US3684722A - Thickened alkali metal hypochlorite bleaching and cleaning composition - Google Patents

Thickened alkali metal hypochlorite bleaching and cleaning composition Download PDF

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Publication number
US3684722A
US3684722A US65691A US3684722DA US3684722A US 3684722 A US3684722 A US 3684722A US 65691 A US65691 A US 65691A US 3684722D A US3684722D A US 3684722DA US 3684722 A US3684722 A US 3684722A
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United States
Prior art keywords
hypochlorite
solution
alkali
thickened
perfume
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US65691A
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English (en)
Inventor
Brian Michael Hynam
John Leslie Wilby
John Ralph Young
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Lever Brothers Co
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Lever Brothers Co
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3953—Inorganic bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the present invention provides a bleaching composition
  • a bleaching composition comprising Water, an alkali-metal hypochlorite, a hypochlorite-soluble surface active agent, preferably an amine oxide, and an alkali-metal salt of a C to C fully saturated fatty acid.
  • a caustic alkali may be included.
  • a bleaching composition comprises water, an alkalimetal hypochlorite, a perfume, preferably in an amount of from about 0.05 to about 0.2% by weight of the composition, a hypochlorite-soluble surface active agent, preferably an amine oxide, an alkali-metal salt of a C -C fully saturated fatty acid, the weight ratio of the hypochlorite-soluble surface active agent to the alkali-metal salt of the fatty acid being from about 90:10 to about 70:30, preferably from about :20 to about 70:30, and the weight ratio of the total surface active agent content of the composition to the amount of perfume present in the composition being not less than about :15, preferably from about 88:12 to about :5.
  • a caustic alkali may be included.
  • the thickener was decomposed by the alkali metal hypochlorite
  • Long-chain substituted betaines suitable for the invention are compounds having the structural formula:
  • the alkali-metal salt (soap) of a fatty acid will usually be the sodium salt, but potassium or lithium salts can also be used.
  • the fatty acid can be any natural or synthetic C C fully saturated fatty acid, such as caprylic 3 acid, capric acid, lauric acid, myristic acid, palmitic acid and stearic acid, and the mixtures of fatty acids, suitably hardened, derived from such natural sources as tallow, coconut oil, groundnut oil and babassu oil can be used.
  • the ratio of the hypochlorite-soluble surface active agent to the alkali-metal salt of the fatty acid is important and, as in the case of the unperfumed thickened hypochlorite solutions described above, an increase in this ratio is generally accompanied by an increase in stability, but a decrease in viscosity.
  • the effect of the addition of a perfume can, to some extent, be counteracted by careful variation of this ratio.
  • the ratio should be between about 90: 10 and about 70:30 preferably about :20 to about 70:30.
  • perfumes incorporated into a thickened hypochlorite solution also influences to some extent the effect of the perfume on the thickened solution, although this generally can be taken care of when adjustments to the basic thickened formulation are made to bring it into line with the requirements outlined above.
  • Perfumes can either be single compounds, or blends of two or more compounds in a variety of different proportions. It will be apparent that the constituents of a perfume should be substantially stable to hypochlorite solution in order to make the perfume suitable for the present invention.
  • EXAMPLE 1 The following polymers were obtained from various manufacturers and their ability to thicken sodium hypochlorite solution investigated.
  • Viscofas/;polyvinyl alcohol stock solution was obtained by dissolving Viscofas L in a solution of polyvinyl alcohol at about 80 C .
  • Montrek 600E and Polymer x 150 which are liquids, they were merely added to 5% (available chlorine) hypochlorite solution.
  • polyacrylate thickeners were, however, more complicated. These consist either of polyacrylic acids, or their sodium or ammonium salts. Addition of an acid to sodium hypochlorite solution causes evolution of chlorine and also reduces the free alkali level, a factor necessary for stability. The preparation of each stock solution therefore, included the addition of sodium hydroxide to form the sodium salt of the polyacrylic acids in alkaline solution. This was then diluted with 10% (available chlorine) sodium hypochlorite solution. The thickened hypochlorite solution thus obtained with Texigel and "Acrysol polyacrylates was placed on storage at room temperature and 37 C. and observed for changes in viscosity and available chlorine. Samples were also prepared containing ultra-marine R.S.l. pigments, attempting to suspend them by means of the thickener.
  • R1 is a C12 alkyl group
  • R2 and R3 are methyl groups
  • R4 contains 2 carbon atoms.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
US65691A 1969-08-29 1970-08-20 Thickened alkali metal hypochlorite bleaching and cleaning composition Expired - Lifetime US3684722A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB4223569 1969-08-29
GB4323569 1969-08-29
GB2509870 1970-05-26

