US3873458A - Resin-containing lubricant coatings - Google Patents

Resin-containing lubricant coatings Download PDF

Info

Publication number
US3873458A
US3873458A US361727A US36172773A US3873458A US 3873458 A US3873458 A US 3873458A US 361727 A US361727 A US 361727A US 36172773 A US36172773 A US 36172773A US 3873458 A US3873458 A US 3873458A
Authority
US
United States
Prior art keywords
composition
resin
oil
copolymer
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US361727A
Other languages
English (en)
Inventor
Robert E Parkinson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
United States Steel Corp
Original Assignee
United States Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United States Steel Corp filed Critical United States Steel Corp
Priority to US361727A priority Critical patent/US3873458A/en
Priority to GB1913974A priority patent/GB1473235A/en
Priority to DE2422013A priority patent/DE2422013A1/de
Priority to BE144034A priority patent/BE814678A/xx
Priority to IT68563/74A priority patent/IT1011835B/it
Priority to FR7417308A priority patent/FR2229477B1/fr
Priority to CA200,310A priority patent/CA1039704A/en
Priority to JP49056056A priority patent/JPS5027802A/ja
Application granted granted Critical
Publication of US3873458A publication Critical patent/US3873458A/en
Assigned to USX CORPORATION, A CORP. OF DE reassignment USX CORPORATION, A CORP. OF DE MERGER (SEE DOCUMENT FOR DETAILS). Assignors: UNITED STATES STEEL CORPORATION (MERGED INTO)
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/20—Deep-drawing
    • B21D22/201—Work-pieces; preparation of the work-pieces, e.g. lubricating, coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/061—Carbides; Hydrides; Nitrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C10M2201/103—Clays; Mica; Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/16—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/18—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/024—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aromatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/02—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06—Perfluoro polymers
    • C10M2213/062—Polytetrafluoroethylene [PTFE]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating

