US6355222B2 - Manufacture of hydrogen bromide gas - Google Patents

Manufacture of hydrogen bromide gas Download PDF

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Publication number
US6355222B2
US6355222B2 US09/210,372 US21037298A US6355222B2 US 6355222 B2 US6355222 B2 US 6355222B2 US 21037298 A US21037298 A US 21037298A US 6355222 B2 US6355222 B2 US 6355222B2
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Prior art keywords
bromine
chamber
hydrogen
bar absolute
process according
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Expired - Fee Related
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US09/210,372
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US20010041161A1 (en
Inventor
Sylvie Frances
Gilles Drivon
Philippe Leduc
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Arkema France SA
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Elf Atochem SA
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Assigned to ELF ATOCHEM S.A. reassignment ELF ATOCHEM S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FRANCES, SYLVIE, DRIVON, GILLES, LEDUC, PHILIPPE
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/093—Hydrogen bromide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/005—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor carried out at high temperatures, e.g. by pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00157—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0227—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B01J2219/0286—Steel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46—Details, e.g. noise reduction means
    • F23D14/62—Mixing devices; Mixing tubes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23M—CASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
    • F23M2900/00—Special features of, or arrangements for combustion chambers
    • F23M2900/05004—Special materials for walls or lining

Definitions

  • the invention relates to a device for the manufacture of hydrogen bromide by direct combustion of bromine in hydrogen.
  • U.S. Pat. No. 2,070,263 describes a method for obtaining aqueous solutions of hydrobromic acid which consists, in a first step, in passing hydrogen through liquid bromine maintained at a temperature of between 37° C. an° 42° C. in order to form a mixture of bromine and hydrogen gas which is burnt at a temperature of between 600° C. and 850° C.
  • liquid bromine maintained at a temperature of between 37° C. an° 42° C. in order to form a mixture of bromine and hydrogen gas which is burnt at a temperature of between 600° C. and 850° C.
  • Patent FR 2,365,516 proposes a process which improves the stability of the flame resulting from the combustion of bromine in hydrogen by establishing a helical stream of bromine in a cylindrical chamber, then injecting the hydrogen radially towards the outside in the helical stream of bromine and continuously supplying a flame close to the chamber with the helical stream of bromine and hydrogen.
  • the complexity of the burner entails a lack of flexibility.
  • several burners are arranged side by side in the same chamber. In such an arrangement, it cannot be avoided that the flame from different burners mounted in parallel will interfere with each other, and furthermore this arrangement is unacceptable with regard to obtaining good distribution of the reactants.
  • This configuration inevitably leads to a lowering in the degree of conversion of the bromine, complicates the control of the cooling of the HBr formed and increases the risks of explosion.
  • Patent application DE 2,738,744 describes a device for the combustion of bromine in hydrogen which comprises a combustion chamber, characterized by its tube shape and a transverse section which gradually largens from the orifice of the conduit of the said combustion chamber.
  • This device has the drawback of being relatively inflexible at low speed, of being sensitive to flame return and of giving mediocre-quality HBr gas (2000 ppm by weight of bromine).
  • any mixture consisting of a gas which is inert towards the reactants of the reaction for the formation of HBr and an amount of oxygen which is sufficient to lead to a combustible mixture with hydrogen may be used as oxidant.
  • Nitrogen may be used as inert gas.
  • the oxidant is preferably air.
