US3917883A - Flocked products and their manufacture - Google Patents

Flocked products and their manufacture Download PDF

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Publication number
US3917883A
US3917883A US401790A US40179073A US3917883A US 3917883 A US3917883 A US 3917883A US 401790 A US401790 A US 401790A US 40179073 A US40179073 A US 40179073A US 3917883 A US3917883 A US 3917883A
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United States
Prior art keywords
stencil
fibres
product
flocked
contact
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Expired - Lifetime
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US401790A
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English (en)
Inventor
Frank M Jepson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nairn Coated Products Ltd
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Nairn Coated Products Ltd
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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H11/00—Non-woven pile fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/16—Flocking otherwise than by spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0097—Web coated with fibres, e.g. flocked
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/10—Decorating textiles by treatment with, or fixation of, a particulate material, e.g. mica, glass beads
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23929—Edge feature or configured or discontinuous surface
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23943—Flock surface

Definitions

  • flocked products comprise a substrate the surface of which carries a very high density of flocked fibres that are usually both short in length and of fine denier and that are bonded to the substrate by a bond ing agent applied to the substrate.
  • flocked fibres that are usually both short in length and of fine denier and that are bonded to the substrate by a bond ing agent applied to the substrate.
  • they are gener ally made by flocking fibres onto a substrate carrying an unhardened adhesive and then hardening the adhe sive. They find application as, for example, upholstery materials, garment materials, shoe materials, carpets and artificial suedes.
  • Flocked products in general have a velvet-like or suede-like feel and appearance and in particular generally have the characteristic sheen of many suedes and velvets.
  • the flocked fibres are oriented substantially vertically with respect to the substrate, because of the influence ofthe electrostatic field. Any deviations from the vertical are random; that is to say, there is no predominant orientation of the fibres other than perpendicular to the substrate. In fact, if precision cut flock is used, there is usually very little deviation from the perpendicular.
  • flocking is by mechanical methods, the fibres tend to have a slightly more random orientation, but again there is no predominant orientation other than vertical.
  • the fibres in the embossed areas are non-linear; that is to say, the individual fibres are bent with the tips being deflected considerably more than the bases of the fibres. Again this tends to detract from the appearance and to render fabric liable to acquire a bruised appearance.
  • embossing techniques generally only enable surface effects of rather limited design interest to be achieved.
  • a flocked product according to the invention comprises a substrate and a surface of flocked fibres bonded to it by a hardened binder.
  • the fibres over part of the surface area of the product are substantially lin ear and have a predominant, non-perpendicular orientation and over another part of the surface area the fibres are substantially linear and have a different, predominant, non-perpendicular orientation.
  • the products have a velvet-like or suedelike appearance. Fibres in one or more areas will have one predominant, nonperpendicular orientation, while fibres in one or more other areas will have a different, predominant, non-perpendicular orientation.
  • products according to the invention differ from products made by embossing methods.
  • the product of the invention is best made by a method in which the fibres are flocked onto a substrate carrying a fluid binder; the fibres are laid in part of the surface area with a predominant, non-perpendicular orientation and in another part with a different, predominant, non-perpendicular orientation and the binder is then hardened.
  • the fibres within each individual area have a more predominant orientation, i.e. are less randomly laid, than in embossed products.
  • the products of the invention have a much more pleasing appearance than flocked products that have been made previously and in particular have an appearance that is more resistant to bruising and other use defects.
  • the orientation of fibres within an area of the surface is usually such that substantially all the fibres in the area of the surface lie substantially all in one direction along the surface, for example at an angle of less than 45 and usually less than 30, for example 10 to 20, to the plane of the surface.
  • the invention it is possible to produce a wide range of design effects in the surface, by suitable choice of orientations in flattened areas and optionally also by the inclusion of unflattened areas.
  • the flattened areas have the particular advantage that their appearance is not harmed by wear and so it is generally preferred that the entire surface of the fabric should have its fibres laid in two or more predominant, non-perpendicular, orientations.
  • the individual areas of fibres having a predominent orientation may be arranged in any desired pattern which may be, for example, a regular or geometric pattern, or it may be one that gives the appearance of being an irregular pattern, for example a marble effect.
  • Various methods of laying the fibres of the flock can be used and include the use of bars or combs against which the flock can be made to move, for example by moving the substrate beneath the bars or combs, or air jets.
  • particularly satisfactory methods involve simple mechanical rolling or brushing.
