Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/34—Derivatives of acids of phosphorus
  • C11D1/345—Phosphates or phosphites
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/72—Ethers of polyoxyalkylene glycols
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/0026—Low foaming or foam regulating compositions

Definitions

• This invention relates in one aspect to detergent compositions and in a second aspect to low foaming deter: gent compositions especially adapted for use in automatic dishwashing machines.
• compositions have many advantageous features, nevertheless, they have the undesirable feature of foaming in the presence of raw egg soil. Since foaming can reduce the efficiency of the automatic dishwashing ma-. chine by retarding the mechanical action of the fine water sprays and by reducing the rate of rotation of the per forated spray arms in certain types of machines, it would be advantageous, therefore, to provide an automatic dish- Washing detergent which does not foam excessively-in the presence of raw egg soil or other proteinaceous matter.
• the nonionic surface active agents which are advantageously employed in the compositions of the invention are generally the polyoxyalkylene adducts of hydrophobic bases wherein the oxygen/carbon atom ratio in the oxyalkylene portion of the molecule is greater than 0.40.
• Those compositions which are condensed with hydrophobic bases to provide a polyoxyalkylene portion having an oxygen/carbon atom ratio greater than 0.40 inelude ethylene oxide, butadiene dioxide and glycidol, mixtures of these alkylene oxides with each other and with minor amounts of propylene oxide, butylene oxide, amylene oxide, styrene oxide, and other higher molecular weight al-kylene oxides.
• Ethylene oxide for example,
• 3,314,891 Patented Apr. 18, 1967 is condensed with the hydrophobic base in an amount sufficient to impart water dispersibility or solubility and surface active properties to the molecule being prepared.
• the exact amount of ethylene oxide condensed with the hydrophobic base Will depend upon the chemical characteristics of the base employed and is readily apparent to those of ordinary skill in the art relating to the synthesis of oxyalkylene surfactant condensates.
• Typical hydrophobic bases which can be condensed with ethylene oxide in order to prepare nonionic surface active agents include monoand po-lyalkyl phenols, polyoxypropylene condensed with a base having from about 1 to 6 carbon atoms and at least one reactive hydrogen atom, fatty acids, fatty amines, fatty amides and fatty alcohols.
• the hydrocarbon ethers such as the benzyl or lower alkyl ether of the polyoxyethylene surf-actant condensates are also advantageously employed inthe compositions of the invention.
• nonionic surfactants are the polyoxyethylene condensates of alkyl phenols having from about 6 to 20 carbon atoms in the alkyl portion and from about 5 to 30 ethenoxy groups in the polyoxyethylene radical.
• the alkyl substituent on the aromatic nucleus may be octyl, diamyl, n-dodecyi, polymerized propylene such as propylene tetramer and trimer, isooctyl, nonyl, etc.
• the benzyl ethers of the poly-oxyethylene condensates of monoalkyl phenols impart good properties to the compositions of the invention and at typical product corresponds to the formula:
• R is hydrogen or an alkyl radical having from about 1 to 12 carbon atoms
• R and R. are alkyl radicals having from about 6 to 16 carbon atoms and n has a value from about 10 to 40, are also suitable as nonionic surfactants.
• a typical oxyethylated polyalkyl phenol is dinonyl phenol condensed with 14 moles of ethylene oxide.
• nonionic surface active agents are co-v generic mixtures of conjugated polyoxyalkylene compounds containing in their structure at least one hydrophobic oxyalkylene chain in which the oxygen/carbon atom ratio does not exceed 0.40 and at least one ZhYdI'O': philic oxyalkylene chain in which the oxygen/carbon atom ratio is greater than 0.40.
• Polymers of oxyalkylene groups obtained from propylene oxide, butylene oxide, am ylene oxide, styrene oxide, mixtures of such oxyalkylene groups with each other and with minor amounts of polyoxyalkylene groups obtained from ethylene oxide, butadiene dioxide, and glycidol are illustrative of hydrophobic oxyalkylene chains having an oxygen/carbon atom ratio not exceeding 0.40.
