US5589181A - Insect repellent - Google Patents

Insect repellent Download PDF

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Publication number
US5589181A
US5589181A US08/290,991 US29099194A US5589181A US 5589181 A US5589181 A US 5589181A US 29099194 A US29099194 A US 29099194A US 5589181 A US5589181 A US 5589181A
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United States
Prior art keywords
weight
oil
fatty
fatty acid
insect repellant
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Expired - Fee Related
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US08/290,991
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English (en)
Inventor
Franz Bencsits
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Perycut-Chemie AG
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Perycut-Chemie AG
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Assigned to BENCSITS, FRANZ, PERYCUT-CHEMIE AG reassignment BENCSITS, FRANZ ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BENCSITS, FRANZ
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00—Drug, bio-affecting and body treating compositions
    • Y10S424/10—Insect repellent

Definitions

  • the present invention relates to an insect repellent against flying, biting and sucking insects.
  • Repellents are chemical substances having a repellent effect on insects. Their use in human and veterinary hygiene is of great practical importance, where they protect man and beast against attack by bloodsucking, biting or otherwise annoying insects. It is required that repellents which are directly applied onto the skin are well tolerated by the skin, non-toxic, perspiration-resistant and light-fast and perfect in cosmetic respect. Moreover, the protection of the treated skin areas is to last for the longest possible period of time and the spectrum of activity of the repellents is to be as broad as possible, i.e. they should act against the largest possible number of harmful and annoying insects.
  • the present invention is based on the object of providing an effective repellent for application onto the skin on the basis of natural and nature-identical raw materials with the least toxicological risk, which also develops a high effectiveness over a long period of time.
  • this object is attained by a repellent which contains at least one fatty acid alkyl ester having 1 to 4 carbon atoms in the alkyl group and at least one natural, nature-identical or synthetic fatty alcohol as the active substance and at least one natural or nature-identical vegetable or animal fatty oil as the carrier.
  • the present invention relates to the use of the repellent according to the invention for repelling flying, biting and sucking insects in man and beast.
  • fatty acid alkyl esters having 1 to 4 carbon atoms in the alkyl group which are used in the insect repellent according to the invention are methyl, ethyl or butyl esters of fatty acids from natural or nature-identical vegetal or animal fatty oils from the group consisting of rape-seed oil, sunflower oil, peanut oil, peanut butter, soy oil, safflower seed oil, cuphea oil, coconut oil, palm kernel oil, palm oil and fish oil.
  • Fatty acids having 5 to 19 carbon atoms are preferred.
  • a natural, nature-identical or synthetic fatty alcohol having preferably 5 to 18 carbon atoms, being saturated or having 1 to 3 unsaturated bonds per molecule is admixed to the used fatty acid alkyl ester as a further active substance according to the invention.
  • the natural fatty alcohols are e.g. obtained from vegetal and/or animal oils and/or the fatty acids and/or fatty acid alkyl esters, which can be obtained therefrom.
  • the nature-identical and/or synthetic fatty alcohols can e.g. be obtained from paraffin and/or ethene.
  • a preferred active substance combination of the repellent according to the invention contains 1 to 99% by weight of the fatty acid alkyl ester and 99 to 1% by weight of the fatty alcohol.
  • the repellent according to the invention contains 70 to 98% by weight of fatty acid alkyl ester and 30 to 2% by weight of fatty alcohol, 30 to 2% by weight of fatty acid alkyl ester and 70 to 98% by weight of fatty alcohol, 60 to 97% by weight of fatty acid alkyl ester and 40 to 3% by weight of fatty alcohol or 40 to 3% by weight of fatty acid alkyl ester and 60 to 97% by weight of fatty alcohol.
  • At least one carrier from the group consisting of natural or nature-identical vegetal or animal fatty oils is added to the repellent according to the invention.
