US3900669A - Pressure-sensitive recording sheet with microcapsules having polyurea walls - Google Patents
Pressure-sensitive recording sheet with microcapsules having polyurea walls Download PDFInfo
- Publication number
- US3900669A US3900669A US298888A US29888872A US3900669A US 3900669 A US3900669 A US 3900669A US 298888 A US298888 A US 298888A US 29888872 A US29888872 A US 29888872A US 3900669 A US3900669 A US 3900669A
- Authority
- US
- United States
- Prior art keywords
- pressure
- recording sheet
- polyamine
- sensitive recording
- adduct
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002396 Polyurea Polymers 0.000 title claims abstract 8
- 239000003094 microcapsule Substances 0.000 title claims abstract 3
- 229920000768 polyamine Polymers 0.000 claims abstract 25
- 239000005056 polyisocyanate Substances 0.000 claims abstract 22
- 229920001228 polyisocyanate Polymers 0.000 claims abstract 22
- 239000012948 isocyanate Substances 0.000 claims abstract 8
- 150000002513 isocyanates Chemical class 0.000 claims abstract 8
- 239000000126 substance Substances 0.000 claims abstract 7
- 238000006243 chemical reaction Methods 0.000 claims abstract 5
- 239000000463 material Substances 0.000 claims abstract 3
- 150000001875 compounds Chemical class 0.000 claims 13
- 239000007788 liquid Substances 0.000 claims 4
- 239000004593 Epoxy Chemical class 0.000 claims 3
- 125000003277 amino group Chemical group 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 2
- 125000005442 diisocyanate group Chemical group 0.000 claims 2
- 229920005862 polyol Polymers 0.000 claims 2
- 150000003077 polyols Chemical class 0.000 claims 2
- 229920006295 polythiol Polymers 0.000 claims 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 claims 1
- -1 1,3-propylene napthalene Chemical compound 0.000 claims 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 claims 1
- SIZPGZFVROGOIR-UHFFFAOYSA-N 1,4-diisocyanatonaphthalene Chemical compound C1=CC=C2C(N=C=O)=CC=C(N=C=O)C2=C1 SIZPGZFVROGOIR-UHFFFAOYSA-N 0.000 claims 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims 1
- KTTUOEDORYKFIS-UHFFFAOYSA-N 1,6-bis(isocyanatosulfanyl)hexane Chemical compound O=C=NSCCCCCCSN=C=O KTTUOEDORYKFIS-UHFFFAOYSA-N 0.000 claims 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 150000004982 aromatic amines Chemical group 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 claims 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- 230000001804 emulsifying effect Effects 0.000 claims 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- NTNWKDHZTDQSST-UHFFFAOYSA-N naphthalene-1,2-diamine Chemical compound C1=CC=CC2=C(N)C(N)=CC=C21 NTNWKDHZTDQSST-UHFFFAOYSA-N 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 claims 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- 239000003463 adsorbent Substances 0.000 abstract 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Color Printing (AREA)
- Focusing (AREA)
- Camera Bodies And Camera Details Or Accessories (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP46083483A JPS4849509A (enrdf_load_stackoverflow) | 1971-10-21 | 1971-10-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
US3900669A true US3900669A (en) | 1975-08-19 |
US3900669B1 US3900669B1 (enrdf_load_stackoverflow) | 1987-08-04 |
Family
ID=13803704
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US298888A Expired - Lifetime US3900669A (en) | 1971-10-21 | 1972-10-19 | Pressure-sensitive recording sheet with microcapsules having polyurea walls |
US00302047A Expired - Lifetime US3810209A (en) | 1971-10-21 | 1972-10-30 | Camera positioning apparatus |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00302047A Expired - Lifetime US3810209A (en) | 1971-10-21 | 1972-10-30 | Camera positioning apparatus |
Country Status (6)
Country | Link |
---|---|
US (2) | US3900669A (enrdf_load_stackoverflow) |
JP (1) | JPS4849509A (enrdf_load_stackoverflow) |
BE (1) | BE790373A (enrdf_load_stackoverflow) |
DE (1) | DE2251381A1 (enrdf_load_stackoverflow) |
ES (1) | ES407671A1 (enrdf_load_stackoverflow) |
GB (1) | GB1396543A (enrdf_load_stackoverflow) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4046741A (en) * | 1976-02-17 | 1977-09-06 | Stauffer Chemical Company | Post-treatment of polyurea microcapsules |
