US4255458A - Method for the selective extraction of caffeine from vegetable materials - Google Patents

Method for the selective extraction of caffeine from vegetable materials Download PDF

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Publication number
US4255458A
US4255458A US05/914,811 US91481178A US4255458A US 4255458 A US4255458 A US 4255458A US 91481178 A US91481178 A US 91481178A US 4255458 A US4255458 A US 4255458A
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Prior art keywords
component
caffeine
extraction
solvent
solution
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US05/914,811
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English (en)
Inventor
Ludwig Roselius
Hans-Albert Kurzhals
Peter Hubert
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Hag AG
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Hag AG
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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F5/00—Coffee; Coffee substitutes; Preparations thereof
    • A23F5/20—Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof
    • A23F5/22—Reducing or removing alkaloid content from coffee extract
    • A23F5/226—Reducing or removing alkaloid content from coffee extract by extraction with selective solvents
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F3/00—Tea; Tea substitutes; Preparations thereof
    • A23F3/36—Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof
    • A23F3/366—Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof by extraction of the leaves with selective solvents
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F3/00—Tea; Tea substitutes; Preparations thereof
    • A23F3/36—Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof
    • A23F3/38—Reducing or removing alkaloid content from tea extract
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F5/00—Coffee; Coffee substitutes; Preparations thereof
    • A23F5/20—Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof
    • A23F5/206—Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof by extraction of the beans with selective solvents other than water or aqueous bean extracts, including supercritical gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/02—Solvent extraction of solids
    • B01D11/0203—Solvent extraction of solids with a supercritical fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/02—Solvent extraction of solids
    • B01D11/0292—Treatment of the solvent

