US5085708A - Lignosulfonates, oxycarboxylates, polycarboxylates, and polyoxalklene, alkylaryl and alkyl ethers admixtures for ultra-dry mix concrete - Google Patents

Lignosulfonates, oxycarboxylates, polycarboxylates, and polyoxalklene, alkylaryl and alkyl ethers admixtures for ultra-dry mix concrete Download PDF

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Publication number
US5085708A
US5085708A US07/645,386 US64538691A US5085708A US 5085708 A US5085708 A US 5085708A US 64538691 A US64538691 A US 64538691A US 5085708 A US5085708 A US 5085708A
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US
United States
Prior art keywords
cement
ultra
parts
weight
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US07/645,386
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English (en)
Inventor
Yoshitaka Moriya
Hiroshi Nomachi
Makoto Takada
Yukihide Takatsu
Kenichi Umezawa
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MBT HOLDLING AG
Original Assignee
Sandoz AG
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Publication of US5085708A publication Critical patent/US5085708A/en
Assigned to MBT HOLDLING AG reassignment MBT HOLDLING AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NOVARTIS AG SUCCESSOR IN TITLE TO SANDOZ LTD.
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034—Physico-chemical characteristics of the mixtures
    • C04B2111/00068—Mortar or concrete mixtures with an unusual water/cement ratio
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S106/00—Compositions: coating or plastic
    • Y10S106/01—Fly ash

Definitions

  • This invention concerns an admixture for ultra-dry-mix concrete.
  • Ultra-dry-mix concrete is a concrete with extremely low unit water content of 80 to 100 kg/m 3 , which is dry and crumbly, will not flow from itself and is a concrete on which slump cannot be measured, so that it is called no-slump concrete.
  • the RCD (Roller Compacted Dam) method developed in recent years for construction of dam bodies uses ultra-dry-mix concrete which is consolidated by vibratory roller to a given density. The results obtained are shortening of construction time and savings in construction cost.
  • cement dispersing agents which are capable of improving workability and reducing unit water content.
  • cement dispersing agents include those mainly consisting of lignosulfonates.
  • lignosulfonates are manufactured industrially from waste sulfite liquor as the raw material and are commonly known as cement dispersing agents. Normally, one of the sodium, potassium, calcium, ammonium, magnesium and amine salts is used.
  • oxycarboxylates specifically, sodium, potassium, calcium, magnesium, ammonium and amine salts of gluconic acid, diketogluconic acid and pentaketogluconic acid may be cited as examples, these products being manufactured by an electrolytic oxidation method, chemical oxidation method or a fermentation method using oxidizing bacteria, from sugars or waste molasses as the raw material.
  • the previously-mentioned polycarboxylates are cement dispersing agents with soluble salts of copolymers of alpha and beta unsaturated carboxylic acids and olefins as the effective ingredients, homopolymers of esters of polyethylene glycol monoaryl ethers and maleic acid as monomers and copolymers derived from monomers possible to copolymerize with these, homopolymers of polyalkylene glycol mono(meth)acrylic acid ester or (meth)acrylic acid and copolymers derived from monomers possible to copolymerize with these monomers.
  • the nonionic surface active agents (B) used for the ultra-dry-mix concrete admixture of this invention are selected from the group of polyoxyalkylene alkylaryl ethers and polyoxyalkylene alkyl ethers, and these are general purpose nonionic surface-active agents manufactured in chemical industry.
