US4765976A - Method for combating the greasy appearance of hair - Google Patents

Method for combating the greasy appearance of hair Download PDF

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Publication number
US4765976A
US4765976A US07/037,014 US3701487A US4765976A US 4765976 A US4765976 A US 4765976A US 3701487 A US3701487 A US 3701487A US 4765976 A US4765976 A US 4765976A
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US
United States
Prior art keywords
hair
composition
weight
unit
chitosan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US07/037,014
Other languages
English (en)
Inventor
Jean F. Grollier
Chantal Fourcadier
Claude Dubief
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Assigned to L'OREAL reassignment L'OREAL ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: DUBIEF, CLAUDE, FOURCADIER, CHANTAL, GROLLIER, JEAN F.
Application filed by LOreal SA filed Critical LOreal SA
Application granted granted Critical
Publication of US4765976A publication Critical patent/US4765976A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/04—Preparations for permanent waving or straightening the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/736—Chitin; Chitosan; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/008—Preparations for oily hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00—Drug, bio-affecting and body treating compositions
    • Y10S424/01—Aerosol hair preparation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00—Drug, bio-affecting and body treating compositions
    • Y10S424/02—Resin hair settings

Definitions

  • the present invention relates to a cosmetic composition for combating the greasy appearance of hair, and more especially a cosmetic composition by means of which the onset of the greasy appearance of the hair may be delayed or by means of which the period during which the hair does not appear greasy may be extended.
  • compositions contain at least one particular polymer derived from chitosan.
  • the subject of the invention is also the use of a polymer derived from chitosan for treating hair, enabling the greasy appearance of the hair to be combated and, in particular, enabling the onset of its greasy appearance to be delayed.
  • European patent application No. 97,229 teaches the use of glycerolated derivatives of chitosan in compositions for treating the skin or hair; however, combating the greasy appearance of the hair is not mentioned in said European patent application.
  • the subject of the invention is a cosmetic composition designed to combat the greasy appearance of hair, characterized in that it contains, in a suitable cosmetic vehicle, at least one particular polymer derived from chitosan and incorporating monomeric units B and C or A, B and C or B and C 1 or A, B and C 1 , in the proportions stated below.
  • composition according to the invention does not appear to affect the production of sebum, but affects, in particular, the appearance of the hair which, despite the production of sebum, appears less “greasy". In other words, a longer period elapses between washing the hair and the onset of the "greasy" appearance when a composition containing a particular class of polymers derived from chitosan is applied to the hair, as will be described below.
  • the subject of the invention is hence a cosmetic composition containing, as active ingredient, at least one particular polymer derived from chitosan incorporating the monomeric units B and C or A, B and C, corresponding to the following formulae: ##STR2## in which the unit A is present in proportions of between 0 and 30% by weight, the unit B is present in proportions of between 5 and 50% by weight and the unit C is present in proportions of between 30 and 90% by weight based on to the total weight of said polymer.
  • R denotes a radical of the formula: ##STR3## where n denotes zero or 1.
  • R 1 , R 2 and R 3 which may be identical or different, each denote a hydrogen atom, a methyl, hydroxyl, acetoxy or amino group, an alkylthio residue in which the alkyl group bears an amino group, or a monalkylamine or dialkylamine residue; it being possible for the monoalkylamine and dialkylamine residues to be interrupted by one or more nitrogen atoms and/or substituted with one or more amine, hydroxyl, carboxyl, alkylthio or sulphonic groups, at least one of the radicals R 1 , R 2 and R 3 in this case being a hydrogen atom.
  • R 1 , R 2 and R 3 denotes a hydrogen atom.
  • the polymers composed of units A, B and C or B and C above can also take the form of a salt formed with a base or with an acid.
  • polymers derived from chitosan which are usable in the compositions according to the invention can be prepared by acylation of chitosan with an acid anhydride, in accordance with the procedure described in Example 1 of French patent No. 2,137,684 or in U.S. Pat. No. 3,879,376.
  • a polymer derived from chitosan which is more especially preferred according to the invention, incorporates from 0 to 20% by weight of units (A), from 40 to 50% by weight of units (B) and from 40 to 50% by weight of units (C1), this latter unit having the formula: ##STR4##
  • polymer P 1 This preferred polymer containing units A, B and C 1 will be designated polymer P 1 in the examples.