DE2808904A1 (de) * | 1977-03-03 | 1978-09-07 | Mead Corp | Verfahren zur herstellung einer druckempfindlichen kohlefreien kopierfolie (copy sheet) unter verwendung von mikrokapseln, die in einem durch bestrahlung haertbaren binder in situ gebildet werden |
US4170483A (en) * | 1975-08-28 | 1979-10-09 | The Mead Corporation | Process for the production of self-contained carbonless copy record sheets and coating composition for use therein |
US4191404A (en) * | 1977-03-03 | 1980-03-04 | The Mead Corporation | Process for producing a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder |
US4200667A (en) * | 1977-03-03 | 1980-04-29 | The Mead Corporation | Process for producing a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder |
US4303719A (en) * | 1980-07-29 | 1981-12-01 | Vassiliades Anthony E | Chromogenic copy system |
US4321093A (en) * | 1980-04-04 | 1982-03-23 | The Standard Register Company | Moisture-set color developer ink |
US4324817A (en) * | 1979-07-26 | 1982-04-13 | Bayer Aktiengesellschaft | Process for making carbonless copying paper |
US4435340A (en) | 1981-01-27 | 1984-03-06 | Kanzaki Paper Manufacturing Company Limited | Process for preparing microcapsules for pressure sensitive manifold paper |
US4483974A (en) * | 1982-08-18 | 1984-11-20 | Bayer Aktiengesellschaft | Process for the production of stabilized polyisocyanates, the polyisocyanates so-stabilized and their use in the production of polyurethanes |
US4547429A (en) * | 1983-09-17 | 1985-10-15 | Cassella Aktiengesellschaft | Encapsulated salts of acid particles wherein the salt particles are surrounded by a polyurethane/polyurea casing |
US4847152A (en) * | 1986-10-22 | 1989-07-11 | Bayer Aktiengesellschaft | Microcapsules with improved polyurea walls |
US4877706A (en) * | 1988-05-25 | 1989-10-31 | Xerox Corporation | Single component cold pressure fixable encapsulated toner compositions |
US4891245A (en) * | 1986-03-21 | 1990-01-02 | Koh-I-Noor Rapidograph, Inc. | Electrophoretic display particles and a process for their preparation |
US4945121A (en) * | 1987-08-18 | 1990-07-31 | Koh-I-Noor Radiograph, Inc. | Thermosetting dyed latex colorant dispersions |
US4970031A (en) * | 1988-06-02 | 1990-11-13 | Nok Corporation | Process for preparing microcapsules with controlled-release |
US5204184A (en) * | 1990-09-10 | 1993-04-20 | The Standard Register Company | Microencapsulation using tertiary aliphatic isocyanate capsule wall material |
US5225118A (en) * | 1990-08-15 | 1993-07-06 | Boise Cascade Corporation | Process for manufacturing polyurea microcapsules and product therefrom |
US5330566A (en) * | 1992-02-24 | 1994-07-19 | Appleton Papers Inc. | Capsule coating |
DE102016006320A1 (de) | 2016-05-25 | 2017-11-30 | Carl Freudenberg Kg | Fixierbare Flächengebilde |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2738509A1 (de) * | 1977-08-26 | 1979-03-08 | Bayer Ag | Reaktionsdurchschreibepapiere |
JPS6026039B2 (ja) * | 1977-09-05 | 1985-06-21 | 三菱製紙株式会社 | 自己発色型感圧記録紙 |
DE2753767C2 (de) * | 1977-12-02 | 1987-01-22 | Bayer Ag, 5090 Leverkusen | Reaktionsdurchschreibepapier sowie Verfahren zu dessen Herstellung |
GB2058111B (en) * | 1979-06-08 | 1983-08-03 | Kanzaki Paper Mfg Co Ltd | Microcapsule dispersions |
DE3020148A1 (de) * | 1980-05-28 | 1981-12-03 | Bayer Ag, 5090 Leverkusen | Konzentrierte mikrokapselsuspensionen fuer reaktionsdurchschreibepapiere |
JPS583898A (ja) * | 1981-06-30 | 1983-01-10 | Kanzaki Paper Mfg Co Ltd | 感圧複写紙用マイクロカプセルの製造方法 |
JPS57140638A (en) * | 1981-01-27 | 1982-08-31 | Kanzaki Paper Mfg Co Ltd | Preparation of microcapsule for pressure sensitive copy paper |
US4681806A (en) * | 1986-02-13 | 1987-07-21 | Minnesota Mining And Manufacturing Company | Particles containing releasable fill material and method of making same |
JPH0619555B2 (ja) * | 1986-03-10 | 1994-03-16 | 富士写真フイルム株式会社 | 感光性マイクロカプセルの製造方法 |
CA2012585A1 (en) * | 1989-04-14 | 1990-10-14 | The Mead Corporation | Preparing high solids cb printing composition by microencapsulation with printing vehicle as continuous phase |
