US4889592A - Process and apparatus for control in burning and slaking of lime and causticizing - Google Patents

Process and apparatus for control in burning and slaking of lime and causticizing Download PDF

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Publication number
US4889592A
US4889592A US07/110,690 US11069087A US4889592A US 4889592 A US4889592 A US 4889592A US 11069087 A US11069087 A US 11069087A US 4889592 A US4889592 A US 4889592A
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United States
Prior art keywords
lime
kiln
mechanical property
adjusting
burnt
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Expired - Fee Related
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US07/110,690
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English (en)
Inventor
Birgitta S. Andersson
Malin C. Zethraeus
Torbjorn Herngren
Jan-Erik V. Gustafsson
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STFI Skogsindustrins Tekniska Forskningsinstitut AB
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STFI Skogsindustrins Tekniska Forskningsinstitut AB
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Assigned to STFI, BOX 5064, S-114 86 STOCKHOLM, SWEDEN reassignment STFI, BOX 5064, S-114 86 STOCKHOLM, SWEDEN ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: ANDERSSON, SUSANNE, GUSTAFSSON, JAN-ERIK V., HERNGREN, TORBJORN, ZETHRAEUS, MALIN C.
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2/00—Lime, magnesia or dolomite
    • C04B2/02—Lime
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/0064—Aspects concerning the production and the treatment of green and white liquors, e.g. causticizing green liquor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/40—Production or processing of lime, e.g. limestone regeneration of lime in pulp and sugar mills
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S162/00—Paper making and fiber liberation
    • Y10S162/09—Uses for paper making sludge
    • Y10S162/10—Computer control of paper making variables
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/03—Papermaking liquor