Definitions

  • the invention relates to a method for the selective extraction of caffeine from vegetable materials using a liquid solvent which is not injurious to health.
  • organic solvents such as esters, aromatic, and halogenated hydrocarbons have mainly been used for methods of extracting caffeine from vegetable materials, in particular those for producing beverages such as coffee or tea. These solvents come in contact either directly with the vegetable material or with its aqueous extracts long enough until the desired degree of caffeine reduction is attained. The treated material is processed after the solvents have been separated.
  • organic solvents are used for processing materials from which articles for consumption are made, they must be removed as thoroughly as possible by means of complex and costly processing techniques to ensure that only small quantities of solvents remain in the material so that they do not constitute a health hazard from the point of view of modern technical technology.
  • a disadvantage is that these processings lead to sensory deteriorations in quality in comparison to an unprocessed product.
  • the removal of solvents requires considerable technical and analytical effort.
  • (b) a second component which, by itself, has physical properties such that a mixture of (a) and (b) is liquid at the operating temperature.
  • the following gases are suitable as first component: CO 2 , N 2 O, SF 6 , Xe, CF 4 , methane, ethane, ethylene, acetylene, cyclopropane.
  • Suitable as second component which, by itself, has physical properties such that they are liquid at working temperature when mixed under operational conditions with the inherently gaseous component, are materials which are not injurious to health, particularly substances contained in the vegetable material to be extracted, e.g., aliphatic compounds such as propane, butane, and higher members of the paraffin hydrocarbon series; ketones, such as acetone, methyl ethyl ketone; esters, such as methyl or ethyl acetate; glycerides, such as contained in coffee oil.
  • aliphatic compounds such as propane, butane, and higher members of the paraffin hydrocarbon series
  • ketones such as acetone, methyl ethyl ketone
  • esters such as methyl or ethyl acetate
  • glycerides such as contained in coffee oil.
  • caffeine may be used alone or mixed with one another. Their choice is determined by the criterion of maximum selectivity and solubility for caffeine, depending on the operational conditions chosen, the type of vegetable material, and the properties of the first component, with which they must form a liquid solution. This means that if the solubility and/or selectivity for caffeine of the first component are relatively low under operational conditions, the second component must be chosen in such a way that the selectivity and solubility of the resultant solution reach a maximum.
  • the following vegetable materials can be processed with the method according to the invention: raw coffee (beans or ground), roasted coffee (beans or ground), tea, cola leaves, and aqueous extracts of these natural products.
  • the temperature of the extraction according to the invention preferably lies between approximately 0° and 100° C., more preferably between ambient temperature and 90° C. for extracting a solid vegetable material using CO 2 as first component, and more preferably between 0° and 70° C. for removing aqueous extracts.
  • the minimum extraction pressure must be chosen sufficiently high that the solution to be used according to the invention is liquid in the case of the chosen composition and at the required temperature, the extraction pressure upwards being limited solely for reasons of economy because, surprisingly, an increase in pressure, e.g., from 100 to 250 bars at 50° C. in the case of CO 2 /acetone mixtures, will result in considerable acceleration of the extraction velocity, although the density of the solution is only slightly increased. Conversely, low pressures will make it possible to use simpler apparatus.
  • the liquid solution is best circulated in a cycle system.
  • the stream velocity and, hence the level of the circulating mass flow of the liquid solution depends on the other parameters chosen for the process, e.g., type of components, temperature, pressure, and the required extraction period which, depending on the vegetable material being processed, may last from 2 to 10 hours.
  • the extracted caffeine may be removed from the circulating liquid solution by means of an adsorbent (FIG. 1).
  • adsorbents are suitable, e.g., activated charcoal and molecular sieves.
  • the separation of the caffeine from the adsorbent may be effected in accordance with conventional adsorbent-regeneration methods. Regeneration with a liquid solvent is preferred. If the second component of the liquid decaffeination solution is used for this purpose, there is no need for subsequent removal of the residual solvent from the adsorbent, which leads to considerable economical advantages.
  • the caffeine may likewise be removed from the cycle system by changing the pressure and/or temperature.
  • the caffeine can very advantageously be extracted by changing the pressure and/or temperature, if the separated second component exhibits a very high dissolving power for caffeine.
  • a concentrated caffeine solution can continuously be drawn off from the cycle, separated by conventional separation processes, and the pure second component can be returned to the cycle (FIG. 2).
  • the liquid solution is separated from the vegetable material. If this separation is effected with simultaneous pressure reduction, only a small portion of the second component will remain in the extraction system and can be removed through evacuation, heating, evaporation (if a solid material is processed) or rinsing with the first component or with other inert gases.
  • the space or volume it occupies in the extraction system may be filled by inert gases or, if the temperature is simultaneously being lowered, also by the pure liquid first component.
  • raw coffee beans having 15-55%, preferably 25-45%, water by weight are used.
  • To moisten the coffee it is treated in the usual manner with liquid water or steam.
  • the water-containing raw coffee beans are extracted in the usual manner in accordance with any conventional solid-liquid extraction method, using continuous as well as batch techniques.
  • CO 2 is preferred as first component mixed with esters or glycerides, ketones, aliphatic compounds, as the case may be, preference being given to materials contained in coffee.
  • Small amounts of ammonia may be utilized as admixture to the second component.
  • the concentration of the second component e.g., methyl acetate, deodorized raw coffee oil, acetone, hexane, is so selected that the solution according to the invention, when diluted with air, has no explosive limits. For example, in the case of acetone this concentration is 8 mole%.
  • This solution is liquid at pressures in excess of 92 bars and at temperatures under approximately 58° C.
  • FIG. 1 shows a cycle system for the decaffeination of a vegetable material, e.g., coffee, with the solution according to the invention, the caffeine being removed therefrom by adsorbents in adsorber 2.
  • Extractor 1 contains a charge of the material to be extracted, e.g., wet raw coffee beans.
  • the first component is fed to the extraction container from storage tank 8, Pump 6 feeds the second component into the cycle system.
  • Circulation pump 3 circulates the liquid solution in the extraction circuit comprising extractor 1, adsorber 2, and heat exchanger 5.
  • Adsorber 2 preferably contains activated carbon as an adsorbent.
  • Heat exchanger 5 is designed to bring the solution to be used in accordance with the invention to the extraction temperature.
  • the caffeine-laden solution in extractor 1 is decaffeinated in adsorber 2 and returns to extractor 1.
  • the purity of the caffeine isolated from the adsorbent is in excess of 95%.
  • FIG. 2 shows a cycle system for decaffeinating a vegetable material, e.g., coffee, with the solution according to the invention, with the caffeine being removed from this solution, for example, by cooling it and bringing about a separation in two liquid phases.
  • the phase separation of the homogeneous caffeine-laden solution flowing out of extractor 1 takes place in cooler 7.
  • separator 4 Assisted by circulating pump 3, the two-phase system originating in cooler 7 flows to separator 4, in which the phases are separated as a result of the difference in density between the two phases.
  • the caffeine-laden phase containing the second component of the solution used for the extraction and forming the lower or upper phase is appropriately separated and flows to separation system 9, where the caffeine is separated from the second component which, in turn, is fed back into the main circuit by pump 6.
  • the medium which is cooled in 7 is reheated in heater 5.
  • the wet raw coffee becomes isobaric in the cycle system in the preferred 50-300-bar pressure range and is extracted isothermally until the required final caffeine content of, say, 0.07% by weight in relation to the dry substance, is attained.
  • the required extraction temperature is set during the circulation by means of the heat exchangers. The levels of both components are calculated in such a way that the desired extraction pressure is obtained.
  • the solution After decaffeination, the solution is drawn off, the pressure simultaneously being reduced.
  • the processed beans can be fed directly, without further steps, into a vacuum drier under normal operating conditions in order to remove the residual solvents.
  • the beans are then roasted in the usual manner. From the sensory point of view, the infusion made from the roasted coffee is similar in quality to that of an unprocessed coffee.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Tea And Coffee (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compounds Of Unknown Constitution (AREA)
US05/914,811 1977-06-16 1978-06-12 Method for the selective extraction of caffeine from vegetable materials Expired - Lifetime US4255458A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2727191 1977-06-16
DE2727191A DE2727191B2 (de) 1977-06-16 1977-06-16 Verfahren zur selektiven Extraktion von Coffein aus pflanzlichen Materialien