• Polymers of oxyalkylene groups obtained from ethylene oxide, butadiene dioxide, glycidol, mixtures of such oxyalkylene groups with each other and with minor amounts of oxyalkylene groups obtained from propylene oxide, butylene oxide, a-rny-lene oxide and styrene oxide are illustrative of 'hydrophilic oxyalkylene chains having an oxygen/ carbon atom ratio greater than 0.40.
• conjugated polyoxyalkylene compounds 'hich can be used in the compositions of the invention re those which correspond to the formula:
• Y is the residue of organic compound having rom about 1 to 6 carbon atoms and one reactive hyrogen atom, 11 has an average value of at least about .4 as determined by hydroxyl number and m has a alue such that the oxyethylene portion constitutes about to 90 weight percent of the molecule.
• vherein Y is the residue of an organic compound having rom about 2 to 6 carbon atoms and containing x re- .ctive hydrogen atoms in which x has a value of at least tbOlll'. 2, n has a value such that the molecular weight if the polyoxypropylene hydrophobic base is at least lbOll't 900 and in has a value such that the oxyethylene :ontent of the molecule is from about to 90 weight )ercent.
• Compounds falling within the scope of the lefinition for Y include, for example, propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene iiamine and the like.
• the oxypropyl- :ne chains optionally, but advantageously, contain small amounts of ethylene oxide and the oxyethylene chains also optionally, but advantageously, contain small amounts of alkylene oxides such as propylene oxide and butylene oxide.
• alkylene oxides such as propylene oxide and butylene oxide.
• P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxypropylene portion is at least about 58 and m has a value such that the oxyethylene content of the molecule is from about 10 to 90 weight percent and the formula:
• n has a value such that the molecular weight of the polyoxyethylene portion is at least about 44 and m has a value such that the oxypropylene content of the molecule is from about 10 to 90 weight percent.
• the oxypropylene chains may contain optionally, but advantageously, small amounts of ethylene oxide and the oxyethylene chains may contain also optionally, but advantageously, small amounts of alkylene oxides such as propylene oxide, butylene oxide and higher alkylene oxides containing 8 to 18 carbon atoms in the alkyl chains.
• cogeneric mixtures of conjugated polyoxyalkylene compounds containing in their structure the residue of an active hydrogen-containing compound and at least one hydrophobic chain of units selected from the group consisting of oxypropylene and oxypropylene-oxyethylene units in which the oxygen/carbon atom ratio does not exceed 0.40 and at least one hydrophilic chain of units selected from the group consisting of oxyethylene and oxyethylene-oxyp-ropylene units in which the oxygen/ carbon atom ratio is greater than 0.40 are suitable nonionic surface active agents.
• nonionic surface active agents are the .4 polyoxyethylene esters of higher fatty acids having from about 8 to 22 carbon atoms in the acyl group and from about 8 to 30 ethenoxy units in the oxyethy-lene portion.
• Typical products are the polyoxyethylene adducts of tall oil, rosin acids, lauric, stearic and oleic acids and the like.
• Additional nonionic surface active agents are the polyoxyethylene condensates of higher fatty acid amines and amides having from about 8 to 22 carbon atoms in the fatty alkyl or acyl group and about 10 to 30 ethenoxy units in the oxyethylene portion.
• Illustrative products are coconut oil fatty acid amines and amides condensed with about 10 to 30 moles of ethylene oxide.
• polyoxyalkylene nonionic surface active agents are the alkylene oxide adducts of higher aliphatic alcohols and thioalcohols having from about 8 to 22 carbon atoms in the aliphatic portion and about 3 to 50 oxyalkylene units in the oxyalkylene portion.
• Typicalproducts are synthetic fatty alcohols, such as n-decyl, nundecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-hexadecyl, n-octadecyl and mixtures thereof condensed with 3 to 50 moles of ethylene oxide, a mixture of normal fatty alcohols condensedwith 8 to 20 moles of ethylene oxide and capped with benzyl halide or an alkyl halide, a mixture of normal fatty alcohols condensed with 10 to 30 moles of a mixture of ethylene and propylene oxides, a mixture of several fatty alcohols condensed sequentially with 2 to 20 moles of ethylene oxide and 3 to 10 moles of propylene oxide, in either order; or a mixture of normal fatty alcohols condensed with a mixture of propylene and ethylene oxides, in which the oxygen/carbon atom ratio is less than 0.40, followed by
• the preferred alkyl phosphate esters which are used in the compositions of this invention are predominantly monostearyl phosphate which can contain, in addition thereto, diand tristearyl phosphates and monooleyl phosphates which can contain, in addition thereto, diand trioleyl phosphates.