  • These nonionic surfactants (B) should have a sufficient permeability for the inorganic hydrophilic substances contained in concrete and it has been shown that surfactants with a hydrophilic-lipophilic balance (HLB-value) of 8-17, preferably 10-14 have the necessary permeability.
  • HLB-value hydrophilic-lipophilic balance
  • Surfactants with a HLB-value higher than 17 have a low adsorbability, caused by their high molecular weight, and are also not suitable.
  • the nonionic surfactants of the above mentioned classes of compounds with a HLB-value from 8 to 17 are polyoxyethylene ethers with a number of ethylene oxide units from 5 to 15. Those with a number of 8 to 10 ethylene oxide units are especially preferred and have a HLB-value of 10-14 and a permeating power lower than 30 seconds, determined by the canvas disk method at 25° C. with an 0.1 percent aqueous solution.
  • the dosages of the cement dispersing agents (A) are in the range of 0.15 to 0.80 percent, preferably 0.40-0.65 percent by weight of cement or total weight of cement and fly ash in terms of solids in the case of lignosulfonates and oxycarboxylates, in the case of polycarboxylates the dosage is preferably 0.02 to 0.20 percent by weight. If the dosages of the cement dispersing agents (A) are below these ranges, the water-reducing effects will not be improved, while with dosages above these ranges entrained air content will be excessive and the retardation of hardening so prominent that strength gain will be affected.
  • nonionic surface-active agent (B) used in order to obtain favourable results are in case of lignosulfonates 1 to 35 parts by weight of (B), preferably 3 to 20 parts by weight on 100 parts by weight of (A), in case of oxycarboxylates 1 to 100 parts by weight of (B), preferably 5 to 50 parts by weight on 100 parts by weight of (A) and in case of polycarboxylates, 1 to 100 parts by weight, preferably 5 to 50 parts by weight, on 100 parts by weight of (A).
  • amounts of 0.01 to 0.05 percent, preferably 0.03 percent by weight of cement or total weight of cement and fly ash in terms of solids will be needed.
  • the cement dispersing agent (A) and the nonionic surface-active agent (B) may be individually added at the time of mixing concrete, but the two components (A) and (B) may both be mixed with concrete mixing water and added simultaneously.
  • Pozzolith No. 8 main ingredient lignosulfonate, powder, mfd. by Nisso Master Builders Co., Ltd. hereinafter abbreviated as "L"
  • Aquarock PM-006 polycarboxylate, powder, mfd. by Nippon Shokubai Kagaku Kogyo Co., Ltd., hereinafter abbreviated as "P"
  • the VC value is a value expressing the consistency of an ultra-dry-mix concrete, in units of seconds, a smaller value indicating wetness.
  • the air content of concrete after vibratory consolidation was determined by a gravimetric method adapted from the Test Method for Unit Weight of Mortar in Appendix 2 of the said Guideline (Draft), while compressive strengths were tested at ages of 28 days and 91 days in accordance with JIS A 1108, Test Method for Compressive Strength of Concrete, on specimens made in accordance with Method of Making Specimens for Compressive Strength Tests in Appendix 3 of the said Guideline (Draft) and after curing in water of 20°+/-3° C.
  • Cement dispersing agents and nonionic surface-active agents were added by dissolving the required quantities beforehand in the concrete mixing water.
  • the admixture for ultra-dry-mix concrete of this invention is extremely effective in preventing variation of consistency (hardening) and increasing compressive strength of ultra-dry-mix concrete.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
US07/645,386 1988-01-20 1991-01-24 Lignosulfonates, oxycarboxylates, polycarboxylates, and polyoxalklene, alkylaryl and alkyl ethers admixtures for ultra-dry mix concrete Expired - Fee Related US5085708A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP63008387A JPH01188449A (ja) 1988-01-20 1988-01-20 超硬練りコンクリート用の混和剤
JP63-8387 1988-01-20