  • the oxidant may be partially or totally replaced. In the case where a certain amount of oxidant is maintained, this amount may vary within a wide range which depends in particular on the organic impurities present in the supply stream of bromine gas, the size characteristics of the apparatus and the use downstream of the HBr produced.
  • Hydrogen and the oxidant are introduced in gaseous form into the chamber.
  • the oxidant is replaced by bromine gas introduced at a temperature above its boiling point and preferably between 100° C. and 160° C.
  • the hydrogen will advantageously be preheated to a temperature not above 150° C. and preferably between 60° C. and 100° C.
  • the pressure in the chamber is at least equal to 1 bar absolute, preferably greater than 1.3 bar absolute and even more preferably between 1.8 bar absolute and 10 bar absolute.
  • the H 2 /Br 2 molar ratio is greater than 1.
  • the H 2 /Br 2 molar ratio is greater than 1 and less than 1.5.
  • the reaction of bromine and hydrogen is accompanied by a release of heat (12.3 kcalories per mole of HBr gas formed) which raises the temperature of the combustion flame to more than 1600° under adiabatic conditions.
  • the cooling of the hydrogen bromide formed starts from the moment of its formation in the combustion zone as a function of the excess hydrogen and of the cooling of the combustion chamber, and then continues in a cooling zone designed such that the temperature falls gradually in these zones and is in the region of 600° C. at the outlet of the cooling zone and is preferably between 40° C. and 125° C.
  • This outlet temperature can be adapted as a function of the constraints of the downstream devices.
  • the pressure prevailing in the said cooling zone is preferably between 1.3 bar absolute and 10 bar absolute.
  • FIG. 1 is a side view of an apparatus which includes a burner and reaction chamber for manufacturing hydrogen bromide;
  • FIG. 2 is a side view of a burner in accordance with the present invention.
  • FIGS. 3A and 3B are side views of the apparatus of FIG. 1 which includes a finishing stage.
  • the device according to the present invention as represented diagrammatically in FIG. 1, successively comprises:
  • a burner ( 1 ) comprising means ( 2 ) for introducing the bromine and/or the oxidant, means ( 3 ) for introducing the hydrogen and means for mixing the bromine and /or oxidant and hydrogen to place these reactants in contact,
  • the burner ( 1 ) consists of a vertical chamber (E) inside which is placed a vertical cylindrical tube, as represented in FIG. 2, including:
  • Part (B) is provided with orifices (F) that are preferably inclined.
  • Parts (A) and (B) are joined by a spherical segment (S).
  • Reaction chamber (E) consists of 4 successive zones:
  • L 1 , L 2 , D 1 , D 2 , D 3 , D 4 , D 5 , h 1 , h 2 , h 3 , h 4 and the number of orifices (F) determine the flexibility of the device. A person skilled in the art will adapt these values to the required capacity and to the exploitation constraints of the plant.
  • the bromine and/or the oxidant are introduced via ( 2 ) directly into the vertical tube at the upper part of the cylindrical part (A) and the hydrogen is introduced via ( 3 ), preferably perpendicular to the vertical tube and inside the volume consisting of the chamber (E) and the said vertical tube.
  • the chamber and the vertical tube may consist of refractory materials with are inert towards reactants, such a silica or quartz, or of a metal having a resistance which is suited to the quality of the reactants, such as nickel.
  • the base of the burner emerges in the reaction chamber ( 4 ), which is advantageously cooled.
  • This reaction chamber is fitted with means ( 5 ) for starting the flame.
  • the flame may be started by a lighting member which provides the energy required for lighting up.
  • This may be a small auxiliary burner, via an inspection port (not represented in FIG. 1 ).
  • this reaction chamber may consist of graphite 19 impregnated with phenolic resins, fluoro polymers or carbon with an outer steel jacket 20 in which a heat-exchange fluid may circulate via lines 21 and 22 .
  • the impregnated graphite should have thermal, mechanical and chemical resistance characteristics that are suited to the process.
  • this reaction chamber can also comprise an inner sleeve 26 along all or part of the height of the said chamber.
  • This sleeve can be made of quartz, of ceramic or of any other material which allows reflection of the radioactive emissions of the flame and which helps to confine the heat within the combustion chamber.