Definitions

  • This invention relates to a method for controlling processes in connection with burning and slaking of lime and causticizing, said processes comprising lime burning in a kiln, washing of lime sludge on a lime sludge filter and a slaking and causticizing process.
  • These processes constitute the so-called lime cycle which is an essential part of the process for production of paper pulp according to the sulphate process.
  • the invention also comprises a device for carrying out the above-mentioned control processes.
  • the following specification concerns the use of the invention in the sulphate pulp industry. Besides this use the invention can be utilized in burning of lime for other purposes where an intended lime quality according to the following specification is desired.
  • lime In production of sulphate pulp lime, i.e. CaO, is used for preparation of boiling liquid.
  • the lime is handled in a cycle of processes, i.e. the lime cycle.
  • Lime is batched together with green liquor in a slaker which is the first vessel in a causticizing plant.
  • Green liquor is causticized to white liquor in the slaker and in the following reaction vessel, also called causticizing tank, meaning that carbonate in the solution is converted into hydroxide and that the lime forms CaCO 3 , so-called lime sludge.
  • the lime sludge is separated from the white liquor, is dewatered and washed e.g. on a lime sludge filter and thereafter burnt to lime which is utilized again for causticizing.
  • lime sludge is almost exclusively dried and reburnt in rotary furnaces, so-called lime kilns. This is a process requiring much energy which is of decisive importance for the energy economy of the sulphate pulp mill.
  • Lime sludge (CaCO 3 ) is disintegrated in the lime kiln to carbon dioxide (CO 2 ) and lime (CaO) at temperatures above 900° C.
  • CO 2 carbon dioxide
  • CaO lime
  • the burnt lime is subjected to higher temperatures (1100°-1400° C.) its structure is changed--it sinters.
  • the lime sludge contains impurities, preferably sodium, sintering may occur at lower temperatures than 1100° C.
  • the impurity content of the lime sludge in this respect is decided by the efficiency of the lime sludge filter.
  • Sintering means that the porosity of the lime and its specific surface are reduced and the reactivity of the lime is impaired in slaking. Sintering also involves influence on the mechanical properties of the lime such as hardness and modulus of elasticity. This is not specific to burning of lime sludge but always occurs when burning materials containing CaCO 3 and/or MgCO 3 .
  • the quality of the burnt lime is of a great importance for the pulp production. An even and good lime quality is a prerequisite for a satisfactorily working causticizing process. The result of that process decides the quality of the white liquor, i.e. that of the boiling liquid, which in turn will influence both quality and production costs of the pulp.
  • the lime must not be burnt too hard nor too loose. Lime that has been burnt too hard has a bad reactivity in slaking, e.g. the slaking rate is low which will influence the preparation of white liquor negatively while lime that has been burnt too loose has a low CaO-content and, moreover, yields a lime sludge that is difficult to separate from the white liquor and to dewater e.g. on a lime sludge filter.
  • both the reactivity of the lime and its CaO-content will influence the result of the causticizing.
  • the CaO-content in lime sludge will not vary inconsiderably under normal circumstances provided the lime is finally burnt, e.g. its CaCO 3 -content is low.
  • the reactivity of the lime can vary considerably. As mentioned above the reactivity of the lime is primarily dependent on the conditions in the kiln--temperature and residence time--and the purity of the lime sludge.
  • the mechanical properties of the lime it is possible to balance the reactivity variations of the lime sludge lime by measuring a suitable mechanical property of the lime and controlling the lime kiln and/or the impurity content of the lime sludge so that a certain desired value is obtained for the measured quantity.
  • the measured value is a measure of the reactivity of the lime in slaking, it can be used in causticizing for adapting batching of lime or, as an alternative, green liquor, to the current lime quality.
  • the method for control of the processes in the lime cycle i.e. adjustment of the slaking and causticizing process, of lime sludge washing on e.g. washing filters and of the lime sludge kiln, consists of maintaining the flow at a constant.
  • Control of slaking-causticizing is then carried out by adjusting the inflow of green liquor and lime, respectively, to a certain nominal value.
  • the nominal values are adjusted manually so that a desired amount of white liquor is obtained on the basis of laboratory analyses of the composition of the resulting white liquor.
  • the nominal values are adjusted on the basis of continuously obtained measured values in respect of the increase of temperature in slaking-causticizing and/or the electric conductivity of the liquid. Adjustment of nominal values by means of measured values from equipment for automatic analysis of chemical components in the liquid, preferably carbonate content, is also used.
  • Washing of lime sludge is normally controlled so that the amount of washing liquid supplied is adjusted to a certain nominal value that in certain cases is proportioned to the inflow of lime sludge.