• the alkyl phosphate esters available on the market are generally mixtures of monoand dialkyl phosphate esters which may also contain some trialkyl phosphate.
• the preferred alkyl phosphate ester compositions can contain, in addition to the monoalkyl phosphate, up to about 50 mole percent of the dialkyl phosphate and up to about 5 weight percent of the trialkyl phosphate.
• at least 50 mole percent of the stearyl acid phosphate component is the monostearyl phosphate.
• the salts and particularly the alkali metal salts of the alkyl phosphate esters may also be employed as is apparent to anyone skilled in the art. Accordingly, the expressions stearyl acid phosphate and oleyl acid phosphate, as used herein, include the salts of the stearyl and oleyl acid phosphates.
• compositions of the invention generally contain from about 50.0 to 99.9 weight percent of the nonionic surface active agent and from about 0.1 to 50.0 Weight percent of the alkyl phosphate ester.
• the compositions are readily prepared by blending the ingredients in the aforementioned proportions in a conventional mixing ap paratus at a temperature from about room temperature up to about C., depending upon the melting point of the materials used and, when desirable, following the blending step by a grinding or flaking step so as to obtain the blended ingredients in a suitable particle size.
• the composition is then added to the automatic dishwashing detergent in order to reduce foaming during use thereof.
• the ingredients of the compositions of the invention can be added separately, in the proportions set forth, to
• the automatic dishwashing detergents to which the compositions of the invention are added in order to reduce foaming of aqueous solutions thereof in the presence of raw egg soil generally contain to 80 weight percent of an alkaline condensed phosphate salt such as tetrasodium pyrophosphate and those polyphosphates of the calcium and magnesium ion sequestering type whose Na O/P O ratios range from 1:1 to 1.67:1 and 20 to 100 weight percent of an alkaline detergent salt such as sodium carbonate, sodium bicarbonate and mixtures thereof, modified soda, diand trisodium orthophosphate, sodium metasilicate, sodium sesquisilicate, borax and sodium borate.
• these detergents often include 5 to 25 weight percent chlorinated trisodium phosphate.
• a mixture of lithium hypochlorite or chlorinated syanuric acid and trisodium phosphate can be used in place of chlorinated trisodium phosphate.
• An automatic dishwashing detergent of this type can be prepared by adding an aqueous silicate solution to substantially anhydrous sodium tripolyphosphate and subsequently adding chlorinated trisodium phosphate thereto under the conditions as described in US. Patent No. 2,895,916. Although the compositions of the invention can be added at any time during the preparation of the dishwashing detergent, they are preferably added simultaneously with the aqueous silicate solution.
• a preferred automatic dishwashing composition characterized by low forming in the presence of proteinaceous matter comprises about 80 to 99.9 weight percent of the automatic dishwashing detergent of the type described above and about 0.1 to 20 weight percent of the composition of this invention.
• the foam characteristics of the detergent compositions were measured by observing the rate of rotation of the perforated spray arm of an automatic dishwashing ma chine during the washing cycle in which raw egg soil and detergent were present in definitive quantities.
• the rate of rotation of the spray arm is, of course, inversely proportional to the amount of foam present.
• foam evaluation was carried out in a Hobart Kitchen Aid dishwasher. The procedure followed was to turn on the machine and, after part of the water had been added, turn off the machine and add the detergent composition and additives, if any, and 15 cc.
• the dishwasher was then turned on again and the balance of the water added.
• the water was at a temperature of about 160 F.
• the rate of rotation of the perforated spray arm was measured from the first to the second minute and from the third to the fourth minute. In the presence of excess foam, the rotor arm stopped or the foam overflowed.
• a spray arm rotation of about 70 rpm. or more is indicative that foam formation is being substantially depressed.
• Example I sets forth the effect of 1) a nonionic surface active agent, (2) an alkyl phosphate ester having 18 carbon atoms in the alkyl radical, and (3) a mixture of a nonionic surface active agent and the alkyl phosphate ester as foam suppressing agents for an automatic dishwashing detergent.