  • the cooling zone or cooling chamber ( 6 ) consists of a steel jacket in which are piled blocks of impregnated graphite ( 28 ).
  • these blocks ( 20 ) consist of axial channels in which the combustion gases circulate, and radial channels in which water, a cold brine or a heat-exchange fluid from inlet ( 30 ) circulates and exits via outlet ( 31 ).
  • the number of blocks to be used may vary within a wide range. It is calculated such that the temperature of the combustion gases arriving into the lower pot ( 8 ) is not more than 125° C. and is preferably between 40° C. and 60° C.
  • the means ( 8 ) for evacuating the combustion gases (HBr) consist of a lower pot, in particular one made of sintered PVDF with an outer steel jacket.
  • This pot is equipped with a side outlet ( 7 ) for the gas produced and safety members such as rupture disc ( 9 ) which is connected to a screen ( 10 ).
  • the combustion chamber is advantageously equipped with one or more inspection ports located closest to the flame.
  • These inspection ports may in particular allow visual or instrument control of the flame and the introduction of the lighting means.
  • This process in accordance with the invention may also be carried out using a specific device as represented diagrammatically in FIGS. 3A and 3B.
  • a finishing stage ( 11 ) which may be equipped with a by-pass circuit ( 12 ) (FIG. 3B) has been inserted within the cooling zone ( 6 ).
  • the finishing stage consists of a vitrified steel jacket in which there is a catalytic charge such as active charcoal.
  • the temperature of the gases entering this finishing stage may vary within a wide range. It is not more than 300° C. and preferably between 200° C. and 300° C.
  • This process in accordance with the invention is of great flexibility while at the same time ensuring good operational safety and good operability.
  • the entry flow rates of the reactants may be varied within a wide range. This is allowed since the burner may be changed easily.
  • This process also has the advantage of leading to a very pure hydrogen bromide, having a weight content of bromine of not more than 100 ppm, at a sufficient pressure, thereby allowing it to be used either as a reactant in organic synthesis or to prepare pure HBr solutions without using expensive recompression and purification means.
  • a generator as represented in FIG. 1 comprising:
  • a burner as represented diagrammatically in FIG. 2, consisting of a vertical quartz mixing chamber (E) inside which is a verticla tube (A and B),
  • This combustion chamber is cooled with water to an inlet temperature equal to 28° C.
  • a cooling zone or cooling chamber ( 6 ) comprising a zone fitted with 5 blocks of graphite impregnated with Graphylor® type HB, sold by the company Carbone Lorrainem, and cooled by circulation of water,
  • the generator is equipped with two inspection ports, arranged on the walls of the combustion chamber in the bottom part of the burner.
  • the size of the items of equipment mentioned above have been determined in order to produce an amount of pure hydrogen bromide ranging from 1.4 to 9.6 tons per day.
  • the flame is started using a device ( 5 ) consisting of an H 2 /air pilot burner which projects a flame via one of the 2 inspection ports.
  • the appearance of the flame may be observed via the inspection port.
  • An adapted cell on one of the inspection ports makes it possible to reveal precisely the proportions of the combustion reactants (color of the flame) and thereby allows the flow rates to be adjusted.
  • the generator operates continuously, producing 400 kg/H of HBr gas including at least 399.9kg of pure HBr leaving at ( 7 ) at 40° C. and at a pressure of 1.8 bar absolute.
  • the hydrogen bromide obtained is colorless and contains on average less than 100 mg of bromine per kg of HBr.
  • the chamber ( 4 ) referred to herein as a combustion chamber and a reaction chamber is a chamber in which the so-called combustion includes the H 2 /Br 2 reaction which results in the production of heat in the absence of an oxidant.
  • the burner ( 1 ) operates as a mixing chamber in which the chamber (E) receives bromine from the line ( 2 ) via a tubular member (A), which bromine is dispensed via slits (F) into an annular space (J) where it mixes with H 2 from line ( 3 ). This mixture is then dispensed out of the chamber (E) by the converging/diverging nozzle (K) formed by components (G), (H) and (I) into the reaction chamber ( 4 ).

