US3385748A - Water release transfer - Google Patents

Water release transfer Download PDF

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Publication number
US3385748A
US3385748A US295054A US29505463A US3385748A US 3385748 A US3385748 A US 3385748A US 295054 A US295054 A US 295054A US 29505463 A US29505463 A US 29505463A US 3385748 A US3385748 A US 3385748A
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US
United States
Prior art keywords
layer
gold
covercoat
design
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US295054A
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English (en)
Inventor
Neale Kenneth William James
Pointon David Wellings
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Application granted granted Critical
Publication of US3385748A publication Critical patent/US3385748A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/12—Transfer pictures or the like, e.g. decalcomanias
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/175—Transfer using solvent
    • B44C1/1752—Decalcomanias provided with a particular decorative layer, e.g. being specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
    • C04B41/4511—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application using temporarily supports, e.g. decalcomania transfers or mould surfaces
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1438—Metal containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23—Sheet including cover or casing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23—Sheet including cover or casing
    • Y10T428/239—Complete cover or casing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/2486—Intermediate layer is discontinuous or differential with outer strippable or release layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/24868—Translucent outer layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24917—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer

Definitions

  • a decalcomania or transfer for use in the decoration of a heat-resisting base usually comprises a sheet or backingor absorbent paper carrying a layer of Water-soluble gum to 'which is directly :applied either a cellulose support film, which itself carries a design to be applied to the base, or the design itself, which is then covered by a support film, which thus constitutes a covercoat as well as a support for the design after its release from the paper backing and before firing of the base decorated therewith.
  • the design which may be applied to the transfer paper in -any suitable manner, such as by the silk-screen printing method, may consist of a ceramic color or vitrifiable enamel or of a metallic Lustre composition, such, for example, as lthat known as Liquid Gold, which consists essentially of a solution of a sulpho-resinate of gold in lsuitable solvents, or of a mixtu-re of the two materials.
  • a ceramic color or vitrifiable enamel or of a metallic Lustre composition such, for example, as lthat known as Liquid Gold, which consists essentially of a solution of a sulpho-resinate of gold in lsuitable solvents, or of a mixtu-re of the two materials.
  • decalcomanias Whilst either of the -above two kinds of decalcomania may be employed for the application of vitrifiable enamel decorations, it has been found that the successful application of decorations in gold cannot be achieved with decalcomanias in which the design is ⁇ applied over the support film, but that it is essential to employ decalcom-anias of the covercoat type, that is to say those in which the support film overlies the design.
  • the covercoat support film at present used on decalcornanias carrying gold designs is of a cellulosic nature and based on ethyl cellulose.
  • Such a covercoat enables a bright gold ldecoration to -be obtained on a glass or pottery base after firing, but is unfortunately not sufficiently fiexible for ease of handling and, consequently, diiculty is often experienced in applying a design film to an article of complicated shape such as is frequently produced in the pottery industry.
  • covercoat-type decalcomanias carrying designs in ceramic color or vitrifiable enamel
  • resinous or resin-based covercoats such, for example, as an acrylic resin, which possesses the physical characteristics, such as Iflexibility, required for ease of application to complicated shapes and is consequently much to be prefer-red to cellulose-based materials.
  • covercoat decalcomanias Whilst resin-based covercoat decalcomanias have proved eminently suitable for use for applying ceramic colors, attempts to use such covercoats with gold-designcarrying decalcomanias have met with little or no success, mainly owing to the fact .that reaction occurs between the lgold ⁇ design film and the covercoat which destroys not only the brightness of the fired gold film, but also its adherence to the base. It appears, moreover, that the usual solvents employed in the covercoat solution tend to dissolve the gold film and separate the 4resinous material in the gold composition.
  • the principal object of this invention is to overcome the above disadvantage in the use of resin-based coverlCe coats and to enable such covercoats to be successfully used with decalcomanias carrying a design :in gold.
  • Another object is to provide an improved gold-carrying decalcomania for use in the decoration of heat-resisting bases.
  • a further object of the invention is to provide an -improved method of decorating a heat-resisting base with designs in gold.
  • the invention provides a decalcomania or transfer of the c-overcoat support film type in which the design is applied to -a paper backing beneath the support film Whichconstitutes the covercoat, which comprises a design layer formed of, or comprising a gold-containing composition, a covercoat support film formed of a resin-based material, and, between the ⁇ design layer and the covercoat film, a protective layer of an oxidizable or polymerizable material which is impervious to the covercoat material and is inert to the gold in the design layer.
  • the intermediate protective layer prevents penetration of any solvents from the covercoat film to the gold design and also prevents any reaction -between the resin in -the covercoat and the gold in the design layer during firing of the design on the base.
  • the invention also comprises a method of making a decalcomania or transfer of the covercoat support film type including the steps of applying 'a gold-containing design layer to a paper backing, applying, to the said layer, an intermediate protective layer of an oxidizable or polymerizable material which is inert to the gold in the design laye-r and then -applying to said intermediate layer a covercoat support film formed of a resin-based -material, said intermedate layer also being impervious to said covercoat material.
  • the intermediate protective layer may consist of :an alkyd resin, a phenolic resin, or a urea resin.
  • the covercoat support film may consist of any known resin-based covercoat solution at present used with cer-amic color or enamel decalcomanias, such, for example, as a methyl methacrylate resin-based film.
  • the intermediate polymerizable protective layer may advantageously have the following composition, namely,
  • a suitable covercoat support film may have the following composition:
  • the gold-containing design layer used may be any known and commercially available Liquid Gold preparation.
  • the composition of such materials forms no part of this invention, and it will sufiice to Say that in general they are composed of -a sulpho-resinate of gold in suitable solvents, usually with the addition of the resinates of other metals.
  • the design layer may consist solely of a gold preparation, or of a mixture of such a preparation and one or more ceramic colors or vitrifiable enamels, -according to the requirements of the final desired decoration.
  • 1 represents a gummed paper backing, the adhesive layer being represented at 1a; 2 a design film or layer formed of a Liquid Gold preparation, 3 an alkyd resin protective layer of the above specified composition, and 4 a covercoat support lm also having the composition given above.
  • the layers 2, 3 and 4 are each preferably applied by the silk-screen printing method, the gold design layer being applied through a plain weave mesh screen having 200 strands to the inch.
  • a coarser mesh screen having 90 strands to the inch is preferably used for applying the the composition given above.
  • any other suitable Liquid Gold design preparation may be used, and linseed oil or tung oil or another polymerizable resin other than an alkyd resin may be employed.
  • the covercoat may have a different composition from that given above.
  • the constituent layers of the decalcomania need not be applied by the silk-screen printing method but any other suitable method, such as spraying or painting may be used instead.
  • the invention is intended to include within its scope a method of decorating a heat-resisting base with a design or decoration in gold with the use of decalcomania in accordance with,
  • a water release transfer of the covercoat support film kind comprising a paper backing carrying a layer of a water-soluble adhesive, a design layer comprising a sulfo-resinate of gold on the said layer of water-soluble adhesive, a protective layer comprising a material selected from the group consisting of alkyd resins, phenolic resins, and urea resins covering said design layer and a flexible covercoat lm formed of resin-based material covering the said protective layer including the edges of said protective layer and the edges of said design layer, the protective layer being impervious to the covercoat film and inert to the gold in the design layer.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Laminated Bodies (AREA)
US295054A 1962-07-17 1963-07-15 Water release transfer Expired - Lifetime US3385748A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB27390/62A GB964938A (en) 1962-07-17 1962-07-17 Improvements in and relating to the decoration of heat-resistance bases