• composition A contained the following ingredients in the proportions set forth:
• Composition A Parts by weight Chlorinated trisodium phosphate- 12 hydrate 7.2
• Composition A and Composition A formulated with additives (1), (2) and (3) above identified were evaluated for foaming characteristics in the presence of raw egg soil in a Hobart dishwasher in accordance with the procedure previously outlined and the ingredients, quantities thereof and results are set forth in Table 1.
• the stearyl acid phosphate used in this example contained 78% by weight monostearyl acid phosphate, 17% by weight distearyl acid phosphate, balance tristearyl acid phosphate, phosphoric acid and impurit es.
• N onionic 1 defines a mixture of nonionic Surface active agents consisting of (a) weight percent polyoxyethylene-polyoxypropylene-polyoxyethylene polyol wherein the average molecular weight of the polyoxypropylene base is about 1,750 and the polyoxyethylene content of the molecule is about 25 weight percent, and (b) 10 weight percent of a polyoxyethylene-polyoxypropylenepolyoxyethylene polyol wherein the average molecular weight of the polyoxypropylene base is about 1,750 and the polyoxyethylene content of the molecule is about 10 weight percent.
• Example 2 This example sets forth the effect of additional nonionic sur-face active agents alone and in admixture with an alkyl acid phosphate ester having 18 carbon atoms in the alkyl radical as foam suppressing agents for an automatic dishwashing detergent.
• composition B contained the following ingredients in the proportions set forth:
• Composition B Parts by weight Sodium tripolyphosphate 41.80 Trisodium phosphate-12 hydrate 11.30 Sodium metasilicate, anhydrous 14.70 Sodium sulfate .51 Sodium chloride .12
• Nonionic 3 defines an N-substituted fatty acid amide raving one fatty acyl group derived from coconut oil and :wo polyoxyethylene groups attached to the nitrogen.
• the general formula is: I
• the stearyl acid phosphate ester was the same as employed in Example 1.
• Examples 1 and 2 illustrate that the combination of various nonionic surface active agents with the alkyl phosphate ester depresses foam formation to a substantial degree as compared to any of the nonionic surface active agents alone in the presence of raw egg soil.
• Examples 3-22 Examples illustrating the effectiveness of additional combinations of stearyl acid phosphate and oleyl acid phosphate with nonionic surface active agents as foam suppressing agents for automatic dishwashing detergents are provided in Table 3 below.
• compositions C, D, and E were prepared containing the following ingredients and the proportions set forth:
• Composition C Parts by weight Compositions A and B set forth above in connection with Examples 13 and Compositions C, D, and E were formulated in the proportions shown in Table 3 below with various nonionic surface active agents and the specified alkyl phosphate esters.
• nonionic surface active agents indicated by numbers ranging from 1-15 in Table 3 below, are as follows:
• Nonionics l and 2 are described above in connection with Examples 1 and 2.
• Nonionic 4 defines the benzyl ether of octylphenoxypolyethoxy ethanol having about 15 ethenoxy units in the oxyethylene portion.
• Nonionic 5 defines the polyoxyethylene adduct of branched chain nonyl phenol having about 9 to 1'0 ethenoxy units in the oxyethylene portion.
• Nonionic 6 defines the polyoxyethylene adduct of polyoxypropylene condensed with ethylene diamine wherein the oxypropylene hydrophobic base has a molecular weight of about 3600 and the oxyethylene content is about 15 weight percent of the molecule.
• Nonionic 7 defines a heteric conjugated polyoxyalkylene polyl wherein a mixture of 90 weight percent propylene oxide and 10 weight percent ethylene oxide is condensed with trimethylolpropane so as to provide a hydrophobic base having a molecular weight of about 3200 and a mixture of 90 weight percent ethylene oxide and 10 weight percent propylene oxide is subsequently condensed With the hydrophobic base so as to provide a hydrophilic portion having a molecular weight of about 1280.
• Nonionic 8 defines an ethoxylated synthetic fatty alcohol, consisting of a mixture of n-dodccanol, n-tetradecanol, n-hexadecanol and n-octadecanol, containing 60-65 percent by weight of ethylene oxide.