Definitions

  • larly useful in processes for working of sheet metals comprising a resin capable of forming a layer adhering to the surface, and an oil for forming an upper layer to enhance the lubricating properties on top of and/or partially distributed within the resin layer; and a method of applying both layers of the coating to the metal surface simultaneously from a single aqueous dispersion or emulsion composition.
  • the coating has been found to greatly increase the ability of the metal sheet to withstand severe fabrication processes, such as deep-drawing, without tearing or galling, compared with ordinary lubricating oils or greases.
  • a resinous coating on metal underneath a layer of oil, soap, wax or grease is known to industry as a lubricant system for deep-drawing (e.g., Milbond, H. A. Montgomery Company).
  • this lubricant system must be applied in two step: 1 a resinous coating is applied and dried; (2) the oil or grease is applied in a second operation.
  • Some other lubricant systems use a phosphate or similar conversion coating as the base to hold the lubricant oil or grease. These also are two-step operations in which the metal must first be treated and then the oil applied separately.
  • a one-step method of applying both the resin layer and the oil layer simultaneously from a single aqueous dispersion or emulsion would be advantageous because it would simplify the application process, and may also enhance the lubrication because the more intimate and uniform distribution of the oil phase over and throughout the resin layer.
  • SUMMARY OF THE INVENTION 1 have developed a composition for the purpose of applying a compositie resin/oil lubricant coating on a substrate such as metal sheetsin a single coating operation.
  • this composition When this composition is applied as a thin coating and dried, it separates into two layers'or phases: (a) a tough resin layer tightly adhering to the substrate, and (b) an oil layer or phase, separated from the resin by mutual insolubility, covering the resin layer or dispersed therein.
  • the tough, adherent resin layer provides a barrier against galling ofthe metalunder high pressure forming processes and intimately holds the oil phase that provides a lower coefficient of friction.
  • the ability of this composition to distribute the two components in layers in proper relationship to the substrate in a single operation greatly simplifies the application process.
  • This resin/oil composite lubricant coating has been found to be particularly useful when preapplied and dried on metal sheets as a once-through lubricant for severe metal-forming processes such as deep-drawing, draw-and-iron processes, and roll-forming. (It is not recommended where the lubricant must be continually replaced, as in machine bearings.) In addition to its lubricating properties, this coating provides protection for the metal surface against corrosion and abrasion.
  • My compositions for applying the lubricant coating are aqueous dispersions consisting essentially of a resin phase" and an oil phase" in a' single composition.
  • the resin must be a tough polymer, which is dispersable in an aqueous medium, which has ability to form a film during the drying that adheres strongly to a metal substrate, which is insoluble in the oil phase, and which may easily be dissolved or stripped from the metal surface after use by a process such as alkaline detergent cleaning.
  • the preferred resins for my lubricating composition include ethyleneacrylic acid copolymers, particularly those with high carboxyl content (e.g., 18 to 24 percent) such as Union Carbide Corporations EAA 9300 or EAA 9500. Although either EAA 9300 may be used, a more stable emulsion is achieved with the higher molecular weight EAA 9300 copolymer solution. These copolymer resins may be dissolved in hot aqueous alkali to give a soap-like colloidal solution of the salt formed by a reaction similar to saponification. They remain in colloidal dispersion on cooling to room temperature.
  • the colloidal solution may be applied as a coating that, when dried to drive off the alkali, reconstitutes the original acid copolymer resin on the surface of the substrate.
  • Such coatings have excellent adhesion to metals and are tough, flexible, and water-resistant; and they may be easily removed by redissolving in hot alkaline solutions such as those used as commercial metal cleaners.
  • One advantage to such dispersions of ethylene-acrylic acid copolymers when used in my lubricating composition is that they are themselves excellent emulsifying or dispersing agents for the oil phase and other additives to the composition.
  • the resin phase of my composition may also contain other resins in addition to or instead of the abovementioned ethylene-acrylic acid dispersion.
  • Aqueous dispersions of other copolymers, terpolymers,or ionomers of ethylene with other ethylenically unsaturated acids, such as methacrylic or crotonic acids, or with ethylenically unsaturated esters, such as vinyl acetate, may be substituted for all or part of the ethylene-acrylic acid copolymer dispersion.
  • Preferred esters of the acrylic acid and other ethylenically unsaturated acids are the lower esters of l 4 carbon atoms.
  • polyvinyl alcohol may also be incorporated as a minor portion of the resin phase.
  • Polyvinyl alcohol was found to improve wetting and give a drier (less greasy) coating by encapsulating most of the oil in the resin, which may be advantageous for certain usages.
  • polyvinyl al' cohol has its disadvantages, such as, separation in storage as a gelatinous third-phase in my emulsion, giving coatings with poorer adhesion to the metal substrate, or more difficulty in removal with alkaline cleaners.