Publications (1)

Publication Number Publication Date
US3385748A true US3385748A (en) 1968-05-28

Family

ID=10258813

Family Applications (1)

Application Number Title Priority Date Filing Date
US295054A Expired - Lifetime US3385748A (en) 1962-07-17 1963-07-15 Water release transfer

Country Status (5)

Country Link
US (1) US3385748A (fr)
DE (1) DE1232168B (fr)
GB (1) GB964938A (fr)
MC (1) MC414A1 (fr)
NL (2) NL140783B (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3452861A (en) * 1966-03-09 1969-07-01 Minnesota Mining & Mfg Decorative wood grain sheet material for automobile panels
US3519525A (en) * 1965-10-02 1970-07-07 Wilh Jackstadt & Co Self-sealing label
US3864855A (en) * 1969-12-08 1975-02-11 Avery Products Corp Destructible label system
US3900643A (en) * 1972-12-20 1975-08-19 Leipold F Xavier Decalcomania with removable lacquer coating
US4056648A (en) * 1975-06-16 1977-11-01 Denbyware Limited Transfers
US4100010A (en) * 1974-06-12 1978-07-11 The D. L. Auld Company Method for making decorative emblems
US4748071A (en) * 1986-05-16 1988-05-31 W. C. Heraeus Gmbh Decal for decoration with bright noble metal
USRE33175E (en) * 1974-06-12 1990-03-06 The D. L. Auld Company Method for making decorative emblems
US5032449A (en) * 1989-01-26 1991-07-16 Af Strom Oscar R F Decals and processes for transfer of images to substrates
US6521322B1 (en) 2001-03-13 2003-02-18 Bryan A. Netsch Food package insert
US6544629B1 (en) 2001-05-24 2003-04-08 Bryan A. Netsch Food grade laminate
US20040059026A1 (en) * 2000-10-13 2004-03-25 Elisabeth Clamer Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing
US6794004B1 (en) 2001-03-13 2004-09-21 Bryan A. Netsch Food package insert and decoder game
US6811646B1 (en) 2001-03-13 2004-11-02 Bryan A. Netsch Food package insert and decoder game