Publications (1)

Publication Number Publication Date
US4255458A true US4255458A (en) 1981-03-10

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US05/914,811 Expired - Lifetime US4255458A (en) 1977-06-16 1978-06-12 Method for the selective extraction of caffeine from vegetable materials

Country Status (15)

Country Link
US (1) US4255458A (fr)
JP (1) JPS5436299A (fr)
AT (1) AT359814B (fr)
BE (1) BE868203A (fr)
CA (1) CA1109324A (fr)
CH (1) CH634202A5 (fr)
DD (1) DD135491A5 (fr)
DE (1) DE2727191B2 (fr)
DK (1) DK149321C (fr)
FR (1) FR2394547A1 (fr)
GB (1) GB1596364A (fr)
IT (1) IT1096612B (fr)
LU (1) LU79810A1 (fr)
NL (1) NL7806406A (fr)
SU (1) SU1056874A3 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4472442A (en) * 1980-09-26 1984-09-18 General Foods Corporation Decaffeination process
US4515695A (en) * 1983-11-28 1985-05-07 E.I. Du Pont De Nemours And Company Extraction of substances from aqueous solution
US4562083A (en) * 1980-07-07 1985-12-31 General Foods Corporation Decaffeination of green coffee with n-butyl acetate
WO1987002697A1 (fr) * 1985-10-31 1987-05-07 Angio-Medical Corporation Extraction de matieres animales en utilisant des fluides supercritiques
US4714617A (en) * 1983-09-03 1987-12-22 Messer Griesheim Gmbh Procedure for segregation of mixture of substances containing organic components
US4820537A (en) * 1987-03-13 1989-04-11 General Foods Corporation Method for decaffeinating coffee with a supercritical fluid
US4861607A (en) * 1981-03-20 1989-08-29 Nestec S. A. Removal of xanthine stimulants from cocoa
US4911941A (en) * 1988-08-05 1990-03-27 General Foods Corporation Method for decaffeinating coffee with a supercritical fluid
WO1991001367A1 (fr) * 1989-07-20 1991-02-07 Bioeng, Inc. Rupture de cellules microbiennes a l'aide de fluides supercritiques et extraction a partir de celles-ci
US5714094A (en) * 1994-07-23 1998-02-03 Nestec S.A. Antioxidant composition and process for the preparation thereof
US20070128327A1 (en) * 2003-12-02 2007-06-07 Kao Corporation Package drink
US20070231445A1 (en) * 2004-07-09 2007-10-04 Nateco2 Gmbh + Co. Kg Method for Decaffeinating Tea
US20170020326A1 (en) * 2011-05-03 2017-01-26 James T. Farley Coffee maker with selective filter assembly for retroactively removing caffeine from brewed coffee
EP3906981A1 (fr) * 2020-05-07 2021-11-10 Feyecon Development & Implementation B.V. Procédé d'extraction utilisant du dioxyde de carbone