  • the subject of the invention is also a cosmetic composition for treating hair, containing, in a suitable vehicle, at least one polymer derived from chitosan and incorporating (1) from 0 to 30% by weight of unit A, (2) between 5 and 50% by weight of unit B and (3) between 30 and 90% by weight of unit C, or alternatively (1) between 0 and 20% by weight of unit A, (2) between 40 and 50% by weight of unit B and (3) between 40 and 50% by weight of unit C 1 .
  • the subject of the invention is also the use of a polymer derived from chitosan and incorporating (1) from 0 to 30% by weight of unit A, (2) from 5 to 50% by weight of unit B and (3) from 30 to 90% by weight of unit (C), or alternatively (1) from 0 to 20% by weight of unit A, (2) from 40 to 50% by weight of unit B and (3) from 40 to 50% by weight of unit C 1 .
  • the content of polymer derived from chitosan in the cosmetic compositions according to the invention can generally vary from 0.1 to 5% by weight, and more especially from 0.25 to 2% by weight, relative to the total weight of the composition.
  • the vehicle used in the compositions of the invention must be capable of dissolving the polymer used as an active ingredient.
  • the vehicle customarily used is selected from the group consisting of water and a mixture of water and alcohol (aqueous-alcoholic mixture), in which the alcohol is preferably an alkanol having from 1 to 4 carbon atoms. Ethanol or isopropyl alcohol is preferred.
  • the alcohol is present in proportions equal to or less than 55% by weight relative to the total weight of the composition.
  • compositions of the invention can contain, in addition to the polymer derived from chitosan, one or more additives chosen from the group consisting of surfactants, perfumes, colourings, preservatives, sequestering agents, foam stabilizers, ultraviolet radiation-absorbing agents and peptizing agents.
  • additives chosen from the group consisting of surfactants, perfumes, colourings, preservatives, sequestering agents, foam stabilizers, ultraviolet radiation-absorbing agents and peptizing agents.
  • the compositions can contain in addition the other additives customarily used in cosmetic compositions.
  • the subject of the invention is also the above-mentioned cosmetic compositions, packaged industrially in a suitable pack and with a direction leaflet containing written instructions for using the compositions for the purpose of delaying the onset of the greasy appearance of the hair.
  • compositions according to the invention can take the form of non-rinsed products, such as styling lotions, sprays or foams, shaping lotions, sprays or foams, setting lotions, sprays or foams or blow-drying lotions, sprays or foams, which are prepared according to the usual methods.
  • non-rinsed products such as styling lotions, sprays or foams, shaping lotions, sprays or foams, setting lotions, sprays or foams or blow-drying lotions, sprays or foams, which are prepared according to the usual methods.
  • compositions according to the invention also take the form of shampoos, lotions, foams or sprays to be rinsed, forming treatment products capable of being applied before or after dyeing or bleaching, before or after shampooing and before or after permanent waving.
  • the pH of these compositions can vary from 3 to 10, and is preferably below 7.
  • compositions When the compositions take the form of pressurized compositions to form aerosols, sprays or foams, they contain a propellant in addition.
  • propellants there may be used, in particular, carbon dioxide, nitrogen, nitrous oxide, volatile hydrocarbons such as butane, isobutane or propane, or preferably chlorinated and/or fluorinated hydrocarbons.
  • the subject of the invention is also the use of the particular polymer derived from chitosan, defined above, in the treatment of hair for the purpose of delaying the onset of its "greasy" appearance.
  • the subject of the invention is also a method for the treatment of hair by means of which the "greasy" appearence of the hair may be combated, consisting in applying to the hair an effective amount of a composition containing at least one particular chitosan derivative defined above.
  • the application of the composition is advantageously carried out immediately after washing the hair using a shampoo, or a short time after this shampooing.
  • the hair After impregnation of the hair with the composition containing the polymer derived from chitosan, the hair can be dried directly (in the case of the non-rinsed compositions). It is also possible to perform rinsing before drying the hair (in the case of the rinsed compositions). Naturally, it is possible to set the hair before drying it.
  • composition according to the invention can also consist in washing the hair with a shampoo containing the particular polymer derived from chitosan. It is then appropriate to leave the shampoo on the hair for a few minutes before rinsing it.
  • An anti-grease lotion of the following formula is prepared:
  • the anti-grease shampoo of the following formula is prepared:
  • An anti-grease shampoo having the following composition is prepared:

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
US07/037,014 1986-04-18 1987-04-10 Method for combating the greasy appearance of hair Expired - Lifetime US4765976A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8605659 1986-04-18
FR8605659A FR2597335B1 (fr) 1986-04-18 1986-04-18 Composition cosmetique permettant de lutter contre l'aspect gras des cheveux, et son utilisation.

Publications (1)

Publication Number Publication Date
US4765976A true US4765976A (en) 1988-08-23

Family

ID=9334408

Family Applications (1)

Application Number Title Priority Date Filing Date
US07/037,014 Expired - Lifetime US4765976A (en) 1986-04-18 1987-04-10 Method for combating the greasy appearance of hair

Country Status (9)

Country Link
US (1) US4765976A (de)
JP (1) JPS62255412A (de)
BE (1) BE1000188A3 (de)
CA (1) CA1294552C (de)
CH (1) CH673943A5 (de)
DE (1) DE3713099C3 (de)
FR (1) FR2597335B1 (de)
GB (1) GB2189145B (de)
IT (1) IT1207390B (de)

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4931271A (en) * 1986-04-30 1990-06-05 Wella Aktiengesellschaft Cosmetic compostions based upon N-hydroxybutyl-chitosans, N-hydroxybutyl-chitosans as well as processes for the production thereof
EP0412744A1 (de) * 1989-08-08 1991-02-13 Unilever Plc Haarbehandlungszusammensetzung
EP0412745A1 (de) * 1989-08-08 1991-02-13 Unilever Plc Haarfestigerzusammensetzung
US5567701A (en) * 1988-08-25 1996-10-22 L'oreal Alkylpolyglycoside and pyrimidine derivative based composition for inducing and stimulating hair growth and/or reducing hair loss
US6362142B1 (en) 1997-07-17 2002-03-26 Cognis Deutschland Gmbh Detergent mixtures containing ester quats, chitosan and/or chitosan derivatives and protein hydrolyzates
US6444659B1 (en) 1996-11-28 2002-09-03 Cognis Deutschland Gmbh Use of mixtures of active substances, containing phytostenols and/or phytostenol esters and potentiators, for the production of hypocholesterolemic agents
US6534091B1 (en) 1999-07-02 2003-03-18 Cognis Iberia S. L. Microcapsules
US20030133891A1 (en) * 2000-03-23 2003-07-17 Claudia Panzer Deodorizing preparations containing nanosacle chitosans and/or chitosan derivatives
US20030145393A1 (en) * 2000-03-24 2003-08-07 Alberto Corbella Hair dyes containing cationic biopolymers
US6623746B1 (en) 1998-07-16 2003-09-23 Cognis Deutschland Gmbh & Co. Kg PIT emulsions, methods of softening paper using the same, and paper substrates treated therewith
US6656454B1 (en) 1999-03-12 2003-12-02 Cognis Deutschland Gmbh & Co. Kg Method for producing surfactant granulates
WO2004013270A1 (en) * 2001-10-26 2004-02-12 S. C. Johnson & Son, Inc. Hard surface cleaners containing chitosan
KR100407880B1 (ko) * 1994-12-22 2004-03-02 시바 스페셜티 케미칼스 홀딩 인크. N-시아노메틸화키토산및이의제조방법
US6733790B1 (en) 1999-07-02 2004-05-11 Cognis Iberia S. L. Microcapsules and processes for making the same using various polymers and chitosans
US6818296B1 (en) 1999-07-02 2004-11-16 Cognis Iberia S.L. Microcapsules
US6846796B2 (en) 2000-04-15 2005-01-25 Cognis Deutschland Gmbh & Co. Kg Method for producing non-ionic tenside granulates
US20050158396A1 (en) * 2002-03-12 2005-07-21 Hans-Udo Kraechter Antioxidative preparations
FR2865210A1 (fr) * 2004-01-20 2005-07-22 Oreal Procede de preparation de derives de chitosane, derives obtenus, compositions les comprenant et procede de traitement
WO2005070971A1 (en) * 2004-01-20 2005-08-04 L'oreal Process for preparing chitosan derivatives, derivatives obtained, compositions comprising them and treatment method
US6979467B1 (en) 1999-07-02 2005-12-27 Cognis Iberia S.L. Microcapsules IV
US20060142255A1 (en) * 1997-11-14 2006-06-29 Bernd Fabry Hypocholesteremic preparations containing phytostenolesters of conjugated fatty acids, and methods of reducing serum cholesterol levels using the same
US20070104781A1 (en) * 1997-11-14 2007-05-10 Bernd Fabry Hypocholesteremic preparations containing mixtures of phytostenol(ester)s and conjugated fatty acids, and methods of using the same
US20100209377A1 (en) * 2007-06-29 2010-08-19 Drovetskaya Tatiana V Hair styling and conditioning personal care films
US20100247459A1 (en) * 2007-06-29 2010-09-30 Drovetskaya Tatiana V Hair styling and conditioning personal care films