  • the apparatus used includes means such that the de- 3 sired pattern of different orientations in different areas is achieved in one operation. although if desired the flocked product can of course be subjected to two or more pressing or brushing processes to achieve the desired pattern.
  • fibres are to have orientations in stripes that extend along the length of the fabrics, then these orientations can adequately be accomplished by passing the flocked substrate beneath brushes, rolls or other members that, in combination with the movement of the substrate relative to the member, cause the fibres to be deflected in the desired directions. If the fibres before orientation have a very random orientation, then it may be desirable to rely upon brushing rather than simple rolling to achieve the desired predominant orientations.
  • a simple form of apparatus for producing a pattern of areas having one predominant non-perpendicular orientation and areas having a different predominant non-perpendicular orientation comprises a stencil (ie a perforated band or roller) and means in the stencil capable of orienting separately fibres in areas corresponding to the apertures of the stencil.
  • a stencil ie a perforated band or roller
  • means in the stencil capable of orienting separately fibres in areas corresponding to the apertures of the stencil.
  • the fibres contacted by the solid areas of the stencil are oriented such that they incline toward the north in a given rug lieing in a given position
  • the fibres in areas corresponding to the perforations in the stencil are oriented such that they incline toward the south.
  • all the fibres in the surface may be deflected in one direction by brush ing or other means, but then fibres in parts only of the surface may be reoriented by the orienting means within the stencil.
  • the orienting means comprise brush bristles that may be moved relative to the stencil.
  • a cylindrical brush may be mounted coaxially with the stencil for rotation independent of the stencil and may have its bristles extending almost to or into the apertures of the stencil.
  • Normally brush bristles or other orienting means in the stencil do not extend out through the apertures, at least to any significant extent, but bring about orientation only of fibres that extend into the apertures.
  • Suitable brush bristles are usually fairly soft, for example having characteristics similar to those of a conventional personal hairbrush.
  • the pressure between the stencil and the product being treated is generally very low.
  • the roller or stencil is normally positioned so as to contact only those parts of the fibres that extend above the adhesive carried on the substrate, and, for the production of products of optimum appearance, it is essential to ensure that the stencil does not squeeze the adhesive with the result that the entire length of the flocked fibres would become embedded within the adhesive and the fine pile desired on the product would be destroyed.
  • the laying conditions should be such that the fibres do not to 4 any substantial extent become further embedded in the adhesive.
  • the substrate is of fibrous material. i.e., is a textile or paper substrate, as such substrates are generally more suitable than continuous plastics films.
  • suitable substrates are woven, knitted and non woven fabrics made from natural or synthetic fibres, and also paper.
  • Binders that can be used include any suitable flocking adhesives. Examples are acrylic binders. vinyl chloride homopolymer or copolymer plastisols and polyurethane binders. Generally they are binders that can be applied from solution or dispersion in very fluid form and can then be solidified by heating at moderate temperatures, for example below C, the solidification either being brought about solely by evaporation of solvent or dispersant or being brought about also by crosslinking or other chemical curing or other means.
  • Fibres that can be flocked include cotton, rayon, nylon, acrylic and polyester fibres. They can be precision cut fibres or ground fibres or mixtures thereof. They can be applied by any suitable method of flocking, for example electrostatic flocking or by mechanical flocking.
  • Typical fibre lengths are 0.1 to 5 mm, preferably 0.3 to 3 mm, most preferably below l.5 mm.
  • Typical deniers are 0.3 to 30 denier, preferably 0.5 to 20 denier.
  • the fibre density is usually high-cg. 10 to 15% of the theoretical maximum for close packed cylinders.
  • FIG. 1 illustrates in side view diagrammatically an apparatus being used for carrying out the method of the invention
  • FIG. 2 is a plan view of the roller illustrated in FIG. I.
  • FIG. 3 is a longitudinal cross section ofa product according to the invention, for example obtainable by apparatus similar to that shown in FIGS. 1 and 2.
  • the apparatus in FIG. 1 comprises a hollow cylinder 1 made of thin sheet material, for example metal, mounted on a central shaft 2.
  • the surface of the cylin der has a number of apertures 3 cut in it so that the cylinder is a stencil.
  • Concentric with the cylinder and mounted on a sleeve 4 over the central shaft 2 is a cylindrical soft brush 5.
  • the bristles of this brush are of such a length that they are approximately flush with the outside surface of the cylinder and thus protrude into the apertures 3.
  • the apparatus also includes means for rotating the brush and the cylinder independently of one another.
  • the cylinder 1 is mounted above a flat table 6 or any other suitable support, eg a roller.
  • Flocked material 7 (for example made by conventional electrostatic flocking) comprising a substrate 8 and fibres 9 substantially vertical to the substrate is led to between cylinder I and the table 6 directly from the flocking operation, while the adhesive on the substrate 8 is still wet.
  • the length of the fibres is greatly exaggerated in FIG. 1).
  • the cylinder rotates in the direction of the arrow at such a speed that its peripheral linear velocity is identical to that of the material 8 as the material passes beneath it.