  • the second essential component of my lubricating coating composition is the oil phase" which is required to reduce the friction of the lubrication coating.
  • This oil phase may consist of a lubricant oil, by which I mean mineral oil, animal or vegetable oils or fats, fatty-acid soaps, greases, waxes, and other natural or synthetic lubricating materials'or combinations thereof.
  • a lubricant oil by which I mean mineral oil, animal or vegetable oils or fats, fatty-acid soaps, greases, waxes, and other natural or synthetic lubricating materials'or combinations thereof.
  • my composition may contain minor amounts of surfactants, solvents, thickeners, alkalis, and other material to improve the stability, wetting, defoaming, dispersion, viscosity, and coating characteristics of the emulsions and the uniformity, smoothness, thickness, and removability ofdried coatings. Thickness of the coating may also be controlled by varying the amount of water vs. the total nonvolatile concentration of the emulsion, or by the means of application. For severe highpressure metal-forming, it may be desirable to add finely-divided solid lubricants such as graphite, poly carbon monofluoride or molybdenum sulfide powders.
  • finely-divided solid lubricants such as graphite, poly carbon monofluoride or molybdenum sulfide powders.
  • Certain fillers selected for low abrasiveness such as clay, talc, or mica, or oxide pigments may also be dispersed in the emulsion and may be advantageous in certain cases to strengthen the resin barrier layer of the coating. It is also possible to disperse powdered or emulsified polymers with low coefficient of friction, such as nylon or teflon, in the composition. 1 have found that my compositions are particularly effective in maintaining stable dispersions of such powdered solids with little settling in storage.
  • composition for the application of my coating is preferably prepared by predissolving or dispersing the resins in an aqueous medium and then emulsifying or dispersing the oil phase into this resin dispersion by highshear mixing. Minor additions may be blended as desired.
  • the oil phase nonvolatiles are preferably 25 to 75 percent by weight of the total nonvolatiles remaining in the coating after drying, although any amount of oil up to as much as 3 times the amount of resin may be blended in my composition. As little as one percent oil, based on the resin, may be desirable where drier coatings are preferred or where additional oil is being applied over the coating before fabrication.
  • the dispersion of my composition is prepared as a low-viscosity fluid (preferably 50 to 1000 centipoises) that may be easily applied to metal as a thin coating by conventional methods such as roll-coating, brushing, dipping, spraying, etc.
  • the viscosity and concentration of the dispersion may be controlled by the amount of water added or by the addition of fillers, thickeners, or gelling agents to adjust desired thickness of the resulting dried coating. Concentrations of about 19 to 45 percent total resin/oil nonvolatiles in the dispersion have been found to be satisfactory for roll-coating.
  • thin coatings with a dried coating weight in the range of approximately 50 to 350 milligrams per square foot (0.54 to 3.77 grams per square meter) or approximately 0.5 to 3.0 micron thickness, give satisfactory lubricating properties to sheet steel. Heavier coatings up to 25 microns may be desirable for some applications.
  • the coating is dried to evaporate the volatiles, such as water and ammonia. Drying at room temperature (for several hours) may be used, but it is preferred to dry with heat from about 120 C to about 200 C (for less than a minute.) Such heat-drying improves the adhesion of the coating to the metal. Over-heating may make some coatings more difficult to remove in subsequent alkaline cleaning.
  • EXAMPLE 1 (See Table I) An aqueous ammonium solution of an ethyleneacrylic acid copolymer resin (containing about 20 percent acid) was prepared by heating the resin to to 130 C in a pressure vessel, in a slightly more than stoichemetric amounts to ammonium hydroxide with sufficient water to give about 22 percent resin solids. A mixture of surfactants was added to improve the wetting properties, the emulsion stability, and foam reduction of the coating composition but were not essential.
  • the total nonvolatiles were about 41 percent of the solution.
  • This composition when dried on steel sheets, gave a smooth coating with a tough layer of resin adjacent and tightly adhering to the steel, with most of the oil in a separate layer over the resin.
  • coating weights of about mg/ft (1.08 g/m to 350 mg/ft (3.77 g/m the depth of draw was increased 20 to 32 percent (to 0.550 to 0.600 inch) in the Olsen cup test (ASTM A344) compared to an average of about 0.450 inch depth with the same steel with a standard mineral oil lubricant.
  • This lubricant coating was also applied to thin carbon steel sheets (blackplate) and fabricated sucessfully into cans by a drawand-iron process without galling or tearing. Tin plating or special phosphate treatments of the steel have generally been necessary to obtain satisfactory draw-and-iron processing with ordinary lubricants. The coefficient of friction between this coating and steel was 0.077.
  • EXAMPLE 2 Molybdenum sulfide of a very fine particle size (0.35 t average) was added to the composition of Example 1. An excellent dispersion with practically no settling in storage was obtained. The purpose of the addition was to improve resistance to galling under severe highpressure fabrication conditionsv The Olsen cup depth of draw and draw-and-iron results in laboratory tests were essentially the same as Example l. It is expected that the MoS addition may give superior performance under more severe fabrication conditions.
