US3854976A - Applicator and method for making a printing form - Google Patents
Applicator and method for making a printing form Download PDFInfo
- Publication number
- US3854976A US3854976A US00182983A US18298371A US3854976A US 3854976 A US3854976 A US 3854976A US 00182983 A US00182983 A US 00182983A US 18298371 A US18298371 A US 18298371A US 3854976 A US3854976 A US 3854976A
- Authority
- US
- United States
- Prior art keywords
- outline
- lacquer
- printing
- layer
- microcapsules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007639 printing Methods 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims description 36
- 239000004922 lacquer Substances 0.000 claims abstract description 41
- 239000003094 microcapsule Substances 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000001464 adherent effect Effects 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229920005992 thermoplastic resin Polymers 0.000 claims 1
- 239000011888 foil Substances 0.000 abstract description 62
- 230000005855 radiation Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 description 10
- 239000002775 capsule Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
- B41C1/1091—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by physical transfer from a donor sheet having an uniform coating of lithographic material using thermal means as provided by a thermal head or a laser; by mechanical pressure, e.g. from a typewriter by electrical recording ribbon therefor
Definitions
- a carrier foil having a layer of microcapsules containing a printing lacquer consisting of a resin and a solvent.
- the carrier foil is superimposed on a printing foil, and the microcapsules broken by the impact of a type or melted by radiation along a desired outline, the lacquer is applied to the printing foil along the desired outline, and adheres to the printing foil when the same is separated from the carrier foil and from the remainder of the layer.
- the present invention relates to a method of making a printable image on a lithographic printing foil consisting of metal, preferably aluminum, paper, or a synthetic material, or consisting of several of the aboveenumerated substances, which may form different superimposed foils.
- the method is carried out by using an applicator sheet, according to the invention, which includes a carrier foil, and a layer of microcapsules bonded to the carrier foil.
- a printable image is formed on the printing foil of a fatty substance, or lacquer is applied to the printing foil by a pen or brush.
- fatty substances forming an image for example of a character, are inferior to a lacquer in forming an adherent base, particularly it is not possible to add to the moistening water, anti-toner substances, since the same creep under the fatty base.
- lacquers are used for making a printing foil, it is not possible to produce the desired outline by the types of a typewriter, or by applying infrared heat along the desired outline.
- Another object of the invention is to provide a method permitting the use of a typewriter for forming an image consisting of lacquer on a printing foil.
- Another object of the invention is to provide a method permitting the use of infrared light for forming an image consisting of a lacquer on a printing foil.
- Another object of the invention is to provide a printing foil with a printable outline of an image having great adhesive capacity, permitting the use of moistening liquids, and having great tone stability during printing.
- Another object of the invention is to make possible the required anti-toner stability for direct lithographic printing in which the printing face of the printing foil is dried by the paper which is being imprinted.
- Another object of the invention is to make a printing foil particularly suited for printing operation in which the printing cylinder is frequently stopped after making a comparatively small number of copies, so that the printing form must be absolutely tone stable after one or two revolutions of the printing cylinder.
- Another object of the invention is to provide an applicator sheet for carrying outthe method of the inventron.
- Another object of the invention is an applicator sheet comprising a carrier foil, and a layer of microcapsules thereon, preferably containing a lacquer, and adapted to be opened along the outline of a desired image to be printed.
- a method according to the invention of making a printing form uses a carrier foil having on the front face a layer of microcapsules containing a substance, such as a lacquer.
- the carrier foil is superimposed on a printing foil so that the layer of capsules is in contact with the front face of the printing foil.
- Energy is applied to the rear face of one of the foils along the outline of an image so as to open the microcapsules of the layer along the outline whereby the substance released by the opened microcapsules adheres to the front face of the printing foil along the outline.
- the printing foil with the adhering substance and the carrier foil with the remaining portions of the layer are separated from each other so that the substance adhering to the printing foil forms a printable outline of the desired image.
- the capsules contain a fast drying oleophilic lacquer consisting of a resin and a solvent.
- Energy can be applied along the outline to be printed by the impact of a moving type on the respective foil so that microcapsules are broken along the character outline by the impacts of the type.
- Energy can also be applied by heating the outline of the image and the remaining portions of the carrier foil differently, so that the capsules forming the image melt and open. After the evaporation of the solvent, the resin forms a very durable base to which the lithographic printing ink reliably adheres.
- the method of the invention can be carried out with different printing foils, for example electrolytically roughened aluminum foils, or brushed aluminum foils.
- a paper backing may be adhesively attached to the aluminum printing foil, and coated with a water-resistant lacquer. Barite paper, or other lithographic paper foils,
- . may also be used as printing foils.
- the lacquer is a mixture of a copolymerisate with a solvent, such as toluol and xylol.
- EXAMPLE 1 22 parts by weight of a copolymerisate consisting of vinylchloride and vinylisobutylether in a ratio of :25 are mixed with 78 parts by weight of toluol.
- EXAMPLE 2 21 parts by weight of a copolymerisate consisting of vinylchloride and vinylisobutylether in a ratio of 75:25 are mixed with 79 parts by weight of xylol.
