US3220869A - Process for improving textile fabrics - Google Patents

Process for improving textile fabrics Download PDF

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Publication number
US3220869A
US3220869A US6954060A US3220869A US 3220869 A US3220869 A US 3220869A US 6954060 A US6954060 A US 6954060A US 3220869 A US3220869 A US 3220869A
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US
United States
Prior art keywords
parts
fabric
aqueous
copolymer
impregnated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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English (en)
Inventor
Ruemens Wilhelm
Goetz Norbert
Zeidler Rolf
Tulo Herbert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of US3220869A publication Critical patent/US3220869A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D06M15/29—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing a N-methylol group or an etherified N-methylol group; containing a N-aminomethylene group; containing a N-sulfidomethylene group
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/08—Decorating textiles by fixation of mechanical effects, e.g. calendering, embossing or Chintz effects, using chemical means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
    • Y10T442/2393—Coating or impregnation provides crease-resistance or wash and wear characteristics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/273—Coating or impregnation provides wear or abrasion resistance

Definitions

  • R; and R are, for example, H, alkyl (for example, with 1 to 18 and especially 1 to 4 carbon atoms), C H or CN, or R and R together may be a divalent radical such as in which R may be H or an alkyl radical of the abovementioned kind, and X is in general :0, 8 or :NH, are especially suitable.
  • R; and R are, for example, H, alkyl (for example, with 1 to 18 and especially 1 to 4 carbon atoms), C H or CN, or R and R together may be a divalent radical such as in which R may be H or an alkyl radical of the abovementioned kind, and X is in general :0, 8 or :NH, are especially suitable.
  • R and R are, for example, H, alkyl (for example, with 1 to 18 and especially 1 to 4 carbon atoms), C H or CN, or R and R together may be a divalent radical such as in which R may be H or an alkyl radical of
  • mixtures of the above mentioned kind in which the copolymer has been prepared from 1 to 25% of an N-methylolamide of an acrylic acid and 99 to 75% of one or more copolymerizable compounds are eminently suitable for imparting to a fabric the properties required for the production of mechanical effects, the mechanical effects being produced by subjecting a fabric impregnated with said aqueous mixture, preferably after drying, to a mechanical treatment at an elevated temperature and heating the fabric thus treated again to a high temperature.
  • the values measured for fabric 13 are obtained by the use of 20 parts of tetramethylolacetone, 20 parts of dimethylolisobutyltriazinone, 40 parts of dimethylolethyleneurea and 15 parts of zinc nitrate in 1000 parts of water.
  • the aqueous bath contained, in 1000 parts, 150 parts of a 70% aqueous crystal pulp of equal parts of monomethylolurea and dimethylolurea and 3 parts of monoammonium phosphate.
  • Each formulanon w1ll 70 contain one agent I, one agent II, one dispersing agent product of iso-octylphenol with ethylene oxide and 5 parts of ammonium nitrate.
  • the fabric thus impregnated is dried at 100 C. until it has a residual moisture content of about 12%. It is then embossed at 180 C. by applying a pressure of about 15 metric tons, and finally heated for 5 minutes at C.
  • Agent Ila.60 parts of a 40% aqueous dispersion of a copolymer derived from:
  • Dispersion agent IlI.-2 to 5 parts of a reaction product of iso-octylphenol or a fatty acid monoethanol amide with ethylene oxide.
  • a process for improving a textile fabric which contains at least 25% by weight of cellulose fibers comprising treating said textile fabric with an aqueous liquor which contains:

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US6954060 1959-03-13 1960-11-16 Process for improving textile fabrics Expired - Lifetime US3220869A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEB52466A DE1110606B (de) 1959-03-13 1959-03-13 Verfahren zum Veredeln von Textilgeweben
DEB55580A DE1128397B (de) 1959-03-13 1959-11-18 Verfahren zum Veredeln von Textilgeweben

Publications (1)

Publication Number Publication Date
US3220869A true US3220869A (en) 1965-11-30

Family

ID=25965350

Family Applications (1)

Application Number Title Priority Date Filing Date
US6954060 Expired - Lifetime US3220869A (en) 1959-03-13 1960-11-16 Process for improving textile fabrics

Country Status (7)