  • the lime kiln is normally adjusted by adjusting the inflow of fuel, combustion air and lime sludge, respectively, to certain nominal values which are regulated in a certain mutual relation. According to more advanced methods these nominal values are adjusted utilizing a continuous measurement of temperature in the kiln--in certain cases the temperature in different parts of the kiln--and a continuous measurement of the content of, e.g. oxygen gas, of the flue gas.
  • the nominal values are adjusted at relatively long time intervals on the basis of manually performed laboratory analyses of the composition of the resulting lime, preferably on the basis of the content of calcium carbonate, CaCO 3 , of the lime.
  • the reported examples of existing technology to maintain a good function of the lime cycle processes are more or less good examples of how one tries to reduce operating problems in the processes.
  • the existing solutions often mean suboptimizations of the lime cycle processes in such a way that they reduce the effects of certain parameter variations but have no or little effect on other variations. For instance, none of the processes described takes variations in the structure of the lime or its sintering into consideration which, as shown, are important points for the operating conditions.
  • the quality of the lime is the process variable that is of a decisive importance for the function of the different processes parts in the lime cycle.
  • Studies have now also shown that the mechanical properties of the lime, e.g. its hardness or modulus of elasticity, are in a given relation to the reactivity and, thus, it is possible to utilize a measurement of the mechanical properties of the lime to obtain a measure of the quality of the lime. It has been found that the mechanical properties of the lime can be used as a variable of adjustment to regulate the process conditions in the process steps of the lime cycle.
  • the main purpose of the invention is to obtain a measuring signal by using a quick and flexible measuring method for lime quality and to utilize this as a true value in control systems for the lime cycle where the function of the control system is to influence the process conditions in the lime cycle when disturbances and changes with consequences for the quality of the lime arise.
  • a lime having a high and even quality can be produced. It is meant by a high lime quality, when production of lime sludge lime in a sulphate pulp mill is concerned, a lime quality that is optimal in the following aspects:
  • a device for adjusting processes in the lime cycle, when carrying out the above method, is characterized in, according to the invention, that it comprises a measuring apparatus for direct or indirect measurement of at least one of the mechanical properties of the burnt lime, e.g. modulus of elasticity or hardness.
  • An adjusting unit optionally via a process computer, utilizes the output signal of the measuring apparatus to vary the properties of the final lime product by adjusting the operating conditions in at least one of the following: in the lime kiln, in washing of lime sludge, and/or in a slaking and causticizing plant.
  • FIG. 1 shows a block diagram illustrating the fundamental embodiment of control systems for the part processes of the lime cycle, i.e. adjustment of the burning process in a lime kiln, washing of lime sludge on e.g. a lime sludge filter and/or the causticizing process.
  • FIG. 2 shows schematically a measuring apparatus for hardness measurement useful in connection with the control arrangement illustrated in FIG. 1.
  • FIG. 3 shows a diagram illustrating a measured relation of a mechanical property to the reactivity of the lime in slaking, the apparatus according to FIG. 2 being utilized.
  • Burning of CaCO 3 to lime is carried out in the kiln 10 in FIG. 1 under supply of heat.
  • the measure of the properties of the lime essential for the invention is obtained by means of an apparatus 12 by which the mechanical properties of the lime are measured.
  • the apparatus 12 can for instance be of the type shown in FIG. 2.
  • the output signal from the apparatus is either connected directly, or via a process computer 14, to a control unit 16.
  • the control unit 16 can operate to vary the properties of the final lime product by adjusting operating conditions in at least one of the following: in the lime kiln 10, in the causticizing plant 18, and/or in the lime sludge washing on e.g. the lime sludge filter 19.
  • the existing process conditions are considered in the process computer 14.
  • the regulator can preferably have the character of PI or PID and can be designed for analogue or digital technique with the corresponding PI or PID algorithms.
  • Control systems for the processes of the lime cycle can be embodied in several ways with access to the measuring signal for the mechanical properties of the lime as true value.
  • One method is that the measured value obtained is connected as true value in a control circuit, the output signal of which is connected to a means for adjusting the fuel supply to the kiln.
  • the nominal value of the lime property can be adjusted manually or be obtained from a superordinated control circuit.
