinal direction of each slit blade 41 is also aligned in a direction of the line, and the appearance of each slit blade row 41 A is in a straight dashed line.
  • the length of such a slit blade 41 in the longitudinal direction is selected from a range of, for example 3 to 5 mm.
  • the pitch Ph in the rotational axis direction C 31 is selected from a range of for example 1 to 7 mm, in a range in which the adjacent slit blades 41 , 41 do not connect to each other.
  • the pitch Pc in the circumferential direction Dc is selected from a range of, for example 2 to 8 mm.
  • the joining target region 5 c ( 7 c ) of the sheet 5 a ( 7 a ) becoming easy to tear due to the formed slits 10 can be effectively suppressed, while certainly weakening the elasticity in the region 5 c ( 7 c ).
  • the arrangement direction (a direction formed by connecting the centers C 41 , C 41 of each slit blade 41 belonging to the slit blade row 41 A) of the slit blade row 41 A is inclined in the circumferential direction Dc by only an inclined angle ea from the rotational axis direction C 31 (refer to the chain double-dashed line).
  • the position in the downstream end 41 d in the circumferential direction Dc of the slit blades 41 , 41 . . . configuring the same slit blade row 41 A is shifted to the downstream side in the circumferential direction Dc subsequently, as it advances in one direction of the rotational axis direction C 31 .
  • the sandwiching timing of the sheet 5 a ( 7 a ) by the downstream end 41 d of the slit blade 41 can be made to be different for each of the slit blades 41 , 41 and dispersed, therefore when the downstream end 41 d of the slit blade 41 sandwiches the sheet 5 a ( 7 a ), the counterforce that acts on the top roll 31 and the bottom roll 35 is alleviated. As a result, the rising of the top roll 31 is suppressed, and each slit blade 41 can certainly divide and cut through the sheet 5 a ( 7 a ) part that the blade itself comes into contact.
  • this rising phenomenon is prone to occur particularly when starting dividing, in other words when the slit blade row 41 A 1 positioned most downstream in the circumferential direction Dc of the slit blade group 41 G divides the sheet 5 a ( 7 a ).
  • the rising phenomenon is alleviated.
  • the inclined angle ⁇ a in regards to the arrangement of the slit blade row 41 A is selected from an angle excluding 0° and 90°, and preferably selected from a range of 0.5° to 10°. If the angle is selected from this range, the plane shape of the joining target region 5 c ( 7 c ) can be maintained in a substantially rectangular shape, and dispersion of the sandwiching timing can be certainly achieved. Note that, the reason that it is better for the plane shape of the joining target region 5 c ( 7 c ) to be a rectangle than a parallelogram is because generally the shape of the end portions 3 a , 3 b in the longitudinal direction of the absorbent main body 3 is a rectangle (refer to for example FIG. 4 ).
  • each slit blade 41 can certainly divide and cut through the sheet 5 a ( 7 a ) part that the blade itself comes into contact.
  • the top and bottom rolls 31 , 35 are stored inside the case like housing 37 shown in the side view in FIG. 8 . Then, via a hydraulic jack 39 arranged in between a chock 32 that supports both end portions of the top roll 31 and a chock 32 that supports both end portions of the bottom roll 35 and a housing 37 , a vertical direction load F is added to the top and bottom rolls 31 , 35 from the housing 37 , and the vertical direction load F is applied for dividing of the slits 10 of the sheet 5 a ( 7 a ). Then, generally, this vertical direction load F is a constant value. In this case, if the sandwiching timing of the plurality of slit blades 41 , 41 . . .
  • this vertical direction load F can be made to act in a concentrated manner on one slit blade 41 or a very small number of slit blades 41 , and the dividing property of the slit blade 41 increases significantly. Then, as a result, each slit blade 41 can certainly divide and cut through the sheet 5 a ( 7 a ) part that the blade itself comes into contact.
  • the slit blades 41 , 41 belonging to the same slit blade row 41 A may be arranged so as not to overlap each other in the circumferential direction Dc.
  • each slit blade 41 belonging to the same slit blade row 41 A is arranged on one line shown by a dotted line in FIG. 9 , and the longitudinal direction of each slit blade 41 is facing the one line direction, and thus, overlap in the circumferential direction Dc can be completely avoided.