Related Parent Applications (1)

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US07298458 Continuation 1989-01-18

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US5085708A true US5085708A (en) 1992-02-04

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US07/645,386 Expired - Fee Related US5085708A (en) 1988-01-20 1991-01-24 Lignosulfonates, oxycarboxylates, polycarboxylates, and polyoxalklene, alkylaryl and alkyl ethers admixtures for ultra-dry mix concrete

Country Status (3)

Country Link
US (1) US5085708A (fr)
JP (1) JPH01188449A (fr)
CN (2) CN1031049C (fr)

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994005606A1 (fr) * 1992-09-01 1994-03-17 W.R. Grace & Co.-Conn. Adjuvants reduisant les cavites du ciment hydraulique et procede d'utilisation de ces derniers
US5494516A (en) * 1992-07-22 1996-02-27 Sandoz Ltd. Workable cementitious compositions
US5654352A (en) * 1995-05-16 1997-08-05 Maxflow Environmental Corp. Air-entraining agent and method of producing same
US5681386A (en) * 1991-01-08 1997-10-28 Mbt Holding Ag Method for blending of admixtures in a sprayed concrete mass and agent for application of the method
EP0813506A1 (fr) * 1995-03-06 1997-12-29 W.R. Grace & Co.-Conn. Composition de ciment
US5703174A (en) * 1995-06-21 1997-12-30 W. R. Grace & Co.-Conn. Air controlling superplasticizers
US6267814B1 (en) 1998-08-14 2001-07-31 Mbt Holding Ag Cementitious dry cast mixture
US6290770B1 (en) 1998-08-14 2001-09-18 Mbt Holding Ag Cementitious mixture containing high pozzolan cement replacement and compatabilizing admixtures therefor
WO2002090286A1 (fr) * 2001-05-04 2002-11-14 Alpb - Aditivos E Ligantes Para Betões, Lda. Melanges de plastifiants a base de lignosulfonates
US6569924B2 (en) 1999-12-10 2003-05-27 Mbt Holdingag Solubilized defoamers for cementitious compositions
US20030127026A1 (en) * 2001-11-05 2003-07-10 James Edward Anderson High early-strength cementitious composition
US20030144385A1 (en) * 1999-07-09 2003-07-31 Vickers Thomas M. Oligomeric dispersant
US20030187101A1 (en) * 1999-12-10 2003-10-02 Mbt Holding Ag Solubilized defoamers for cementitious compositions
US20030187100A1 (en) * 1999-12-10 2003-10-02 Mbt Holding Ag Water soluble air controlling agents for cementitious compositions
US20040211342A1 (en) * 2003-04-25 2004-10-28 Mbt Holding Ag Rheology stabilizer for cementitious compositions
EP2096089A1 (fr) * 2008-02-26 2009-09-02 Neil Spindler Additif de béton
US20090235845A1 (en) * 2008-03-19 2009-09-24 Hexion Specialty Chemicals, Inc. Modifier for concrete and cement formulations and methods of preparing the same
US20110030587A1 (en) * 2009-08-07 2011-02-10 Lignotech Usa, Inc. Agglomerated particulate lignosulfonate
WO2011038426A2 (fr) * 2009-09-28 2011-03-31 Pieter Gideo Van Der Merwe Additif pour des compositions à base de ciment et de suppression des poussières
US8088842B2 (en) 1999-12-10 2012-01-03 Construction Research & Technology Gmbh Solubilized defoamers for cementitious compositions
US8404040B2 (en) 2009-07-07 2013-03-26 Momentive Specialty Chemicals Inc. Curing or sealing compositions for concrete and cement formulations and processes for using the same
JP2024056323A (ja) * 2022-10-11 2024-04-23 竹本油脂株式会社 水硬性組成物用添加剤、その製造方法及び水硬性組成物の製造方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2661670B1 (fr) * 1990-05-04 1993-07-30 Francais Ciments Adjuvant pour coulis mortier ou beton de ciment.
US6310143B1 (en) 1998-12-16 2001-10-30 Mbt Holding Ag Derivatized polycarboxylate dispersants
CN1109004C (zh) * 2000-04-04 2003-05-21 北京市建筑材料科学研究院 聚羧酸系引气高效混凝土减水剂
CN1093095C (zh) * 2000-11-07 2002-10-23 复旦大学 羧酸类接枝型高效减水剂及其合成方法
CN102311548B (zh) * 2011-06-09 2013-03-13 江苏博特新材料有限公司 梳形木质素减水剂、其制备方法及应用
CN105731897A (zh) * 2016-02-04 2016-07-06 中国建筑材料科学研究总院 一种利用珊瑚礁石制备粗骨料的方法及其混凝土
CN105541236B (zh) * 2016-02-04 2018-01-26 中国建筑材料科学研究总院 一种海水海砂混凝土

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4102697A (en) * 1975-07-09 1978-07-25 Sumitomo Chemical Company, Limited Fluid plaster composition
JPS5659661A (en) * 1979-10-18 1981-05-23 Yoshitomi Pharmaceutical Concrete admixing agent denaturization prevention
JPS6042260A (ja) * 1983-08-10 1985-03-06 山陽国策パルプ株式会社 モルタル用混和材
JPS60127253A (ja) * 1983-12-12 1985-07-06 花王株式会社 コンクリ−ト混和剤

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4102697A (en) * 1975-07-09 1978-07-25 Sumitomo Chemical Company, Limited Fluid plaster composition
JPS5659661A (en) * 1979-10-18 1981-05-23 Yoshitomi Pharmaceutical Concrete admixing agent denaturization prevention
JPS6042260A (ja) * 1983-08-10 1985-03-06 山陽国策パルプ株式会社 モルタル用混和材
JPS60127253A (ja) * 1983-12-12 1985-07-06 花王株式会社 コンクリ−ト混和剤