  • EXAMPLE 3 This composition was prepared by dissolving polyvinyl alcohol in hot water and then adding the ethyleneacrylic acid copolymer ammonium solution and emulsifying mixed lard oil and oleic acid into it. This composition gave smooth, adherent, dry coatings in which the oil appeared to be dispered in a matrix of resin. Coating of 52 to 104 milligrams per square foot (0.56 to l.l2 g/m increased the Olsen draw depth by about 13 to 25 percent on stainless steel sheet. Carbon steel blackplate" sheets coated with this composition were successfully draw-and-ironed into cans without galling in laboratory tests. Initial adhesion of these coatings to the steel was good, but after storage for several months this composition gave coatings with poor adhesion. The
  • EXAMPLE 4 In this composition an inorganic filler was added to the composition of Example 3. Both talc and a very fine iron oxide pigment were tried. Dispersants such as lignosulfonates and phosphates were effective in main- EXAMPLE 7 by about 14 percent.
  • Talc or iron oxide Molybdenum Sulfide UIM Water (To dilute to 14 to 40 percent nonvolatilcs according to thickness of coating desired l p illl taining good suspension of the solids. Concentrations used are given in Table 1. With talc additions, there was evidence of slight improvement in resistance to galling in coatings on blackplate in draw-and-iron can tests on production equipment. However, iron oxide gave satisfactory results on laboratory equipment but caused excessive breakage and galling in more severe processes.
  • EXAMPLE This example illustrates the substitution of another resin dispersion for a portion of the ethylene-acrylic acid copolymer solution.
  • the ethyleneionomer dispersion (Elvax D1249, E. l. du Pont de Nemours Co.) is an ethylene-methacrylic acid copolymer partly neutralized with sodium hydroxide and dispersed by an emulsion polymerization process with surfactants.
  • the performance of this composition as a lubricant coating was similar to that of Example 3.
  • Process for cold forming or shaping metal comprising subjecting to deformation pressure against a solid surface metal which has been coated with a resin-oil layer by applying to its surface a single aqueous dispersion composition and drying said composition to remove water and other volatiles, said composition prepared by blending (a) a lubricant oil selected from mineral oil, animal or vegetable oils, fats, soaps, fatty esters, or other natural or synthetic oil, grease, or wax lubricant materials or mixtures thereof, and (b) a dispersion or solution of a normally solid copolymer of ethylene and acrylic acid, containing 15 to 25% acrylic acid, in water containing alkali sufficient to form a watersoluble or dispersable salt or ionomer of the copolymer, said lubricant oil comprising from about 1 to about of the total nonvolatiles of the coating composition and being substantiallyinsoluble in the resin.
  • a lubricant oil selected from mineral oil, animal or vegetable oils, fats, soaps, fatty esters, or other natural
  • Process for cold forming or shaping metal comprising subjecting to deformation pressure against a solid surface metal 'which has been coated with a resin-oil thereof and (b-)' the balance an aqueous dispersion or latex of a normally solid copolymer or terpolymer of ethylene and vinyl acetate or methacrylic acid containa ing 60 to 85% ethylene, to 40% vinyl acetate, and O to 25% methacrylic acid.
  • Method of forming metal comprising:
  • Method of claim 4 wherein the dried coating has an average weight of at least about 50 milligrams per square foot.
  • composition useful for forming lubricant coatings comprising an emulsion of a lubricant oil in an aqueous dispersion of a normally solid adhesive resin copolymer, terpolymer or ionomer of ethylene and an ethylenically unsaturated monomer selected from the group consisting of vinyl acetate, acrylic acid, methacrylic acid, crotonic acid, their salts and lower esters, said resin containing about 50% to about 90% by weight ethylene, the weight ratio of resin to lubricant oil being from about lO0;l to about 1:3, the lubricant oil being substantially insoluble in the resin.
  • Method of lubricating surfaces comprising applying to said surface a composition of claim 9 and drying it to form a coating having an average weight range of at least 50 milligrams per square foot.
  • Method of making a composition useful for forming lubricant coatings comprising dispersing a copolymer of about to about by weight ethylene and about 15 to about 25% acrylic acid in water containing a volatile alkali, and emulsifying a lubricant oil in the resulting dispersion, the ratio of copolymer to lubricant oil being about :1 to about 1:3.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Shaping Metal By Deep-Drawing, Or The Like (AREA)
US361727A 1973-05-18 1973-05-18 Resin-containing lubricant coatings Expired - Lifetime US3873458A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
US361727A US3873458A (en) 1973-05-18 1973-05-18 Resin-containing lubricant coatings
GB1913974A GB1473235A (en) 1973-05-18 1974-05-01 Process for forming or shaping a metal substrate
BE144034A BE814678A (fr) 1973-05-18 1974-05-07 Revetement lubrifiant contenant une resine
DE2422013A DE2422013A1 (de) 1973-05-18 1974-05-07 Verfahren zur verformung von metallen und mittel zur durchfuehrung des verfahrens
IT68563/74A IT1011835B (it) 1973-05-18 1974-05-17 Composizione per formare rivesti menti lubrificanti particolarmen te nella lavorazione dei metalli
FR7417308A FR2229477B1 (enrdf_load_stackoverflow) 1973-05-18 1974-05-17
CA200,310A CA1039704A (en) 1973-05-18 1974-05-17 Resin-containing lubricant coatings
JP49056056A JPS5027802A (enrdf_load_stackoverflow) 1973-05-18 1974-05-17