Publications (1)

Publication Number Publication Date
US3684722A true US3684722A (en) 1972-08-15

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Application Number Title Priority Date Filing Date
US65691A Expired - Lifetime US3684722A (en) 1969-08-29 1970-08-20 Thickened alkali metal hypochlorite bleaching and cleaning composition

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US (1) US3684722A (US06482866-20021119-C00009.png)
BE (1) BE755338A (US06482866-20021119-C00009.png)
CH (1) CH542922A (US06482866-20021119-C00009.png)
DE (1) DE2042037C3 (US06482866-20021119-C00009.png)
FR (1) FR2059755B1 (US06482866-20021119-C00009.png)
GB (1) GB1329086A (US06482866-20021119-C00009.png)
NL (2) NL148103B (US06482866-20021119-C00009.png)

Cited By (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3876551A (en) * 1972-02-14 1975-04-08 Int Flavors & Fragrances Inc Perfumed aqueous hypochlorite composition and method for preparation of same
JPS5089280A (US06482866-20021119-C00009.png) * 1973-12-11 1975-07-17
US3989638A (en) * 1975-03-27 1976-11-02 The Procter & Gamble Company Bleaching article
US3996152A (en) * 1975-03-27 1976-12-07 The Procter & Gamble Company Bleaching composition
US4005027A (en) * 1973-07-10 1977-01-25 The Procter & Gamble Company Scouring compositions
US4011172A (en) * 1975-03-27 1977-03-08 The Procter & Gamble Company Bleaching articles
US4017411A (en) * 1975-03-27 1977-04-12 The Procter & Gamble Company Bleaching articles
US4017412A (en) * 1975-03-27 1977-04-12 The Procter & Gamble Company Bleaching composition
US4029591A (en) * 1974-09-27 1977-06-14 Lion Fat & Oil Co., Ltd. Liquid detersive bleaching composition
JPS538604A (en) * 1976-07-14 1978-01-26 Lion Corp Colored liquid detergent composition
US4113645A (en) * 1977-07-26 1978-09-12 Polak's Frutal Works, Inc. Bleach compositions containing perfume oils
US4116851A (en) * 1977-06-20 1978-09-26 The Procter & Gamble Company Thickened bleach compositions for treating hard-to-remove soils
US4116849A (en) * 1977-03-14 1978-09-26 The Procter & Gamble Company Thickened bleach compositions for treating hard-to-remove soils
US4229313A (en) * 1977-09-02 1980-10-21 Imperial Chemical Industries Limited Alkali metal hypochlorite bleaching and cleaning compositions thickened with branch chain amine oxides
US4271030A (en) * 1977-11-18 1981-06-02 Lever Brothers Company Pourable liquid compositions
US4282109A (en) * 1979-05-30 1981-08-04 Reckitt & Colman Products Limited Aqueous hypochlorite solutions
US4287084A (en) * 1980-06-19 1981-09-01 International Flavors & Fragrances Inc. Use of mixture of aliphatic C10 branched olefins in augmenting or enhancing the aroma of perfumed alkaline metal hypochlorite solutions
US4330425A (en) * 1980-06-19 1982-05-18 International Flavors & Fragrances Inc. Use of mixture of aliphatic C10 branched olefin epoxides in augmenting or enhancing the aroma of articles subjected to action of aqueous hypochlorites
US4335009A (en) * 1980-06-19 1982-06-15 International Flavors & Fragrances Inc. Mixture of aliphatic C10 branched olefin epoxides and use thereof in augmenting or enhancing the aroma of perfumes and/or articles
US4337163A (en) * 1979-12-05 1982-06-29 Lever Brothers Company Liquid, thickened chlorine bleaching composition
US4339344A (en) * 1980-09-18 1982-07-13 International Flavors & Fragrances Inc. Use of mixture of aliphatic C10 -branched olefins in augmenting or enhancing the aroma of perfumes and/or perfumed articles
