US3519419A - Superplastic nickel alloys - Google Patents
Superplastic nickel alloys Download PDFInfo
- Publication number
- US3519419A US3519419A US563630A US3519419DA US3519419A US 3519419 A US3519419 A US 3519419A US 563630 A US563630 A US 563630A US 3519419D A US3519419D A US 3519419DA US 3519419 A US3519419 A US 3519419A
- Authority
- US
- United States
- Prior art keywords
- alloy
- alloys
- chromium
- gamma
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000990 Ni alloy Inorganic materials 0.000 title description 6
- 229910045601 alloy Inorganic materials 0.000 description 282
- 239000000956 alloy Substances 0.000 description 282
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 137
- 229910052804 chromium Inorganic materials 0.000 description 94
- 239000011651 chromium Substances 0.000 description 94
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 91
- 239000010936 titanium Substances 0.000 description 72
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 70
- 229910052719 titanium Inorganic materials 0.000 description 68
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 66
- 229910052759 nickel Inorganic materials 0.000 description 60
- 239000000203 mixture Substances 0.000 description 36
- 229910052782 aluminium Inorganic materials 0.000 description 35
- 229910052742 iron Inorganic materials 0.000 description 35
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 29
- 238000000034 method Methods 0.000 description 25
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 24
- 238000005260 corrosion Methods 0.000 description 20
- 238000005096 rolling process Methods 0.000 description 20
- 230000007797 corrosion Effects 0.000 description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
- 229910052799 carbon Inorganic materials 0.000 description 18
- 239000002245 particle Substances 0.000 description 18
- 239000004014 plasticizer Substances 0.000 description 17
- 239000011777 magnesium Substances 0.000 description 14
- 230000008569 process Effects 0.000 description 14
- 239000011575 calcium Substances 0.000 description 13
- 239000010941 cobalt Substances 0.000 description 13
- 229910017052 cobalt Inorganic materials 0.000 description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 12
- 229910052791 calcium Inorganic materials 0.000 description 12
- 229910052749 magnesium Inorganic materials 0.000 description 12
- 239000010955 niobium Substances 0.000 description 12
- 230000009467 reduction Effects 0.000 description 12
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 10
- 229910052796 boron Inorganic materials 0.000 description 10
- 229910052750 molybdenum Inorganic materials 0.000 description 10
- 239000011733 molybdenum Substances 0.000 description 10
- 229910052715 tantalum Inorganic materials 0.000 description 10
- 229910052726 zirconium Inorganic materials 0.000 description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 9
- 239000000788 chromium alloy Substances 0.000 description 9
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 9
- 229910052721 tungsten Inorganic materials 0.000 description 9
- 239000010937 tungsten Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- 238000001953 recrystallisation Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 238000005098 hot rolling Methods 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 230000035882 stress Effects 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052790 beryllium Inorganic materials 0.000 description 5
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 5
- 238000005242 forging Methods 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 230000001376 precipitating effect Effects 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- 229910018487 Ni—Cr Inorganic materials 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000002596 correlated effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000000399 optical microscopy Methods 0.000 description 3
- 230000033458 reproduction Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- -1 0.1% or more iron Chemical compound 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- RZJQYRCNDBMIAG-UHFFFAOYSA-N [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] Chemical class [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] RZJQYRCNDBMIAG-UHFFFAOYSA-N 0.000 description 2
- BIJOYKCOMBZXAE-UHFFFAOYSA-N chromium iron nickel Chemical compound [Cr].[Fe].[Ni] BIJOYKCOMBZXAE-UHFFFAOYSA-N 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 150000002611 lead compounds Chemical class 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 238000003303 reheating Methods 0.000 description 2
- 238000005486 sulfidation Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 239000012498 ultrapure water Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 229910000846 In alloy Inorganic materials 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 241000283986 Lepus Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- GVEHJMMRQRRJPM-UHFFFAOYSA-N chromium(2+);methanidylidynechromium Chemical compound [Cr+2].[Cr]#[C-].[Cr]#[C-] GVEHJMMRQRRJPM-UHFFFAOYSA-N 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910003470 tongbaite Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/052—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 40%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/06—Alloys based on chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S420/00—Alloys or metallic compositions
- Y10S420/902—Superplastic
Definitions
- the alloys can also contain up to 3% molybdenum and up to about 1.5% tungsten for enhancing corrosion resistance and room temperature strength, but the total molybdenum plus one half the percentage of tungsten should not exceed about 3% in order to avoid detrimental phases such as the sigma phase and to avoid adversely affecting hot workability.