• Nonionic 9 defines a polyoxyethylene ester of tall oil.
• Nonionic 1O defines the polyoxyethylene adduct of a straight chain n-alkyl phenol having about 10l4 ethenoxy units in the oxyethylene portion and about 12-14 carbons in the alkyl portion.
• Nonionic 11 defines polyethylene glycol tert. dodecyl thioether.
• Nonionic 12 defines the polyoxyethylene adduct of a polyoxypropylene hydrophobic base having a molecular weight of about 1750 wherein the oxyethylene content is about 10 weight percent of the molecule.
• Nonionic 13 defines a polyoxyalkylene polyol wherein a mixture of 1500 parts by weight of ethylene oxide and 500 parts by weight of propylene oxide is condensed with 500 parts by weight of a mixture of normal fatty alcohols having from 10 to 18 carbon atoms and, more specifically, a mixture of by weight 35 percent of a IO-carbon atom fatty alcohol, 15 percent of a 12-carbon atom fatty alcohol, 15 percent of a 16-carbon atom fatty alcohol, and 35 percent of an l8-carbon atom fatty alcohol.
• Nonionic 14 defines a polyoxyalkylene polyol wherein 788 parts by weight of commercial lauryl alcohol is sequentially condensed with 1056 parts by weight of ethylene oxide and 696 parts by weight of propylene oxide.
• Nonionic 15 defines a heteric conjugated polyoxyalkylene polyol wherein a mixture of 252 parts by weight of propylene oxide and 108 parts by weight of ethylene oxide is condensed with 600 parts by weight of a mixture of normal fatty alcohols having from 12 to 18 carbon atoms and, more specifically, a mixture of by weight 40 percent of a 12-carbon atom fatty alcohol, 30 percent of a 14-carbon atom fatty alcohol, 20 percent of a 16-carbon atom fatty alcohol, and 10 percent of an 18-carbon atom fatty alcohol to provide a hydrophobic base.
• a mixture of 1008 parts by weight ethylene oxide and 432 parts by weight propylene oxide is subsequently condensed with the hydrophobic base.
• the stearyl acid phosphate is the same as that employed in Example 1.
• the oleyl acid phosphate is a mixture of equimolar amounts of monooleyl acid phosphate and dioleyl acid phosphate.
• Example 2 A series of 18.6-gram portions of the automatic dishwashing detergent, set forth in Example 2 as Composition B, were formulated with 0.3 gram of the nonionic surface active agent set forth in Example 2 as Nonionic 2 and 0.1 gram of a lower alkyl phosphate ester indicated in Table 4 below. These formulations were evaluated for foam characteristics in the presence of egg soil in accordance with the procedure outlined in Example 1 at a water temperature of 140 F.
• composition which, when formulated with an automatic dishwashing detergent, will substantially reduce foam formation during use thereof as is more particularly described herein.
• a composition adapted to be formulated with automatic dishwashing detergents for reducing foam during use thereof in the presence of proteinaceous matter comprising:
• nonionic surface active component selected, from the group consisting of polyoxyethylene condensates of alkyl phenols having from about '6 to 20 carbon atoms in the alkyl portion, the benzyl ethers of said polyoxyethylene condensates of alkyl phenols, cogeneric mixtures of conjugated polyoxyalkylene compounds containing in their structure the residue of an active hydrogen-containing compound and at least one hydrophobic chain of units selected from the group consisting of oxypropylene and oxypropylene-oxyethylene units in which the oxygen/ carbon atom ratio does not exceed 0.40 and at least one hydrophilic chain of units selected from the group consisting of oxyethylene and oxyethylene-oxypropylene units in which the oxygen/carbon atom ratio is greater than 0.40,
• polyoxyethylene esters of higher fatty acids having from about 8 to 22 carbon atoms in the acyl group polyoxyethylene condensates of higher fatty amines having from about -8 to 22 carbon atoms in the fatty alkyl group, polyoxyethylene condensates of higher fatty amides having from about 8 to 22 carbon atoms in the fatty acyl group, and alkylene oxide adducts of higher aliphatic compounds selected from the group consisting of alcohols and thioalcohols having from about 8 to 22 carbon atoms in the aliphatic portion, and about 0.1 to 50.0 weight percent alkyl phosphate ester component selected from the group consisting of stearyl acid phosphate and oley'l acid phosphate.
