US3627517A - Ternary fusible alloy - Google Patents

Ternary fusible alloy Download PDF

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Publication number
US3627517A
US3627517A US783764A US3627517DA US3627517A US 3627517 A US3627517 A US 3627517A US 783764 A US783764 A US 783764A US 3627517D A US3627517D A US 3627517DA US 3627517 A US3627517 A US 3627517A
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US
United States
Prior art keywords
alloy
ternary
fusible
eutectic
melting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US783764A
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English (en)
Inventor
Rolf A Ibscher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Canada Co
Original Assignee
General Electric Canada Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Canada Co filed Critical General Electric Canada Co
Application granted granted Critical
Publication of US3627517A publication Critical patent/US3627517A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H85/00Protective devices in which the current flows through a part of fusible material and this current is interrupted by displacement of the fusible material when this current becomes excessive
    • H01H85/02Details
    • H01H85/04Fuses, i.e. expendable parts of the protective device, e.g. cartridges
    • H01H85/05Component parts thereof
    • H01H85/055Fusible members
    • H01H85/06Fusible members characterised by the fusible material
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C13/00Alloys based on tin
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C28/00Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H37/00Thermally-actuated switches
    • H01H37/74Switches in which only the opening movement or only the closing movement of a contact is effected by heating or cooling
    • H01H37/76Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material
    • H01H2037/768Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material characterised by the composition of the fusible material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H37/00Thermally-actuated switches
    • H01H37/74Switches in which only the opening movement or only the closing movement of a contact is effected by heating or cooling
    • H01H37/76Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material
    • H01H37/761Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material with a fusible element forming part of the switched circuit

Definitions

  • This invention relates to fusible or low melting point alloys and, more particularly, to a ternary alloy suitable for use in the manufacture of thermal protective devices for electrical circuitry.
  • fusible link comprising a length of a suitable low-melting alloy.
  • Such links are subject to stringent temperature-time standards or, in other words, must be capable of melting rapidly at a specified temperature in order to drop out of and disrupt a circuit when critical conditions arise.
  • a fusible link or the alloy from which it is made, to be suitable in every respect, must be characterized by rapid and substantially isothermal phase transition from solid to liquid.
  • the alloy must possess satisfactory mechanical strength and good resistance to the formation of surface films (occurring primarily through the agency of oxidation), such that the desired response to critical temperature changes remains unimpaired.
  • an alloy in order to be satisfactory in use as a fusible link, must remain substantially solid with limited expansion or contraction until the temperature in its operative environment reaches a predetermined point. At that time, the alloy must transform rapidly and substantially isothermally to the liquid phase, dropping out of circuit and thus disrupting the latter.
  • the temperature range over which an alloy melts may be termed a function of the variation as between the crystallization rates of the components elements, while the phase transition time may be stated as a function of the various crystallization rates considered together with the latent heat of fusion of the particular composition.
  • the melting point of an alloy bears no apparent relationship to the individual melting points of its components and, similarly, it is extremely difiicult to predict, with any accuracy, the numerical value of latent heat of fusion of an alloy merely by reference to the characteristics of the individual elements involved.
  • Copper was found to provide a definite decrease in melting point while silver has an even more desirable effect.
  • metallographic examination of a sample of the new alloy revealed a substantially homogenous structure over the entire cross-section, indicative of a eutectic or near-eutectic composition.
  • the true eutectic is the most preferred composition when one considers the desirability of a pure isothermal transition, but observation has established that for the purpose in question, the alloy may be comprised within the approximate composition given and still melt at a temperature in the prescribed area.
  • a fusible link manufactured from the novel material proved to have satisfactory mechanical strength for its purpose and exhibited good resistance to surface film formation (oxidation).
  • the new ternary alloy of In- Sn-Ag is eminently suitable for use in the manufacture of fusible links while additions of about 0.17% copper to the In-Sn eutectic result in an alloy suitable for use under present regulations, having an M.P. of 1l7.6 C. :1" C.
  • the ternary fusible alloy according to the present invention can be processed to any desired configuration for use as a fusible link.
  • any desired configuration for use as a fusible link.
  • such use is not intended as being exhaustive of the overall utility of the alloy.
  • Pat. No. 3,354,282 reveals a thermal fuse with capillary action in which the molten fusible link will separate reliably and completely under any practical service conditions, in any position, and after long, useful life.
  • a tubular sleeve Enclosed within a tubular sleeve is a fusible link and a means attached to each end of the fusible link for providing capillary action on the molten fuse link so that when the fusible link melts upon increase of the environmental temperature beyond its melting point, the molten material is withdrawn into the capillary means thus en suring that the current flow in the electrical lead is entirely interrupted.
  • a ternary fusible alloy comprising a substantially eutectic composition of ln-Sn with the balance made up of silver.
  • a ternary fusible alloy having a composition of about 51.4% In, 47.3% Sn, and 1.3% Ag, characterized by a melting point of 113.811 C.
  • a ternary fusible alloy as recited in claim 1, wherein the composition is chosen to have the lowest possible melting point, which is approximately 114 C.
  • a ternary fusible alloy as recited in claim 1, wherein a sufiicient amount of silver is added to the ln-Sn to lower its melting point below the 117 C. minimum melting point of an In-Sn eutectic.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Fuses (AREA)
US783764A 1967-12-16 1968-12-13 Ternary fusible alloy Expired - Lifetime US3627517A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA7770 1967-12-16