- the alloys can contain up to about 0.1% carbon, up to about 0.5% silicon, up to about 0.5 manganese, up to 4% tantalum, provided the sum of the percent columbium plus one half the percent tantalum in the alloy does not exceed about 2.5% of the alloy, up to about 1% beryllium and up to about 0.2% vanadium.
- Gamma grain size 3/2 (1/N microns
- (l/N is an average intragranular dimension, in microns per grain, obtained by averaging the intragranular distances between a representative number of gamma grain boundaries intersecting one or more randomly oriented lines on a micrograph.
- a micron grain size microstructure of an alloy of the invention can be differentiated by optical microscopy from other alloys having larger grain sizes, the very fine grain sizes of 5 microns and less, often present in the alloy of the invention, are so fine as not to be easily resolvable by optical microscopy. Electron micrographs are usually needed if such very fine grain sizes are to be accurately measured.
- An example of a fine grain gamma-alpha microstructure having an average grain size of about 1 to 2 microns in accordance with the invention is illustrated by FIG. 5.
- alloy 37 of the invention has the important advantage of being hot workable with low rolling loads which are similar to the rolling loads for alloy I and which are very substantially lower than the loads for rolling alloy K, both of which are much lower in chromium.
- a corroison resistant, unfired pressure vessel can be produced by providing a tube of the fine grain gamma-alpha alloy, welding one end of the tube closed gas-tight, heating a portion of the'tube to about 1800 F., connecting the open end of the tube to a gas pressure source and expanding the heated portion to a predetermined size by fluid pressure exerted at the interior of the tube. Thereafter, the pressure is released, the article cooled to room temperature and the open end of the tube shortened to desired length.
- Another illustration is the production from a flat plate, of a dished, dimpled or grooved article, by a procedure wherein a heated portion of the plate is bulged and expanded by gas pressure on one side to force the opposite side into contact with an open-faced forming die.
- An alloy as set forth in claim 1 containing 34% to about 43% chromium, about 7% to 34% iron, about 0.55% to 2.5 titanium, up to about 0.08% carbon, up to about 1.4% aluminum, with at least 0.36% effective titanium and a titanium-to-aluminum ratio of at least about 1.5 :1 characterized by superplastic deformability enabling the alloy to be elongated at least 500% in tension at 1800 F. at a constant elongation rate from an initial strain rate of at least about 0.16 inch per inch per minute.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55918566A | 1966-06-21 | 1966-06-21 | |
| US56363066A | 1966-06-30 | 1966-06-30 | |
| US63851967A | 1967-05-15 | 1967-05-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3519419A true US3519419A (en) | 1970-07-07 |
Family
ID=27415788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US563630A Expired - Lifetime US3519419A (en) | 1966-06-21 | 1966-06-30 | Superplastic nickel alloys |
Country Status (12)
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3640777A (en) * | 1968-02-08 | 1972-02-08 | Int Nickel Co | Heat treatment of high-chromium alloys to improve ductility |