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US361727A US3873458A (en) 1973-05-18 1973-05-18 Resin-containing lubricant coatings

Publications (1)

Publication Number Publication Date
US3873458A true US3873458A (en) 1975-03-25

Family

ID=23423208

Family Applications (1)

Application Number Title Priority Date Filing Date
US361727A Expired - Lifetime US3873458A (en) 1973-05-18 1973-05-18 Resin-containing lubricant coatings

Country Status (8)

Country Link
US (1) US3873458A (enrdf_load_stackoverflow)
JP (1) JPS5027802A (enrdf_load_stackoverflow)
BE (1) BE814678A (enrdf_load_stackoverflow)
CA (1) CA1039704A (enrdf_load_stackoverflow)
DE (1) DE2422013A1 (enrdf_load_stackoverflow)
FR (1) FR2229477B1 (enrdf_load_stackoverflow)
GB (1) GB1473235A (enrdf_load_stackoverflow)
IT (1) IT1011835B (enrdf_load_stackoverflow)

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4108099A (en) * 1975-05-01 1978-08-22 Metal Box Limited Method and apparatus for forming a coated container
FR2439815A1 (fr) * 1978-10-27 1980-05-23 Pennwalt Corp Procede pour diminuer les residus de produits carbones non volatils resultant du traitement, a temperature elevee, d'un substrat metallique par une composition de traitement
FR2441657A1 (fr) * 1978-11-15 1980-06-13 Dow Corning Gmbh Composition aqueuse pour la production de lubrifiants sous forme de pellicule seche
WO1981003293A1 (en) * 1980-05-14 1981-11-26 Nat Can Corp Precoated stock material for containers and method of forming seamless container
EP0043182A1 (en) * 1980-06-02 1982-01-06 Uss Engineers And Consultants, Inc. Lubricant composition and metal forming process
US4354370A (en) * 1980-09-02 1982-10-19 Kessler Products Co., Inc. Method for deep drawing sheet metal
US4411962A (en) * 1981-12-08 1983-10-25 Vought Corporation Induced or constrained superplastic laminates for forming
US4416132A (en) * 1981-06-24 1983-11-22 E/M Lubricants, Inc. Metal forming lubricant and method of use thereof
US4876116A (en) * 1986-09-11 1989-10-24 Raychem Corporation Metal conductors with improved solderability
US5049291A (en) * 1988-09-30 1991-09-17 Idemitsu Kosan Co., Ltd. Lubricating oil composition for two-cycle engines
US5067859A (en) * 1990-02-15 1991-11-26 Systems Division Incorporated Method for drilling small holes in printed circuit boards
US5151297A (en) * 1990-03-26 1992-09-29 Armco Steel Company, L.P. Thermoplastic acrylic coated steel sheet
US5248528A (en) * 1990-03-26 1993-09-28 Armco Steel Company, L.P. Thermoplastic acrylic coated steel sheet
WO1995031297A1 (en) * 1994-05-13 1995-11-23 Henkel Corporation Aqueous metal coating composition and process with reduced staining and corrosion
US5531912A (en) * 1994-09-02 1996-07-02 Henkel Corporation Composition and process for lubricating metal before cold forming
US5549836A (en) * 1995-06-27 1996-08-27 Moses; David L. Versatile mineral oil-free aqueous lubricant compositions
WO1996040849A1 (en) * 1995-06-07 1996-12-19 Lee County Mosquito Control District Lubricant compositions and methods
US5859124A (en) * 1996-10-30 1999-01-12 Kawasaki Steel Corporation Lubricant for use in hot work
US5883168A (en) * 1996-06-13 1999-03-16 Valeo Systemes D'essuyage Aqueous emulsion or dispersion for forming a coating on a profiled element
EP0784663A4 (en) * 1994-10-07 1999-07-21 Henkel Corp AQUEOUS METAL COATING COMPOSITION AND METHOD WITH IMPROVED HUMIDIFICATION OF OILY OR LIKE SOILED SURFACES
WO2000029524A1 (de) * 1998-11-12 2000-05-25 Henkel Kommanditgesellschaft Auf Aktien Schmiermittel mit feststoffpartikeln einer teilchengrösse unter 500 nm
US6150315A (en) * 1999-01-29 2000-11-21 Sports Care Products, Inc. Terpene based aqueous cleaning gel for sporting equipment
US6175986B1 (en) 1996-06-13 2001-01-23 Valeo Systemes D'essuyage Wiping strip for a motor vehicle screen wiper
US6273969B1 (en) 1998-01-07 2001-08-14 Rensselaer Polytechnic Institute Alloys and methods for their preparation
US6538051B1 (en) * 1997-03-27 2003-03-25 Dow Corning Asia, Ltd. Aqueous coating agent of hydrophilic resin, MoS2 and Sb2S3 and/or Sb2S5
US20040167043A1 (en) * 1995-06-07 2004-08-26 Lee County Mosquito Control District Lubricant compositions and method
EP1577372A1 (de) * 2004-03-19 2005-09-21 Sika Technology AG Stabile wässrige Dispersion von Partikeln sowie Verwendung und Herstellungsverfahren solcher Dispersionen
US7718585B2 (en) 1995-06-07 2010-05-18 Lee County Mosquito Control District Lubricant compositions and methods
US20110100081A1 (en) * 2008-01-30 2011-05-05 Uwe Rau Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer
US20220203418A1 (en) * 2020-12-29 2022-06-30 Jin Yuncheng Enterprise Co., Ltd. Method for manufacturing cold-forged extruded aluminum alloy rod