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2737793A1 (de) * 1977-08-22 1979-03-08 Peter Siegfried Verfahren zur entcoffeinierung von rohkaffee
DE2844781A1 (de) * 1978-10-13 1980-04-24 Hag Ag Verfahren zur extraktiven bearbeitung von pflanzlichen und tierischen materialien
DE2846976C3 (de) * 1978-10-28 1982-05-06 Fried. Krupp Gmbh, 4300 Essen Verfahren zur Entcoffeinierung von Rohkaffee
US4237288A (en) * 1979-05-17 1980-12-02 Societe D'assistance Technique Pour Produits Nestle S.A. Decaffeination of fatty materials
US4472443A (en) * 1980-09-26 1984-09-18 General Foods Corporation Aprotic solvent decaffeination
GB2095091B (en) * 1981-03-20 1984-08-22 Nestle Sa Removal of xanthine stimulants from cocoa
DE3339181A1 (de) * 1983-10-28 1985-05-09 Uhde Gmbh, 4600 Dortmund Verfahren und vorrichtung zur entkoffeinierung von teeblaettern
DE3413869A1 (de) * 1984-04-12 1985-10-17 Hopfenextraktion HVG Barth, Raiser & Co, 8069 Wolnzach Verfahren zur entcoffeinierung von schwarzem tee
DE3414767A1 (de) * 1984-04-18 1985-11-07 Hopfenextraktion HVG Barth, Raiser & Co, 8069 Wolnzach Verfahren zur herstellung von entcoffeiniertem schwarzen oder gruenen tee
DE3415844C2 (de) * 1984-04-27 1994-02-03 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von entkoffeiniertem Tee
DE3632401A1 (de) * 1986-09-24 1988-04-07 Barth Raiser Hopfenextraktion Verfahren zur extraktion unpolarer inhaltsstoffe aus hopfen
FR2629735B1 (fr) * 1988-04-11 1991-03-22 Agronomique Inst Nat Rech Procede d'extraction au dioxyde de carbone supercritique de composes volatils, et composes obtenus
DE4000474A1 (de) * 1990-01-10 1990-11-15 Ben Nasr Hedi Dr Verfahren zur quasikontinuierlichen entcoffeinierung von rohkaffee
DE202018003618U1 (de) 2018-02-14 2018-08-21 Sven Miric Vorrichtung zur Extraktion und/ oder Konzentration von lipophilen Molekülen mittels flüssigem oder überkritischem Kohlenstoffdioxid

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1957358A (en) * 1931-07-07 1934-05-01 Scheele Erich Process of producing caffein-free coffee
US3769033A (en) * 1970-04-24 1973-10-30 Gen Foods Corp Green bean decaffination employing fluorinated hydrocarbons
US3806619A (en) * 1971-05-07 1974-04-23 Studiengesellschaft Kohle Mbh Process for recovering caffeine
US3843824A (en) * 1971-04-22 1974-10-22 Hag Ag Method for the production of caffeine-free coffee extract
US3879569A (en) * 1972-03-14 1975-04-22 Hag Ag Process for the decaffeination of raw coffee
US4081561A (en) * 1976-04-13 1978-03-28 General Foods Corporation Partially decaffeinated soluble coffee product and method therefor

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR12612E (fr) * 1909-11-11 1910-10-20 Louis Klein Procédé pour l'obtention de grains de café exempts de caféine
CH147145A (de) * 1930-01-03 1931-05-31 Carl Helmke Wilhelm Arnold Verfahren zur Gewinnung von koffeinfreiem, bezw. koffeinarmen Rohkaffee.
FR733915A (fr) * 1931-09-03 1932-10-13 Koro Kaffee Kompagnie G M B H Procédé de fabrication de café sans caféine
FR791055A (fr) * 1934-06-09 1935-12-02 Procédé de préparation de thé ne contenant pas de théine
FR995441A (fr) * 1945-03-02 1951-12-03 Produits alimentaires tirés du café ou autres matières d'origine végétale et leur procédé de fabrication
CH535543A (de) * 1970-02-05 1973-04-15 Studiengesellschaft Kohle Mbh Verfahren zur Entcoffeinierung von Rohkaffee
DE2450978A1 (de) * 1974-10-26 1976-04-29 Helmut Dallinga Verfahren und vorrichtung zum entkoffeinieren von kaffee