| US3816106A (en) * | 1972-08-25 | 1974-06-11 | Int Nickel Co | Strong, corrosion resistant alloy |
| US3837846A (en) * | 1971-04-08 | 1974-09-24 | Ver Deutsche Metallwerke Ag | Austenitic steel alloy adapted to be welded without cracking |
| US3975219A (en) * | 1975-09-02 | 1976-08-17 | United Technologies Corporation | Thermomechanical treatment for nickel base superalloys |
| US4025314A (en) * | 1975-12-17 | 1977-05-24 | The International Nickel Company, Inc. | Nickel-chromium filler metal |
| US4065302A (en) * | 1975-12-29 | 1977-12-27 | The International Nickel Company, Inc. | Powdered metal consolidation method |
| US4066448A (en) * | 1976-04-07 | 1978-01-03 | The International Nickel Company, Inc. | Nickel-chromium-cobalt containing alloys |
| US4492672A (en) * | 1982-04-19 | 1985-01-08 | The United States Of America As Represented By The Secretary Of The Navy | Enhanced microstructural stability of nickel alloys |
| US4529452A (en) * | 1984-07-30 | 1985-07-16 | United Technologies Corporation | Process for fabricating multi-alloy components |
| US4613388A (en) * | 1982-09-17 | 1986-09-23 | Rockwell International Corporation | Superplastic alloys formed by electrodeposition |
| US5413752A (en) * | 1992-10-07 | 1995-05-09 | General Electric Company | Method for making fatigue crack growth-resistant nickel-base article |
| FR2722510A1 (fr) * | 1994-07-13 | 1996-01-19 | Societe Nationale D Etude Et De Construction De Mo | Procede d'elaboration de toles en alliage 718 et de formage superplastique de ces toles |
| US20080110534A1 (en) * | 2002-12-25 | 2008-05-15 | Manabu Kanzaki | Method for manufacturing nickel alloy |
| US20090038717A1 (en) * | 2005-11-07 | 2009-02-12 | Huntington Alloys Corporation | Process for Manufacturing High Strength Corrosion Resistant Alloy For Oil Patch Applications |
| US20110011500A1 (en) * | 2007-11-19 | 2011-01-20 | Huntington Alloys Corporation | Ultra high strength alloy for severe oil and gas environments and method of preparation |
| US20120027607A1 (en) * | 2010-07-27 | 2012-02-02 | General Electric Company | Nickel alloy and articles |
| US20130224068A1 (en) * | 2010-03-23 | 2013-08-29 | Siemens Aktiengesellschaft | Metallic bondcoat with a high gamma/gamma' transition temperature and a component |
| US20160015384A1 (en) * | 2013-04-04 | 2016-01-21 | Merete Medical Gmbh | Staple Implant for Influencing the Growth in Bone Regions Bordering an Epiphyseal Plate |
| US20160067834A1 (en) * | 2014-09-05 | 2016-03-10 | Ametek, Inc. | Nickel-chromium alloy and method of making the same |
| CN108699635A (zh) * | 2016-02-24 | 2018-10-23 | 日立金属株式会社 | 热锻性优异的高强度高耐腐蚀性Ni基合金 |
| US10184166B2 (en) | 2016-06-30 | 2019-01-22 | General Electric Company | Methods for preparing superalloy articles and related articles |
| US10253382B2 (en) | 2012-06-11 | 2019-04-09 | Huntington Alloys Corporation | High-strength corrosion-resistant tubing for oil and gas completion and drilling applications, and process for manufacturing thereof |
| US10458005B2 (en) | 2016-03-15 | 2019-10-29 | Hitachi Metals, Ltd. | Heat-resistant and corrosion-resistant high-chromium nickel-based alloy with superior hot forgeability |
| US10640858B2 (en) | 2016-06-30 | 2020-05-05 | General Electric Company | Methods for preparing superalloy articles and related articles |
| CN112157122A (zh) * | 2020-11-10 | 2021-01-01 | 贵州大学 | 提高3003铝合金板材强度和塑性的深冷加工方法 |