  • this relationship is the best state established across all the slit blade rows 41 A, 41 A . . . of the slit blade group 41 G, but this relationship may be established for at least one or more rows of the slit blade row 41 A, and in that case a reasonable effect can be achieved.
  • the slit blade rows 41 A, 41 A . . . can be aligned so that the adjacent slit blade rows 41 A, 41 A do not overlap each other in the circumferential direction Dc.
  • an interval W 1 in the circumferential direction between a downstream end 41 Ad of an adjacent slit blade row 41 A to the upstream side in the circumferential direction Dc of the focused slit blade row 41 A and an upstream end 41 Au of the adjacent slit blade row 41 A to the downstream side in the circumferential direction Dc of the focused slit blade row 41 A is wider than a dimension W 2 of the focused slit blade row 41 A in the circumferential direction Dc.
  • this relationship is the best state established across all the slit blade rows 41 A, 41 A . . . of the slit blade group 41 G, but the relationship can be established between at least an adjacent set of slit blade rows 41 A, 41 A, and in such a case a reasonable effect can also be achieved.
  • the pair of the slit blade groups 41 G, 41 G may be aligned so that the slit blade 41 belonging to the right side slit blade group 41 G of the left and right pair of the slit blade groups 41 G, 41 G and the slit blade 41 belonging to the left side slit blade group 41 G do not overlap in respect to the circumferential direction Dc.
  • the right side slit blade group 41 G and the left side slit blade group 41 G changes from a state in which the positions of the most downstream slit blade rows 41 A 1 , 41 A 1 of each group are matched with each other in respect to the circumferential direction Dc to a state in which one slit blade group 41 G is relatively moved entirely in the circumferential direction Dc by just a predetermined amount.
  • the slit blade row 41 A of the left side slit blade group 41 G is fitted in the intervals between the slit blade rows 41 A, 41 A adjacent to each other of the right side slit blade group 41 G.
  • the right side slit blade group 41 G and the left side slit blade group 41 G are arranged based on an arrangement pattern in which they are in a mirror image relationship with each other in respect to a central line CL of the top roll 31 in the CD direction (refer to FIG. 6A ).
  • the counterforce that acts on the top roll 31 and bottom roll 35 can be pressure distributed substantially symmetrically in respect to the central line CL, and as a result an asymmetric load in respect to the central line CL is not put on the sheets 5 a , 7 a or the rolls 31 , 35 , and therefore is superior in view of stability when cutting.
  • FIG. 10 to FIG. 12 are explanatory diagrams of modified examples of arrangement patterns, and one part is shown opened on a plane. Note that, the shape of the slit blade 41 is the same as the above-described embodiment.
  • the arrangement pattern example shown in FIG. 10 is different from the above-described embodiment in view of a pitch Pc in the circumferential direction Dc of the slit blade row 41 A.
  • the pitch Pc to align the plurality of slit blade rows 41 A, 41 A . . . in the circumferential direction Dc is made narrower than in the above-described embodiment, and therefore, the adjacent slit blade rows 41 A, 41 A are overlapped with each other in respect to the circumferential direction Dc.
  • the arrangement pattern examples shown in FIG. 11 and FIG. 12 are different from the above-described embodiment in view of an orientation in the longitudinal direction of the slit blades 41 .
  • the orientation in the longitudinal direction of the slit blades 41 match the arrangement direction of the slit blade row 41 A, and thus all the slit blades 41 of the slit blade row 41 A are on one line as a whole, but in the arrangement pattern in FIG.
  • the inclined angle ⁇ s of the slit blade 41 in the longitudinal direction from the rotational axis direction C 31 is made larger than the inclined angle ⁇ a in the arrangement direction from the rotational axis direction C 31 , and the slit blades 41 , 41 adjacent in the rotational axis direction C 31 are overlapped with each other in respect to the circumferential direction Dc.
  • the arrangement pattern in FIG. 12 is, conversely, an example in which the inclined angle ⁇ s is smaller than the inclined angle ⁇ a, and in more detail is an example in which the longitudinal direction of the slit blade 41 is facing a direction parallel to the rotational axis direction C 31 .