  • the stability of the adjustment can be improved by connecting instead the output signal of the control circuit to the input of the nominal value of a control circuit for adjusting the temperature in the kiln, the output signal from this interior temperature control circuit being connected to an adjusting means for fuel supply.
  • the output signal of the temperature control circuit can be alternatively connected, optionally via an interior control circuit, to an adjusting means for the flow of flue gas through the kiln or to an adjusting means for the inflow of combustion air.
  • the temperature control circuit can alternatively consist of a multivariable adjusting means by which several of the adjusting means as above can be utilized coordinately.
  • One method is that the measured value is connected as true value to a control circuit, the output signal of which is connected directly or via an interior control circuit to an adjusting means for the speed of a motor by which the kiln is rotated.
  • One method is that the measured value is connected as true value to a control circuit, the output signal of which is transferred directly or via an interior control circuit to the adjusting means for the liquid flow to the lime sludge washing.
  • One method is to connect the measured value as true value to a circuit for advance control, the output signal of which is connected directly or via an interior control circuit to an adjusting means for the flow of green liquor to the slaker or to an adjusting means for the flow of cooling water through a cooler for green liquor or for the flow of steam through a heater for green liquor.
  • the method that is at present considered to give the best performance is a combination of the described way of connecting the measured value of the mechanical properties of the lime as a true value to an adjusting circuit for fuel supply via an interior control circuit for kiln temperature and the described way of utilizing a control circuit for advancing the flow of green liquor to the slaker.
  • the apparatus 12 comprises a metal plate 20 seen laterally which per se can be part of the lime handling system.
  • a piezoelectric crystal 24 is attached to the plate 20.
  • the crystal 24 is electrically connected to two separate signal branches.
  • the first signal branch comprises in series a high pass filter 26, an amplifier 28 and a rectifier and integrator 30.
  • the second signal branch comprises in series an amplifier 32 and a rectifier and integrator 34.
  • a comparator 36 is connected to the two signal branches.
  • the frequency spectrum of the waves comprises the basic frequency specific to the plate 20 as well as superimposed tones. It is found that the content of high frequencies is greater when the plate 20 is hit by a hard sintered ball than when it is hit by a softer normally burnt ball.
  • the piezoelectric crystal will generate a varying voltage and the output signal from the crystal is made to pass through both signal branches. The signal is filtered through a high pass filter in the first signal branch, the basic frequency being eliminated, after which the signal is amplified, full wave rectified and integrated. In this way a measure is obtained specifying how much energy is present in the high-frequency mechanical waves.
  • the signal is treated in the same way in the second signal branch except for the filtration in the high pass filter, after which the quotient of the signals received from the signal branches is calculated.
  • "The overtone content" of the vibrations in the plate i.e. the share of the total energy in the mechanical waves consisting of high frequencies, is then obtained.
  • the distribution of the mechanical waves on different frequencies when a surface is hit by lime nodules of a varying quality can be utilized in several different ways.
  • the quotient of two suitably selected frequency bands can be used.
  • the way in which these bands are selected is largely dependent on the properties of the surface.
  • An alternative way of measuring the vibrations of a surface consists in using a microphone to detect the acoustic waves caused by the vibrations. If a microphone is used the lime can be made to fall against a surface completely damped. In this case the measured acoustic waves substantially derive from the lime nodule. In the same way as before the content of high frequencies separates a hard burnt lime from a soft one, and therefore the same signal processing can be utilized.
  • the measuring device can also be formed in another way, measurement being carried out e.g. with respect to the work required at mechanical influence on the lime.
  • mechanical influence can consist of compression, crushing, grinding, or of the work performed when a body is made to penetrate into the lime.
  • FIG. 3 a relation between the hardness of the lime measured by the measuring device and the reactivity of the lime at slaking water is reported. This relation shows that the signal from the measuring device indicates a measure of the quality of the lime relating to its reactivity at slaking.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
  • Treatment Of Sludge (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
US07/110,690 1986-02-11 1987-02-02 Process and apparatus for control in burning and slaking of lime and causticizing Expired - Fee Related US4889592A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8600597A SE449112B (sv) 1986-02-11 1986-02-11 Forfarande for reglering vid kalkbrenning, kalksleckning och kausticering genom anvendning av en av kalkens mekaniska egenskaper
SE8600597 1986-02-11