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5175863A (ja) * 1974-12-26 1976-06-30 Ishihara Chemical Co Ltd Junkatsusoseibutsu
NZ191183A (en) * 1979-03-01 1981-05-01 American Can Co Deep drawing lubricant containing lubricant silicone resin and solvent
GB2048934B (en) * 1979-05-08 1983-08-03 Nippon Kokan Kk Lubricating oil compositions and methods of manufacturing and supplying them
JPS55152909A (en) * 1979-05-17 1980-11-28 Nippon Oils & Fats Co Ltd Clamping member treated with torque stabilization
GB2053264B (en) * 1979-07-09 1983-08-10 Steetley Minerals Ltd Polymer lubricants for metal forming
AU554386B2 (en) * 1981-05-04 1986-08-21 American Can Co. Lubrication coating for container manufacture
AU555074B2 (en) * 1981-05-04 1986-09-11 American Can Co. Dry lubricant for drawing steel plate
US4403490A (en) * 1981-06-24 1983-09-13 E/M Lubricants, Inc. Metal forming lubricant and method of use thereof
US4409111A (en) * 1982-04-12 1983-10-11 Loctite Corporation Anti-galling lubricative composition
JPS6099200A (ja) * 1983-11-02 1985-06-03 Nippon Parkerizing Co Ltd 金属の潤滑処理方法
CH669603A5 (enrdf_load_stackoverflow) * 1986-09-23 1989-03-31 Lonza Ag
DE3924160A1 (de) * 1989-07-21 1991-01-24 Henkel Kgaa Additiv zur beeinflussung der rheologie von oelen und fetten, seine herstellung und seine verwendung
FR2742364B1 (fr) * 1995-12-14 1998-01-09 Lorraine Laminage Procede de traitement de surface d'une tole metallique pour emboutissage
FR2962426B1 (fr) * 2010-07-09 2013-05-24 Peugeot Citroen Automobiles Sa Dispositif de detection de defauts de flans de tole au cours du procede d'emboutissage

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2425845A (en) * 1945-04-21 1947-08-19 Carbide & Carbon Chem Corp Mixtures of polyoxyalkylene diols and methods of making such mixtures
US2753305A (en) * 1955-09-26 1956-07-03 Pennsylvania Salt Mfg Co Lubricating composition
US2966425A (en) * 1959-02-18 1960-12-27 Montgomery H A Co Drawing lubricant coating methods and compositions
US3024193A (en) * 1957-12-26 1962-03-06 Standard Oil Co Stabilized metal-working lubricant
US3250103A (en) * 1964-01-30 1966-05-10 Shell Oil Co Metal working process
US3258319A (en) * 1962-11-23 1966-06-28 Du Pont Lubricant coated formable metal article
US3472825A (en) * 1964-12-24 1969-10-14 Union Carbide Corp Alkali metal salts of ethylene-acrylic acid interpolymers
US3478554A (en) * 1967-05-26 1969-11-18 Aluminum Co Of America Coated sheet metal and method of forming the same
US3706124A (en) * 1970-03-07 1972-12-19 Bayer Ag Process for the pre-treating of metal sheets which are provided with a coating following a forming operation
US3765928A (en) * 1971-03-31 1973-10-16 Union Carbide Corp Ethylene/alpha, beta-unsaturated acid interpolymers as adhesive systems for polyurethanes

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT974269B (it) * 1971-12-27 1974-06-20 Nippon Steel Corp Lamiera metallica trattata con lubrificante per lavorazione alla pressa

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2425845A (en) * 1945-04-21 1947-08-19 Carbide & Carbon Chem Corp Mixtures of polyoxyalkylene diols and methods of making such mixtures
US2753305A (en) * 1955-09-26 1956-07-03 Pennsylvania Salt Mfg Co Lubricating composition
US3024193A (en) * 1957-12-26 1962-03-06 Standard Oil Co Stabilized metal-working lubricant
US2966425A (en) * 1959-02-18 1960-12-27 Montgomery H A Co Drawing lubricant coating methods and compositions
US3258319A (en) * 1962-11-23 1966-06-28 Du Pont Lubricant coated formable metal article
US3250103A (en) * 1964-01-30 1966-05-10 Shell Oil Co Metal working process
US3472825A (en) * 1964-12-24 1969-10-14 Union Carbide Corp Alkali metal salts of ethylene-acrylic acid interpolymers
US3478554A (en) * 1967-05-26 1969-11-18 Aluminum Co Of America Coated sheet metal and method of forming the same
US3706124A (en) * 1970-03-07 1972-12-19 Bayer Ag Process for the pre-treating of metal sheets which are provided with a coating following a forming operation
US3765928A (en) * 1971-03-31 1973-10-16 Union Carbide Corp Ethylene/alpha, beta-unsaturated acid interpolymers as adhesive systems for polyurethanes