  • Such an inclined angle ⁇ s of the longitudinal direction of such a slit blade 41 is selected from an arbitrary angle other than 90°, and is preferably selected from a range of 0.5° to 5°. If the angle is selected from the latter range, the longitudinal direction of the slit blade 41 is substantially perpendicular to the transporting direction, and the joining target region 5 c ( 7 c ) is divided with the slit blade 41 with multiple slits 10 along the CD direction, and thus the elasticity of the joining target region 5 c ( 7 c ) in the transporting direction (the width direction in the diaper 1 ) is certainly weakened.
  • the sheet that has flexibility in the sheet itself was illustrated as the skin side sheets 5 a , 7 a , but it is not limited to this.
  • a sheet added with flexibility by laying down and fastening an elastic member such as a rubber thread that has been extended may be used.
  • the elastic member in the joining target region is divided by the slit blades 41 in the slit blade group 41 G.
  • the protruding portion As one example of the protruding portion a flat blade like (linear blade like) slit blade 41 is illustrated, but it is not limited to the above.
  • it may be a slit blade 41 that has a planar view shape of the blade edge curved in an arc shape.
  • the protruding portion is not limited to a cutter, and for example it may be an embossing protruding portion having a substantially flat top surface in a predetermined area.
  • a rectangle, a rhombus, a circle and the like can be illustrated.
  • a staggered pattern is illustrated as an arrangement pattern of the slit blade 41 of the slit blade group 41 G, but it is not limited to this, and for example it may be a lattice pattern (a grid pattern). In other words, it may be a pattern in which a center C 41 of each slit blade 41 is not arranged in each intersection point of the lattice pattern.
  • the sheet added with flexibility by such as a gear drawing processing is illustrated, but it not limited to the above as long as it has flexibility.
  • a laminated sheet in which the sheet added with the flexibility is extended and a sheet with a lower flexibility than the sheet is overlapped and adhered may be used.
  • a nonwoven fabric configured from an extensile fiber and a flexible fiber can be given. Then, the nonwoven fabric is passed through a pair of the top and the bottom gear rolls that rotate, and at that time the nonwoven fabric is extended in a rotating direction of the gear rolls with outer gear teeth of the top and the bottom gear rolls, and thus flexibility is developed in the nonwoven fabric.
  • the flexible fiber refers to a fiber that is elastically extensile
  • the extensile fiber refers to a fiber that is substantially non-elastically extensile.
  • the extensile fiber can also be referred to as a fiber in which plastic deformation occurs with a smaller elongation than the elongation that is an elastic limit of the flexible fiber.
  • a thermoplastic polyolefin fiber can be illustrated, and further as a flexible fiber a thermoplastic elastomer fiber can be illustrated.
  • thermoplastic polyolefin fiber is, for example, a single fiber such as polypropylene fiber or polyester fiber, or a composite fiber with a core sheath structure made of a polypropylene or a polyester, and further the thermoplastic elastomer fiber is, for example a polyurethane fiber and the like.
  • the nonwoven fabric may be laminated in the thickness direction of the nonwoven fabric with, for example, a layer of only the extensile fiber and a layer of only the flexible fiber which are separated in layers.

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Vascular Medicine (AREA)
  • Epidemiology (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
US13/262,718 2009-04-03 2010-03-10 Method of manufacturing sheet, method of manufacturing material of absorbent article, and apparatus to manufacture sheet Expired - Fee Related US9198804B2 (en)

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PCT/JP2010/054038 WO2010113609A1 (fr) 2009-04-03 2010-03-10 Procédé de production d'un feuillet, procédé de production d'un matériau apparenté à un article absorbant, et dispositif de production du feuillet

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CN102427787A (zh) 2012-04-25
EP2415430A4 (fr) 2014-01-15
KR20110139760A (ko) 2011-12-29
JP2010240112A (ja) 2010-10-28
KR101691681B1 (ko) 2016-12-30
EP2415430A1 (fr) 2012-02-08
BRPI1006503A2 (pt) 2018-05-29
WO2010113609A1 (fr) 2010-10-07
US20120086145A1 (en) 2012-04-12
JP5469902B2 (ja) 2014-04-16

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