  • the natural or nature-identical vegetal or animal fatty oils are rape-seed oil, sunflower oil, peanut oil, peanut butter, soy oil, safflower seed oil, cuphea oil, coconut oil, palm kernel oil, palm oil and fish oil.
  • At least one free fatty acid may be contained in the repellent according to the invention as an additional carrier.
  • These are e.g. obtained by means of the hydrolytic decomposition of natural or nature-identical vegetal and/or animal oils and have preferably 5 to 19 carbon atoms in the chain.
  • valeric acid caproic acid, oenanthic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid and nonadecanoic acid and isovaleric acid, palmitoleic acid, oleic acid, sorbic acid, linolic acid, linolenic acid and elaeostearic acid.
  • An insect repellent containing 75 to 98% by weight of the fatty acid alkyl ester and 2 to 25% by weight of the fatty oil is also preferred.
  • an insect repellent is preferred, which contains 8 to 70% by weight of the fatty acid alkyl ester, 5 to 90% by weight of the fatty alcohol and 2 to 25% by weight of the fatty oil
  • a further preferred insect repellent contains 75 to 98% by weight of the fatty acid alkyl ester and 25 to 2% by weight of the free fatty acid or 1 to 97% by weight of the fatty acid alkyl ester, 1 to 97% by weight of the fatty alcohol and 2 to 25% by weight of the free fatty acid.
  • a preferred insect repellent comprises 1 to 96% by weight of the fatty acid alkyl ester, 2 to 25% by weight of the fatty oil and 2 to 25% by weight of the free fatty acid or 1 to 95% by weight of the fatty acid alkyl ester, 1 to 95% by weight of the fatty alcohol and respectively 2 to 25% by weight of the fatty oil or the free fatty acid.
  • Rape seed oil is preferred as natural vegetal oil, which may e.g. be contained in an amount of 20% to 80% by weight of a first runnings coconut methyl ester in the insect repellent.
  • the fatty alcohols, fatty acid alkyl esters and fatty acids may be obtained by means of a simple chemical reaction from natural or nature-identical, toxicologically harmless raw materials, e.g. by means of hydrolysis, reesterification, hydrogenation, high-pressure hydrogenation, hardening and/or dehydration as known in the prior art.
  • the fatty oils used according to the invention may also be obtained by means of conventional processes from oil-supplying materials such as plant seeds and animal fats.
  • the insect repellent according to the invention contains one or several substances prepared from completely harmless, synthetic (nature-identical) basic substances or directly from natural basic substances, and, consequently, has the least toxicological and irritative risk with an excellent repelling effect. It is preferably used by applying it onto the skin of man and beast to repel flying, biting and sucking insects.
  • insect repellents (I) and (II) were tested with two different persons.
  • the forearm of a test subject was treated with the corresponding test substances (I) or (II) on an area of approx. 250 cm 2 .
  • the amount of 2 ml of the corresponding test substance was distributed uniformly.
  • the treated forearm area was sealed at both ends with a mosquito-tight adhesive tape and a short plastic hose.
  • the untreated hand was covered by a thick glove and, thus, served at the same time as a control for the biting activity of the test animals.
  • the forearm and the hand were held into the mosquito cage for the test every hour, and, for 10 minutes, the number of mosquitos was recorded, which
  • Test substance (I) (Test subject (1))
  • Test substance (II) (Test subject (2))
  • the parameters a) and b) are estimated values since an exact determination is not possible.
  • the effectiveness of a substances results above all from the ratio of the mosquitoes, which are ready to bite and remain seated on the glove.
  • the number of the biting mosquitoes is the decisive factor for the duration of the effect and, thus, in the tropics, indirectly also for the risk of infection.
  • the tested substances ensure protection of more than 3 hours.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US08/290,991 1992-02-27 1993-02-24 Insect repellent Expired - Fee Related US5589181A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4206090A DE4206090C2 (de) 1992-02-27 1992-02-27 Insektenabwehrmittel
DE4206090.7 1992-02-27
PCT/EP1993/000427 WO1993016594A1 (de) 1992-02-27 1993-02-24 Insektenabwehrmittel