US4342663A (en) * 1980-09-18 1982-08-03 International Flavors & Fragrances, Inc. Use of mixture of aliphatic C10 branched olefins in augmenting or enhancing the aroma of articles subjected to action of aqueous hypochlorites
US4354951A (en) * 1980-10-09 1982-10-19 International Flavors & Fragrances Inc. Mixture of aliphatic C10 branched olefin epoxides and use thereof in augmenting or enhancing the aroma of perfumes and/or articles
US4388204A (en) * 1982-03-23 1983-06-14 The Drackett Company Thickened alkali metal hypochlorite compositions
US4399050A (en) * 1980-05-13 1983-08-16 Sandoz Products Limited Bleach composition
US4552680A (en) * 1983-11-04 1985-11-12 The Procter & Gamble Company Hypochlorite bleach containing surfactant and organic antifoamant
US4554091A (en) * 1983-06-09 1985-11-19 Lever Brothers Company Colored bleaching compositions
US4576728A (en) * 1983-11-11 1986-03-18 The Procter & Gamble Company Cleaning compositions
US4599186A (en) * 1984-04-20 1986-07-08 The Clorox Company Thickened aqueous abrasive scouring cleanser
US4657692A (en) * 1984-04-20 1987-04-14 The Clorox Company Thickened aqueous abrasive scouring cleanser
US4666622A (en) * 1985-01-03 1987-05-19 Lever Brothers Company Stable thickened low pH liquid bleaching compositions containing inorganic peroxy compounds
US4695394A (en) * 1984-04-20 1987-09-22 The Clorox Company Thickened aqueous cleanser
US4708816A (en) * 1984-01-27 1987-11-24 The Clorox Company Bleach composition containing controlled density capsules
EP0256638A1 (en) * 1986-08-07 1988-02-24 The Clorox Company Thickened hypochlorite composition and use thereof
US4743395A (en) * 1986-09-12 1988-05-10 The Drackett Company Thickened acid cleaner compositions containing quaternary ammonium germicides and having improved thermal stability
US4775492A (en) * 1986-02-11 1988-10-04 Lever Brothers Company Thickened liquid bleaching composition
US4789495A (en) * 1987-05-18 1988-12-06 The Drackett Company Hypochlorite compositions containing a tertiary alcohol
US4790953A (en) * 1984-12-28 1988-12-13 The Proctor & Gamble Company Liquid hypochlorite bleach containing optical brightener solubilized by amine oxide
US4800036A (en) * 1985-05-06 1989-01-24 The Dow Chemical Company Aqueous bleach compositions thickened with a viscoelastic surfactant
US4828748A (en) * 1986-01-03 1989-05-09 The Drackett Company Thickened alkali metal hypochlorite compositions
US4842757A (en) * 1988-01-21 1989-06-27 The Clorox Company Thickened liquid, improved stability abrasive cleanser
US4847089A (en) * 1986-07-16 1989-07-11 David N. Kramer Cleansing and distinfecting compositions, including bleaching agents, and sponges and other applicators incorporating the same
US4863633A (en) * 1987-08-07 1989-09-05 The Clorox Company Mitigation of stress-cracking in stacked loads of fragranced bleach-containing bottles
US4900467A (en) * 1988-05-20 1990-02-13 The Clorox Company Viscoelastic cleaning compositions with long relaxation times
US4917814A (en) * 1988-08-11 1990-04-17 The Drackett Company Pigmented hypochlorite compositions
US4931207A (en) * 1984-01-27 1990-06-05 The Clorox Company Bleaching and bluing composition and method
US4946619A (en) * 1988-07-19 1990-08-07 The Clorox Company Solubilization of brighter in liquid hypochlorite
US4952333A (en) * 1984-01-27 1990-08-28 The Clorox Company Bleaching and brightening composition and method