| EP3757241A4 (en) * | 2018-02-20 | 2021-10-20 | Hitachi, Ltd. | CR-FE-NI TYPE ALLOY PRODUCT |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2708448A1 (de) * | 1976-03-01 | 1977-10-13 | Kubota Ltd | Verfahren zur herstellung von rostfreien stahlprodukten |
| US4410489A (en) * | 1981-07-17 | 1983-10-18 | Cabot Corporation | High chromium nickel base alloys |
| JPS6059291B2 (ja) * | 1982-02-23 | 1985-12-24 | 株式会社クボタ | 製紙サクションロ−ル用高腐食疲労強度二相ステンレス鋳鋼 |
| JPS6052523A (ja) * | 1983-09-01 | 1985-03-25 | Nippon Stainless Steel Co Ltd | フエライト−オ−ステナイト二相ステンレス鋼の製造方法 |
| CA1242095A (en) * | 1984-02-07 | 1988-09-20 | Akira Yoshitake | Ferritic-austenitic duplex stainless steel |
| JPS60211028A (ja) * | 1984-04-03 | 1985-10-23 | Daido Steel Co Ltd | 排気バルブ用合金 |
| JPS61119640A (ja) * | 1984-11-16 | 1986-06-06 | Honda Motor Co Ltd | 排気バルブ用合金 |
| GB2173816B (en) * | 1985-03-28 | 1989-06-21 | Sumitomo Metal Ind | Superplastic ferrous duplex-phase alloy and a hot working method therefor |
| RU2302326C2 (ru) * | 2005-09-15 | 2007-07-10 | Федеральное Государственное Унитарное Предприятие "Центральный Научно-Исследовательский Институт Конструкционных Материалов "Прометей" (Фгуп "Цнии Км "Прометей") | Состав сварочной проволоки для сварки коррозионно-стойких сталей и жаропрочных сплавов на никелевой основе |
| RU2373038C1 (ru) * | 2008-06-02 | 2009-11-20 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") | Присадочный материал на основе никеля |
| RU2441089C1 (ru) * | 2010-12-30 | 2012-01-27 | Юрий Васильевич Кузнецов | КОРРОЗИОННО-СТОЙКИЙ СПЛАВ НА ОСНОВЕ Fe-Cr-Ni, ИЗДЕЛИЕ ИЗ НЕГО И СПОСОБ ИЗГОТОВЛЕНИЯ ИЗДЕЛИЯ |
| CN104379773B (zh) | 2012-01-20 | 2017-09-12 | 索罗不锈有限责任公司 | 奥氏体不锈钢产品及其制造方法 |
| WO2017168640A1 (ja) * | 2016-03-30 | 2017-10-05 | 株式会社日立製作所 | クロム基二相合金製造物およびその製造方法 |
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- 1967-06-15 DE DE19671533976 patent/DE1533976A1/de active Pending
- 1967-06-16 NO NO168625A patent/NO122157B/no unknown
- 1967-06-19 NO NO168644A patent/NO121050B/no unknown
- 1967-06-19 NL NL6708496A patent/NL6708496A/xx unknown
- 1967-06-20 ES ES342039A patent/ES342039A1/es not_active Expired
- 1967-06-20 ES ES342038A patent/ES342038A1/es not_active Expired
- 1967-06-20 AT AT572967A patent/AT295176B/de not_active IP Right Cessation
- 1967-06-20 ES ES342040A patent/ES342040A1/es not_active Expired
- 1967-06-21 BE BE700250D patent/BE700250A/xx unknown
- 1967-06-21 SE SE8808/67A patent/SE346122B/xx unknown
- 1967-06-21 SE SE8809/67A patent/SE346121B/xx unknown
- 1967-06-21 BE BE700251D patent/BE700251A/xx unknown
- 1967-06-22 AT AT581167A patent/AT296636B/de not_active IP Right Cessation
- 1967-06-22 AT AT571470A patent/AT295872B/de not_active IP Right Cessation
- 1967-06-28 FR FR1550996D patent/FR1550996A/fr not_active Expired
- 1967-06-29 DE DE1558521A patent/DE1558521C3/de not_active Expired
- 1967-06-30 JP JP42041913A patent/JPS512413B1/ja active Pending
- 1967-06-30 BE BE700752D patent/BE700752A/xx unknown
- 1967-06-30 CH CH931067A patent/CH524685A/fr not_active IP Right Cessation
- 1967-06-30 NL NL6709130A patent/NL6709130A/xx unknown
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| US2809139A (en) * | 1952-10-24 | 1957-10-08 | Research Corp | Method for heat treating chromium base alloy |
| US3015558A (en) * | 1959-09-16 | 1962-01-02 | Grant | Nickel-chromium-aluminum heat resisting alloy |
| US3212886A (en) * | 1961-10-03 | 1965-10-19 | Armco Steel Corp | High temperature alloy |