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Pre-Mixing And Non-Premixing Gas Burner (AREA)
  • Gas Burners (AREA)
US09/210,372 1997-12-12 1998-12-14 Manufacture of hydrogen bromide gas Expired - Fee Related US6355222B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR97/15765 1997-12-12
FR9715765A FR2772368B1 (fr) 1997-12-12 1997-12-12 Procede de production de bromure d'hydrogene gazeux pur et dispositif pour sa mise en oeuvre

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US20010041161A1 US20010041161A1 (en) 2001-11-15
US6355222B2 true US6355222B2 (en) 2002-03-12

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US (1) US6355222B2 (fr)
EP (1) EP0922668B9 (fr)
JP (1) JP2977825B2 (fr)
KR (1) KR100288897B1 (fr)
CN (1) CN1229766A (fr)
AT (1) ATE240260T1 (fr)
CA (1) CA2254318C (fr)
DE (1) DE69814571T2 (fr)
DK (1) DK0922668T3 (fr)
ES (1) ES2200291T3 (fr)
FR (1) FR2772368B1 (fr)
JO (1) JO2063B1 (fr)
NO (1) NO985817L (fr)
PT (1) PT922668E (fr)
RU (1) RU2157789C2 (fr)
UA (1) UA60306C2 (fr)

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BR112018005896B1 (pt) * 2015-10-01 2022-02-08 Sgl Carbon Se Dispositivo de combustão para a produção de halogenetos de hidrogênio
CN110523351A (zh) * 2019-09-18 2019-12-03 苏州金宏气体股份有限公司 一种溴化氢的合成装置及合成方法
CN113716526B (zh) * 2021-10-11 2022-11-15 福建福豆新材料有限公司 一种生产高纯电子级溴化氢用燃烧反应器及其设备

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1380084A (en) * 1919-12-22 1921-05-31 Tschudi Aegidius Process and apparatus for the manufacture of hydrobromic acid from bromin and hydrogen
GB173300A (en) * 1919-11-19 1921-12-23 Basf Ag Improvements in the manufacture and production of hydrochloric acid
DE428225C (de) * 1923-01-11 1926-04-28 J D Riedel Akt Ges Verfahren zur Darstellung von Bromwasserstoff
US1905432A (en) * 1928-06-02 1933-04-25 Rohm & Haas Ag Manufacture of hydrogen chloride or hydrogen bromide or their corresponding acid solutions
US2070263A (en) 1933-10-30 1937-02-09 Dow Chemical Co Method of making hydrobromic acid
US2366670A (en) * 1941-11-10 1945-01-02 Hooker Electrochemical Co Method for synthesizing hydrogen chloride
US3119669A (en) * 1961-03-13 1964-01-28 Du Pont Chemical process control
US3925540A (en) * 1970-06-10 1975-12-09 David G Hatherly Production of chlorine dioxide
US3988427A (en) * 1974-05-22 1976-10-26 Ethyl Corporation Flame reaction process for producing hydrogen bromide
US3998926A (en) * 1974-03-21 1976-12-21 Matthey Rustenburg Refiners (Pty) Ltd. Treatment of material with hydrogen chloride
DE2738744A1 (de) * 1977-08-27 1979-03-08 Dynamit Nobel Ag Vorrichtung zur durchfuehrung von flammenreaktionen
US4960378A (en) 1987-09-26 1990-10-02 Ruhrgas Aktiengesellschaft Gas burner
EP0497712A1 (fr) * 1991-01-14 1992-08-05 Le Carbone Lorraine Procédé de dépollution d'effluents gazeux riches en oxygene et contenant des dérives chlores
JPH0632601A (ja) * 1992-07-17 1994-02-08 Asahi Denka Kogyo Kk 臭化水素の精製法
WO1996008442A1 (fr) 1994-09-14 1996-03-21 Teisan Kabushiki Kaisha Appareil et methode de preparation de bromure d'hydrogene a haut degre de purete
US6036936A (en) * 1996-06-28 2000-03-14 Elf Atochem, S.A. Process for the production of hydrogen bromide gas and device for its implementation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2365516A1 (fr) * 1976-09-24 1978-04-21 Ethyl Corp Procede de production de gaz bromhydrique par reaction a la flamme