US4986926A (en) * 1989-04-10 1991-01-22 The Drackett Company Thickened alkali metal hypochlorite compositions
US5024776A (en) * 1987-08-21 1991-06-18 Lever Brothers Company, Division Of Conopco, Inc. Machine dishwashing compositions
US5075027A (en) * 1989-02-06 1991-12-24 Colgate Palmolive Co. Thixotropic aqueous scented automatic dishwasher detergent compositions
US5080826A (en) * 1987-08-07 1992-01-14 The Clorox Company Stable fragranced bleaching composition
US5104571A (en) * 1984-01-27 1992-04-14 The Clorox Company Bleaching and brightening composition and method
EP0517311A1 (en) 1991-06-07 1992-12-09 Colgate-Palmolive Company Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
US5188752A (en) * 1991-04-22 1993-02-23 Colgate-Palmolive Company Linear viscoelastic automatic dishwasher compositions containing a crosslinked methyl vinyl ether/maleic anhydride copolymer
US5227366A (en) * 1987-08-07 1993-07-13 The Clorox Company Mitigation of stress-cracking in fragranced bleach-containing bottles
US5252242A (en) * 1989-05-18 1993-10-12 Colgate-Palmolive Co. Linear visoelastic aqueous liquid detergent composition, especially for automatic dishwashers, of improved high temperature stability
US5348682A (en) * 1988-12-15 1994-09-20 The Procter & Gamble Company Stable thickened aqueous bleach compositions
US5427707A (en) * 1985-06-14 1995-06-27 Colgate Palmolive Co. Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer
US5462689A (en) * 1992-10-19 1995-10-31 The Clorox Company Composition and method for developing extensional viscosity in cleaning compositions
US5554321A (en) * 1993-09-23 1996-09-10 The Clorox Company Thickened aqueous abrasive cleanser with improved rinsability
US5728665A (en) * 1995-09-13 1998-03-17 The Clorox Company Composition and method for developing extensional viscosity in cleaning compositions
US5804545A (en) * 1993-11-24 1998-09-08 West Argo, Inc. Stable alkaline chlorine compositions
US5972866A (en) * 1997-02-05 1999-10-26 Ecolab, Inc. Thickened noncorrosive cleaner
US5985817A (en) * 1997-02-24 1999-11-16 Reckitt & Colman South Africa Ltd. Pourable, thickened aqueous bleach and abrasive containing compositions
US6100228A (en) * 1993-10-29 2000-08-08 The Clorox Company Bleaching gel cleaner thickened with amine oxide, soap and solvent
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US6409994B1 (en) * 1999-01-19 2002-06-25 Mediteam Dental Ab Preparation for dental treatment
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US6582681B1 (en) * 1998-08-17 2003-06-24 Mediteam Dentalutveckling I Goteborg Ab Method and a preparation for cleaning tooth root surfaces and surrounding tissue
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US20110092398A1 (en) * 1997-06-10 2011-04-21 Rhodia Inc. Viscoelastic surfactant fluids and related methods of use
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ATE47423T1 (de) * 1983-10-14 1989-11-15 Procter & Gamble Reinigungsmittelzusammensetzungen.
US5075029A (en) * 1984-01-27 1991-12-24 The Clorox Company Stable emulsified bleaching compositions
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GB8513293D0 (en) * 1985-05-28 1985-07-03 Procter & Gamble Ntc Ltd Cleaning compositions
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DE29903535U1 (de) * 1999-02-27 1999-06-10 Henkel Kgaa Aktivchlorhaltige Zubereitungen mit Färbemitteln in Mikrokapseln
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CN108467804B (zh) * 2018-03-27 2020-05-08 珠海市洁丽雅生物科技有限公司 一种医用杀菌洗涤剂