  • the cylinder presses the tips of the flock lightly in such a manner that the flock in all areas except in the apertures is laid in the direction opposite to the direction of movement of the material by the surface of the cylinder.
  • the flock would. in the absence of the brush, retain its vertical orientation.
  • the brush 5 is provided and this is rotated at a considerably higher speed that the cylinder, but in the same direction as the cylinder, and this causes the flock in the positions of the apertures to be deflected in the direction of movement of the material.
  • the fabric leaving the cylinder has the fibres over the majority of the surface deflected in one direction while the fibres in the areas corresponding to the apertures 3 are orientated in the opposite direction.
  • the fibres are anchored in the provided orientations.
  • the resultant product comprises a textile base 8 carrying adhesive and fibres 9a oriented in one direction and fibres 9b parallel to these but oriented in the opposite direction.
  • a typical angle of orientation is to the plane of the surface.
  • a further process, for producing striped effects involves the use of a rotating brush which first lays all the flock in one direction. This is followed by a second brush operating through a fixed stencil, which rotates in the opposite direction and reorientates alternate stripes in a direction opposite to the original lay of the flock. Alternatively, the second brush and stencil may be replaced by a suitably profiled brush.
  • a further method of producing striped effects involves the use of complementary profiled brushes rotating in opposite directions.
  • EXAMPLE I A plain weave cotton cloth weighing about 5 ounces per square yard is spread with a thickened, cross-linking acrylic adhesive (sold under the trade name Primal HA8) at an application weight of about 10 ounces per square yard (wet weight), i.e., 4 ounces per square yard dry weight.
  • Precision cut nylon flock of length 1 mm and denier 3, is electrostatically deposited on the adhesive.
  • the flocked material is then passed through the apparatus illustrated at a rate of 6 feet per minute.
  • the cylinder has a diameter of 6 inches and rotates with a peripheral velocity the same as the rate of movement of the fabric.
  • the brush rotates at a peripheral velocity of 24 ft/min.
  • the fabric is then led through a curing oven for 5 minutes at l40C.
  • the finished product is suitable for use as an upholstering material.
  • EXAMPLE 2 A plain weave cotton cloth weighing about 3% oz. per square yard is spread with a thickened cross linking acrylic adhesive (sold under the trade name Primal K87) at a wet application weight of about 10 oz./sq. yd. (4 ounces per square yard dry weight).
  • Precision cut rayon flock of length 0.5 mm and 0.5 denier is electrostatically deposited at a weight of 2 oz. per sq. yd. onto the adhesive.
  • the flocked material then passes under a rotating profiled brush which lays part of the flocked surface in one direction and then under a complementary profiled brush, rotating in the opposite direction to the first, which lays the remaining flock to give a striped effect.
  • the fabric is led through a curing oven for 5 minutes at 140C.
  • the finished products is suit able for use as a garment material.
  • EXAMPLE 3 A wallpaper base of weight 2% oz. per. sq. yd. is coated with a PVC plastisol adhesive at an application weight of approximately 3 oz. per sq. yd. Precision cut rayon flock of length 1 mm and 4% denier is electrostatically deposited onto the adhesive at a weight of 2% oz. per sq. yd.
  • the flocked material is then passed through the apparatus illustrated in FIG. 1 under the conditions of Example 1. The material is then passed through a curing oven for 3 minutes at C. The finished product is suitable for use as a wall covering.
  • flocked prod ucts can be made, for example other upholstery cloths. or garment materials, carpets, shoe materials or curtain fabrics.
  • a method of making a flocked product comprising a substrate having bonded to its surface a layer of flocked fibres which are substantially linear and which, in different parts of the surface, have different predominant non-perpendicular orientations, said method comprising the steps of:
  • the separately movable orienting means comprise a rotatable brush whose axis is parallel with the axis of the stencil and whose bristles extend to but not beyond the perforations where they are in contact with the product and which rotates at a speed faster than the stencil in the same direction as the stencil.
  • fibres are precision cut flock fibres.
  • a method of making a flocked product comprising a substrate having bonded to its surface a layer of flocked fibres which are substantially linear and which, in different parts of the surface, have different predominant non-perpendicular orientations, said method comprising the steps of:
  • Apparatus comprising a support for sheet material
  • a stencil having openings in the surface thereof rotat 8 able in contact with sheet material carried on the support, and separately movable orienting means contained in the stencil for orienting fibres at the openings in the surface of the stencil.
  • the separately movable orienting means comprise a rotatable brush whose axis is parallel with the stencil. whose bristles extend to but not substantially beyond the perforations in the stencil surface where they may contact the sheet material on the support, and which is rotatable at a speed faster than the stencil in the same direction as the stencil.
  • Apparatus according to claim 7 additionally comprising means for applying a fluid binder to the sheet material, means for flocking fibres onto the fluid binder before the sheet material contacts the stencil. and means for hardening the binder after the sheet mate rial has contacted the stencil.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Carpets (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatment Of Fiber Materials (AREA)
US401790A 1972-10-03 1973-09-28 Flocked products and their manufacture Expired - Lifetime US3917883A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4558872A GB1428138A (pl) 1972-10-03 1972-10-03