Country Link
US (1) US3220869A (no)
BE (1) BE588503A (no)
CH (2) CH388244A (no)
DE (2) DE1110606B (no)
GB (2) GB882743A (no)
NL (3) NL249327A (no)
SE (1) SE310481B (no)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3322569A (en) * 1962-11-10 1967-05-30 Basf Ag Treatment of cellulosic textiles with a crease resisting finish and a copolymer of a n-methylolamide of an acrylic acid for the purpose of reducing wet soiling
US3420702A (en) * 1965-05-11 1969-01-07 Dan River Mills Inc Double bath treatment of cellulosic fabrics to impart crease resistance and high abrasion resistance thereto
US3448462A (en) * 1964-09-14 1969-06-10 Deering Milliken Res Corp Collar and cuff-like garment member and method of making it
US3516781A (en) * 1967-02-13 1970-06-23 Stevens & Co Inc J P Novel modifying process
US3519459A (en) * 1964-09-23 1970-07-07 Ciba Ltd Process for producing finely porous coatings
US3632419A (en) * 1967-11-15 1972-01-04 Fukui Seiren Kako Co Ltd Method for imparting durable soil-resistant finish to polyamide and polyester fabrics and the treated fabrics
US3731411A (en) * 1971-06-11 1973-05-08 Burlington Industries Inc Process for producing durable press textiles
US3807952A (en) * 1971-10-08 1974-04-30 Raduner & Co Ag Method of crosslinking cellulosic fibres
US3949108A (en) * 1973-06-01 1976-04-06 The United States Of America As Represented By The Secretary Of Agriculture Process for producing fire resistant organic textile materials
JPS6053551A (ja) * 1983-08-06 1985-03-27 ヘキスト・アクチエンゲゼルシヤフト 架橋性重合体を基礎とするホルムアルデヒド不含の合成樹脂水性分散物、その製造方法およびその用途
EP0206588A1 (en) * 1985-06-04 1986-12-30 Sumitomo Chemical Company, Limited Copolymer binder composition and fabrics and papers treated therewith
CN106049101A (zh) * 2016-06-12 2016-10-26 青岛大学 一种海藻无纺布常温快速浸染及增强防紫外线性能的方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1351590A (fr) * 1962-12-28 1964-02-07 Nobel Bozel Produits de condensation de l'acrylamide avec l'acétylène-mono-uréine
GB1054682A (no) * 1963-04-13 1900-01-01
CH1357464D (no) * 1964-09-21 1900-01-01
DE1594914B1 (de) * 1966-10-06 1970-06-04 Basf Ag Verfahren zum Veredeln von Cellulose enthaltendem oder daraus bestehendem Fasergut
DE3443327C1 (de) * 1984-11-28 1985-09-05 Rosorius, Gerhard, 2085 Quickborn Verfahren zur Verbesserung der Eigenschaften von Textilien,die aus nativen pflanzlichen oder tierischen Fasern bestehen oder diese enthalten
US4927698A (en) * 1989-03-15 1990-05-22 Springs Industries, Inc. Pucker and shrink resistant flame retardant fabric formed of corespun yarns
DE4233497A1 (de) * 1992-10-06 1994-04-07 Basf Ag Verwendung von wäßrigen Polymerisatdispersionen als Textilhilfsmittel zur pflegeleichten Veredlung von Textilien

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2536050A (en) * 1947-11-10 1951-01-02 American Cyanamid Co Treatment of cellulosic textile materials and products thereof
US2819179A (en) * 1954-01-18 1958-01-07 American Cyanamid Co Textile finishing process
US2864093A (en) * 1954-10-20 1958-12-16 Chicopec Mfg Corp Washable garment part
US2876062A (en) * 1953-09-03 1959-03-03 Phrix Werke Ag Process of crease-proofing cellulose fibers and fabrics by applying ureaformaldehyde-glyoxal reaction products
US2950553A (en) * 1957-01-16 1960-08-30 Rohm & Haas Method of producing wrinkle resistant garments and other manufactured articles of cotton-containing fabrics
US2974432A (en) * 1956-02-20 1961-03-14 Koret Of California Press-free crease retained garments and method of manufacture thereof
US2976167A (en) * 1955-08-17 1961-03-21 Ciba Ltd Process for improving fibrous material and composition therefor
US3037963B1 (en) * 1955-02-24 1962-06-05 Reexamination certificate

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE906568C (de) * 1951-10-20 1954-03-15 Basf Ag Verfahren zur Herstellung nassfester UEberzuege, Impraegnierungen, Drucke u. dgl. auf faserigem Material
DE1014957B (de) * 1955-07-08 1957-09-05 Basf Ag Textilhilfsmittel auf Basis von wasserloeslichen Mischpolymerisaten