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4068033A (en) * 1976-11-17 1978-01-10 Commercial Decal, Inc. Heat-releasable decalcomanias and adhesive composition therefor
DE19831141C2 (de) 1998-07-11 2003-02-27 Dmc2 Degussa Metals Catalysts Edelmetallpräparat und dessen Verwendung zur Herstellung von Edelmetalldekoren durch Direkt- und Indirektdruck
DE102005018672B4 (de) * 2005-04-21 2010-07-15 W.C. Heraeus Gmbh Verfahren zur Herstellung von Ätzimitationen auf silikatischen Substraten und Verwendung eines hierfür angepassten Mediums
DE102013020376A1 (de) 2013-12-05 2015-06-11 Günter Landgraf Bindemittel für die Herstellung von Siebdruckpasten
WO2023104849A1 (fr) 2021-12-08 2023-06-15 Ferro Gmbh Milieu écologique pour couleurs céramiques pour la décoration indirecte du verre, de la porcelaine, de la porcelaine phosphatique, de l'émail et de la céramique

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1634617A (en) * 1926-01-14 1927-07-05 Hart Frank Method and means for producing and affixing signs to materials
US1658263A (en) * 1925-01-14 1928-02-07 Stanley Mfg Company Metal label
US1888154A (en) * 1928-03-16 1932-11-15 Allen Leonard Manufacture and production of transfers
US2017367A (en) * 1934-02-01 1935-10-15 Kurz Konrad Method of producing an embossing foil by providing a support adapted to be embossed with a mirror coating
US2124232A (en) * 1935-10-21 1938-07-19 Foilfilm Inc Metal foil
GB784966A (en) * 1954-12-11 1957-10-23 Cromtryck Aktiebolag Improvements in or relating to the application of decalcomanias
US2970076A (en) * 1957-01-14 1961-01-31 Meyercord Co Vitreous decalcomania and method of decorating ceramic articles
US3156580A (en) * 1960-01-29 1964-11-10 Bell Aerospace Corp Method of surface finishing metal surfaces with epoxy and acrylic resins

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE898909C (de) * 1951-10-13 1953-12-07 Francalco S R L Verfahren zum Herstellen von Abziehbildern fuer den keramischen Druck

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1658263A (en) * 1925-01-14 1928-02-07 Stanley Mfg Company Metal label
US1634617A (en) * 1926-01-14 1927-07-05 Hart Frank Method and means for producing and affixing signs to materials
US1888154A (en) * 1928-03-16 1932-11-15 Allen Leonard Manufacture and production of transfers
US2017367A (en) * 1934-02-01 1935-10-15 Kurz Konrad Method of producing an embossing foil by providing a support adapted to be embossed with a mirror coating
US2124232A (en) * 1935-10-21 1938-07-19 Foilfilm Inc Metal foil
GB784966A (en) * 1954-12-11 1957-10-23 Cromtryck Aktiebolag Improvements in or relating to the application of decalcomanias
US2970076A (en) * 1957-01-14 1961-01-31 Meyercord Co Vitreous decalcomania and method of decorating ceramic articles
US3156580A (en) * 1960-01-29 1964-11-10 Bell Aerospace Corp Method of surface finishing metal surfaces with epoxy and acrylic resins

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3519525A (en) * 1965-10-02 1970-07-07 Wilh Jackstadt & Co Self-sealing label
US3452861A (en) * 1966-03-09 1969-07-01 Minnesota Mining & Mfg Decorative wood grain sheet material for automobile panels
US3864855A (en) * 1969-12-08 1975-02-11 Avery Products Corp Destructible label system
US3900643A (en) * 1972-12-20 1975-08-19 Leipold F Xavier Decalcomania with removable lacquer coating
US4100010A (en) * 1974-06-12 1978-07-11 The D. L. Auld Company Method for making decorative emblems
USRE33175E (en) * 1974-06-12 1990-03-06 The D. L. Auld Company Method for making decorative emblems
US4056648A (en) * 1975-06-16 1977-11-01 Denbyware Limited Transfers
US4748071A (en) * 1986-05-16 1988-05-31 W. C. Heraeus Gmbh Decal for decoration with bright noble metal
US5032449A (en) * 1989-01-26 1991-07-16 Af Strom Oscar R F Decals and processes for transfer of images to substrates
US20040059026A1 (en) * 2000-10-13 2004-03-25 Elisabeth Clamer Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing
US7041722B2 (en) 2000-10-13 2006-05-09 Ferero Gmbh Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing
US6521322B1 (en) 2001-03-13 2003-02-18 Bryan A. Netsch Food package insert
US6596118B1 (en) 2001-03-13 2003-07-22 Bryan A. Netsch Food package insert
US6794004B1 (en) 2001-03-13 2004-09-21 Bryan A. Netsch Food package insert and decoder game
US6811646B1 (en) 2001-03-13 2004-11-02 Bryan A. Netsch Food package insert and decoder game
US6544629B1 (en) 2001-05-24 2003-04-08 Bryan A. Netsch Food grade laminate

Also Published As

Publication number Publication date
NL295436A (fr)
GB964938A (en) 1964-07-29
NL140783B (nl) 1974-01-15
DE1232168B (de) 1967-01-12
MC414A1 (fr) 1964-03-24

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