Publications (1)

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US3917883A true US3917883A (en) 1975-11-04

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US401790A Expired - Lifetime US3917883A (en) 1972-10-03 1973-09-28 Flocked products and their manufacture

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US (1) US3917883A (pl)
JP (1) JPS5715232B2 (pl)
BE (1) BE805560A (pl)
CA (1) CA997259A (pl)
DE (1) DE2349194A1 (pl)
ES (1) ES419247A1 (pl)
FR (1) FR2201656A5 (pl)
GB (1) GB1428138A (pl)
IE (1) IE38453B1 (pl)
IT (1) IT996226B (pl)
NL (1) NL175443C (pl)
SE (1) SE410799B (pl)
ZA (1) ZA737472B (pl)

Cited By (43)

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US4062093A (en) * 1972-10-24 1977-12-13 United Merchants And Manufacturers, Inc. Apparatus for texturizing flocked fabric
WO1981001905A1 (en) * 1979-12-26 1981-07-09 Minnesota Mining & Mfg Recording diskette having flocked-fiber wiping fabric and method of making
US4362773A (en) * 1979-06-26 1982-12-07 Takiron Co., Ltd. Flocked foam with embossed pattern
US4417291A (en) * 1979-12-26 1983-11-22 Minnesota Mining And Manufacturing Company Recording diskette having flocked-fiber wiping fabric
US4623572A (en) * 1983-08-24 1986-11-18 Flachglas Ag Method and apparatus for producing textured napped surfaces
US4961896A (en) * 1988-11-04 1990-10-09 Cadillac Products, Inc. Method of making simulated fabric
US5308009A (en) * 1992-06-11 1994-05-03 Fuji Photo Film Co., Ltd. Photographic film cassette and light-trapping method for the same
US5510143A (en) * 1989-09-06 1996-04-23 Microfibres, Inc. Method and apparatus for impressing a pattern on flocked materials
US5543195A (en) * 1994-01-12 1996-08-06 Squires; William J. Flocked woven fabric with flattened flock fibers
US5756180A (en) * 1994-01-12 1998-05-26 Squires; William J. Flocked fabric suitable as outerwear
US5863633A (en) * 1994-01-12 1999-01-26 Squires; William J. Flocked fabric with water resistant film
US6214141B1 (en) * 1998-11-02 2001-04-10 John Chinung Kim Decorative flocking techniques
US6247215B1 (en) 1996-04-02 2001-06-19 Microfibres, Inc. Printed flocked pile fabric and method for making same
US20020009571A1 (en) * 2000-07-24 2002-01-24 Abrams Louis Brown Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film
US20030151206A1 (en) * 2001-10-25 2003-08-14 Smith Walter J. Method, apparatus and system for creating a brush seal
US20030186019A1 (en) * 2000-07-24 2003-10-02 High Voltage Graphics, Inc. Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film
US6634070B2 (en) * 2001-08-03 2003-10-21 Milliken & Company Multi-colored materials and method of making same
US20040173969A1 (en) * 2001-10-25 2004-09-09 Smith Walter J. Turbine brush seal
US20050005471A1 (en) * 2003-07-10 2005-01-13 Kung-Sheng Pan Flocked footwear
US20050046089A1 (en) * 1999-05-21 2005-03-03 Microfibres, Inc. Systems and methods for air embossing utilizing improved air lances