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2693903B1 (fr) * 1992-07-24 1994-09-09 Oreal Laque aérosol capillaire à base de N-carboxybutyl chitosane.
DE19857548C1 (de) * 1998-12-14 2000-08-03 Cognis Deutschland Gmbh O-substituierte Biopolymere, Verfahren zur Herstellung und Verwendung
JP2006312593A (ja) * 2005-05-06 2006-11-16 Sunstar Inc 水−エタノール系化粧料組成物
EP2724713A1 (de) 2012-10-26 2014-04-30 Basf Se Klare, transparente Haargele

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2137684A1 (de) * 1971-05-10 1972-12-29 Oreal
EP0097229A2 (de) * 1982-06-23 1984-01-04 Wella Aktiengesellschaft Kosmetische Mittel auf der Basis von Chitosanderivaten, neue Chitosanderivate sowie Verfahren zur Herstellung dieser Derivate

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2754796A1 (de) * 1977-12-09 1979-06-13 Wella Ag Haarkur- und haarwaschmittel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2137684A1 (de) * 1971-05-10 1972-12-29 Oreal
US3879376A (en) * 1971-05-10 1975-04-22 Oreal Chitosan derivative, method of making the same and cosmetic composition containing the same
EP0097229A2 (de) * 1982-06-23 1984-01-04 Wella Aktiengesellschaft Kosmetische Mittel auf der Basis von Chitosanderivaten, neue Chitosanderivate sowie Verfahren zur Herstellung dieser Derivate
US4528283A (en) * 1982-06-23 1985-07-09 Wella Aktiengesellschaft Cosmetic composition based upon chitosan derivatives, new chitosan derivatives as well as processes for the production thereof