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2536050A (en) * 1947-11-10 1951-01-02 American Cyanamid Co Treatment of cellulosic textile materials and products thereof
US2876062A (en) * 1953-09-03 1959-03-03 Phrix Werke Ag Process of crease-proofing cellulose fibers and fabrics by applying ureaformaldehyde-glyoxal reaction products
US2819179A (en) * 1954-01-18 1958-01-07 American Cyanamid Co Textile finishing process
US2864093A (en) * 1954-10-20 1958-12-16 Chicopec Mfg Corp Washable garment part
US3037963B1 (en) * 1955-02-24 1962-06-05 Reexamination certificate
US3037963A (en) * 1955-02-24 1962-06-05 Pittsburgh Plate Glass Co Resinous materials
US2976167A (en) * 1955-08-17 1961-03-21 Ciba Ltd Process for improving fibrous material and composition therefor
US2974432A (en) * 1956-02-20 1961-03-14 Koret Of California Press-free crease retained garments and method of manufacture thereof
US2950553A (en) * 1957-01-16 1960-08-30 Rohm & Haas Method of producing wrinkle resistant garments and other manufactured articles of cotton-containing fabrics

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3322569A (en) * 1962-11-10 1967-05-30 Basf Ag Treatment of cellulosic textiles with a crease resisting finish and a copolymer of a n-methylolamide of an acrylic acid for the purpose of reducing wet soiling
US3448462A (en) * 1964-09-14 1969-06-10 Deering Milliken Res Corp Collar and cuff-like garment member and method of making it
US3519459A (en) * 1964-09-23 1970-07-07 Ciba Ltd Process for producing finely porous coatings
US3420702A (en) * 1965-05-11 1969-01-07 Dan River Mills Inc Double bath treatment of cellulosic fabrics to impart crease resistance and high abrasion resistance thereto
US3516781A (en) * 1967-02-13 1970-06-23 Stevens & Co Inc J P Novel modifying process
US3632419A (en) * 1967-11-15 1972-01-04 Fukui Seiren Kako Co Ltd Method for imparting durable soil-resistant finish to polyamide and polyester fabrics and the treated fabrics
US3731411A (en) * 1971-06-11 1973-05-08 Burlington Industries Inc Process for producing durable press textiles
US3807952A (en) * 1971-10-08 1974-04-30 Raduner & Co Ag Method of crosslinking cellulosic fibres
US3949108A (en) * 1973-06-01 1976-04-06 The United States Of America As Represented By The Secretary Of Agriculture Process for producing fire resistant organic textile materials
JPS6053551A (ja) * 1983-08-06 1985-03-27 ヘキスト・アクチエンゲゼルシヤフト 架橋性重合体を基礎とするホルムアルデヒド不含の合成樹脂水性分散物、その製造方法およびその用途
EP0143175A1 (de) * 1983-08-06 1985-06-05 Hoechst Aktiengesellschaft Formaldehydfreie wässrige Kunststoffdispersionen auf Basis eines vernetzbaren Polymerisats, Verfahren zu ihrer Herstellung und ihre Verwendung
AU568391B2 (en) * 1983-08-06 1987-12-24 Hoechst A.G. Formaldehyde-free aqueous polymer dispersion
JPH0791434B2 (ja) 1983-08-06 1995-10-04 ヘキスト・アクチェンゲゼルシャフト 架橋性重合体を基礎とするホルムアルデヒド不含の合成樹脂水性分散物およびその製造方法
EP0206588A1 (en) * 1985-06-04 1986-12-30 Sumitomo Chemical Company, Limited Copolymer binder composition and fabrics and papers treated therewith
US4847143A (en) * 1985-06-04 1989-07-11 Sumitomo Chemical Company, Limited Binder composition and nonwoven fabrics and impregnated papers using the same
CN106049101A (zh) * 2016-06-12 2016-10-26 青岛大学 一种海藻无纺布常温快速浸染及增强防紫外线性能的方法

Also Published As

Publication number Publication date
BE588503A (no) 1900-01-01
GB916698A (en) 1963-01-23
CH388244A (de) 1965-06-15
DE1110606B (de) 1961-07-13
NL257973A (no) 1900-01-01
CH1180060A4 (no) 1965-10-15
SE310481B (no) 1969-05-05
GB882743A (en) 1961-11-22
DE1128397B (de) 1962-04-26
NL249327A (no) 1900-01-01
NL128429C (no) 1900-01-01
CH407939A (de) 1966-09-15
CH231360A4 (no) 1964-08-31

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