US20050053758A1 (en) * 2001-10-25 2005-03-10 Smith Walter J. Method, apparatus and system for creating a brush seal
US20050268407A1 (en) * 2004-05-26 2005-12-08 Abrams Louis B Process for high and medium energy dye printing a flocked article
US20070025785A1 (en) * 2005-07-27 2007-02-01 Brother Kogyo Kabushiki Kaisha Cleaning member for photosensitive drum
US20070022548A1 (en) * 2005-08-01 2007-02-01 High Voltage Graphics, Inc. Process for heat setting polyester fibers for sublimation printing
US7229680B1 (en) 1999-09-21 2007-06-12 Microfibres, Inc. Realistically textured printed flocked fabrics and methods for making the fabrics
US20080003399A1 (en) * 2005-12-07 2008-01-03 High Voltage Graphics, Inc. Wet-on-wet method for forming flocked adhesive article
US20080050548A1 (en) * 2005-07-28 2008-02-28 High Voltage Graphics, Inc. Decorative article with control shrinkage carrier
US7393576B2 (en) 2004-01-16 2008-07-01 High Voltage Graphics, Inc. Process for printing and molding a flocked article
US20080176089A1 (en) * 2007-01-24 2008-07-24 Lee Gi-Bong Wallpaper type decoration panel having decoration pattern of unevenness form
US7410682B2 (en) 2002-07-03 2008-08-12 High Voltage Graphics, Inc. Flocked stretchable design or transfer
US7465485B2 (en) * 2003-12-23 2008-12-16 High Voltage Graphics, Inc. Process for dimensionalizing flocked articles or wear, wash and abrasion resistant flocked articles
US20090308309A1 (en) * 2008-06-13 2009-12-17 Mohamed Abdel Aziz Flocked applicator and method of making
US7749589B2 (en) 2005-09-20 2010-07-06 High Voltage Graphics, Inc. Flocked elastomeric articles
US7799164B2 (en) 2005-07-28 2010-09-21 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
US8007889B2 (en) 2005-04-28 2011-08-30 High Voltage Graphics, Inc. Flocked multi-colored adhesive article with bright lustered flock and methods for making the same
US8206800B2 (en) 2006-11-02 2012-06-26 Louis Brown Abrams Flocked adhesive article having multi-component adhesive film
US8354050B2 (en) 2000-07-24 2013-01-15 High Voltage Graphics, Inc. Co-molded direct flock and flock transfer and methods of making same
US8475905B2 (en) 2007-02-14 2013-07-02 High Voltage Graphics, Inc Sublimation dye printed textile
US9012005B2 (en) 2009-02-16 2015-04-21 High Voltage Graphics, Inc. Flocked stretchable design or transfer including thermoplastic film and method for making the same
US9144285B2 (en) 2012-08-27 2015-09-29 Goody Products, Inc. Hair accessories and methods for their manufacture
US9175436B2 (en) 2010-03-12 2015-11-03 High Voltage Graphics, Inc. Flocked articles having a resistance to splitting and methods for making the same
US9193214B2 (en) 2012-10-12 2015-11-24 High Voltage Graphics, Inc. Flexible heat sealable decorative articles and method for making the same
US11524520B2 (en) * 2019-02-18 2022-12-13 Diamond Art Club, Llc Canvas flocking diamond picture