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4931271A (en) * 1986-04-30 1990-06-05 Wella Aktiengesellschaft Cosmetic compostions based upon N-hydroxybutyl-chitosans, N-hydroxybutyl-chitosans as well as processes for the production thereof
US5567701A (en) * 1988-08-25 1996-10-22 L'oreal Alkylpolyglycoside and pyrimidine derivative based composition for inducing and stimulating hair growth and/or reducing hair loss
EP0412744A1 (de) * 1989-08-08 1991-02-13 Unilever Plc Haarbehandlungszusammensetzung
EP0412745A1 (de) * 1989-08-08 1991-02-13 Unilever Plc Haarfestigerzusammensetzung
AU628204B2 (en) * 1989-08-08 1992-09-10 Unilever Plc Hair treatment composition
KR100407880B1 (ko) * 1994-12-22 2004-03-02 시바 스페셜티 케미칼스 홀딩 인크. N-시아노메틸화키토산및이의제조방법
US6444659B1 (en) 1996-11-28 2002-09-03 Cognis Deutschland Gmbh Use of mixtures of active substances, containing phytostenols and/or phytostenol esters and potentiators, for the production of hypocholesterolemic agents
US6362142B1 (en) 1997-07-17 2002-03-26 Cognis Deutschland Gmbh Detergent mixtures containing ester quats, chitosan and/or chitosan derivatives and protein hydrolyzates
US20070104781A1 (en) * 1997-11-14 2007-05-10 Bernd Fabry Hypocholesteremic preparations containing mixtures of phytostenol(ester)s and conjugated fatty acids, and methods of using the same
US20060142255A1 (en) * 1997-11-14 2006-06-29 Bernd Fabry Hypocholesteremic preparations containing phytostenolesters of conjugated fatty acids, and methods of reducing serum cholesterol levels using the same
US6623746B1 (en) 1998-07-16 2003-09-23 Cognis Deutschland Gmbh & Co. Kg PIT emulsions, methods of softening paper using the same, and paper substrates treated therewith
US6656454B1 (en) 1999-03-12 2003-12-02 Cognis Deutschland Gmbh & Co. Kg Method for producing surfactant granulates
US6979467B1 (en) 1999-07-02 2005-12-27 Cognis Iberia S.L. Microcapsules IV
US6534091B1 (en) 1999-07-02 2003-03-18 Cognis Iberia S. L. Microcapsules
US6733790B1 (en) 1999-07-02 2004-05-11 Cognis Iberia S. L. Microcapsules and processes for making the same using various polymers and chitosans
US6818296B1 (en) 1999-07-02 2004-11-16 Cognis Iberia S.L. Microcapsules
US6916465B2 (en) 2000-03-23 2005-07-12 Cognis Deutschland Gmbh & Co. Kg Deodorizing preparations containing nanosacle chitosans and/or chitosan derivatives
US20030133891A1 (en) * 2000-03-23 2003-07-17 Claudia Panzer Deodorizing preparations containing nanosacle chitosans and/or chitosan derivatives
US20030145393A1 (en) * 2000-03-24 2003-08-07 Alberto Corbella Hair dyes containing cationic biopolymers
US6846796B2 (en) 2000-04-15 2005-01-25 Cognis Deutschland Gmbh & Co. Kg Method for producing non-ionic tenside granulates
US6849586B2 (en) 2001-10-26 2005-02-01 S. C. Johnson & Son, Inc. Hard surface cleaners containing chitosan
WO2004013270A1 (en) * 2001-10-26 2004-02-12 S. C. Johnson & Son, Inc. Hard surface cleaners containing chitosan
US20050158396A1 (en) * 2002-03-12 2005-07-21 Hans-Udo Kraechter Antioxidative preparations
FR2865210A1 (fr) * 2004-01-20 2005-07-22 Oreal Procede de preparation de derives de chitosane, derives obtenus, compositions les comprenant et procede de traitement
WO2005070971A1 (en) * 2004-01-20 2005-08-04 L'oreal Process for preparing chitosan derivatives, derivatives obtained, compositions comprising them and treatment method
US20100209377A1 (en) * 2007-06-29 2010-08-19 Drovetskaya Tatiana V Hair styling and conditioning personal care films
US20100247459A1 (en) * 2007-06-29 2010-09-30 Drovetskaya Tatiana V Hair styling and conditioning personal care films

Also Published As

Publication number Publication date
FR2597335A1 (fr) 1987-10-23
BE1000188A3 (fr) 1988-07-19
FR2597335B1 (fr) 1990-08-24
DE3713099A1 (de) 1987-10-29
JPS62255412A (ja) 1987-11-07
CH673943A5 (de) 1990-04-30
IT8767304A0 (it) 1987-04-14
CA1294552C (fr) 1992-01-21
GB2189145B (en) 1990-04-04
DE3713099C2 (de) 1996-02-22
IT1207390B (it) 1989-05-17
DE3713099C3 (de) 1998-05-20
GB8709218D0 (en) 1987-05-20
GB2189145A (en) 1987-10-21

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AS Assignment

Owner name: L'OREAL, 14, RUE ROYALE F-75008 PARIS, FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:GROLLIER, JEAN F.;FOURCADIER, CHANTAL;DUBIEF, CLAUDE;REEL/FRAME:004700/0369

Effective date: 19870331

Owner name: L'OREAL,FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GROLLIER, JEAN F.;FOURCADIER, CHANTAL;DUBIEF, CLAUDE;REEL/FRAME:004700/0369

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