- the layer on the carrier foil of microcapsules having a diameter between 20 micron and 50 micron.
- the layer is adhesively attached to the carrier sheet.
- FIG. I is a schematic side view illustrating the use of a typewriter for making a mirror-reversed printable image on a printing form for direct lithographic printing;
- FIG. 2 is a schematic side view illustrating the applicator sheet andthe printing foil of FIG. 1 after separation of the printing form from the applicator sheet;
- FIGS. 3 and 4 are schematic side views corresponding to FIGS. 1 and 2, but illustrating the making of an offset printing foil with a true image
- FIGS. and 6 are schematic side views illustrating a modified method using radiation for making a printing form.
- a carrier foil 1 has a front face to which a layer 2 consisting of microcapsules is adhesively bonded.
- a printing foil 3 is used.
- the type bar 5 of a typewriter has a type 4 with a character whose outline is to be represented by the finished printing form.
- an infrared lamp 8 is used together with a transparent sheet, to which heatabsorbent material 7 forming the outline-of the desired image is attached.
- the layer 2 of capsules containing the lacquer is superimposed on the front face of a printing foil 3.
- the type 4 is moved against the rear face of printing foil 3, and the impact of the type causes breaking of the microcapsules of layer 2 along the outline of the respective character.
- the broken and opened microcapsules apply lacquer portions to the front face of the printing foil 3, forming with the same a printing form when printing foil 3 is separated from carrier foil I with the remainder of the layer 2.
- the image 2a is a mirror-reversed image.
- the type bar 5 with type 4 is placed at the rear face of the carrier 1 of the layer 2, and the impact along the outline of the character of type 4, breaks capsules along this outline, so that lacquer adheres at 2a to the printing foil 3, formingwith the same a printing form after separation of the carrier sheet I with the remainder oflayer 2 from the printing form 3,2 a.
- a printing foil 3 is superimposed on the layer 2 which adheres to the carrier sheet 1.
- a transparent sheet 6 with heat-absorbing material 7 arranged in accordance with the desired outline. is superimposed on the rear face of carrier foil 1.
- Infrared light applied by lamp 8 passes through the transparent sheet, and is particularly absorbed by the heat-absorbing, image-forming material 7, so that microcapsules of layer 2 melt and open in'the pattern of the heat-absorbing material 7, so that lacquer adheres in the same pattern at 2a to the printing foil 3.
- the printing form 3,2 a is separated from the carrier sheet I with the remainder of layer 2, the printing foil 3 carries a mirror-reversed image formed of the lacquer portions 20.
- the heat-absorbent material 7 is applied to the rear face of the transparent sheet 6 which directly abuts It will be understood that each of the elements described above, or two or more together, may also find a useful application in other types of methods of making a printing form differing from the types described above.
- the layer 2 has a thickness from about 20 to about 400 microns.
- Typical monomers which may be polymerized in the form of capsules by the process described in the US. Pat. Nos. 2,800,457 and 2,800,458 to Greeniin include ethylacrylate, methylacrylate, methylmethacrylate, ethylmethacrylate, vinyl acetate, styrene and mixtures thereof.
- the adhesive by which the layer 2 is bonded to the carrier foil 1 may comprise resinous acid, casein, a colloidal material, or a synthetic resin dispersion, or a combination of all or some of such substances.
- a method of making a printing form comprising the steps of providing a printing sheet having a face on which a printable outline of an image is to be formed; providing a carrier sheet having a surface provided with a layer, said layer including microcapsules containing a fast drying oleophilic lacquer comprising a mixture of at least one resin and at least one liquid solvent which is to be transferred at least in part to said face to form said outline contacting said layer with said face; releasing said lacquer from at least some of said microcapsules by transmitting energy to regions of said layer corresponding to said outline so that the released lacquer contacts said face along said outlinelhereby enabling an adherent coating to be formed on said face along said outline; and separating said sheets; whereby a printing form having said outline is obtained.
- said resin comprises a copolymer of vinylchloride and vinylisobutylether, said solvent being selected from the group consisting of toluol and xylol.
- step of releasing said lacquer comprises breaking the micro- 6 capsules in said regions by transmitting impact energy thereto.