Cited By (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4108099A (en) * 1975-05-01 1978-08-22 Metal Box Limited Method and apparatus for forming a coated container
FR2439815A1 (fr) * 1978-10-27 1980-05-23 Pennwalt Corp Procede pour diminuer les residus de produits carbones non volatils resultant du traitement, a temperature elevee, d'un substrat metallique par une composition de traitement
FR2441657A1 (fr) * 1978-11-15 1980-06-13 Dow Corning Gmbh Composition aqueuse pour la production de lubrifiants sous forme de pellicule seche
WO1981003293A1 (en) * 1980-05-14 1981-11-26 Nat Can Corp Precoated stock material for containers and method of forming seamless container
US4474669A (en) * 1980-06-02 1984-10-02 United States Steel Corporation Can-making lubricant
EP0043182A1 (en) * 1980-06-02 1982-01-06 Uss Engineers And Consultants, Inc. Lubricant composition and metal forming process
US4354370A (en) * 1980-09-02 1982-10-19 Kessler Products Co., Inc. Method for deep drawing sheet metal
US4416132A (en) * 1981-06-24 1983-11-22 E/M Lubricants, Inc. Metal forming lubricant and method of use thereof
US4411962A (en) * 1981-12-08 1983-10-25 Vought Corporation Induced or constrained superplastic laminates for forming
US4876116A (en) * 1986-09-11 1989-10-24 Raychem Corporation Metal conductors with improved solderability
US5049291A (en) * 1988-09-30 1991-09-17 Idemitsu Kosan Co., Ltd. Lubricating oil composition for two-cycle engines
US5067859A (en) * 1990-02-15 1991-11-26 Systems Division Incorporated Method for drilling small holes in printed circuit boards
US5151297A (en) * 1990-03-26 1992-09-29 Armco Steel Company, L.P. Thermoplastic acrylic coated steel sheet
US5248528A (en) * 1990-03-26 1993-09-28 Armco Steel Company, L.P. Thermoplastic acrylic coated steel sheet
WO1995031297A1 (en) * 1994-05-13 1995-11-23 Henkel Corporation Aqueous metal coating composition and process with reduced staining and corrosion
US6248701B1 (en) * 1994-05-13 2001-06-19 Henkel Corporation Aqueous metal coating composition and process with reduced staining and corrosion
US5531912A (en) * 1994-09-02 1996-07-02 Henkel Corporation Composition and process for lubricating metal before cold forming
EP0778877A4 (en) * 1994-09-02 1999-07-21 Henkel Corp PREPARATION AND PROCESS FOR LUBRICATING METAL BEFORE COLD TREATMENT
EP0784663A4 (en) * 1994-10-07 1999-07-21 Henkel Corp AQUEOUS METAL COATING COMPOSITION AND METHOD WITH IMPROVED HUMIDIFICATION OF OILY OR LIKE SOILED SURFACES
US20050197259A1 (en) * 1995-06-07 2005-09-08 Lee County Mosquito Control District Lubricant compositions and methods
US7358216B2 (en) 1995-06-07 2008-04-15 Lee County Mosquito Control District Lubricant compositions and methods
US7767631B2 (en) 1995-06-07 2010-08-03 Lee County Mosquito Control District Lubricant compositions and methods
AU691758B2 (en) * 1995-06-07 1998-05-21 Lee County Mosquito Control District Lubricant compositions and methods
US7718585B2 (en) 1995-06-07 2010-05-18 Lee County Mosquito Control District Lubricant compositions and methods
US7553541B2 (en) 1995-06-07 2009-06-30 Lee County Mosquite Control District Lubricant compositions and methods
US7338926B2 (en) 1995-06-07 2008-03-04 Lee County Mosquito Control District Lubricant compositions and methods
US20040167038A1 (en) * 1995-06-07 2004-08-26 Lee County Mosquito Control District Lubricant compositions and methods
US20040167043A1 (en) * 1995-06-07 2004-08-26 Lee County Mosquito Control District Lubricant compositions and method
WO1996040849A1 (en) * 1995-06-07 1996-12-19 Lee County Mosquito Control District Lubricant compositions and methods
US20040138072A1 (en) * 1995-06-07 2004-07-15 Lee County Mosquito Control District Lubricant compositions and methods
US6734147B2 (en) 1995-06-07 2004-05-11 Lcc County Mosquito Control Lubricant compositions and methods
US5549836A (en) * 1995-06-27 1996-08-27 Moses; David L. Versatile mineral oil-free aqueous lubricant compositions
US20030149136A1 (en) * 1996-04-03 2003-08-07 Atsushi Ikezawa Aqueous coating agent for forming lubricating films
US5883168A (en) * 1996-06-13 1999-03-16 Valeo Systemes D'essuyage Aqueous emulsion or dispersion for forming a coating on a profiled element
US6175986B1 (en) 1996-06-13 2001-01-23 Valeo Systemes D'essuyage Wiping strip for a motor vehicle screen wiper
US6010752A (en) * 1996-06-13 2000-01-04 Valeo Systemes D'essuyage Method for coating a profiled element with an aqueous emulsion or dispersion
US5859124A (en) * 1996-10-30 1999-01-12 Kawasaki Steel Corporation Lubricant for use in hot work
US6538051B1 (en) * 1997-03-27 2003-03-25 Dow Corning Asia, Ltd. Aqueous coating agent of hydrophilic resin, MoS2 and Sb2S3 and/or Sb2S5
US6273969B1 (en) 1998-01-07 2001-08-14 Rensselaer Polytechnic Institute Alloys and methods for their preparation
WO2000029524A1 (de) * 1998-11-12 2000-05-25 Henkel Kommanditgesellschaft Auf Aktien Schmiermittel mit feststoffpartikeln einer teilchengrösse unter 500 nm
US6153571A (en) * 1999-01-29 2000-11-28 Sports Care Products, Inc. Terpene based aqueous cleaning gel for sporting equipment
US6150315A (en) * 1999-01-29 2000-11-21 Sports Care Products, Inc. Terpene based aqueous cleaning gel for sporting equipment
US20070197705A1 (en) * 2004-03-19 2007-08-23 Sika Technology Ag Stable aqueous particle dispersion the use thereof and method for producing said dispersion
WO2005090533A1 (de) * 2004-03-19 2005-09-29 Sika Technology Ag Stabile wässrige dispersion von partikeln sowie verwendung und herstellungsverfahren solcher dispersionen
EP1577372A1 (de) * 2004-03-19 2005-09-21 Sika Technology AG Stabile wässrige Dispersion von Partikeln sowie Verwendung und Herstellungsverfahren solcher Dispersionen
CN101068911B (zh) * 2004-03-19 2012-11-07 Sika技术股份公司 颗粒的稳定水分散体以及这样的分散体的用途和制备方法
US20110100081A1 (en) * 2008-01-30 2011-05-05 Uwe Rau Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer
US9422503B2 (en) * 2008-01-30 2016-08-23 Chemetall Gmbh Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer
US20220203418A1 (en) * 2020-12-29 2022-06-30 Jin Yuncheng Enterprise Co., Ltd. Method for manufacturing cold-forged extruded aluminum alloy rod