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DE4300150A1 (de) * 1993-01-08 1994-07-14 Coronet Werke Gmbh Verfahren zur Herstellung eines textilen Bodenbelags
DE4300147A1 (de) * 1993-01-08 1994-07-14 Coronet Werke Gmbh Verfahren zur Herstellung von textilem Belagmaterial
DE4322871A1 (de) * 1993-07-09 1995-01-12 Coronet Werke Gmbh Mittel zum Reinigen oder Behandeln von Oberflächen und Verfahren zu ihrer Herstellung
CN105082713B (zh) * 2014-05-12 2018-11-13 唯亚威通讯技术有限公司 包含磁性薄片的光学可变装置

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US3171484A (en) * 1959-11-18 1965-03-02 Alamac Knitting Mills Inc Pile fabrics

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US4062093A (en) * 1972-10-24 1977-12-13 United Merchants And Manufacturers, Inc. Apparatus for texturizing flocked fabric
US4362773A (en) * 1979-06-26 1982-12-07 Takiron Co., Ltd. Flocked foam with embossed pattern
WO1981001905A1 (en) * 1979-12-26 1981-07-09 Minnesota Mining & Mfg Recording diskette having flocked-fiber wiping fabric and method of making
US4417291A (en) * 1979-12-26 1983-11-22 Minnesota Mining And Manufacturing Company Recording diskette having flocked-fiber wiping fabric
US4623572A (en) * 1983-08-24 1986-11-18 Flachglas Ag Method and apparatus for producing textured napped surfaces
US4961896A (en) * 1988-11-04 1990-10-09 Cadillac Products, Inc. Method of making simulated fabric
US5510143A (en) * 1989-09-06 1996-04-23 Microfibres, Inc. Method and apparatus for impressing a pattern on flocked materials
US5308009A (en) * 1992-06-11 1994-05-03 Fuji Photo Film Co., Ltd. Photographic film cassette and light-trapping method for the same
US5543195A (en) * 1994-01-12 1996-08-06 Squires; William J. Flocked woven fabric with flattened flock fibers
US5756180A (en) * 1994-01-12 1998-05-26 Squires; William J. Flocked fabric suitable as outerwear
US5863633A (en) * 1994-01-12 1999-01-26 Squires; William J. Flocked fabric with water resistant film
US6247215B1 (en) 1996-04-02 2001-06-19 Microfibres, Inc. Printed flocked pile fabric and method for making same
US6350504B1 (en) * 1996-04-02 2002-02-26 Microfibres, Inc. Printed flocked pile fabric and method for making same
US6214141B1 (en) * 1998-11-02 2001-04-10 John Chinung Kim Decorative flocking techniques
US7507364B2 (en) 1999-05-21 2009-03-24 Microfibres, Inc. Systems and methods for air embossing utilizing improved air lances
US20050046089A1 (en) * 1999-05-21 2005-03-03 Microfibres, Inc. Systems and methods for air embossing utilizing improved air lances
US7229680B1 (en) 1999-09-21 2007-06-12 Microfibres, Inc. Realistically textured printed flocked fabrics and methods for making the fabrics
US7390552B2 (en) 2000-07-24 2008-06-24 High Voltage Graphics, Inc. Flocked transfer and article of manufacturing including the flocked transfer
US20020009571A1 (en) * 2000-07-24 2002-01-24 Abrams Louis Brown Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film
US7402222B2 (en) 2000-07-24 2008-07-22 High Voltage Graphics, Inc. Flocked transfer and article of manufacture including the flocked transfer
US7381284B2 (en) 2000-07-24 2008-06-03 High Voltage Graphics, Inc. Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film
US8354050B2 (en) 2000-07-24 2013-01-15 High Voltage Graphics, Inc. Co-molded direct flock and flock transfer and methods of making same
US20030186019A1 (en) * 2000-07-24 2003-10-02 High Voltage Graphics, Inc. Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film
US7632371B2 (en) 2000-07-24 2009-12-15 High Voltage Graphics, Inc. Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film
US20040020020A1 (en) * 2001-08-03 2004-02-05 Willauer Howard C. Multi-colored materials and method of making same
US6634070B2 (en) * 2001-08-03 2003-10-21 Milliken & Company Multi-colored materials and method of making same