Publications (1)

Publication Number Publication Date
US3627517A true US3627517A (en) 1971-12-14

Family

ID=4083945

Family Applications (1)

Application Number Title Priority Date Filing Date
US783764A Expired - Lifetime US3627517A (en) 1967-12-16 1968-12-13 Ternary fusible alloy

Country Status (6)

Country Link
US (1) US3627517A (fr)
CA (1) CA868830A (fr)
DE (1) DE1814107A1 (fr)
FR (1) FR1594275A (fr)
GB (1) GB1244186A (fr)
NO (1) NO120655B (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3833362A (en) * 1970-09-18 1974-09-03 Ppg Industries Inc Electroconductive solder
US5120498A (en) * 1991-05-15 1992-06-09 C-Innovations, Inc. Solders having exceptional adhesion to glass
US5242658A (en) * 1992-07-07 1993-09-07 The Indium Corporation Of America Lead-free alloy containing tin, zinc and indium
US5256370A (en) * 1992-05-04 1993-10-26 The Indium Corporation Of America Lead-free alloy containing tin, silver and indium
EP1189252A1 (fr) * 2000-09-13 2002-03-20 Siemens Aktiengesellschaft Elément fusible, son procédé de fabrication et matériau de soudure
EP1383149A2 (fr) * 2002-07-16 2004-01-21 Uchihashi Estec Co., Ltd. Fusible thermique à alliage et fil pour un élément fusible
WO2005045870A1 (fr) * 2003-11-06 2005-05-19 Pratt & Whitney Canada Corp. Interrupteur de courant a optimisation electromagnetique
US20050128044A1 (en) * 2003-12-15 2005-06-16 Uchihashi Estec Co., Ltd. Alloy type thermal fuse and wire member for a thermal fuse element
US20140138155A1 (en) * 2011-05-03 2014-05-22 Pilkington Group Limited Glazing with a soldered connector

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2121120C3 (de) * 1971-04-29 1973-11-22 Robert Bosch Gmbh, 7000 Stuttgart Übertemperatursicherung fur eine elektrische Wicklung

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3833362A (en) * 1970-09-18 1974-09-03 Ppg Industries Inc Electroconductive solder
US5120498A (en) * 1991-05-15 1992-06-09 C-Innovations, Inc. Solders having exceptional adhesion to glass
US5256370A (en) * 1992-05-04 1993-10-26 The Indium Corporation Of America Lead-free alloy containing tin, silver and indium
US5580520A (en) * 1992-05-04 1996-12-03 The Indium Corporation Of America Lead-free alloy containing tin, silver and indium
US5242658A (en) * 1992-07-07 1993-09-07 The Indium Corporation Of America Lead-free alloy containing tin, zinc and indium
US7109839B2 (en) 2000-09-13 2006-09-19 Siemens Aktiengesellschaft Fuse link, method for the production thereof and soldering substance
EP1189252A1 (fr) * 2000-09-13 2002-03-20 Siemens Aktiengesellschaft Elément fusible, son procédé de fabrication et matériau de soudure
WO2002023575A1 (fr) * 2000-09-13 2002-03-21 Siemens Aktiengesellschaft Cartouche fusible, son procede de production, ainsi que substance de brasure
CZ299341B6 (cs) * 2000-09-13 2008-06-25 Siemens Aktiengesellschaft Pojistková vložka, zpusob její výroby a pájecí materiál
US20040027226A1 (en) * 2000-09-13 2004-02-12 Alexander Etschmaier Fuse link, method for the production thereof and soldering substance
CN100350539C (zh) * 2000-09-13 2007-11-21 西门子公司 保险丝、其制造方法与焊料
EP1383149A3 (fr) * 2002-07-16 2004-01-28 Uchihashi Estec Co., Ltd. Fusible thermique à alliage et fil pour un élément fusible
EP1383149A2 (fr) * 2002-07-16 2004-01-21 Uchihashi Estec Co., Ltd. Fusible thermique à alliage et fil pour un élément fusible
WO2005045870A1 (fr) * 2003-11-06 2005-05-19 Pratt & Whitney Canada Corp. Interrupteur de courant a optimisation electromagnetique
EP1544883A1 (fr) * 2003-12-15 2005-06-22 Uchihashi Estec Co., Ltd. Fusible thermique à alliage et fil pour un élément fusible
US20050128044A1 (en) * 2003-12-15 2005-06-16 Uchihashi Estec Co., Ltd. Alloy type thermal fuse and wire member for a thermal fuse element
CN100508095C (zh) * 2003-12-15 2009-07-01 内桥艾斯泰克股份有限公司 合金型温度熔断器和温度熔丝用线材
US20140138155A1 (en) * 2011-05-03 2014-05-22 Pilkington Group Limited Glazing with a soldered connector
US9595768B2 (en) * 2011-05-03 2017-03-14 Pilkington Group Limited Glazing with a soldered connector

Also Published As

Publication number Publication date
DE1814107A1 (de) 1969-08-14
NO120655B (fr) 1970-11-16
FR1594275A (fr) 1970-06-01
CA868830A (en) 1971-04-20
GB1244186A (en) 1971-08-25

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