Also Published As

Publication number Publication date
BE814678A (fr) 1974-11-07
FR2229477A1 (enrdf_load_stackoverflow) 1974-12-13
IT1011835B (it) 1977-02-10
JPS5027802A (enrdf_load_stackoverflow) 1975-03-22
CA1039704A (en) 1978-10-03
DE2422013A1 (de) 1974-12-05
FR2229477B1 (enrdf_load_stackoverflow) 1978-11-17
GB1473235A (en) 1977-05-11

Similar Documents

Publication Publication Date Title
US3873458A (en) Resin-containing lubricant coatings
US4474669A (en) Can-making lubricant
CA2334716C (en) Composition and process for lubricated plastic working of metals
TWI457431B (zh) 將金屬表面施以一種潤滑劑組成物的方法
CA2284545C (en) Metal forming lubricant with differential solid lubricants
US4636321A (en) Water soluble lubricant
WO2002014458A1 (fr) Composition aqueuse permettant la formation d'une pellicule protectrice
US5442005A (en) Multi-function protective coating for zinc coated steel surfaces and its alloys
US5307660A (en) New water based lubricant composition for cold impact extrusion of spark plug bodies or other metal parts and process
US5368757A (en) Lubrication for cold forming of metals
JPS59227985A (ja) 金属加工油組成物
US4663061A (en) Metal-working oil composition
US4800033A (en) Process for the non-cutting reshaping of metals, and lubricant compositions for this process
US6255260B1 (en) Metal forming lubricant with differential solid lubricants
US4411145A (en) Can-making method
WO1992007924A1 (en) Composition and method for treating metal
JP4398827B2 (ja) 樹脂塗装金属板
JP4172087B2 (ja) 塗料組成物および潤滑処理金属板
GB2174713A (en) Process for lubricating a metal surface
KR100643781B1 (ko) 냉간단조 공정에 사용되는 표면 윤활처리제의 제조방법
JP4478055B2 (ja) 樹脂塗装金属板
JPH04271872A (ja) プレス成形性、加工後塗装性及び耐食性にすぐれる樹脂塗装鋼板
JP4551837B2 (ja) 樹脂塗装金属板
JPH02117993A (ja) Ｄｉ缶用加工油組成物
JPH08259979A (ja) 高潤滑性防錆油及びこれを塗布した金属板

Legal Events

Date Code Title Description
AS Assignment

Owner name: USX CORPORATION, A CORP. OF DE, STATELESS

Free format text: MERGER;ASSIGNOR:UNITED STATES STEEL CORPORATION (MERGED INTO);REEL/FRAME:005060/0960

Effective date: 19880112