US20050053758A1 (en) * 2001-10-25 2005-03-10 Smith Walter J. Method, apparatus and system for creating a brush seal
US20030151206A1 (en) * 2001-10-25 2003-08-14 Smith Walter J. Method, apparatus and system for creating a brush seal
US20040173969A1 (en) * 2001-10-25 2004-09-09 Smith Walter J. Turbine brush seal
US7410682B2 (en) 2002-07-03 2008-08-12 High Voltage Graphics, Inc. Flocked stretchable design or transfer
US20050005471A1 (en) * 2003-07-10 2005-01-13 Kung-Sheng Pan Flocked footwear
US7465485B2 (en) * 2003-12-23 2008-12-16 High Voltage Graphics, Inc. Process for dimensionalizing flocked articles or wear, wash and abrasion resistant flocked articles
US7393576B2 (en) 2004-01-16 2008-07-01 High Voltage Graphics, Inc. Process for printing and molding a flocked article
US20050268407A1 (en) * 2004-05-26 2005-12-08 Abrams Louis B Process for high and medium energy dye printing a flocked article
US8007889B2 (en) 2005-04-28 2011-08-30 High Voltage Graphics, Inc. Flocked multi-colored adhesive article with bright lustered flock and methods for making the same
US20070025785A1 (en) * 2005-07-27 2007-02-01 Brother Kogyo Kabushiki Kaisha Cleaning member for photosensitive drum
US7689155B2 (en) * 2005-07-27 2010-03-30 Brother Kogyo Kabushiki Kaisha Cleaning member for photosensitive drum
US7799164B2 (en) 2005-07-28 2010-09-21 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
US20080050548A1 (en) * 2005-07-28 2008-02-28 High Voltage Graphics, Inc. Decorative article with control shrinkage carrier
USRE45802E1 (en) 2005-07-28 2015-11-17 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
US20070022548A1 (en) * 2005-08-01 2007-02-01 High Voltage Graphics, Inc. Process for heat setting polyester fibers for sublimation printing
US7749589B2 (en) 2005-09-20 2010-07-06 High Voltage Graphics, Inc. Flocked elastomeric articles
US8168262B2 (en) 2005-09-20 2012-05-01 High Voltage Graphics, Inc. Flocked elastomeric articles
US20080003399A1 (en) * 2005-12-07 2008-01-03 High Voltage Graphics, Inc. Wet-on-wet method for forming flocked adhesive article
US8206800B2 (en) 2006-11-02 2012-06-26 Louis Brown Abrams Flocked adhesive article having multi-component adhesive film
US20080176089A1 (en) * 2007-01-24 2008-07-24 Lee Gi-Bong Wallpaper type decoration panel having decoration pattern of unevenness form
US8475905B2 (en) 2007-02-14 2013-07-02 High Voltage Graphics, Inc Sublimation dye printed textile
US20090308309A1 (en) * 2008-06-13 2009-12-17 Mohamed Abdel Aziz Flocked applicator and method of making
US9012005B2 (en) 2009-02-16 2015-04-21 High Voltage Graphics, Inc. Flocked stretchable design or transfer including thermoplastic film and method for making the same
US9175436B2 (en) 2010-03-12 2015-11-03 High Voltage Graphics, Inc. Flocked articles having a resistance to splitting and methods for making the same
US9144285B2 (en) 2012-08-27 2015-09-29 Goody Products, Inc. Hair accessories and methods for their manufacture
US9193214B2 (en) 2012-10-12 2015-11-24 High Voltage Graphics, Inc. Flexible heat sealable decorative articles and method for making the same
US11524520B2 (en) * 2019-02-18 2022-12-13 Diamond Art Club, Llc Canvas flocking diamond picture

Also Published As

Publication number Publication date
ZA737472B (en) 1974-08-28
JPS5715232B2 (pl) 1982-03-29
IE38453L (en) 1974-04-03
DE2349194A1 (de) 1974-04-11
CA997259A (en) 1976-09-21
SE410799B (sv) 1979-11-05
ES419247A1 (es) 1976-06-16
NL175443C (nl) 1984-11-01
IE38453B1 (en) 1978-03-15
AU6092473A (en) 1975-04-10
BE805560A (fr) 1974-04-02
NL175443B (nl) 1984-06-01
FR2201656A5 (pl) 1974-04-26
IT996226B (it) 1975-12-10
NL7313391A (pl) 1974-04-05
JPS4993659A (pl) 1974-09-05
GB1428138A (pl) 1976-03-17

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