DE4130743A1 (de) * | 1991-09-16 | 1993-03-18 | Bayer Ag | Mikrokapseln aus isocyanaten mit polyethylenoxidhaltigen gruppen |
US5825502A (en) * | 1996-10-09 | 1998-10-20 | Teach Screen Software Gmbh | Device for close-up photography of surfaces |
WO2001045627A1 (en) | 1999-12-23 | 2001-06-28 | Hill-Rom Services, Inc. | Surgical theater system |
DE102008002145A1 (de) | 2008-06-02 | 2009-12-03 | Symrise Gmbh & Co. Kg | Kapsel mit organisch-anorganischer Hybridwand |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3016308A (en) * | 1957-08-06 | 1962-01-09 | Moore Business Forms Inc | Recording paper coated with microscopic capsules of coloring material, capsules and method of making |
US3429827A (en) * | 1962-11-23 | 1969-02-25 | Moore Business Forms Inc | Method of encapsulation |
US3619238A (en) * | 1968-07-15 | 1971-11-09 | Fuji Photo Film Co Ltd | Pressure sensitive copying paper |
US3660304A (en) * | 1968-06-04 | 1972-05-02 | Fuji Photo Film Co Ltd | Method of producing oily liquid-containing microcapsules |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1453843A (en) * | 1921-09-22 | 1923-05-01 | Roy W Johnston | Focusing mechanism |
US1837704A (en) * | 1928-04-19 | 1931-12-22 | Harrie J Dean | Apparatus for photographing |
US2282768A (en) * | 1940-08-03 | 1942-05-12 | Remington Rand Inc | Copyholder for document photographing cameras |
US2612824A (en) * | 1950-08-09 | 1952-10-07 | Jr Walter F Kroemmelbein | Television photographic device |
-
0
- BE BE790373D patent/BE790373A/xx unknown
-
1971
- 1971-10-21 JP JP46083483A patent/JPS4849509A/ja active Pending
-
1972
- 1972-10-16 ES ES407671A patent/ES407671A1/es not_active Expired
- 1972-10-19 US US298888A patent/US3900669A/en not_active Expired - Lifetime
- 1972-10-19 DE DE2251381A patent/DE2251381A1/de not_active Withdrawn
- 1972-10-20 GB GB4852072A patent/GB1396543A/en not_active Expired
- 1972-10-30 US US00302047A patent/US3810209A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3016308A (en) * | 1957-08-06 | 1962-01-09 | Moore Business Forms Inc | Recording paper coated with microscopic capsules of coloring material, capsules and method of making |
US3429827A (en) * | 1962-11-23 | 1969-02-25 | Moore Business Forms Inc | Method of encapsulation |
US3660304A (en) * | 1968-06-04 | 1972-05-02 | Fuji Photo Film Co Ltd | Method of producing oily liquid-containing microcapsules |
US3619238A (en) * | 1968-07-15 | 1971-11-09 | Fuji Photo Film Co Ltd | Pressure sensitive copying paper |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4170483A (en) * | 1975-08-28 | 1979-10-09 | The Mead Corporation | Process for the production of self-contained carbonless copy record sheets and coating composition for use therein |
US4046741A (en) * | 1976-02-17 | 1977-09-06 | Stauffer Chemical Company | Post-treatment of polyurea microcapsules |
FR2341359A1 (fr) * | 1976-02-17 | 1977-09-16 | Stauffer Chemical Co | Post-traitement de microcapsules de polyuree |
DE2808904A1 (de) * | 1977-03-03 | 1978-09-07 | Mead Corp | Verfahren zur herstellung einer druckempfindlichen kohlefreien kopierfolie (copy sheet) unter verwendung von mikrokapseln, die in einem durch bestrahlung haertbaren binder in situ gebildet werden |
US4191404A (en) * | 1977-03-03 | 1980-03-04 | The Mead Corporation | Process for producing a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder |
US4200667A (en) * | 1977-03-03 | 1980-04-29 | The Mead Corporation | Process for producing a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder |
US4324817A (en) * | 1979-07-26 | 1982-04-13 | Bayer Aktiengesellschaft | Process for making carbonless copying paper |
US4321093A (en) * | 1980-04-04 | 1982-03-23 | The Standard Register Company | Moisture-set color developer ink |
US4303719A (en) * | 1980-07-29 | 1981-12-01 | Vassiliades Anthony E | Chromogenic copy system |
US4435340A (en) | 1981-01-27 | 1984-03-06 | Kanzaki Paper Manufacturing Company Limited | Process for preparing microcapsules for pressure sensitive manifold paper |
US4483974A (en) * | 1982-08-18 | 1984-11-20 | Bayer Aktiengesellschaft | Process for the production of stabilized polyisocyanates, the polyisocyanates so-stabilized and their use in the production of polyurethanes |