| US3340101A (en) * | 1965-04-02 | 1967-09-05 | Ibm | Thermoforming of metals |
Cited By (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3640777A (en) * | 1968-02-08 | 1972-02-08 | Int Nickel Co | Heat treatment of high-chromium alloys to improve ductility |
| US3837846A (en) * | 1971-04-08 | 1974-09-24 | Ver Deutsche Metallwerke Ag | Austenitic steel alloy adapted to be welded without cracking |
| US3816106A (en) * | 1972-08-25 | 1974-06-11 | Int Nickel Co | Strong, corrosion resistant alloy |
| US3975219A (en) * | 1975-09-02 | 1976-08-17 | United Technologies Corporation | Thermomechanical treatment for nickel base superalloys |
| US4025314A (en) * | 1975-12-17 | 1977-05-24 | The International Nickel Company, Inc. | Nickel-chromium filler metal |
| DE2656929A1 (de) * | 1975-12-17 | 1977-07-07 | Inco Europ Ltd | Nickel-chrom-legierung |
| US4065302A (en) * | 1975-12-29 | 1977-12-27 | The International Nickel Company, Inc. | Powdered metal consolidation method |
| US4066448A (en) * | 1976-04-07 | 1978-01-03 | The International Nickel Company, Inc. | Nickel-chromium-cobalt containing alloys |
| US4492672A (en) * | 1982-04-19 | 1985-01-08 | The United States Of America As Represented By The Secretary Of The Navy | Enhanced microstructural stability of nickel alloys |
| US4613388A (en) * | 1982-09-17 | 1986-09-23 | Rockwell International Corporation | Superplastic alloys formed by electrodeposition |
| US4529452A (en) * | 1984-07-30 | 1985-07-16 | United Technologies Corporation | Process for fabricating multi-alloy components |
| US5413752A (en) * | 1992-10-07 | 1995-05-09 | General Electric Company | Method for making fatigue crack growth-resistant nickel-base article |
| FR2722510A1 (fr) * | 1994-07-13 | 1996-01-19 | Societe Nationale D Etude Et De Construction De Mo | Procede d'elaboration de toles en alliage 718 et de formage superplastique de ces toles |
| US6328827B1 (en) | 1994-07-13 | 2001-12-11 | Societe Nationale d'Etude et de Construction de Moteurs d'Aviation “SNECMA” | Method of manufacturing sheets made of alloy 718 for the superplastic forming of parts therefrom |
| US7799152B2 (en) * | 2002-12-25 | 2010-09-21 | Sumitomo Metal Industries, Ltd. | Method for manufacturing nickel alloy |
| US20080110534A1 (en) * | 2002-12-25 | 2008-05-15 | Manabu Kanzaki | Method for manufacturing nickel alloy |
| US20090038717A1 (en) * | 2005-11-07 | 2009-02-12 | Huntington Alloys Corporation | Process for Manufacturing High Strength Corrosion Resistant Alloy For Oil Patch Applications |
| US8133334B2 (en) * | 2005-11-07 | 2012-03-13 | Huntington Alloys Corporation | Process for manufacturing high strength corrosion resistant alloy for oil patch applications |
| US20110011500A1 (en) * | 2007-11-19 | 2011-01-20 | Huntington Alloys Corporation | Ultra high strength alloy for severe oil and gas environments and method of preparation |
| US10100392B2 (en) | 2007-11-19 | 2018-10-16 | Huntington Alloys Corporation | Ultra high strength alloy for severe oil and gas environments and method of preparation |
| US9017490B2 (en) | 2007-11-19 | 2015-04-28 | Huntington Alloys Corporation | Ultra high strength alloy for severe oil and gas environments and method of preparation |
| US9074268B2 (en) * | 2010-03-23 | 2015-07-07 | Siemens Aktiengesellschaft | Metallic bondcoat with a high gamma/gamma' transition temperature and a component |