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5681386A (en) * 1991-01-08 1997-10-28 Mbt Holding Ag Method for blending of admixtures in a sprayed concrete mass and agent for application of the method
US5494516A (en) * 1992-07-22 1996-02-27 Sandoz Ltd. Workable cementitious compositions
US5609681A (en) * 1992-07-22 1997-03-11 Sandoz Ltd. Workable cementitious compositions
WO1994005606A1 (fr) * 1992-09-01 1994-03-17 W.R. Grace & Co.-Conn. Adjuvants reduisant les cavites du ciment hydraulique et procede d'utilisation de ces derniers
US5478521A (en) * 1992-09-01 1995-12-26 W. R. Grace & Co.-Conn. Method for making bughole-free hardened cement structural units using bughole-reducing cement admixtures
EP0813506A1 (fr) * 1995-03-06 1997-12-29 W.R. Grace & Co.-Conn. Composition de ciment
EP0813506A4 (fr) * 1995-03-06 1999-01-27 Grace W R & Co Composition de ciment
US5654352A (en) * 1995-05-16 1997-08-05 Maxflow Environmental Corp. Air-entraining agent and method of producing same
US5703174A (en) * 1995-06-21 1997-12-30 W. R. Grace & Co.-Conn. Air controlling superplasticizers
US6290770B1 (en) 1998-08-14 2001-09-18 Mbt Holding Ag Cementitious mixture containing high pozzolan cement replacement and compatabilizing admixtures therefor
US6391106B2 (en) 1998-08-14 2002-05-21 Mbt Holding Ag Cementitious mixture containing high pozzolan cement replacement and compatabilizing admixtures therefor
US6267814B1 (en) 1998-08-14 2001-07-31 Mbt Holding Ag Cementitious dry cast mixture
US20030144385A1 (en) * 1999-07-09 2003-07-31 Vickers Thomas M. Oligomeric dispersant
US6861459B2 (en) 1999-07-09 2005-03-01 Construction Research & Technology Gmbh Oligomeric dispersant
US20030187101A1 (en) * 1999-12-10 2003-10-02 Mbt Holding Ag Solubilized defoamers for cementitious compositions
US8088842B2 (en) 1999-12-10 2012-01-03 Construction Research & Technology Gmbh Solubilized defoamers for cementitious compositions
US20030187100A1 (en) * 1999-12-10 2003-10-02 Mbt Holding Ag Water soluble air controlling agents for cementitious compositions
US6569924B2 (en) 1999-12-10 2003-05-27 Mbt Holdingag Solubilized defoamers for cementitious compositions
US6875801B2 (en) 1999-12-10 2005-04-05 Construction Research & Technology Gmbh Solubilized defoamers for cementitious compositions
US20060030643A1 (en) * 1999-12-10 2006-02-09 Bury Jeffrey R Water soluble air controlling agents for cementitious compositions
WO2002090286A1 (fr) * 2001-05-04 2002-11-14 Alpb - Aditivos E Ligantes Para Betões, Lda. Melanges de plastifiants a base de lignosulfonates
US20030127026A1 (en) * 2001-11-05 2003-07-10 James Edward Anderson High early-strength cementitious composition
US6858074B2 (en) * 2001-11-05 2005-02-22 Construction Research & Technology Gmbh High early-strength cementitious composition
US20040211342A1 (en) * 2003-04-25 2004-10-28 Mbt Holding Ag Rheology stabilizer for cementitious compositions
US7883577B2 (en) 2003-04-25 2011-02-08 Construction Research And Technology Gmbh Rheology stabilizer for cementitious compositions
EP2096089A1 (fr) * 2008-02-26 2009-09-02 Neil Spindler Additif de béton
EP2260010A2 (fr) * 2008-03-19 2010-12-15 Hexion Specialty Chemicals, Inc. Adjuvant pour formulations de béton et de ciment et ses procédés de préparation
US20090235845A1 (en) * 2008-03-19 2009-09-24 Hexion Specialty Chemicals, Inc. Modifier for concrete and cement formulations and methods of preparing the same
US8252106B2 (en) 2008-03-19 2012-08-28 Momentive Specialty Chemicals Inc. Modifier for concrete and cement formulations and methods of preparing the same
EP2260010A4 (fr) * 2008-03-19 2012-07-11 Momentive Specialty Chemicals Res Belgium Adjuvant pour formulations de béton et de ciment et ses procédés de préparation
US8404040B2 (en) 2009-07-07 2013-03-26 Momentive Specialty Chemicals Inc. Curing or sealing compositions for concrete and cement formulations and processes for using the same
US20110030587A1 (en) * 2009-08-07 2011-02-10 Lignotech Usa, Inc. Agglomerated particulate lignosulfonate
WO2011015950A3 (fr) * 2009-08-07 2011-05-05 Borregaard Industries Limited Lignosulfonate particulaire aggloméré
US8277557B2 (en) 2009-08-07 2012-10-02 Borregaard Industries Limited Agglomerated particulate lignosulfonate
US8946396B2 (en) 2009-08-07 2015-02-03 Borregaard Industries Limited Agglomerated particulate lignosulfonate
WO2011038426A3 (fr) * 2009-09-28 2011-06-09 Pieter Gideo Van Der Merwe Additif pour des compositions à base de ciment et de suppression des poussières
WO2011038426A2 (fr) * 2009-09-28 2011-03-31 Pieter Gideo Van Der Merwe Additif pour des compositions à base de ciment et de suppression des poussières
JP2024056323A (ja) * 2022-10-11 2024-04-23 竹本油脂株式会社 水硬性組成物用添加剤、その製造方法及び水硬性組成物の製造方法

Also Published As

Publication number Publication date
JPH0553740B2 (fr) 1993-08-10
CN1110261A (zh) 1995-10-18
CN1035485A (zh) 1989-09-13
CN1041711C (zh) 1999-01-20
CN1031049C (zh) 1996-02-21
JPH01188449A (ja) 1989-07-27

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