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB173300A (en) * 1919-11-19 1921-12-23 Basf Ag Improvements in the manufacture and production of hydrochloric acid
US1380084A (en) * 1919-12-22 1921-05-31 Tschudi Aegidius Process and apparatus for the manufacture of hydrobromic acid from bromin and hydrogen
DE428225C (de) * 1923-01-11 1926-04-28 J D Riedel Akt Ges Verfahren zur Darstellung von Bromwasserstoff
US1905432A (en) * 1928-06-02 1933-04-25 Rohm & Haas Ag Manufacture of hydrogen chloride or hydrogen bromide or their corresponding acid solutions
US2070263A (en) 1933-10-30 1937-02-09 Dow Chemical Co Method of making hydrobromic acid
US2366670A (en) * 1941-11-10 1945-01-02 Hooker Electrochemical Co Method for synthesizing hydrogen chloride
US3119669A (en) * 1961-03-13 1964-01-28 Du Pont Chemical process control
US3925540A (en) * 1970-06-10 1975-12-09 David G Hatherly Production of chlorine dioxide
US3998926A (en) * 1974-03-21 1976-12-21 Matthey Rustenburg Refiners (Pty) Ltd. Treatment of material with hydrogen chloride
US3988427A (en) * 1974-05-22 1976-10-26 Ethyl Corporation Flame reaction process for producing hydrogen bromide
DE2738744A1 (de) * 1977-08-27 1979-03-08 Dynamit Nobel Ag Vorrichtung zur durchfuehrung von flammenreaktionen
US4960378A (en) 1987-09-26 1990-10-02 Ruhrgas Aktiengesellschaft Gas burner
EP0497712A1 (fr) * 1991-01-14 1992-08-05 Le Carbone Lorraine Procédé de dépollution d'effluents gazeux riches en oxygene et contenant des dérives chlores
JPH0632601A (ja) * 1992-07-17 1994-02-08 Asahi Denka Kogyo Kk 臭化水素の精製法
WO1996008442A1 (fr) 1994-09-14 1996-03-21 Teisan Kabushiki Kaisha Appareil et methode de preparation de bromure d'hydrogene a haut degre de purete
US5685169A (en) 1994-09-14 1997-11-11 Teisan Kabushiki Kaisha Method and apparatus for preparing high purity hydrogen bromide
US6036936A (en) * 1996-06-28 2000-03-14 Elf Atochem, S.A. Process for the production of hydrogen bromide gas and device for its implementation

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
FR 2365516-English Abstract.
FR 2365516—English Abstract.
FR 2750412-English Abstract.
FR 2750412—English Abstract.
Translation for DE 2,738,744, Mar. 1979. *
Translation for DE 428,225, Apr. 1926.*

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Publication number Publication date
US20010041161A1 (en) 2001-11-15
ATE240260T1 (de) 2003-05-15
DK0922668T3 (da) 2003-09-15
JO2063B1 (en) 2000-05-21
JP2977825B2 (ja) 1999-11-15
NO985817D0 (no) 1998-12-11
UA60306C2 (uk) 2003-10-15
CA2254318C (fr) 2002-02-19
PT922668E (pt) 2003-08-29
DE69814571T2 (de) 2004-03-18
RU2157789C2 (ru) 2000-10-20
KR100288897B1 (ko) 2001-05-02
CA2254318A1 (fr) 1999-06-12
JPH11236201A (ja) 1999-08-31
NO985817L (no) 1999-06-14
EP0922668B1 (fr) 2003-05-14
EP0922668B9 (fr) 2004-09-08
DE69814571D1 (de) 2003-06-18
CN1229766A (zh) 1999-09-29
FR2772368B1 (fr) 2002-06-14
EP0922668A1 (fr) 1999-06-16
FR2772368A1 (fr) 1999-06-18
ES2200291T3 (es) 2004-03-01
KR19990063016A (ko) 1999-07-26

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