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1957358A (en) * 1931-07-07 1934-05-01 Scheele Erich Process of producing caffein-free coffee
US3769033A (en) * 1970-04-24 1973-10-30 Gen Foods Corp Green bean decaffination employing fluorinated hydrocarbons
US3843824A (en) * 1971-04-22 1974-10-22 Hag Ag Method for the production of caffeine-free coffee extract
US3806619A (en) * 1971-05-07 1974-04-23 Studiengesellschaft Kohle Mbh Process for recovering caffeine
US3879569A (en) * 1972-03-14 1975-04-22 Hag Ag Process for the decaffeination of raw coffee
US4081561A (en) * 1976-04-13 1978-03-28 General Foods Corporation Partially decaffeinated soluble coffee product and method therefor

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4562083A (en) * 1980-07-07 1985-12-31 General Foods Corporation Decaffeination of green coffee with n-butyl acetate
US4472442A (en) * 1980-09-26 1984-09-18 General Foods Corporation Decaffeination process
US4861607A (en) * 1981-03-20 1989-08-29 Nestec S. A. Removal of xanthine stimulants from cocoa
US4714617A (en) * 1983-09-03 1987-12-22 Messer Griesheim Gmbh Procedure for segregation of mixture of substances containing organic components
US4515695A (en) * 1983-11-28 1985-05-07 E.I. Du Pont De Nemours And Company Extraction of substances from aqueous solution
WO1987002697A1 (fr) * 1985-10-31 1987-05-07 Angio-Medical Corporation Extraction de matieres animales en utilisant des fluides supercritiques
US4749522A (en) * 1985-10-31 1988-06-07 Angio-Medical Corporation Supercritical fluid extraction of animal derived materials
US4820537A (en) * 1987-03-13 1989-04-11 General Foods Corporation Method for decaffeinating coffee with a supercritical fluid
US4911941A (en) * 1988-08-05 1990-03-27 General Foods Corporation Method for decaffeinating coffee with a supercritical fluid
WO1991001367A1 (fr) * 1989-07-20 1991-02-07 Bioeng, Inc. Rupture de cellules microbiennes a l'aide de fluides supercritiques et extraction a partir de celles-ci
US5380826A (en) * 1989-07-20 1995-01-10 Aphios Corporation Supercritical fluid disruption of and extraction from microbial cells
US5714094A (en) * 1994-07-23 1998-02-03 Nestec S.A. Antioxidant composition and process for the preparation thereof
US20070128327A1 (en) * 2003-12-02 2007-06-07 Kao Corporation Package drink
US8088429B2 (en) * 2003-12-02 2012-01-03 Kao Corporation Package drink
US20070231445A1 (en) * 2004-07-09 2007-10-04 Nateco2 Gmbh + Co. Kg Method for Decaffeinating Tea
US7858138B2 (en) 2004-07-09 2010-12-28 Nateco2 Gmbh + Co. Kg Method for decaffeinating tea
US20170020326A1 (en) * 2011-05-03 2017-01-26 James T. Farley Coffee maker with selective filter assembly for retroactively removing caffeine from brewed coffee
EP3906981A1 (fr) * 2020-05-07 2021-11-10 Feyecon Development & Implementation B.V. Procédé d'extraction utilisant du dioxyde de carbone
WO2021224502A1 (fr) 2020-05-07 2021-11-11 Feyecon Development & Implementation B.V. Procédé et appareil d'extraction au moyen de dioxyde de carbone

Also Published As

Publication number Publication date
NL7806406A (nl) 1978-12-19
DD135491A5 (de) 1979-05-09
DK149321C (da) 1986-10-06
DE2727191A1 (de) 1978-12-21
BE868203A (fr) 1978-10-16
SU1056874A3 (ru) 1983-11-23
IT7824022A0 (it) 1978-05-30
CA1109324A (fr) 1981-09-22
AT359814B (de) 1980-12-10
DK269678A (da) 1978-12-17
IT1096612B (it) 1985-08-26
GB1596364A (en) 1981-08-26
DK149321B (da) 1986-05-05
JPS5633395B2 (fr) 1981-08-03
FR2394547B1 (fr) 1981-08-14
DE2727191B2 (de) 1980-07-03
FR2394547A1 (fr) 1979-01-12
ATA374278A (de) 1980-04-15
LU79810A1 (de) 1979-07-20
JPS5436299A (en) 1979-03-16
CH634202A5 (de) 1983-01-31

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