- step of releasing said lacquer comprises opening the microcapsules in said regions by preferentially heating the same.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Optics & Photonics (AREA)
- Manufacturing & Machinery (AREA)
- Printing Methods (AREA)
- Printing Plates And Materials Therefor (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702049019 DE2049019A1 (de) | 1970-09-25 | 1970-09-25 | Verfahren zur Bilderzeugung auf einer lithographischen Druckformfohe |
Publications (1)
Publication Number | Publication Date |
---|---|
US3854976A true US3854976A (en) | 1974-12-17 |
Family
ID=5784327
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00182983A Expired - Lifetime US3854976A (en) | 1970-09-25 | 1971-09-23 | Applicator and method for making a printing form |
Country Status (7)
Country | Link |
---|---|
US (1) | US3854976A (enrdf_load_stackoverflow) |
CH (1) | CH562100A5 (enrdf_load_stackoverflow) |
DE (1) | DE2049019A1 (enrdf_load_stackoverflow) |
FR (1) | FR2108292A5 (enrdf_load_stackoverflow) |
GB (1) | GB1323965A (enrdf_load_stackoverflow) |
NL (1) | NL7109832A (enrdf_load_stackoverflow) |
SE (1) | SE375265B (enrdf_load_stackoverflow) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5045430A (en) * | 1985-10-25 | 1991-09-03 | Shackle Dale R | Method for making printing plates and assembly useful therein |
JPS62250454A (ja) * | 1986-04-23 | 1987-10-31 | Fuji Photo Film Co Ltd | 平版印刷版の製造法 |
JPH0668622B2 (ja) * | 1986-04-23 | 1994-08-31 | 富士写真フイルム株式会社 | 平版印刷版の製造法 |
JPH0677147B2 (ja) * | 1986-04-23 | 1994-09-28 | 富士写真フイルム株式会社 | 平版印刷原版 |
WO1994023954A1 (en) * | 1993-04-20 | 1994-10-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Lithographic printing original plate and method for producing the same |
ITMI20120049A1 (it) * | 2012-01-18 | 2013-07-19 | Printgraph Waterless S P A | Rivestimento avvolgibile per un cilindro porta-caucciu' o porta lastra di verniciatura per la finitura superficiale di un supporto stampato |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2939009A (en) * | 1956-02-01 | 1960-05-31 | Jack M Tien | Thermotransfer duplicating process |
US3298895A (en) * | 1962-12-17 | 1967-01-17 | Du Pont | Process for producing images and products thereof |
US3317433A (en) * | 1958-10-23 | 1967-05-02 | Ncr Co | Heat rupturable capsules |
US3470059A (en) * | 1965-12-22 | 1969-09-30 | Minnesota Mining & Mfg | Matrix for molding a positive relief impression |
US3476937A (en) * | 1963-12-05 | 1969-11-04 | Agfa Gevaert Nv | Thermographic recording method employing a recording material comprising a uniform layer of discrete hydrophobic thermoplastic polymer particles |
US3484318A (en) * | 1966-06-23 | 1969-12-16 | Ibm | Method of concurrently producing visible and magnetizable indicia |
US3505955A (en) * | 1966-01-17 | 1970-04-14 | Gerhard Ritzerfeld | Method and arrangement for producing printing forms |
US3598581A (en) * | 1967-04-03 | 1971-08-10 | Xerox Corp | Manifold imaging method |
US3697323A (en) * | 1971-01-06 | 1972-10-10 | Ncr Co | Pressure-sensitive record material |
US3728210A (en) * | 1969-06-27 | 1973-04-17 | J Piron | Dry transfer |
-
1970
- 1970-09-25 DE DE19702049019 patent/DE2049019A1/de active Pending
-
1971
- 1971-07-16 NL NL7109832A patent/NL7109832A/xx unknown
- 1971-08-09 CH CH1168471A patent/CH562100A5/xx not_active IP Right Cessation
- 1971-08-27 GB GB1023371*[A patent/GB1323965A/en not_active Expired
- 1971-09-20 FR FR7133708A patent/FR2108292A5/fr not_active Expired
- 1971-09-23 US US00182983A patent/US3854976A/en not_active Expired - Lifetime
- 1971-09-24 SE SE7112131A patent/SE375265B/xx unknown
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2939009A (en) * | 1956-02-01 | 1960-05-31 | Jack M Tien | Thermotransfer duplicating process |
US3317433A (en) * | 1958-10-23 | 1967-05-02 | Ncr Co | Heat rupturable capsules |
US3298895A (en) * | 1962-12-17 | 1967-01-17 | Du Pont | Process for producing images and products thereof |
US3476937A (en) * | 1963-12-05 | 1969-11-04 | Agfa Gevaert Nv | Thermographic recording method employing a recording material comprising a uniform layer of discrete hydrophobic thermoplastic polymer particles |
US3470059A (en) * | 1965-12-22 | 1969-09-30 | Minnesota Mining & Mfg | Matrix for molding a positive relief impression |
US3505955A (en) * | 1966-01-17 | 1970-04-14 | Gerhard Ritzerfeld | Method and arrangement for producing printing forms |
US3484318A (en) * | 1966-06-23 | 1969-12-16 | Ibm | Method of concurrently producing visible and magnetizable indicia |
US3598581A (en) * | 1967-04-03 | 1971-08-10 | Xerox Corp | Manifold imaging method |
US3728210A (en) * | 1969-06-27 | 1973-04-17 | J Piron | Dry transfer |
US3697323A (en) * | 1971-01-06 | 1972-10-10 | Ncr Co | Pressure-sensitive record material |
Also Published As
Publication number | Publication date |
---|---|
CH562100A5 (enrdf_load_stackoverflow) | 1975-05-30 |
NL7109832A (enrdf_load_stackoverflow) | 1972-03-28 |
DE2049019A1 (de) | 1972-03-30 |
FR2108292A5 (enrdf_load_stackoverflow) | 1972-05-19 |
SE375265B (enrdf_load_stackoverflow) | 1975-04-14 |
GB1323965A (en) | 1973-07-18 |
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