Publications (1)

Publication Number Publication Date
US5589181A true US5589181A (en) 1996-12-31

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US08/290,991 Expired - Fee Related US5589181A (en) 1992-02-27 1993-02-24 Insect repellent

Country Status (14)

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US (1) US5589181A (el)
EP (1) EP0627881B1 (el)
AT (1) ATE156659T1 (el)
CA (1) CA2130450C (el)
CZ (1) CZ285166B6 (el)
DE (2) DE4206090C2 (el)
DK (1) DK0627881T3 (el)
ES (1) ES2106324T3 (el)
GR (1) GR3024481T3 (el)
HU (1) HU214544B (el)
PL (1) PL172451B1 (el)
RU (1) RU2113791C1 (el)
SK (1) SK281182B6 (el)
WO (1) WO1993016594A1 (el)

Cited By (31)

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US5801196A (en) * 1996-03-15 1998-09-01 Agraquest, Inc. Methods of using emu oil and active fractions thereof as an insect repellent
WO1998057542A1 (en) * 1997-06-16 1998-12-23 Agraquest, Inc. Compositions comprising ratite oil or active fractions thereof and methods of using these compositions as insect repellents
US6051538A (en) * 1999-01-26 2000-04-18 The Procter & Gamble Company Pour point depression of heavy cut methyl esters via alkyl methacrylate copolymer
EP1018873A1 (en) * 1997-06-30 2000-07-19 William G. Reifenrath Natural insect and arthropod repellent
US6147091A (en) * 1996-05-06 2000-11-14 Bayer Aktiengesellschaft Arthropod repellant
US6300324B1 (en) * 1999-01-04 2001-10-09 Scott E. Partelow Composition for repelling ticks
US6538027B2 (en) 1996-03-15 2003-03-25 Agraquest, Inc. Compositions comprising ratite oil or active fractions thereof and methods of using these composition as insect repellents
US6555143B2 (en) 2001-02-28 2003-04-29 Johnson & Johnson Consumer Products, Inc. Legume products
US6750229B2 (en) 1998-07-06 2004-06-15 Johnson & Johnson Consumer Companies, Inc. Methods for treating skin pigmentation
US20040191290A1 (en) * 2003-03-28 2004-09-30 Redline, Inc. Solid pest control system
US20040265349A1 (en) * 2001-07-30 2004-12-30 Franz Bencsits Insect repellent
US20060127434A1 (en) * 2004-12-14 2006-06-15 Jones Allen L Jr Pest-combating compositions comprising soy methyl ester
US20060171978A1 (en) * 2005-01-28 2006-08-03 Lopes John A Disinfecting and antimicrobial compositions
US20070129253A1 (en) * 2005-12-02 2007-06-07 Alefesh Hailu Fatty acid ester blends as carriers for pesticide active ingredients
US20080069785A1 (en) * 2004-12-14 2008-03-20 Jones Allen L Pest-control compositions, and methods and products utilizing same
EP1916988A2 (en) * 2005-08-03 2008-05-07 International Flora Technologies, Ltd. Cosmetic and topical compositions comprising cuphea oil and derivatives thereof
US20080153708A1 (en) * 2006-12-24 2008-06-26 Jones Allen L Fatty acids and fatty acid esters as herbicidal agents and carriers
US20080256844A1 (en) * 2007-04-21 2008-10-23 Allen Jones Biodiesel candle
US20080293809A1 (en) * 2007-05-21 2008-11-27 Redline, Inc. Pest control formulation
US20100227010A1 (en) * 2009-02-02 2010-09-09 Ecoblend, Llc Pesticidal compositions and methods of use thereof
US7879823B2 (en) 1999-11-05 2011-02-01 Johnson & Johnson Consumer Companies Topical anti-cancer compositions and methods of use thereof
US7897144B2 (en) 2001-02-28 2011-03-01 Johnson & Johnson Comsumer Companies, Inc. Compositions containing legume products
US20110086890A1 (en) * 2009-10-08 2011-04-14 Redline Products, Inc. Liquid pest control formulation
US7985404B1 (en) 1999-07-27 2011-07-26 Johnson & Johnson Consumer Companies, Inc. Reducing hair growth, hair follicle and hair shaft size and hair pigmentation
US8039026B1 (en) 1997-07-28 2011-10-18 Johnson & Johnson Consumer Companies, Inc Methods for treating skin pigmentation
US8093293B2 (en) 1998-07-06 2012-01-10 Johnson & Johnson Consumer Companies, Inc. Methods for treating skin conditions
US8106094B2 (en) 1998-07-06 2012-01-31 Johnson & Johnson Consumer Companies, Inc. Compositions and methods for treating skin conditions
US20120136056A1 (en) * 2009-04-17 2012-05-31 Stratacor, Inc. Pesticidal Compositions For Insects And Arthropods
WO2012142452A3 (en) * 2011-04-13 2013-01-31 Biosafe Technologies, Inc. Cleaning, insecticide, insect repellant, glue solvent and anti-irritation composition
US8431550B2 (en) 2000-10-27 2013-04-30 Johnson & Johnson Consumer Companies, Inc. Topical anti-cancer compositions and methods of use thereof
US8889731B2 (en) 2007-03-28 2014-11-18 Contech Enterprises Inc. Compounds, compositions and methods for repelling blood-feeding arthropods and deterring their landing and feeding

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DE19729852A1 (de) * 1997-07-11 1999-09-09 Feil Mückenabweisendes hautverträgliches Mittel
CA2225352C (en) * 1998-01-30 2003-10-21 Nam Fong Han Vegetable derived petroleum jelly replacement
AU2001254785A1 (en) * 2000-04-06 2001-10-23 Filo Holding S.A. Bee and/or wasp repellent
ATE425760T1 (de) 2003-05-22 2009-04-15 Bioniche Life Sciences Inc Insektenabwehrmittel
DE102006007544A1 (de) * 2006-02-16 2007-08-30 Lanxess Deutschland Gmbh Wasserfreie Öl-Formulierung zur Arthropoden- und Plathelminthen-Abwehr
EP2509632B1 (en) 2009-12-10 2023-05-03 Guerry L. Grune Glycerine based jelly compositions
US9913787B2 (en) 2015-05-18 2018-03-13 Guerry L. Grune Glycerine based jelly compositions

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DK0627881T3 (da) 1998-02-02
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RU2113791C1 (ru) 1998-06-27
CA2130450A1 (en) 1993-09-02
CA2130450C (en) 2000-10-03
SK101094A3 (en) 1995-01-12
DE59307124D1 (de) 1997-09-18
HUT68118A (en) 1995-05-29
WO1993016594A1 (de) 1993-09-02
DE4206090C2 (de) 1998-02-05
RU94040710A (ru) 1996-08-20
DE4206090A1 (de) 1993-09-02
CZ285166B6 (cs) 1999-05-12
ES2106324T3 (es) 1997-11-01
PL172451B1 (pl) 1997-09-30
EP0627881B1 (de) 1997-08-13
HU214544B (hu) 1998-03-30
HU9402456D0 (en) 1994-11-28
SK281182B6 (sk) 2001-01-18
GR3024481T3 (en) 1997-11-28
ATE156659T1 (de) 1997-08-15

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