| US20130224068A1 (en) * | 2010-03-23 | 2013-08-29 | Siemens Aktiengesellschaft | Metallic bondcoat with a high gamma/gamma' transition temperature and a component |
| US20120027607A1 (en) * | 2010-07-27 | 2012-02-02 | General Electric Company | Nickel alloy and articles |
| US9562276B2 (en) | 2010-07-27 | 2017-02-07 | General Electric Company | Nickel alloy and articles |
| US8608877B2 (en) * | 2010-07-27 | 2013-12-17 | General Electric Company | Nickel alloy and articles |
| US10253382B2 (en) | 2012-06-11 | 2019-04-09 | Huntington Alloys Corporation | High-strength corrosion-resistant tubing for oil and gas completion and drilling applications, and process for manufacturing thereof |
| US20160015384A1 (en) * | 2013-04-04 | 2016-01-21 | Merete Medical Gmbh | Staple Implant for Influencing the Growth in Bone Regions Bordering an Epiphyseal Plate |
| US10085743B2 (en) * | 2013-04-04 | 2018-10-02 | Aristotech Industries Gmbh | Staple implant for influencing the growth in bone regions bordering an epiphyseal plate |
| US20160067834A1 (en) * | 2014-09-05 | 2016-03-10 | Ametek, Inc. | Nickel-chromium alloy and method of making the same |
| US11130201B2 (en) * | 2014-09-05 | 2021-09-28 | Ametek, Inc. | Nickel-chromium alloy and method of making the same |
| CN108699635A (zh) * | 2016-02-24 | 2018-10-23 | 日立金属株式会社 | 热锻性优异的高强度高耐腐蚀性Ni基合金 |
| US10450635B2 (en) | 2016-02-24 | 2019-10-22 | Hitachi Metals, Ltd. | High strength and high corrosion-resistance nickle-based alloy with superior hot forgeability |
| US10458005B2 (en) | 2016-03-15 | 2019-10-29 | Hitachi Metals, Ltd. | Heat-resistant and corrosion-resistant high-chromium nickel-based alloy with superior hot forgeability |
| US10640858B2 (en) | 2016-06-30 | 2020-05-05 | General Electric Company | Methods for preparing superalloy articles and related articles |
| US10184166B2 (en) | 2016-06-30 | 2019-01-22 | General Electric Company | Methods for preparing superalloy articles and related articles |
| EP3757241A4 (en) * | 2018-02-20 | 2021-10-20 | Hitachi, Ltd. | CR-FE-NI TYPE ALLOY PRODUCT |
| US11466347B2 (en) | 2018-02-20 | 2022-10-11 | Hitachi, Ltd. | Cr—Fe—Ni-based alloy product |
| CN112157122A (zh) * | 2020-11-10 | 2021-01-01 | 贵州大学 | 提高3003铝合金板材强度和塑性的深冷加工方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1192945A (en) | 1970-05-28 |
| AT295176B (de) | 1971-12-27 |
| CH524685A (fr) | 1972-06-30 |
| FR1550996A (enrdf_load_stackoverflow) | 1968-12-27 |
| NO122157B (enrdf_load_stackoverflow) | 1971-05-24 |
| SE346121B (enrdf_load_stackoverflow) | 1972-06-26 |
| DE1558521A1 (de) | 1970-04-02 |
| DE1558519A1 (de) | 1970-04-09 |
| NL6709130A (enrdf_load_stackoverflow) | 1968-01-02 |
| SE346122B (enrdf_load_stackoverflow) | 1972-06-26 |
| AT295872B (de) | 1972-01-25 |
| NO121050B (enrdf_load_stackoverflow) | 1971-01-11 |
| DE1533976A1 (de) | 1970-06-18 |
| AT296636B (de) | 1972-02-25 |
| BE700250A (enrdf_load_stackoverflow) | 1967-12-31 |
| BE700251A (enrdf_load_stackoverflow) | 1967-12-21 |
| BE700752A (enrdf_load_stackoverflow) | 1968-01-02 |
| DE1558521C3 (de) | 1973-10-31 |
| NL6708309A (enrdf_load_stackoverflow) | 1967-12-22 |
| DE1558521B2 (de) | 1973-04-12 |
| GB1192934A (en) | 1970-05-28 |
| NL6708496A (enrdf_load_stackoverflow) | 1967-12-22 |
| ES342038A1 (es) | 1968-10-01 |
| ES342039A1 (es) | 1968-10-16 |
| ES342040A1 (es) | 1968-10-16 |
| JPS512413B1 (enrdf_load_stackoverflow) | 1976-01-26 |
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