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Cited By (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3876551A (en) * 1972-02-14 1975-04-08 Int Flavors & Fragrances Inc Perfumed aqueous hypochlorite composition and method for preparation of same
US4005027A (en) * 1973-07-10 1977-01-25 The Procter & Gamble Company Scouring compositions
JPS5089280A (US06482866-20021119-C00009.png) * 1973-12-11 1975-07-17
JPS565800B2 (US06482866-20021119-C00009.png) * 1973-12-11 1981-02-06
US4029591A (en) * 1974-09-27 1977-06-14 Lion Fat & Oil Co., Ltd. Liquid detersive bleaching composition
US3989638A (en) * 1975-03-27 1976-11-02 The Procter & Gamble Company Bleaching article
US3996152A (en) * 1975-03-27 1976-12-07 The Procter & Gamble Company Bleaching composition
US4011172A (en) * 1975-03-27 1977-03-08 The Procter & Gamble Company Bleaching articles
US4017411A (en) * 1975-03-27 1977-04-12 The Procter & Gamble Company Bleaching articles
US4017412A (en) * 1975-03-27 1977-04-12 The Procter & Gamble Company Bleaching composition
JPS5520519B2 (US06482866-20021119-C00009.png) * 1976-07-14 1980-06-03
JPS538604A (en) * 1976-07-14 1978-01-26 Lion Corp Colored liquid detergent composition
US4116849A (en) * 1977-03-14 1978-09-26 The Procter & Gamble Company Thickened bleach compositions for treating hard-to-remove soils
US4116851A (en) * 1977-06-20 1978-09-26 The Procter & Gamble Company Thickened bleach compositions for treating hard-to-remove soils
US4113645A (en) * 1977-07-26 1978-09-12 Polak's Frutal Works, Inc. Bleach compositions containing perfume oils
US4229313A (en) * 1977-09-02 1980-10-21 Imperial Chemical Industries Limited Alkali metal hypochlorite bleaching and cleaning compositions thickened with branch chain amine oxides
US4271030A (en) * 1977-11-18 1981-06-02 Lever Brothers Company Pourable liquid compositions
US4282109A (en) * 1979-05-30 1981-08-04 Reckitt & Colman Products Limited Aqueous hypochlorite solutions
US4337163A (en) * 1979-12-05 1982-06-29 Lever Brothers Company Liquid, thickened chlorine bleaching composition
US4399050A (en) * 1980-05-13 1983-08-16 Sandoz Products Limited Bleach composition
US4330425A (en) * 1980-06-19 1982-05-18 International Flavors & Fragrances Inc. Use of mixture of aliphatic C10 branched olefin epoxides in augmenting or enhancing the aroma of articles subjected to action of aqueous hypochlorites
US4335009A (en) * 1980-06-19 1982-06-15 International Flavors & Fragrances Inc. Mixture of aliphatic C10 branched olefin epoxides and use thereof in augmenting or enhancing the aroma of perfumes and/or articles
US4287084A (en) * 1980-06-19 1981-09-01 International Flavors & Fragrances Inc. Use of mixture of aliphatic C10 branched olefins in augmenting or enhancing the aroma of perfumed alkaline metal hypochlorite solutions
US4339344A (en) * 1980-09-18 1982-07-13 International Flavors & Fragrances Inc. Use of mixture of aliphatic C10 -branched olefins in augmenting or enhancing the aroma of perfumes and/or perfumed articles
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NL148103B (nl) 1975-12-15
DE2042037C3 (de) 1985-10-03
CH542922A (de) 1973-11-30
FR2059755A1 (US06482866-20021119-C00009.png) 1971-06-04
BE755338A (fr) 1971-02-26
NL134221C (US06482866-20021119-C00009.png)
DE2042037A1 (de) 1971-03-04
GB1329086A (en) 1973-09-05
NL7012822A (US06482866-20021119-C00009.png) 1971-03-02
DE2042037B2 (de) 1978-05-11
FR2059755B1 (US06482866-20021119-C00009.png) 1976-09-03

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