• composition in accordance with claim 1 wherein said surface active component is the polyoxyethylene condensate of an alkyl phenol having from about 6 to 20 carbon atoms in the alkyl portion.
• composition in accordance with claim 1 wherein said surface active component is the benzyl ether of a polyoxyethylene condensate of an allkyl phenol having from about 6 to 20 carbon atoms in the alkyl portion.
• composition in accordance with claim 1 wherein said surface active component is a cogeneric mixture of conjugated polyoxyal'kylene compounds containing in their structure at least one hydrophobic oxypropylene chain in which the oxygen/carbon atom ratio does not exceed 0.40 and at least one hydrophilic oxyethylene chain in which the oxygen/carbon atom ratio is greater than 0.40.
• composition in accordance with claim 1 wherein said surface active component is a polyoxyethylene ester of a higher fatty acid having from about 8 to 22 carbon atoms in the acyl group.
• composition in accordance with claim 1 wherein said surface active component is the ethylene oxide adduct of a higher aliphatic alcohol having from about 8 to 22 carbon atoms in the aliphatic portion.
• alkyl phosphate ester component consists essentially of up to about 50 mole percent dialkyl phosphate, up to about 5 weight percent trialkyl phosphate, balance monoalkyl phosphate.
• a low-foaming, automatic dishwashing detergent characterized by low foaming in the presence of proteinaceous matter, comprising:
• Composition A containing 20 to percent of an alkaline detergent salt selected from the group consisting of sodium carbonate, sodium bicarbonate, modified soda, disodinm orthophosphate, trisodium orthophosphate, sodium metasilicate, sodium sesqui- 11 silicate, waterglass, borax, sodium borate, and mixtures thereof, and to 80 weight percent of an alkaline condensed phosphate salt selected from the group consisting of tetrasodium pyrophosphate and those polyphosphates of the calcium and magnesium ion sequestering type whose Na O/P O ratios range from 1:1 to 1.67:1, and about 0.1 to 20 weight percent of Composition B containing about 50.0 to 99.9 weight percent nonionic surface active component, selected from the group consisting of polyoxyethylene condensates of alkyl phenols having from about 6 to 20 carbon atoms in the alkyl portion, the benzyl ethers of said polyoxyethylene condensates of alkyl phenols, cogene
• nonionic surface active component is a mixture of 90 weight percent of polyexythylene-polyoxypropylene-polyoxyethylene polyol wherein the average molecular weight of the polyoxypropylene base is about 1750 and the polyoxyethylene content of the molecule is about 25 weight percent and 10 weight percent of a polyoxyethylene polyoxypropylene polyoxyethylene polyol wherein the molecular weight of the oxypropylene base is about 1750 and the polyoxyethylene content of the molecule is about 10 weight percent.
• composition of claim 8 wherein said alkyl phosphate ester component consists essentially of up to about mole percent dialkyl phosphate, up to about 5 weight percent trialkyl phosphate, balance monoalkyl phosphate.
• composition of claim 7 wherein said alkyl phosphate ester is stearyl acid phosphate, at least 50 mole percent of which is monostearyl acid phosphate.
• composition of claim 7 wherein said alkyl phosphate ester is oleyl acid phosphate.
• composition of claim 1 1 wherein said alkyl phosphate ester is. stearyl acid phosphate, at least 50 mole percent of which is monostearyl acid phosphate.

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Citations (9)

• 0
  • CA CA789509A patent/CA789509A/en not_active Expired
• 1965
  • 1965-11-12 US US507561A patent/US3314891A/en not_active Expired - Lifetime
• 1966
  • 1966-10-21 GB GB47393/66A patent/GB1126888A/en not_active Expired
  • 1966-11-07 DE DE1617239A patent/DE1617239B2/de active Pending
  • 1966-11-10 FR FR83334A patent/FR1499000A/fr not_active Expired
  • 1966-11-11 NL NL6615978A patent/NL6615978A/xx unknown
  • 1966-11-11 LU LU52349D patent/LU52349A1/xx unknown
  • 1966-11-14 BE BE689666D patent/BE689666A/xx not_active IP Right Cessation

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