US4547429A (en) * | 1983-09-17 | 1985-10-15 | Cassella Aktiengesellschaft | Encapsulated salts of acid particles wherein the salt particles are surrounded by a polyurethane/polyurea casing |
US4891245A (en) * | 1986-03-21 | 1990-01-02 | Koh-I-Noor Rapidograph, Inc. | Electrophoretic display particles and a process for their preparation |
US4847152A (en) * | 1986-10-22 | 1989-07-11 | Bayer Aktiengesellschaft | Microcapsules with improved polyurea walls |
US4945121A (en) * | 1987-08-18 | 1990-07-31 | Koh-I-Noor Radiograph, Inc. | Thermosetting dyed latex colorant dispersions |
US4877706A (en) * | 1988-05-25 | 1989-10-31 | Xerox Corporation | Single component cold pressure fixable encapsulated toner compositions |
US4970031A (en) * | 1988-06-02 | 1990-11-13 | Nok Corporation | Process for preparing microcapsules with controlled-release |
US5225118A (en) * | 1990-08-15 | 1993-07-06 | Boise Cascade Corporation | Process for manufacturing polyurea microcapsules and product therefrom |
US5324584A (en) * | 1990-08-15 | 1994-06-28 | Boise Cascade Corporation | Process for manufacturing polyurea microcapsules and product therefrom |
US5204184A (en) * | 1990-09-10 | 1993-04-20 | The Standard Register Company | Microencapsulation using tertiary aliphatic isocyanate capsule wall material |
US5330566A (en) * | 1992-02-24 | 1994-07-19 | Appleton Papers Inc. | Capsule coating |
DE102016006320A1 (de) | 2016-05-25 | 2017-11-30 | Carl Freudenberg Kg | Fixierbare Flächengebilde |
Also Published As
Publication number | Publication date |
---|---|
US3900669B1 (enrdf_load_stackoverflow) | 1987-08-04 |
ES407671A1 (es) | 1976-02-16 |
US3810209A (en) | 1974-05-07 |
GB1396543A (en) | 1975-06-04 |
JPS4849509A (enrdf_load_stackoverflow) | 1973-07-12 |
BE790373A (fr) | 1973-02-15 |
DE2251381A1 (de) | 1973-04-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3900669A (en) | Pressure-sensitive recording sheet with microcapsules having polyurea walls | |
US4193889A (en) | Microencapsulation with modified aliphatic polyisocyanates | |
US4021595A (en) | Pressure sensitive recording sheet | |
US3394165A (en) | Stabilized methylenebis-(phenyl isocyanate) compositions | |
US6020066A (en) | Microcapsules using iminooxadiazinedione polyisocyanates | |
US3394164A (en) | Stabilized methylenebis-(phenyl isocyanate) compositions | |
US4428983A (en) | Process for the production of microcapsules | |
US3124605A (en) | Biuret polyisocyanates | |
US4738898A (en) | Microencapsulation by interfacial polyaddition | |
US4667008A (en) | Process for the production of solid polyisocyanates of retarded reactivity, polymer-coated, finely divided polyisocyanates and their use | |
KR880011277A (ko) | 폴리우레아를 반응사출성형하기 위한 개선된 초기 중합체 조성물 | |
EP0174724B1 (en) | Microencapsulation of polyisocyanates by interchange of emulsions | |
DE3585567D1 (de) | Aktivierte anionische polymerisation von lactamen. | |
US4876290A (en) | Microencapsulation by interfacial polyaddition | |
US3691112A (en) | Process for the production of polyamide foams and elastomers from amino-crotonic acid esters | |
US3248424A (en) | Process for the production of amino ureas | |
GB1596085A (en) | Polyurethane adhesive composition for bonding substrates | |
US3975428A (en) | Aromatic amines formed by the reaction of isatoic acid anhydride with compounds containing at least one tertiary nitrogen atom and at least two hydroxyl groups | |
US3239480A (en) | Polyurethanes synthesized with the aid of carboxylic acid salts | |
CA1178054A (en) | Process for preparing microcapsules for pressure sensitive manifold paper | |
US4530905A (en) | Crosslinked gelatin foams | |
US4120518A (en) | Carbonless copying papers | |
US4874832A (en) | Microcapsules having polyurethane walls | |
EP0303183A3 (de) | Verfahren zur Herstellung von in der Wärme härtbaren Einkomponenten-Polyurethan-Polyharnstoff-Systemen | |
US3222303A (en) | Tertiary aminophenol catalytic polyurethane production |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RR | Request for reexamination filed |
Effective date: 19860811 |
|
B1 | Reexamination certificate first reexamination |