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US (1) US4889592A (enrdf_load_stackoverflow)
JP (1) JPS63502604A (enrdf_load_stackoverflow)
DE (1) DE3790059T1 (enrdf_load_stackoverflow)
DK (1) DK528987A (enrdf_load_stackoverflow)
FI (1) FI85690C (enrdf_load_stackoverflow)
FR (1) FR2594117B1 (enrdf_load_stackoverflow)
GB (1) GB2199023B (enrdf_load_stackoverflow)
SE (1) SE449112B (enrdf_load_stackoverflow)
WO (1) WO1987004738A1 (enrdf_load_stackoverflow)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2186042C2 (ru) * 2000-07-31 2002-07-27 ЗАО "Еврофинчермет Ко" Способ получения извести
US20040175324A1 (en) * 2003-03-04 2004-09-09 Mohamad Hassibi Method and apparatus for hydration of calcium oxide

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3300196A (en) * 1964-03-02 1967-01-24 Bendy Engineering Company Method and apparatus for rotary kiln control with a calcining rate meter
DE1648770A1 (de) * 1967-03-18 1970-05-21 Vnii Abrazivov I Slifovanija Vorrichtung zur Haertepruefung an Schleifkoerpern
US3743697A (en) * 1971-10-28 1973-07-03 Paraho Corp Process of calcination
US3991172A (en) * 1970-05-20 1976-11-09 Rheinische Kalksteinwerke Gmbh Process for the production of reactive calcium oxide
SE7903919L (sv) * 1978-05-08 1979-11-09 Smidth & Co As F L Reglering av kalkbrenning
US4236960A (en) * 1978-07-18 1980-12-02 Mo Och Domsjo Aktiebolag Process for controlling the degree of causticization in the preparation of white liquid from the chemicals recovered from black liquor
US4302281A (en) * 1978-08-30 1981-11-24 Ab Rosenblads Patenter Method for producing pulp
US4391671A (en) * 1981-05-27 1983-07-05 Pulp And Paper Research Institute Of Canada Method of producing lime in a rotary kiln
SU1152942A1 (ru) * 1983-11-14 1985-04-30 Предприятие П/Я А-3732 Способ автоматического управлени процессом получени извести в производстве кальцинированной соды
US4536253A (en) * 1981-09-25 1985-08-20 Kemotron A/S Process for controlling the properties of white liquor
US4748010A (en) * 1985-03-11 1988-05-31 Chemstar, Inc. Energy conserving limestone calcining system

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3300196A (en) * 1964-03-02 1967-01-24 Bendy Engineering Company Method and apparatus for rotary kiln control with a calcining rate meter
DE1648770A1 (de) * 1967-03-18 1970-05-21 Vnii Abrazivov I Slifovanija Vorrichtung zur Haertepruefung an Schleifkoerpern
US3991172A (en) * 1970-05-20 1976-11-09 Rheinische Kalksteinwerke Gmbh Process for the production of reactive calcium oxide
US3743697A (en) * 1971-10-28 1973-07-03 Paraho Corp Process of calcination
US4283202A (en) * 1978-05-08 1981-08-11 Friis Hansen J Method and apparatus for burning CaCO3 and MgCO3 materials
SE7903919L (sv) * 1978-05-08 1979-11-09 Smidth & Co As F L Reglering av kalkbrenning
US4236960A (en) * 1978-07-18 1980-12-02 Mo Och Domsjo Aktiebolag Process for controlling the degree of causticization in the preparation of white liquid from the chemicals recovered from black liquor
US4311666A (en) * 1978-07-18 1982-01-19 Mo Och Domsjo Aktiebolag Apparatus for controlling the degree of causticization in the preparation of white liquor from the chemicals recovered from black liquor
US4302281A (en) * 1978-08-30 1981-11-24 Ab Rosenblads Patenter Method for producing pulp
US4391671A (en) * 1981-05-27 1983-07-05 Pulp And Paper Research Institute Of Canada Method of producing lime in a rotary kiln
US4536253A (en) * 1981-09-25 1985-08-20 Kemotron A/S Process for controlling the properties of white liquor
SU1152942A1 (ru) * 1983-11-14 1985-04-30 Предприятие П/Я А-3732 Способ автоматического управлени процессом получени извести в производстве кальцинированной соды
US4748010A (en) * 1985-03-11 1988-05-31 Chemstar, Inc. Energy conserving limestone calcining system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2186042C2 (ru) * 2000-07-31 2002-07-27 ЗАО "Еврофинчермет Ко" Способ получения извести
US20040175324A1 (en) * 2003-03-04 2004-09-09 Mohamad Hassibi Method and apparatus for hydration of calcium oxide
US7105146B2 (en) 2003-03-04 2006-09-12 Chemco Systems L.P. Method and apparatus for hydration of calcium oxide

Also Published As

Publication number Publication date
FI874452A7 (fi) 1987-10-09
SE449112B (sv) 1987-04-06
DK528987D0 (da) 1987-10-09
FI85690B (fi) 1992-02-14
SE8600597D0 (sv) 1986-02-11
GB2199023B (en) 1990-06-20
FR2594117A1 (fr) 1987-08-14
WO1987004738A1 (en) 1987-08-13
GB8722752D0 (en) 1987-11-04
JPS63502604A (ja) 1988-09-29
FI874452A0 (fi) 1987-10-09
DE3790059T1 (enrdf_load_stackoverflow) 1988-04-21
FI85690C (fi) 1992-05-25
DK528987A (da) 1987-10-09
GB2199023A (en) 1988-06-29
FR2594117B1 (fr) 1990-12-14

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